用准经典轨线的方法对H+OBr→HO+Br反应产物的散射和产物角动量进行了研究.计算中的碰撞能为0.5、1.0、1.5、2.0 e V并且初始振转动能级为ν=0,j=0.结果显示,在四个碰撞能下的散射和产物角动量取向有不同的特点.同时从反应机理和势能面...用准经典轨线的方法对H+OBr→HO+Br反应产物的散射和产物角动量进行了研究.计算中的碰撞能为0.5、1.0、1.5、2.0 e V并且初始振转动能级为ν=0,j=0.结果显示,在四个碰撞能下的散射和产物角动量取向有不同的特点.同时从反应机理和势能面的角度分析了它们对碰撞能的影响.展开更多
The scattering and resonance reactions of ^22Mg＋p and ^22Mg＋α play crucial roles for studying deeply not only in the structure of proton-rich nuclei of ^23A1 and ^26Si but also for the interest of astrophysics. It ...The scattering and resonance reactions of ^22Mg＋p and ^22Mg＋α play crucial roles for studying deeply not only in the structure of proton-rich nuclei of ^23A1 and ^26Si but also for the interest of astrophysics. It is believed that ^22Mg nucleus is a waiting point in the αp-process of nucleosynthesis in novae. We supposed to perform direct measurement the ^22Mg＋α system in invert kinematics using radioactive ion （RI） beam. The ^22Mg beam of 3.73 MeV/u was produced at CRIB facility of the University of Tokyo located at RIKEN, Japan in 2011. In this paper, we report the results the scattering and resonance reactions with the alpha target. of the ^22Mg beam production used for the direct measurement of展开更多
Developing efficient electrocatalysts for the oxygen evolution reaction(OER)under neutral conditions is important for microbial electrolysis cells(MECs).However,the OER kinetics in neutral electrolytes at present are ...Developing efficient electrocatalysts for the oxygen evolution reaction(OER)under neutral conditions is important for microbial electrolysis cells(MECs).However,the OER kinetics in neutral electrolytes at present are extremely sluggish,resulting in high overpotentials that greatly limit the energy conversion efficiencies of MECs.Previous studies failed to probe the adsorbates on surface metal sites of catalysts at the atomic scale and elucidate their influence on the catalytic activities,which has impeded the rational design of efficient neutral OER catalysts with optimal surface structures.Here,using in situ transmission electron microscopy(TEM),in situ X-ray photoelectron spectroscopy(XPS)and in situ low-energy ion scattering studies,we have identified,for the first time,that the electrochemically activated adsorbates on surface metal sites play a critical role in boosting the neutral OER activities of Ru-Ir binary oxide(RuxIryO2)catalysts.The adsorbate-activated RuxIryO2on a glassy carbon electrode achieved a low overpotential of 324 m V at10 m A cm-2in neutral electrolyte,with a 36-fold improvement in turnover frequency compared with that of Ir O2benchmark.Upon application in an MEC system,the resulting full cell showed a decreased voltage of 1.8 V,200 m V lower than the best value reported to date,facilitating efficient synthesis of poly(3-hydroxybutyrate)from bioelectrochemical CO2reduction.Density functional theory(DFT)studies revealed that the enhanced OER activity of RuxIryO2catalyst arose from local structural distortion of adjacent adsorbate-covered Ru octahedra at the catalyst surface and the consequently decreased adsorption energies of OER intermediates on Ir active center.展开更多
文摘The scattering and resonance reactions of ^22Mg＋p and ^22Mg＋α play crucial roles for studying deeply not only in the structure of proton-rich nuclei of ^23A1 and ^26Si but also for the interest of astrophysics. It is believed that ^22Mg nucleus is a waiting point in the αp-process of nucleosynthesis in novae. We supposed to perform direct measurement the ^22Mg＋α system in invert kinematics using radioactive ion （RI） beam. The ^22Mg beam of 3.73 MeV/u was produced at CRIB facility of the University of Tokyo located at RIKEN, Japan in 2011. In this paper, we report the results the scattering and resonance reactions with the alpha target. of the ^22Mg beam production used for the direct measurement of
基金supported by the Ministry of Science and Technology(2016YFA0203302)the National Natural Science Foundation of China(21875042,21634003,51573027 and 11227902)+3 种基金Science and Technology Commission of Shanghai Municipality(16JC1400702 and 18QA1400800)Shanghai Municipal Education Commission(2017-01-07-00-07-E00062)Yanchang Petroleum Groupthe Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning。
文摘Developing efficient electrocatalysts for the oxygen evolution reaction(OER)under neutral conditions is important for microbial electrolysis cells(MECs).However,the OER kinetics in neutral electrolytes at present are extremely sluggish,resulting in high overpotentials that greatly limit the energy conversion efficiencies of MECs.Previous studies failed to probe the adsorbates on surface metal sites of catalysts at the atomic scale and elucidate their influence on the catalytic activities,which has impeded the rational design of efficient neutral OER catalysts with optimal surface structures.Here,using in situ transmission electron microscopy(TEM),in situ X-ray photoelectron spectroscopy(XPS)and in situ low-energy ion scattering studies,we have identified,for the first time,that the electrochemically activated adsorbates on surface metal sites play a critical role in boosting the neutral OER activities of Ru-Ir binary oxide(RuxIryO2)catalysts.The adsorbate-activated RuxIryO2on a glassy carbon electrode achieved a low overpotential of 324 m V at10 m A cm-2in neutral electrolyte,with a 36-fold improvement in turnover frequency compared with that of Ir O2benchmark.Upon application in an MEC system,the resulting full cell showed a decreased voltage of 1.8 V,200 m V lower than the best value reported to date,facilitating efficient synthesis of poly(3-hydroxybutyrate)from bioelectrochemical CO2reduction.Density functional theory(DFT)studies revealed that the enhanced OER activity of RuxIryO2catalyst arose from local structural distortion of adjacent adsorbate-covered Ru octahedra at the catalyst surface and the consequently decreased adsorption energies of OER intermediates on Ir active center.
