Research on degradation of 2, 4 dichlorophenol and pentachlorophenol in water by electron beam irradiation

Electron beam was successfully used for the degradation of 2,4-dichlorophenol (2,4-DCP) and pentachlorophenol (PCP) in water. The effects of radiation doses on substrate degradation and dechlorination of solutions with concentrations of 50 mg/L for both chlorophenols were investigated. The effects of initial concentration, pH and absence of oxygen on the degradation were also investigated. The concentrations of 2,4-DCP and PCP remaining in solution after irradiation were measured by high-performance liquid chromatograph (HPLC). The results showed that an increased radiation dose led to increased degradation of the chlorophenols and increased Cl- yields. In all cases, the rate of degradation was found to be higher than the corresponding inorganic chloride yield from the parent compound. Deoxygenation was also found to increase the rate of degradation of the chlorophenols in water while degradation under alkaline condition was lower than at low to neutral pH.

Performance analysis of coded OFDM systems using a novel class of LDPC codes

A new method of constructing regular low-density parity-check (LDPC) codes was proposed. And the novel class of LDPC codes was applied in a coded orthogonal frequency division multiplexing (OFDM) system. This method extended the class of LDPC codes which could be constructed from shifted identity matrices. The method could avoid short cycles in Tanner graphs with simple inequation in the construction of shifting identity matrices, which made the girth of Tanner graphs 8. Because of the quasicyclic structure and the inherent block configuration of parity-check matrices, the encoders and the decoders were practically feasible. They were linear-time encodable and decodable. The LDPC codes proposed had various code rates, ranging from low to high. They performed excellently with iterative decoding and demonstrate better performance than other regular LDPC codes in OFDM systems.

Effects of acute hepatic damage on natriuresis and water excretion after acute normal saline loading in rats

AIMS To investigate the relationship between the liver function- al impairment and sodium and water retention. METHODS Acute liver damage model was established with carbon tetrachloride (CCl_4) administration to male Sprague-Daw- ley rats. Twenty-four and 48 hours later after CCl_4 administration, the excretion of acute sodium and water load was examined,and 24 hours later after normal saline administration,the excretion of acute sodium and water load was examined in control group. The concentration of plasma caffeine was analysed with high pressure liquid chromatograph (HPLC). The half life time of plasma caffein (Caft 1/2) sewed as a quantitative index of hepatic function. Plasma ALT was measured with Reitman method. The hepatic tis- sue was sectioned in the same site for water content measurement and pathological observation. The serumal and urinary sodium was measured with flame photometry. RESULTS Twenty-four hours later after CCl_4 administration, plasma alanine aminotransferase (ALT,n=6,37.5±12.6→ 189.4±34.4U,P<0.01) and water content of hepatic tissue (n =6,70.0%±1.1%→73.0%±1.0%,P<0.01) rose significantly,Caft 1/2 was prolonged significantly (94.9±18.9→ 326.4±85.8 minutes,P<0.01 ). The renal function of excretion of acute salt and water load declined obviously (n=6,Na^+: 92.4%±14.1%→50.1%±13.1%,P<0.01;H_2O:86.3%± 14.3%→42.1%±8.8%,P<0.01). Forty-eight hours later, the indexes above somewhat recovered,but were still markedly different from those of the control. Furthermore,the relationships betweenCaft 1/2 andALT (r=0.752,P<0.01),and between Caft 1/2 and excretory rate of sodium (r=-0.634,P<0.05) and water were still significant (r=-0. 612,P<0.01). CONCLUSIONS Caft 1/2 is a good index to assess the degree of hepatic damage. The hepatic dysfunction may be a factor caus- ing the renal excretory impairment to the acute sodium and water load.

Effects of Nitric Oxide on the Germination of Wheat Seeds and Its Reactive Oxygen Species Metabolisms Under Osmotic Stress

Effects of sodium nitroprusside (SNP), a nitric oxide (NO) donor, on the germination and metabolism of reactive oxygen species were surveyed in wheat (Triticum aestivum L.) seeds. Germination of wheat seeds and even the elongation of radicle and plumule were dramatically promoted by SNP treatments during the germination under osmotic stress. Meanwhile, activities of amylase and EP were enhanced, thus leading to the degradation of storage reserve in seeds. After osmotic stress was removed, higher viability of wheat seeds was also maintained. In addition, the activities of CAT, APX and the content of proline were increased by SNP treatment simultaneously, but activities of LOX were inhibited, and both of which were beneficial for improving the antioxidant capacity during the germination of wheat seeds under osmotic stress. It was also shown that the increase of the activity of amylase induced by SNP in embryoless half-seeds of wheat in the beginning period of germination (6 h) might be indirectly related to GA(3).

Theoretical Study of the C-CI Bond Dissociation Enthalpy and Electronic Structure of Substituted Chlorobenzene Compounds

Quantum chemical calculations were used to estimate the bond dissociation energies （BDEs） for 13 substituted chlorobenzene compounds. These compounds were studied by the hybrid density functional theory （B3LYP, B3PW91, B3P86） methods together with 6-31G^＊＊ and 6-311G^＊＊ basis sets. The results show that B3P86/6-311G^＊＊ method is the best method to compute the reliable BDEs for substituted chlorobenzene compounds which contain the C-C1 bond. It is found that the C-C1 BDE depends strongly on the computational method and the basis sets used. Substituent effect on the C-C1 BDE of substituted chlorobenzene compounds is further discussed. It is noted that the effects of substitution on the C-C1 BDE of substituted chlorobenzene compounds are very insignificant. The energy gaps between the HOMO and LUMO of studied compounds estimate the relative thermal stability ordering are also investigated and from this data we of substituted chlorobenzene compounds.

On the growth of transcendental entire solutions of algebraic differential equations

In this paper, we investigate the growth of transcendental entire solutionsof the following algebraic differential equation a(z)f'~2 +(b_2(z)f^2 +b_1(z)f +b_0(z))f'=d_3(z)f^3+d_2(z)f^2 +d_1(z)f +d_0(z), where a(z), b_i(z) (0<- i <=2) and d_j (z) (0<=j<= 3) are allpolynomials, and this equation relates closely to the following well-known algebraic differentialequation C(z,w)w'~2 + B(z,w)w' + A(z,w) =0, where G(z,w)not ident to 0, B(z,w) and A(z,w) are threepolynomials in z and w. We give relationships between the growth of entire solutions and the degreesof the above three polynomials in detail.

Singularity-free expression of magnetic field of cuboid under undulating terrain

Most of the current computing methods used to determine the magnetic field of a uniformly magnetized cuboid assume that the observation point is located in the upper half space without a source. However, such methods may generate analytical singularities for conditions of undulating terrain. Based on basic geomagnetic field theories, in this study an improved magnetic field expression is derived using an integration method of variable substitution, and all singularity problems for the entire space without a source are discussed and solved. This integration process is simpler than that of previous methods, and final integral results with a more uniform form. AT at all points in the source-flee space can be calculated without requiring coordinate transformation; thus forward modeling is also simplified. Corresponding model tests indicate that the new magnetic field expression is more correct because there is no analytical singularity and can be used with undulating terrain.

SYMMETRIC POSITIVE DEFINITE SOLUTIONS OF MATRIX EQUATIONS (AX,XB)=(C,D) AND AXB=C

The symmetric positive definite solutions of matrix equations (AX,XB)=(C,D) and AXB=C are considered in this paper. Necessary and sufficient conditions for the matrix equations to have symmetric positive definite solutions are derived using the singular value and the generalized singular value decompositions. The expressions for the general symmetric positive definite solutions are given when certain conditions hold.

Generalized Variational Iteration Solution of Soliton for Disturbed KdV Equation

The corresponding solution for a class of disturbed KdV equation is considered using the analytic method. From the generalized variational iteration theory, the problem of solving soliton for the corresponding equation translates into the problem of variational iteration. And then the approximate solution of the soliton for the equation is obtained.

An Analytical Solution for One-Dimensional Water Infiltration and Redistribution in Unsaturated Soil

Soil infiltration and redistribution are important processes in field water cycle, and it is necessary to develop a simple model to describe the processes. In this study, an algebraic solution for one-dimensional water infiltration and redistribution without evaporation in unsaturated soil was developed based on Richards equation. The algebraic solution had three parameters, namely, the saturated water conductivity, the comprehensive shape coefficient of the soil water content distribution, and the soil suction allocation coefficient. To analyze the physical features of these parameters, a relationship between the Green-Ampt model and the algebraic solution was established. The three parameters were estimated based on experimental observations, whereas the soil water content and the water infiltration duration were calculated using the algebraic solution. The calculated soil water content and infiltration duration were compared with the experimental observations, and the results indicated that the algebraic solution accurately described the unsaturated soil water flow processes.

Iterative Solution for Systems of Nonlinear Two Binary Operator Equations

Using the cone and partial ordering theory and mixed monotone operator theory, the existence and uniqueness of solutions for some classes of systems of nonlinear two binary operator equations in a Banach space with a partial ordering are discussed. And the error estimates that the iterative sequences converge to solutions are also given. Some relevant results of solvability of two binary operator equations and systems of operator equations are improved and generalized.

An Introduction to the Theory of C~*-modules

This paper,combined algebraical structure with analytical system,has studied the part of theory of C~*-modules over A by using the homolgical methods, where A is a commutative C~*-algebra over complex number field C. That is to say we have not only defined some relevant new concept,but also obtained some results about them.

SERIALLY CONCATENATED CONTINUOUS PHASE MODULATION WITH REDUCED ITERATIVE DEMODULATION AND DETECTION

A reduced state Soft Input Soft Output (SISO) a posteriori probability algorithm for Seri-ally Concatenated Continuous Phase Modulation (SCCPM) is proposed in this paper. Based on the Reduced State Sequence Detection (RSSD),it has more general form compared with other reduced state SISO algorithms. The proposed algorithm can greatly reduce the state number,thus leads to the computation complexity reduction. It also minimizes the degradation in Euclidean distance with decision feedback in the reduced state trellis. Analysis and simulation results show that the perform-ance degradation is little with proper reduction scheme.

Advances in Molecular Mechanism of Microbiological Degradation of Salicylate

Salicylate is a type of pollutant widely and persistently existed in environ- ment. Microbiological degradation of salicylate as one kind of biological remediation methods has the advantages of low cost, good effect and no secondary pollution, and also attracts wide attention both at home and abroad. Currently, many salicy- late-degrading bacteria are isolated and screened, while the molecular mechanism of salicylate metabolism is also worth deep research. The research about molecular mechanism of microorganism degradation was overviewed, various degrading path- ways including catechol meta-cleavage pathway and gentisate pathway were intro- duced, and the latest progress in regulating genes of salicylate degradation was summarized.

Signed Additive Fuzzy Measure

In this paper, we introduce the concept of signed additive fuzzy measure on a class of fuzzy sets, then, on certain condition, a series of decomposition theorems of signed additive fuzzy measure are proved.

CHANNEL ESTIMATION FOR ITERATIVE DECODING OVER FADING CHANNELS

A method of coherent detection and channel estimation for punctured convolutional coded binary Quadrature Amplitude Modulation (QAM) signals transmitted over a frequency-flat Rayleigh fading channels used for a digital radio broadcasting transmission is presented. Some known symbols are inserted in the encoded data stream to enhance the channel estimation process.The pilot symbols are used to replace the existing parity symbols so no bandwidth expansion is required. An iterative algorithm that uses decoding information as well as the information contained in the known symbols is used to improve the channel parameter estimate. The scheme complexity grows exponentially with the channel estimation filter length. The performance of the system is compared for a normalized fading rate with both perfect coherent detection (corresponding to a perfect knowledge of the fading process and noise variance) and differential detection of Differential Amplitude Phase Shift Keying (DAPSK). The tradeoff between simplicity of implementation and bit-error-rate performance of different techniques is also compared.

Effect of Nitrogen on the Degradation of Cypermethrin and Its Metabolite 3-Phenoxybenzoic Acid in Soil

Increasing use of pyrethroid insecticides has resulted in concerns regarding potential effects on human health and ecosystems. Cypermethrin and its metabolite 3-phenoxybenzoic acid(PBA) have exerted adverse biological impacts on the environment;therefore,it is critically important to develop different methods to enhance their degradation. In this study,incubation experiments were conducted using samples of an Aquic Inceptisol supplied with nitrogen(N) in the form of NH4NO3 at different levels to investigate the effect of nitrogen on the degradation of cypermethrin and PBA in soil. The results indicated that appropriate N application can promote the degradation of cypermethrin and PBA in soil. The maximum degradation rates were 80.0% for cypermethrin after 14 days of incubation in the treatment with N at a rate of 122.1 kg ha-1 and 41.0% for PBA after 60 days of incubation in the treatment with N at a rate of 182.7 kg ha-1. The corresponding rates in the treatments without nitrogen were 62.7% for cypermethrin and 27.8% for PBA. However,oversupplying N significantly reduced degradation of these compounds. Enhancement of degradation could be explained by the stimulation of microbial activity after the addition of N. In particular,dehydrogenase activities in the soil generally increased with the addition of N,except in the soil where N was applied at the highest level. The lower degradation rate measured in the treatment with an oversupply of N may be attributed to the microbial metabolism shifts induced by high N.

A Series of Exact Solutions of （2＋l）-Dimensional CDGKS Equation

An algebraic method with symbolic computation is devised to uniformly construct a series of exact solutions of the （2＋1）-dimensional Caudrey-Dodd-Gibbon-Kotera-Sawda equation. The solutions obtained in this paper include solitary wave solutions, rational solutions, triangular periodic solutions, Jacobi and Weierstrass doubly periodic solutions. Among them, the Jacobi periodic solutions exactly degenerate to the solutions at a certain limit condition. Compared with most existing tanh method, the method used here can give new and more general solutions. More importantly, this method provides a guldeline to classifj, the various types of the solution according to some parameters.

Exact Solutions of the Harry-Dym Equation

The aim of this paper is to generate exact travelling wave solutions of the Harry-Dym equation through the methods of Adomian decomposition, He＇s variational iteration, direct integration, and power series. We show that the two later methods are more successful than the two former to obtain more solutions of the equation.