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介电弛豫光谱学及其在药学中的应用
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作者 SmithG 王晋 《国外医学(药学分册)》 1996年第4期234-236,共3页
介电弛豫光谱学(DRS)对分子运动及结构敏感,对样品无损,为了测定样品性质,仅需应用弱电磁场。该技术覆盖宽带频率窗(从10(-5)~10(11)Hz),可研究各种过程,从缓慢受阻的大分子振动,到小分子或侧链基团的相对快速重取向。... 介电弛豫光谱学(DRS)对分子运动及结构敏感,对样品无损,为了测定样品性质,仅需应用弱电磁场。该技术覆盖宽带频率窗(从10(-5)~10(11)Hz),可研究各种过程,从缓慢受阻的大分子振动,到小分子或侧链基团的相对快速重取向。介电响应可提供如下信息:聚合物、凝胶、蛋白质、乳状液的结构特性;分子膜的界面性质;膜性能;水含量及所处的状态;生物分子的冷冻干燥。本文详述介电理论的基础及测量介电性质的原理,并介绍DRS在药学领域的一些应用。 展开更多
关键词 弛豫光谱学 药学 应用
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Analytical Dielectric Spectrum Formula Based on Representative Frequencies
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作者 孔博 傅克祥 +1 位作者 单敏华 李象远 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2009年第3期262-268,339,共8页
According to experimental data available for the complex refractive index of particular dielectrics, a dielectric spectrum formula is proposed by the least square fitting technique combined with selected natural frequ... According to experimental data available for the complex refractive index of particular dielectrics, a dielectric spectrum formula is proposed by the least square fitting technique combined with selected natural frequencies. From the dielectric spectrum formula, the spectra of optical and dielectric constants can be obtained in the whole frequency region. Three dielectrics, water, ethanol, and toluene, are taken as examples. In the region where the ex- perimental data are available, the spectra of the optical constants calculated by the formula are in good agreement with the real refractive spectrum obtained by Kramers-Kronig (K-K) transform and the experimental imaginary refractive spectrum. In the region where no ex- perimental data are available, the extrapolation of our formula can make predictions. The merits of the present treatment are that we are able to get the uniform spectrum formula, without splitting into different frequency sections, and the analytical form of the dielectric spectra will be useful in the theoretical description of solvation dynamics. 展开更多
关键词 FREQUENCY Least square fitting technique Dielectric spectrum Optical constant POLARIZATION
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Dielectric properties and relaxation dynamics in PbF_2-TeO_2-B_2_O3-Eu_2O_3 glasses
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作者 Akshatha WAGH Y.RAVIPRAKASH Sudha D.KAMATH 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第8期2637-2645,共9页
Frequency and temperature dependent dielectric dispersion of 20PbF2?20TeO2?(60?x)B2O3?xEu2O3(x=0 to 2.5, mole fraction, %) glasses prepared by the melt?quenching technique were investigated in the frequency r... Frequency and temperature dependent dielectric dispersion of 20PbF2?20TeO2?(60?x)B2O3?xEu2O3(x=0 to 2.5, mole fraction, %) glasses prepared by the melt?quenching technique were investigated in the frequency range 1 Hz?10 MHz and temperature range 313?773 K. Dielectric relaxation dynamics was analyzed based on the electric modulus behavior. Dielectric losses (tanδ) are found to be negligibly small in the temperature range 313?523 K, proving good thermal stability of the glasses. The present Eu2O3-doped oxyfluroborate glasses showed low dielectric loss at higher frequency and lower temperature, proving their suitability for nonlinear optical materials. 展开更多
关键词 doped glass dielectric spectroscopy electric modulus AC conductivity activation energy Arrhenius equation
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Effects of heavy metal on dielectric properties of E. coli revealed by dielectric spectroscopy
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作者 白伟 Zhao Kongshuang 《High Technology Letters》 EI CAS 2006年第4期441-445,共5页
Dielectric spectroscopy of E. coli cell before and after exposure to heavy metals Cd^2+ , Cu^2+ , Zn^2+ and Ca^2+ was investigated. The results indicate that changes in dielectric spectra reflect effects of heavy ... Dielectric spectroscopy of E. coli cell before and after exposure to heavy metals Cd^2+ , Cu^2+ , Zn^2+ and Ca^2+ was investigated. The results indicate that changes in dielectric spectra reflect effects of heavy metal on the structure and function of E. coli cells. Heavy metal can change membrane capacitance as well as pennittivity and conductivity of the cytoplasm. Changes in volume fraction suggested that dielectric measurement could monitor the growth of E. coli cells. These results demonstrated that dielectric spectroscopy was a potential effective technique for studying electric properties of biological cells. 展开更多
关键词 E. coli dielectric spectroscopy heavy metal electric properties
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