压裂后产水层的压裂前预测

针对压裂前测试不产水、压裂后地层产水;由于产水量过大,产油量比压裂前还低的井进行压后产水层的压前预测十分必要。对以往压裂前后试油资料统计分析,把压前测试曲线分为四类,可根据其中两类特征判定压后产水:一类为测试时关井压力恢复速度快,二关井压力接近于初关井压力,压力恢复及其导数双对数曲线下降,有油水边界反映;另一类为测试时初关井压力恢复速度快,二关井压力恢复不起来,压力恢复及其导数双对数曲线具有明显的均质无限大地层特征。现场实际应用证明,能准确判断压后产水情况。

聚合物基前置液可用于压裂靠近产水层段的油层

前置液技术在阿根廷和美国一些矿场的压裂处理中均已得到成功应用。此项技术可通过降低地层对水的渗透率降低水流量 ,从而可使油气产量不致大幅度降低。

插管桥塞卡堵水工艺的现场应用

常规挤灰作业对油层上部存在大段破漏的井来说,施工难度大及占井周期长。为克服上述困难,介绍了插管桥塞在大段破漏井卡堵水工艺中的应用。经研发改进,扩大了插管桥塞在卡堵水工艺中的应用范围,该工艺适用于产层上部存在大段、多段破漏或出水层的油井,且施工简单作业周期短。

A Pilot-scale Demonstration of Reverse Osmosis Unit for Treatment of Coal-bed Methane Co-produced Water and Its Modeling

This study presents the first demonstration project in China for treatment of coal-bed methane(CBM) co-produced water and recycling.The work aims to provide a research and innovation base for solving the pollution problem of CBM extraction water.The reverse osmosis(RO) unit is applied to the treatment of CBM co-produced water.The results indicate that system operation is stable,the removal efficiency of the total dissolved solids(TDS) is as high as 97.98%,and Fe,Mn,and F-are almost completely removed.There is no suspended solids(SS) detected in the treated water.Furthermore,a model for the RO membrane separation process is developed to describe the quantitative relationship between key physical quantities-membrane length,flow velocity,salt concentration,driving pressure and water recovery rate,and the water recovery restriction equation based on mass balance is developed.This model provides a theoretical support for the RO system design and optimization.The TDS in the CBM co-produced water are removed to meet the "drinking water standards" and "groundwater quality standards" of China and can be used as drinking water,irrigation water,and livestock watering.In addition,the cost for treatment of CBM co-produced water is assessed,and the RO technology is an efficient and cost-effective treatment method to remove pollutants.

Integration of 2D layered CdS/WO_(3) S-scheme heterojunctions and metallic Ti_(3)C_(2) MXene-based Ohmic junctions for effective photocatalytic H_(2) generation

The rapid recombination of photo-generated electron-hole pairs,insufficient active sites,and strong photocorrosion have considerably restricted the practical application of Cd S in photocatalytic fields.Herein,we designed and constructed a 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling interfaces.Experiments using electron spin resonance spectroscopy,ultraviolet photoelectron spectroscopy,and in-situ irradiation X-ray photoelectron spectroscopy were conducted to confirm the 2D layered CdS/WO_(3) step-scheme(S-scheme)heterojunctions and CdS/MX ohmic junctions.Impressively,it was found that the strong interfacial electric fields in the S-scheme heterojunction photocatalysts could effectively promote spatially directional charge separation and transport between CdS and WO_(3) nanosheets.In addition,2D Ti_(3)C_(2) MXene nanosheets with a smaller work function and excellent metal conductivity when used as a co-catalyst could build ohmic junctions with Cd S nanosheets,thus providing a greater number of electron transfer pathways and hydrogen evolution sites.Results showed that the highest visible-light hydrogen evolution rate of the optimized MX-Cd S/WO_(3) layered multi-heterostructures could reach as high as 27.5 mmol/g/h,which was 11.0 times higher than that of pure CdS nanosheets.Notably,the apparent quantum efficiency reached 12.0% at 450 nm.It is hoped that this study offers a reliable approach for developing multifunctional photocatalysts by integrating S-scheme and ohmic-junction built-in electric fields and rationally designing a 2D/2D interface for efficient light-to-hydrogen fuel production.

Tribological behavior of Cu-15Ni-8Sn/graphite under sea water, distilled water and dry-sliding conditions

The tribological behaviors of Cu-15Ni-8Sn/graphite composites with the graphite content of 38 vol.%against AISI321 stainless steel under dry-sliding,deionized water and sea water were investigated on a block-on-ring configuration.The results indicated that the friction coefficient was the lowest under dry-sliding,and the highest in deionized water.The wear rate decreased to reach the minimum value of 1.39×10-15 m3/(N·m)in sea water and in deionized water,it increased to the maximum value of 5.56×10-15 m3/(N·m).The deionized water hindered the formation of tribo-oxide layer and lubricating film,which resulted in the largest friction coefficient and wear rate.In sea water,however,the corrosion products comprised of oxides,hydroxides and chlorides were found on the worn surface,and the compacted layer composed of corrosion products and graphite played an important role in keeping the excellent wear resistance.It was elucidated that the tribological behaviors of Cu-15Ni-8Sn/graphite composite were powerful influenced by the friction environments.

Layered farming for Marsupenaeus japonicus Bate

Marsupenaeusjaponicus Bate is one of the most valuable cultured shrimp species in China and outdoor earthen pond farming is the most common method of culturing this organism. The need to increase soil usage efficiency in aquaculture has been recognized and a great deal of research effort has been directed toward development of super-intensive farming systems. However, current research and development in this field is largely devoted to Litopenaeus vannamei Boone, while to M.japonicus Bate it has been neglected. In this study, a layered fanning system was designed and a 66-day study was conducted in M.japonicus Bate culture. The system comprised bracket and sand layers that divided a shrimp tank filled to a depth of 1.2 m into four water layers. Conventional tank culture （unlayered） was used as a control. The results show that survival rate, feed conversion efficiency and production of M.japonicus Bate in the layered farming system were 68%, 18%, and 0.59 kg/m^2, respectively, all of which are significantly higher than in the unlayered fanning system （P〈0.01）. These findings confirmed the possibility of using a layered system to culture M. japonicus Bate.

Research on forced gas draining from coal seams by surface well drilling

Surface drilling was performed at the Luling Coal Mine,in Huaibei,to shorten the period required for gas draining.The experimental study was designed to reduce the cost of gas control by efficiently draining gas from the upper protected layer.The structural arraignment and technical principles of pressure relief via surface drilling are discussed.Results from the trial showed that gas drained from the surface system over a period of 10 months.The total amount of collected gas was 248.4 million m^3.The gas draining occurred in three stages：a growth period;a period of maximum gas production;and an attenuation period.The period of maximum gas production lasted for 4 months.During this time the methane concentration ranged from 60%to 90%and the average draining rate was 10.6 m^3/min.Combined with other methods of draining it was possible to drain 70.6%of the gas from middle coal seam groups.The amount of residual gas dropped to 5.2 m^3/ton,and the pressure of the residual gas fell to 0.53 MPa, thereby eliminating the outburst danger in the middle coal seam groups.The factors affecting pressure relief gas draining by surface drilling were analysed.

Productivity of coalbed methane wells in southern of Qinshui Basin

Based on regional CBM geological characteristics and drainage data of three typical Coalbed Methane(CBM) wells in the southern Qinshui Basin,history matching,productivity prediction and factor analysis of gas production control are conducted by using COMET3 reservoir modeling software.The results show that in the next 20 years,the cumulative and average daily gas production of the QN01 well are expected to be 800×104 m3 and 1141.1 m3/d,for the QN02 well 878×104 m3 and 1202.7 m3/d and 97.5×104 m3 and 133.55 m3/d for the QN03 well.Gas content and reservoir pressure are the key factors controlling gas production in the area;coal thickness,permeability and porosity are less important;the Langmuir volume,Langmuir pressure and adsorption time have relatively small effect.In the process of CBM recovery,the material source and driving force are the key features affecting gas productivity,while the permeation process is relatively important and the desorption process has some impact on gas recovery.