This paper analyzes the entropy generation rate of simple pure droplet combustion in a tempera-ture-elevated air convective environment based on the solutions of flow, and heat and mass transfer between the two phases...This paper analyzes the entropy generation rate of simple pure droplet combustion in a tempera-ture-elevated air convective environment based on the solutions of flow, and heat and mass transfer between the two phases. The flow-field calculations are carried out by solving the respective conservation equations for each phase, accounting for the droplet deformation with the axisymmetric model. The effects of the temperature, velocity and oxygen fraction of the free stream air on the total entropy generation rate in the process of the droplet combustion are investigated. Special attention is given to analyze the quantitative effects of droplet deformation. The results re-veal that the entropy generation rate due to chemical reaction occupies a large fraction of the total entropy generated, as a result of the large areas covered by the flame. Although, the magnitude of the entropy generation rate per volume due to heat transfer and combined mass and heat transfer has a magnitude of one order greater than that due to chemical reaction, they cover a very limited area, leading to a small fraction of the total entropy generated. The en-tropy generation rate due to mass transfer is negligible. High temperature and high velocity of the free stream are advantageous to increase the exergy efficiency in the range of small Reynolds number (<1) from the viewpoint of the second-law analysis over the droplet lifetime. The effect of droplet deformation on the total entropy generation is the modest.展开更多
Palladium(Pd)‐based catalysts are essential to drive high‐performance Suzuki coupling reactions,which are powerful tools for the synthesis of functional organic compounds.Herein,we developed a solution‐rapid‐annea...Palladium(Pd)‐based catalysts are essential to drive high‐performance Suzuki coupling reactions,which are powerful tools for the synthesis of functional organic compounds.Herein,we developed a solution‐rapid‐annealing process to stabilize nitrogen‐mesoporous carbon supported Pd single‐atom/cluster(Pd/NMC)material,which provided a catalyst with superior performance for Suzuki coupling reactions.In comparison with commercial palladium/carbon(Pd/C)catalysts,the Pd/NMC catalyst exhibited significantly boosted activity(100%selectivity and 95%yield)and excellent stability(almost no decay in activity after 10 reuse cycles)for the Suzuki coupling reactions of chlorobenzenes,together with superior yield and excellent selectivity in the fields of the board scope of the reactants.Moreover,our newly developed rapid annealing process of precursor solutions is applied as a generalized method to stabilize metal clusters(e.g.Pd,Pt,Ru),opening new possibilities in the construction of efficient highly dispersed metal atom and sub‐nanometer cluster catalysts with high performance.展开更多
This article introduces the specifics of the MIP technology involving respectively the case for production of clean gasoline, the case for producing clean gasoline coupled with production of diesel and the case for pr...This article introduces the specifics of the MIP technology involving respectively the case for production of clean gasoline, the case for producing clean gasoline coupled with production of diesel and the case for producing gasoline with increased output of propylene. The performance of the MIP units that were in operation was wrapped up. Test results have shown that the MIP technology is characterized by improved product distribution as evidenced by the reduced yields of dry gas and slurry and the increased total liquid yield; the upgraded product quality as evidenced by the reduced olefin and sulphur contents in gasoline; and the more ideal techno-economic indicators as evidenced by the reduced unit consumption of catalyst and the reduced energy consumption of the process unit.展开更多
Phosphorus （P） and metal （M） components were incorporated into promoters for enhancing FCC propylene yield, and the reactive behavior of promoters, before and after modification, were investigated. The results sho...Phosphorus （P） and metal （M） components were incorporated into promoters for enhancing FCC propylene yield, and the reactive behavior of promoters, before and after modification, were investigated. The results showed that both LPG and propylene yields were increased, and propylene selectivity was improved after the incorporation of P or M into the matrix, resulting in an increased C3 to C4 ratio in LPG during FCC process. But the sole incorporation of M into the matrix also led to an increase in coke and H2 yields on the other hand. Simultaneous modification of the matrix by P and M components resulted in more enhancement in propylene yield and selectivity along with little influence on FCC product distribution. Physico-chemical characterizations and model compound reactions were used to assist in analyzing the mechanism for improving propylene selectivity. Two types of active centers could strengthen the oligomerization of C4 olefins in LPG and these oligomers could be further cracked into C3 olefins on ZSM-5 zeolite, therefore maximizing the ratio of C3 to C4 in liquefied petroleum gas obtained during FCC process.展开更多
In this paper, a novel system using direct contact heat transfer between air and water solution was proposed to generate ice slurry. The heat transfer process and the system performance were studied; energy efficiency...In this paper, a novel system using direct contact heat transfer between air and water solution was proposed to generate ice slurry. The heat transfer process and the system performance were studied; energy efficiency coefficients of 0.038, 0.053, and 0.064 were obtained using different solutions. An empirical relationship between the volumetric heat transfer coefficient U v and the main parameters was obtained by fitting the experimental data. The U v calculated from the empirical formula agreed with the experimental U v quite well with a relative error of less than 15%. Based on the empirical formula, a laboratory-scale direct contact ice slurry generator was then constructed, with practical application in mind. If the air flow rate is fixed at 200 m 3 /h, the ice production rate will be 0.091 kg/min. The experimental results also showed that the cold energy consumption of the air compressor accounted for more than half of the total amount. To improve the system energy efficiency coefficient, it is necessary to increase the air pipes insulation and the solution's thermal capacity, and also it is appropriate to utilize the free cold energy of liquefied natural gas (LNG).展开更多
基金Supported by the National Natural Science Foundation of China （51276157） and the Natural Science Foundation of Zhejiang Province （LY 12E060026）.
文摘This paper analyzes the entropy generation rate of simple pure droplet combustion in a tempera-ture-elevated air convective environment based on the solutions of flow, and heat and mass transfer between the two phases. The flow-field calculations are carried out by solving the respective conservation equations for each phase, accounting for the droplet deformation with the axisymmetric model. The effects of the temperature, velocity and oxygen fraction of the free stream air on the total entropy generation rate in the process of the droplet combustion are investigated. Special attention is given to analyze the quantitative effects of droplet deformation. The results re-veal that the entropy generation rate due to chemical reaction occupies a large fraction of the total entropy generated, as a result of the large areas covered by the flame. Although, the magnitude of the entropy generation rate per volume due to heat transfer and combined mass and heat transfer has a magnitude of one order greater than that due to chemical reaction, they cover a very limited area, leading to a small fraction of the total entropy generated. The en-tropy generation rate due to mass transfer is negligible. High temperature and high velocity of the free stream are advantageous to increase the exergy efficiency in the range of small Reynolds number (<1) from the viewpoint of the second-law analysis over the droplet lifetime. The effect of droplet deformation on the total entropy generation is the modest.
文摘Palladium(Pd)‐based catalysts are essential to drive high‐performance Suzuki coupling reactions,which are powerful tools for the synthesis of functional organic compounds.Herein,we developed a solution‐rapid‐annealing process to stabilize nitrogen‐mesoporous carbon supported Pd single‐atom/cluster(Pd/NMC)material,which provided a catalyst with superior performance for Suzuki coupling reactions.In comparison with commercial palladium/carbon(Pd/C)catalysts,the Pd/NMC catalyst exhibited significantly boosted activity(100%selectivity and 95%yield)and excellent stability(almost no decay in activity after 10 reuse cycles)for the Suzuki coupling reactions of chlorobenzenes,together with superior yield and excellent selectivity in the fields of the board scope of the reactants.Moreover,our newly developed rapid annealing process of precursor solutions is applied as a generalized method to stabilize metal clusters(e.g.Pd,Pt,Ru),opening new possibilities in the construction of efficient highly dispersed metal atom and sub‐nanometer cluster catalysts with high performance.
文摘This article introduces the specifics of the MIP technology involving respectively the case for production of clean gasoline, the case for producing clean gasoline coupled with production of diesel and the case for producing gasoline with increased output of propylene. The performance of the MIP units that were in operation was wrapped up. Test results have shown that the MIP technology is characterized by improved product distribution as evidenced by the reduced yields of dry gas and slurry and the increased total liquid yield; the upgraded product quality as evidenced by the reduced olefin and sulphur contents in gasoline; and the more ideal techno-economic indicators as evidenced by the reduced unit consumption of catalyst and the reduced energy consumption of the process unit.
文摘Phosphorus （P） and metal （M） components were incorporated into promoters for enhancing FCC propylene yield, and the reactive behavior of promoters, before and after modification, were investigated. The results showed that both LPG and propylene yields were increased, and propylene selectivity was improved after the incorporation of P or M into the matrix, resulting in an increased C3 to C4 ratio in LPG during FCC process. But the sole incorporation of M into the matrix also led to an increase in coke and H2 yields on the other hand. Simultaneous modification of the matrix by P and M components resulted in more enhancement in propylene yield and selectivity along with little influence on FCC product distribution. Physico-chemical characterizations and model compound reactions were used to assist in analyzing the mechanism for improving propylene selectivity. Two types of active centers could strengthen the oligomerization of C4 olefins in LPG and these oligomers could be further cracked into C3 olefins on ZSM-5 zeolite, therefore maximizing the ratio of C3 to C4 in liquefied petroleum gas obtained during FCC process.
基金Project (No. 51176164) supported by the National Natural Science Foundation of China
文摘In this paper, a novel system using direct contact heat transfer between air and water solution was proposed to generate ice slurry. The heat transfer process and the system performance were studied; energy efficiency coefficients of 0.038, 0.053, and 0.064 were obtained using different solutions. An empirical relationship between the volumetric heat transfer coefficient U v and the main parameters was obtained by fitting the experimental data. The U v calculated from the empirical formula agreed with the experimental U v quite well with a relative error of less than 15%. Based on the empirical formula, a laboratory-scale direct contact ice slurry generator was then constructed, with practical application in mind. If the air flow rate is fixed at 200 m 3 /h, the ice production rate will be 0.091 kg/min. The experimental results also showed that the cold energy consumption of the air compressor accounted for more than half of the total amount. To improve the system energy efficiency coefficient, it is necessary to increase the air pipes insulation and the solution's thermal capacity, and also it is appropriate to utilize the free cold energy of liquefied natural gas (LNG).
