A straightforward protocol using readily available aromatic amines,N,N,N',N'-tetramethyl-p-phenylenediamine or N,N,N',N'-tetramethylbenzidine,as photocatalysts was developed for theefficient hydrodehal...A straightforward protocol using readily available aromatic amines,N,N,N',N'-tetramethyl-p-phenylenediamine or N,N,N',N'-tetramethylbenzidine,as photocatalysts was developed for theefficient hydrodehalogenation of organic halides,such as 4'-bromoacetophenone,polyfluoroarenes,cholorobenzene,and 2,2',4,4'-tetrabromodiphenyl ether(a resistant and persistent organic pollu-tant).The strongly reducing singlet excited states of the amines enabled diffusion-controlled disso-ciative electron transfer to effectively cleave carbon-halogen bonds,followed by radical hydrogena-tion.Diisopropylethylamine served as the terminal electron/proton donor and regenerated theamine sensitizers.展开更多
Exciplex-emitters are attractive due to their distinct feature of easily achieving small singlet-triplet energy splitting for thermally activated delayed fluorescence(TADF),but face with challenges in convenient desig...Exciplex-emitters are attractive due to their distinct feature of easily achieving small singlet-triplet energy splitting for thermally activated delayed fluorescence(TADF),but face with challenges in convenient design of electron acceptors.New 9-phenylfluorene-based acceptor 9-[6-(2-cyano-7-isocyano-9-phenyl-9H-fluoren-9-yl)-9-ethyl-9H-carbazol-3-yl]-9-phenyl-9H-fluorene-2,7-dicarbonitrile(TriCNDPFCz)was designed and synthesized through tricyano-substitution.By mixing TriCNDPFCz with conventional donor 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane(TAPC),bright exciplex-TADF was obtained with a maximum current efficiency of 46.7 cd·A^(-1),power efficiency of 52.3 lm·W^(-1)and external quantum efficiency of 14.5%.The experimental characterizations indicate that tricyano-substitution in 9-phenylfluorene skeleton can form strong electron-accepting ability,which is useful and convenient for constructing electron acceptor in exciplex emission.展开更多
Objective： To study whether the range of knee flexion （ROF） is affected by geometrical mismatch of the femoral component and the resultant change in the pos- terior condylar offset （PCO） after high-flexion poster...Objective： To study whether the range of knee flexion （ROF） is affected by geometrical mismatch of the femoral component and the resultant change in the pos- terior condylar offset （PCO） after high-flexion posterior-sta- bilized total knee arthroplasty （TKA）. Methods： One hundred osteoarthritic patients （50 males and 50 females） underwent femoral osteotomy by the ante- rior referencing technique. The PCO for each patient was measured from lateral radiographs before, during and 2 years after TKA. The thickness of the joint cartilage was mea- sured by magnetic resonance imaging before TKA and added onto the radiographic measurement. The relationship between changes in the PCO and improvements in the ROF before, during and 2 years after TKA were statistically analyzed. Results： Compared with the preoperative value, the PCO was reduced by （3.45±3.28） mm after TKA, with a significantly larger reduction observed in female patients than male patients （P〈0.05）. When examining the subject popu- lation as a whole, there was a significant positive correla- tion between PCO and ROF improvement during TKA （P〈 0.05）, but this improvement was not maintained 2 years after TKA （P〉0.05）. However, when male and female patients were analyzed separately, there was a significant positive correlation between PCO change and ROF improvement for both sexes at both time points （all P〈0.05）. Conclusions： Restoration of PCO plays an important role in the optimization of knee flexion even after posteriorstabilized TKA. Femoral components based on Caucasian anatomic characteristics could not match the native anatomy of distal femurs in Chinese population especially female Chinese. Rotated resection of distal femur with anterior referencing technique usually leads to a decreased PCO and therefore reduces maximal obtainable flexion.展开更多
文摘A straightforward protocol using readily available aromatic amines,N,N,N',N'-tetramethyl-p-phenylenediamine or N,N,N',N'-tetramethylbenzidine,as photocatalysts was developed for theefficient hydrodehalogenation of organic halides,such as 4'-bromoacetophenone,polyfluoroarenes,cholorobenzene,and 2,2',4,4'-tetrabromodiphenyl ether(a resistant and persistent organic pollu-tant).The strongly reducing singlet excited states of the amines enabled diffusion-controlled disso-ciative electron transfer to effectively cleave carbon-halogen bonds,followed by radical hydrogena-tion.Diisopropylethylamine served as the terminal electron/proton donor and regenerated theamine sensitizers.
文摘Exciplex-emitters are attractive due to their distinct feature of easily achieving small singlet-triplet energy splitting for thermally activated delayed fluorescence(TADF),but face with challenges in convenient design of electron acceptors.New 9-phenylfluorene-based acceptor 9-[6-(2-cyano-7-isocyano-9-phenyl-9H-fluoren-9-yl)-9-ethyl-9H-carbazol-3-yl]-9-phenyl-9H-fluorene-2,7-dicarbonitrile(TriCNDPFCz)was designed and synthesized through tricyano-substitution.By mixing TriCNDPFCz with conventional donor 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane(TAPC),bright exciplex-TADF was obtained with a maximum current efficiency of 46.7 cd·A^(-1),power efficiency of 52.3 lm·W^(-1)and external quantum efficiency of 14.5%.The experimental characterizations indicate that tricyano-substitution in 9-phenylfluorene skeleton can form strong electron-accepting ability,which is useful and convenient for constructing electron acceptor in exciplex emission.
文摘Objective： To study whether the range of knee flexion （ROF） is affected by geometrical mismatch of the femoral component and the resultant change in the pos- terior condylar offset （PCO） after high-flexion posterior-sta- bilized total knee arthroplasty （TKA）. Methods： One hundred osteoarthritic patients （50 males and 50 females） underwent femoral osteotomy by the ante- rior referencing technique. The PCO for each patient was measured from lateral radiographs before, during and 2 years after TKA. The thickness of the joint cartilage was mea- sured by magnetic resonance imaging before TKA and added onto the radiographic measurement. The relationship between changes in the PCO and improvements in the ROF before, during and 2 years after TKA were statistically analyzed. Results： Compared with the preoperative value, the PCO was reduced by （3.45±3.28） mm after TKA, with a significantly larger reduction observed in female patients than male patients （P〈0.05）. When examining the subject popu- lation as a whole, there was a significant positive correla- tion between PCO and ROF improvement during TKA （P〈 0.05）, but this improvement was not maintained 2 years after TKA （P〉0.05）. However, when male and female patients were analyzed separately, there was a significant positive correlation between PCO change and ROF improvement for both sexes at both time points （all P〈0.05）. Conclusions： Restoration of PCO plays an important role in the optimization of knee flexion even after posteriorstabilized TKA. Femoral components based on Caucasian anatomic characteristics could not match the native anatomy of distal femurs in Chinese population especially female Chinese. Rotated resection of distal femur with anterior referencing technique usually leads to a decreased PCO and therefore reduces maximal obtainable flexion.
