This article describes the application of technology for quenching catalytic pyrolysis gas at the Daqing commercial CPP test unit and the Shenyang commercial CPP production unit.On the basis of results for application...This article describes the application of technology for quenching catalytic pyrolysis gas at the Daqing commercial CPP test unit and the Shenyang commercial CPP production unit.On the basis of results for application of the Shenyang CPP unit this paper puts forward an improved process flow scheme for quenching the pyrolysis gas and made calculations using the process flowsheet software.Case Ⅰ of the process flow scheme,which is designed for full circulation of slurry,intends to use the pyrolysis light oil and fresh feed oil as the quenching media with the product slurry oil and fresh feedstock being discharged from the quench cooler bottom and routed directly to the reactor so that the fresh feed oil can be preheated prior to pyrolysis.Case Ⅱ of the process flow scheme intends to adopt recycle oil as the quenching medium with the product slurry and recycle oil being discharged from the quench cooler bottom to the fractionator,which then delivers the slurry from the bottom.These two cases for improving the process flow diagram can all effectively control the density and viscosity of the quenching medium to secure the smooth operation of quench cooler.展开更多
In this paper, multi-refinery using the same heavy crude oils as raw materials is studied, while a new nonlinear model for mixed heavy crude distillation is proposed. In practical crude distillation operation, the dis...In this paper, multi-refinery using the same heavy crude oils as raw materials is studied, while a new nonlinear model for mixed heavy crude distillation is proposed. In practical crude distillation operation, the distillate yield and product distribution of distillation units are different due to their various equipment and operating parameters, even the same ratio of raw materials is provided, so different process models for multi-refinery planning is therefore required. For process modeling, the relationships between total yields and mixing ratio of different refineries were determined, which is combined with process simulation using production data. Then,the yields and properties of crude distillation unit(CDU) fractions were calculated with the use of true boiling point(TBP) curves and property curves respectively when the initial cutting temperatures were given. Finally,in order to maximize the economic benefit of distillation, the optimal product distribution and the best mixing ratio of crude oil were calculated under the constraints of different properties of fractions. Comparing to previous models, the proposed model takes the influence of different refinery parameters on production process into account, while avoiding the complex process for determining the cutting points, which is considered more efficient and more accurate with respect to heavy crude refinery. Model was successfully verified by a case study,allowing a significant improvement of the refinery profit to be achieved.展开更多
A FCC mechanism model was used to predict the effects of propylene promoter in a 3.0 Mt/a FCCU. The FCC mechanism model was developed based on one set of commercial FCC data without using the promoter, and was modifie...A FCC mechanism model was used to predict the effects of propylene promoter in a 3.0 Mt/a FCCU. The FCC mechanism model was developed based on one set of commercial FCC data without using the promoter, and was modified by using another set of commercial FCC data with 3m% promoter in the catalyst inventory, and the calculations by means of this simulation model were performed to predict the data of the FCC unit containing 4m% promoter in the catalyst inventory. The test results showed that the calculated values agreed well with the data obtained from the commercial FCC unit, in which the deviations of calculated product yields versus the actual product yields at the commercial FCC unit were equal to 1.74 percentage points for gasoline, 2.59 percentage points for diesel, 1.50 percentage points for dry gas and LPG, and 0.28 percentage points for coke. The proposed method regarding the development of a simulation model and modifications to the model for commercial FCC unit was feasible.展开更多
文摘This article describes the application of technology for quenching catalytic pyrolysis gas at the Daqing commercial CPP test unit and the Shenyang commercial CPP production unit.On the basis of results for application of the Shenyang CPP unit this paper puts forward an improved process flow scheme for quenching the pyrolysis gas and made calculations using the process flowsheet software.Case Ⅰ of the process flow scheme,which is designed for full circulation of slurry,intends to use the pyrolysis light oil and fresh feed oil as the quenching media with the product slurry oil and fresh feedstock being discharged from the quench cooler bottom and routed directly to the reactor so that the fresh feed oil can be preheated prior to pyrolysis.Case Ⅱ of the process flow scheme intends to adopt recycle oil as the quenching medium with the product slurry and recycle oil being discharged from the quench cooler bottom to the fractionator,which then delivers the slurry from the bottom.These two cases for improving the process flow diagram can all effectively control the density and viscosity of the quenching medium to secure the smooth operation of quench cooler.
文摘In this paper, multi-refinery using the same heavy crude oils as raw materials is studied, while a new nonlinear model for mixed heavy crude distillation is proposed. In practical crude distillation operation, the distillate yield and product distribution of distillation units are different due to their various equipment and operating parameters, even the same ratio of raw materials is provided, so different process models for multi-refinery planning is therefore required. For process modeling, the relationships between total yields and mixing ratio of different refineries were determined, which is combined with process simulation using production data. Then,the yields and properties of crude distillation unit(CDU) fractions were calculated with the use of true boiling point(TBP) curves and property curves respectively when the initial cutting temperatures were given. Finally,in order to maximize the economic benefit of distillation, the optimal product distribution and the best mixing ratio of crude oil were calculated under the constraints of different properties of fractions. Comparing to previous models, the proposed model takes the influence of different refinery parameters on production process into account, while avoiding the complex process for determining the cutting points, which is considered more efficient and more accurate with respect to heavy crude refinery. Model was successfully verified by a case study,allowing a significant improvement of the refinery profit to be achieved.
文摘A FCC mechanism model was used to predict the effects of propylene promoter in a 3.0 Mt/a FCCU. The FCC mechanism model was developed based on one set of commercial FCC data without using the promoter, and was modified by using another set of commercial FCC data with 3m% promoter in the catalyst inventory, and the calculations by means of this simulation model were performed to predict the data of the FCC unit containing 4m% promoter in the catalyst inventory. The test results showed that the calculated values agreed well with the data obtained from the commercial FCC unit, in which the deviations of calculated product yields versus the actual product yields at the commercial FCC unit were equal to 1.74 percentage points for gasoline, 2.59 percentage points for diesel, 1.50 percentage points for dry gas and LPG, and 0.28 percentage points for coke. The proposed method regarding the development of a simulation model and modifications to the model for commercial FCC unit was feasible.
