Highly dispersed bimetallic alloy nanoparticle electrocatalysts have been demonstrated to exhibit exceptional performance in driving the nitrate reduction reaction(NO_(3)RR)to generate ammonia(NH_(3)).In this study,we...Highly dispersed bimetallic alloy nanoparticle electrocatalysts have been demonstrated to exhibit exceptional performance in driving the nitrate reduction reaction(NO_(3)RR)to generate ammonia(NH_(3)).In this study,we prepared mesoporous carbon nanofibers(mCNFs)functionalized with ordered PtFe alloys(O-PtFe-mCNFs)by a composite micelle interface-induced co-assembly method using poly(ethylene oxide)-block-polystyrene(PEO-b-PS)as a template.When employed as electrocatalysts,O-PtFe-mCNFs exhibited superior electrocatalytic performance for the NO_(3RR)compared to the mCNFs functionalized with disordered PtFe alloys(D-PtFe-mCNFs).Notably,the NH_(3)production performance was particularly outstanding,with a maximum NH_(3)yield of up to 959.6μmol/(h·cm~2).Furthermore,the Faraday efficiency(FE)was even 88.0%at-0.4 V vs.reversible hydrogen electrode(RHE).This finding provides compelling evidence of the potential of ordered PtFe alloy catalysts for the electrocatalytic NO_(3)RR.展开更多
The extraction behavior of heavy metals from municipal waste incineration （MWI） fly ash was investigated systematically. The extraction process includes two steps, namely, fly ash was firstly washed with water, and ...The extraction behavior of heavy metals from municipal waste incineration （MWI） fly ash was investigated systematically. The extraction process includes two steps, namely, fly ash was firstly washed with water, and then subjected to hydrochloric acid leaching. The main parameters for water washing process were tested, and under the optimal conditions, about 86% Na, 70% K and 12% Ca were removed from fly ash, respectively. Hydrochloric acid was used for the extraction of valuable elements from the water-washed fly ash, and the optimal extraction was achieved for each heavy metal as follows： 86% for Pb, 98% for Zn, 82% for Fe, 96% for Cd, 62% for Cu, 80% for Al, respectively. And the main compositions of the finally obtained solid residue are Ca2PbO4, CaSi2Os, PbsSiO7, Ca3A12Si3012 and SiO2.展开更多
BaTiO3/polyurethane （BaTiO3/PU） nanocomposite elastomers were prepared from barium titanate nanoparticles, polyester polyol, 2, 4-toluene diisocyanate, 1,4-butanediol and 1, 1, 1-trimethanol propane by the one-step ...BaTiO3/polyurethane （BaTiO3/PU） nanocomposite elastomers were prepared from barium titanate nanoparticles, polyester polyol, 2, 4-toluene diisocyanate, 1,4-butanediol and 1, 1, 1-trimethanol propane by the one-step method. The density, hardness and dielectric constant of BaTiO3/PU nanocomposite elastomers increased with the increase of the content of BaTiO3 nanoparticles in nanocomposites. The electrostrictive properties of BaTiO3/PU nanocomposite elastomers were investigated by the digital speckle correlation method （DSCM）. It was found that through the on-and-off of the electric field, the electrostrictive strains of BaTiO3/PU nanocomposite elastomers revealed corresponding shrinkage and recovery. The electrostrictive coefficient of BaTiO3/PU nanocomposite elastomers was greater than that of the corresponding polyurethane elastomers, and the electrostrictive coefficient of composites decreased with the increase of the content of barium titanate nanoparticles.展开更多
Taking into account three important porous media mechanisms during wave propagation （the Biot-flow, squirt-flow, and solid-skeleton viscoelastic mechanisms）, we introduce water saturation into the dynamic governing ...Taking into account three important porous media mechanisms during wave propagation （the Biot-flow, squirt-flow, and solid-skeleton viscoelastic mechanisms）, we introduce water saturation into the dynamic governing equations of wave propagation by analyzing the effective medium theory and then providing a viscoelastic Biot/squirt （BISQ） model which can analyze the wave propagation problems in a partially viscous pore fluid saturated porous media. In this model, the effects of pore fluid distribution patterns on the effective bulk modulus at different frequencies are considered. Then we derive the wave dynamic equations in the time-space domain. The phase velocity and the attenuation coefficient equations of the viscoelatic BISQ model in the frequency-wavenumber domain are deduced through a set of plane harmonic solution assumptions. Finally, by means of numerical simulations, we investigate the effects of water saturation, permeability, and frequency on compressional wave velocity and attenuation. Based on tight sandstone and carbonate experimental observed data, the compressional wave velocities of partially saturated reservoir rocks are calculated. The compressional wave velocity in carbonate reservoirs is more sensitive to gas saturation than in sandstone reservoirs.展开更多
基金National Natural Science Foundation of China(Nos.52225204,52173233 and 52202085)Innovation Program of Shanghai Municipal Education Commission,China(No.2021-01-07-00-03-E00109)+3 种基金Natural Science Foundation of Shanghai,China(No.23ZR1479200)“Shuguang Program”Supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission,China(No.20SG33)Fundamental Research Funds for the Central Universities,China(No.2232024Y-01)DHU Distinguished Young Professor Program,China(Nos.LZA2022001 and LZB2023002)。
文摘Highly dispersed bimetallic alloy nanoparticle electrocatalysts have been demonstrated to exhibit exceptional performance in driving the nitrate reduction reaction(NO_(3)RR)to generate ammonia(NH_(3)).In this study,we prepared mesoporous carbon nanofibers(mCNFs)functionalized with ordered PtFe alloys(O-PtFe-mCNFs)by a composite micelle interface-induced co-assembly method using poly(ethylene oxide)-block-polystyrene(PEO-b-PS)as a template.When employed as electrocatalysts,O-PtFe-mCNFs exhibited superior electrocatalytic performance for the NO_(3RR)compared to the mCNFs functionalized with disordered PtFe alloys(D-PtFe-mCNFs).Notably,the NH_(3)production performance was particularly outstanding,with a maximum NH_(3)yield of up to 959.6μmol/(h·cm~2).Furthermore,the Faraday efficiency(FE)was even 88.0%at-0.4 V vs.reversible hydrogen electrode(RHE).This finding provides compelling evidence of the potential of ordered PtFe alloy catalysts for the electrocatalytic NO_(3)RR.
文摘The extraction behavior of heavy metals from municipal waste incineration （MWI） fly ash was investigated systematically. The extraction process includes two steps, namely, fly ash was firstly washed with water, and then subjected to hydrochloric acid leaching. The main parameters for water washing process were tested, and under the optimal conditions, about 86% Na, 70% K and 12% Ca were removed from fly ash, respectively. Hydrochloric acid was used for the extraction of valuable elements from the water-washed fly ash, and the optimal extraction was achieved for each heavy metal as follows： 86% for Pb, 98% for Zn, 82% for Fe, 96% for Cd, 62% for Cu, 80% for Al, respectively. And the main compositions of the finally obtained solid residue are Ca2PbO4, CaSi2Os, PbsSiO7, Ca3A12Si3012 and SiO2.
文摘BaTiO3/polyurethane （BaTiO3/PU） nanocomposite elastomers were prepared from barium titanate nanoparticles, polyester polyol, 2, 4-toluene diisocyanate, 1,4-butanediol and 1, 1, 1-trimethanol propane by the one-step method. The density, hardness and dielectric constant of BaTiO3/PU nanocomposite elastomers increased with the increase of the content of BaTiO3 nanoparticles in nanocomposites. The electrostrictive properties of BaTiO3/PU nanocomposite elastomers were investigated by the digital speckle correlation method （DSCM）. It was found that through the on-and-off of the electric field, the electrostrictive strains of BaTiO3/PU nanocomposite elastomers revealed corresponding shrinkage and recovery. The electrostrictive coefficient of BaTiO3/PU nanocomposite elastomers was greater than that of the corresponding polyurethane elastomers, and the electrostrictive coefficient of composites decreased with the increase of the content of barium titanate nanoparticles.
基金supported by the National Natural Science Foundation of China (No. 11002025, 40114066)the National Basic Research Program of China (973 Program) (No.2007CB209505)the RIPED Youth Innovation Foundation (No. 2010-A-26-01)
文摘Taking into account three important porous media mechanisms during wave propagation （the Biot-flow, squirt-flow, and solid-skeleton viscoelastic mechanisms）, we introduce water saturation into the dynamic governing equations of wave propagation by analyzing the effective medium theory and then providing a viscoelastic Biot/squirt （BISQ） model which can analyze the wave propagation problems in a partially viscous pore fluid saturated porous media. In this model, the effects of pore fluid distribution patterns on the effective bulk modulus at different frequencies are considered. Then we derive the wave dynamic equations in the time-space domain. The phase velocity and the attenuation coefficient equations of the viscoelatic BISQ model in the frequency-wavenumber domain are deduced through a set of plane harmonic solution assumptions. Finally, by means of numerical simulations, we investigate the effects of water saturation, permeability, and frequency on compressional wave velocity and attenuation. Based on tight sandstone and carbonate experimental observed data, the compressional wave velocities of partially saturated reservoir rocks are calculated. The compressional wave velocity in carbonate reservoirs is more sensitive to gas saturation than in sandstone reservoirs.
