The mechanism of oxygen pressure acid leaching of sphalerite catalyzed by Fe^3+/Fe^2+self-precipitation was investigated in this study.Artificial sphalerite was fabricated with varying amounts of iron content via the ...The mechanism of oxygen pressure acid leaching of sphalerite catalyzed by Fe^3+/Fe^2+self-precipitation was investigated in this study.Artificial sphalerite was fabricated with varying amounts of iron content via the sintering of ZnS and FeS and used for the pressure acid leaching experiment.The variations in the potential of the pressure leaching system were investigated by using a self-designed potential autoclave.The results showed that compared to the non-iron sphalerite,there was a violent redox reaction between the 25.70%Fe-artificial sphalerite and dissolved oxygen during the process of pressure leaching;and the catalytic mechanism was attributed to the redox couple Fe^3+/Fe^2+,where Fe3+oxidizes the H2S gas film and the reduced Fe2+state is subsequently oxidized by the dissolved oxygen.Furthermore,the effect of temperature,H2SO4 concentration,and oxygen partial pressure on the artificial sphalerite with different iron contents was studied.The sphalerite samples with iron content were observed to dissolve more easily in sulfuric acid compared to the non-iron samples.Moreover,the activation energy of artificial sphalerite was observed to be lower in the sample with 25.70%iron content(22.26 kJ/mol)compared to that with no iron(32.31 kJ/mol);and the apparent reaction orders were obtained with respect to H2SO4 concentration(1.10 and 1.36)and oxygen partial pressure(1.29 and 1.41),respectively.A comprehensive kinetic model was developed on the basis of the experimental data and the fitted leaching ratio plot;and the kinetic equations for the leaching of sphalerite catalyzed by Fe^3+/Fe^2+self-precipitation were determined.展开更多
Radio Frequency Interference (RFI) degrades the quality of focused Ultra-WideBand Syn- thetic Aperture Radar (UWB SAR) images. From both the theoretical analysis and real data valida- tion, it is concluded that target...Radio Frequency Interference (RFI) degrades the quality of focused Ultra-WideBand Syn- thetic Aperture Radar (UWB SAR) images. From both the theoretical analysis and real data valida- tion, it is concluded that target echo and RFI have different Region Of Support (ROS) in 2-D fast- time wavenumber and aperture wavenumber domain. Consequently, a novel adaptive filter is pro- posed according to the Wiener optimum criterion on the distinct ROS characteristics of target echo and RFI. Compared with the notch filter and the Least Mean Square (LMS) adaptive filter in previ- ous literatures, the proposed method is more computationally efficient with satisfactory suppression results. In terms of Signal-to-Interference Ratio Improvement (SIRI) and processing time, the per- formance of the proposed adaptive filter is verified with the field data collected with a UWB SAR system.展开更多
In the study of the application of MODIS satellite remote sensing data to earthquake prediction, the paper puts forward for the first time a quantitative method to estimate the ratio for the pixels with abnormal brigh...In the study of the application of MODIS satellite remote sensing data to earthquake prediction, the paper puts forward for the first time a quantitative method to estimate the ratio for the pixels with abnormal brightness temperature (BT) increase and a preliminary scheme for cloud removal. The principle is that, firstly, the cloudless data observed by the same satellite at the same period of time but in different days (usually 1 day to 3 days) are mosaiced to get high ratio of clear sky, and then the BT variation curve and mean square difference (MSD) of each pixel are calculated with the data from the covered area to determine daily whether the BT data of the day is normal or not at a certain pixel by using double the MSD as the criterion. The ratio for the pixels with abnormal BT increase can be calculated by dividing the total number of abnormal pixels with the total pixels of the whole area. Analysis on a series of recent earthquakes in the Taiwan Region shows that the ratio for pixels with abnormal BT increase, which normally undulates around zero, has a sudden enhancement 1 day to 20 days before medium-strong earthquakes. It is expected that a new method for identifying earthquake auspice could be found through special studies in regions with frequent seismic activity by analyzing the change of the ratio for the pixels with abnormal BT increase from MODIS satellite remote sensing infrared (IR) information from which the effect of clouds has been removed to a certain extent.展开更多
Nowadays the flexible configuration of manufacturing cells becomes to an important requirement especially at small and medium sized companies. This method can make the production fast and effective at small series or ...Nowadays the flexible configuration of manufacturing cells becomes to an important requirement especially at small and medium sized companies. This method can make the production fast and effective at small series or frequent manufacturing changes. The shop-floor control method, presented in this paper, offers a solution for the facing problem of fast and easy reconfiguration. The hardware of the controller designed modular with software components for online configuration. This solution allows sensor integration on different levels for every part of the manufacturing cell. With unified programming language and the machine specific controllers (post-processing) the cells can be defined easily by different types of human-machine interaction. The shop-floor control architecture is implemented and validated on an Adept SCARA (selective compliance assembly robot arm) robot. The robot is driven by standalone, low-level, interchangeable, software and hardware components.展开更多
基金Projects(51804136,51764016)supported by the National Natural Science Foundation of ChinaProject(U1402271)supported by the Joint Funds of the National Natural Science Foundation of China+2 种基金Project(20181BAB216017)supported by the Jiangxi Provincial Natural Science Foundation,ChinaProject(GK-201803)supported by the Research Fund Program of State Key Laboratory of Rare Metals Separation and Comprehensive Utilization,ChinaProjects(yy2016001,yy2016012)supported by the Research Fund Program of the State Key Laboratory of Pressure Hydrometallurgical Technology of Associated Nonferrous Metal Resources,China。
文摘The mechanism of oxygen pressure acid leaching of sphalerite catalyzed by Fe^3+/Fe^2+self-precipitation was investigated in this study.Artificial sphalerite was fabricated with varying amounts of iron content via the sintering of ZnS and FeS and used for the pressure acid leaching experiment.The variations in the potential of the pressure leaching system were investigated by using a self-designed potential autoclave.The results showed that compared to the non-iron sphalerite,there was a violent redox reaction between the 25.70%Fe-artificial sphalerite and dissolved oxygen during the process of pressure leaching;and the catalytic mechanism was attributed to the redox couple Fe^3+/Fe^2+,where Fe3+oxidizes the H2S gas film and the reduced Fe2+state is subsequently oxidized by the dissolved oxygen.Furthermore,the effect of temperature,H2SO4 concentration,and oxygen partial pressure on the artificial sphalerite with different iron contents was studied.The sphalerite samples with iron content were observed to dissolve more easily in sulfuric acid compared to the non-iron samples.Moreover,the activation energy of artificial sphalerite was observed to be lower in the sample with 25.70%iron content(22.26 kJ/mol)compared to that with no iron(32.31 kJ/mol);and the apparent reaction orders were obtained with respect to H2SO4 concentration(1.10 and 1.36)and oxygen partial pressure(1.29 and 1.41),respectively.A comprehensive kinetic model was developed on the basis of the experimental data and the fitted leaching ratio plot;and the kinetic equations for the leaching of sphalerite catalyzed by Fe^3+/Fe^2+self-precipitation were determined.
文摘Radio Frequency Interference (RFI) degrades the quality of focused Ultra-WideBand Syn- thetic Aperture Radar (UWB SAR) images. From both the theoretical analysis and real data valida- tion, it is concluded that target echo and RFI have different Region Of Support (ROS) in 2-D fast- time wavenumber and aperture wavenumber domain. Consequently, a novel adaptive filter is pro- posed according to the Wiener optimum criterion on the distinct ROS characteristics of target echo and RFI. Compared with the notch filter and the Least Mean Square (LMS) adaptive filter in previ- ous literatures, the proposed method is more computationally efficient with satisfactory suppression results. In terms of Signal-to-Interference Ratio Improvement (SIRI) and processing time, the per- formance of the proposed adaptive filter is verified with the field data collected with a UWB SAR system.
基金This project was sponsored by the Science and Technology Programof Sichuan Province (05SG031-004)
文摘In the study of the application of MODIS satellite remote sensing data to earthquake prediction, the paper puts forward for the first time a quantitative method to estimate the ratio for the pixels with abnormal brightness temperature (BT) increase and a preliminary scheme for cloud removal. The principle is that, firstly, the cloudless data observed by the same satellite at the same period of time but in different days (usually 1 day to 3 days) are mosaiced to get high ratio of clear sky, and then the BT variation curve and mean square difference (MSD) of each pixel are calculated with the data from the covered area to determine daily whether the BT data of the day is normal or not at a certain pixel by using double the MSD as the criterion. The ratio for the pixels with abnormal BT increase can be calculated by dividing the total number of abnormal pixels with the total pixels of the whole area. Analysis on a series of recent earthquakes in the Taiwan Region shows that the ratio for pixels with abnormal BT increase, which normally undulates around zero, has a sudden enhancement 1 day to 20 days before medium-strong earthquakes. It is expected that a new method for identifying earthquake auspice could be found through special studies in regions with frequent seismic activity by analyzing the change of the ratio for the pixels with abnormal BT increase from MODIS satellite remote sensing infrared (IR) information from which the effect of clouds has been removed to a certain extent.
文摘Nowadays the flexible configuration of manufacturing cells becomes to an important requirement especially at small and medium sized companies. This method can make the production fast and effective at small series or frequent manufacturing changes. The shop-floor control method, presented in this paper, offers a solution for the facing problem of fast and easy reconfiguration. The hardware of the controller designed modular with software components for online configuration. This solution allows sensor integration on different levels for every part of the manufacturing cell. With unified programming language and the machine specific controllers (post-processing) the cells can be defined easily by different types of human-machine interaction. The shop-floor control architecture is implemented and validated on an Adept SCARA (selective compliance assembly robot arm) robot. The robot is driven by standalone, low-level, interchangeable, software and hardware components.