The floating photovoltaic membrane prototype developed by Ocean Sun was selected as a reference object,and a 1∶40 scale laboratory model was designed and produced to further explore the impact of inflow conditions on...The floating photovoltaic membrane prototype developed by Ocean Sun was selected as a reference object,and a 1∶40 scale laboratory model was designed and produced to further explore the impact of inflow conditions on the hydrodynamic properties of the membrane structure.By conducting free attenuation tests,results showed that the inflow has only a slight effect on the natural frequencies of the heave,pitch,and surge of the membrane structure.This finding shows that the dynamic properties of the membrane structure remain essentially stable under different inflow conditions.The results of further regular and irregular wave hydrodynamic experiments show that,compared with the control group,the response of the membrane structure under inflow conditions in terms of heave,pitch,surge,and heave acceleration motions is relatively gentle,whereas the response of the membrane structure to the mooring force is strong.Especially when the waves are irregular,the inflow conditions have a more significant impact on the membrane structure,which may lead to more complex response changes in the structure.Therefore,in the actual engineering design process,the impact of inflow conditions on the behavior of the membrane structure must be fully considered,and appropriate engineering measures must be taken to ensure the safety and stability of the structure.展开更多
We studied finite-element-method-based two-dimensional frequency-domain acoustic FWI under rugged topography conditions. The exponential attenuation boundary condition suitable for rugged topography is proposed to sol...We studied finite-element-method-based two-dimensional frequency-domain acoustic FWI under rugged topography conditions. The exponential attenuation boundary condition suitable for rugged topography is proposed to solve the cutoff botmdary problem as well as to consider the requirement of using the same subdivision grid in joint multifrequency inversion. The proposed method introduces the attenuation factor, and by adjusting it, acoustic waves are sufficiently attenuated in the attenuation layer to minimize the cutoff boundary effect. Based on the law of exponential attenuation, expressions for computing the attenuation factor and the thickness of attenuation layers are derived for different frequencies. In multifrequency-domain FWI, the conjugate gradient method is used to solve equations in the Gauss-Newton algorithm and thus minimize the computation cost in calculating the Hessian matrix. In addition, the effect of initial model selection and frequency combination on FWI is analyzed. Examples using numerical simulations and FWI calculations are used to verify the efficiency of the proposed method.展开更多
This paper describes a study on the combined impacts of antecedent earthquakes and droughts on disastrous debris flows.This is a novel attempt in quantifying such impacts using the effective peak acceleration(EPA)(to ...This paper describes a study on the combined impacts of antecedent earthquakes and droughts on disastrous debris flows.This is a novel attempt in quantifying such impacts using the effective peak acceleration(EPA)(to represent earthquakes) and standardized precipitation index(SPI)(to represent droughts).The study is based on the analysis of 116 disastrous debris flow events occurred in China's Mainland in the last 100 years covering a wide spectrum of climate types and landforms.It has been found that the combined impacts from earthquakes and droughts on disastrous debris flows do exist and vary from low to very high according to different climate conditions and terrains.The impacts from earthquakes increase with the increased terrain relief,and the impacts from droughts are strongest in semi-humid climate condition(with reduced impacts in humid and semi-arid /arid climate conditions).Hypothetical explanations on the study discoveries have been proposed.This study reveals the possible reasons for the disastrous debris flow distributions around the world and has significant implications in paleo-climate-seismicanalysis and disastrous debris flow risk management.展开更多
This article presents our experimental studies to unravel the dynamic photovoltaic processes occurring at donor:acceptor(D:A)and electrode:active layer(E:A)interfaces under device-operating conditions by using two uni...This article presents our experimental studies to unravel the dynamic photovoltaic processes occurring at donor:acceptor(D:A)and electrode:active layer(E:A)interfaces under device-operating conditions by using two unique magneto-optical measurements,namely photo-induced capacitance and magnetic field effect measurement.First,we have found that a higher surface polarization of dielectric thin film can decrease the surface charge accumulation at E:A interface.The photo-induced capacitance results indicate that dielectric thin film plays a crucial role in the charge collection in generating photocurrent in organic solar cells.Second,our experimental results from magnetic field effect show that the binding energies of charge transfer(CT)states at D:A interface can be evaluated by using the critical bias required to completely dissociate the CT states.This is the first experimental demonstration that the binding energies of CT states can be measured under deviceoperating conditions.Furthermore,we use our measurement of magnetic field effect to investigate the most popular organic photovoltaic solar cells,organometal halide perovskite photovoltaic devices.The results of magneto-photoluminescence show that the photogenerated electrons and holes are inevitably recombined into electron–hole pairs through a spin-dependent process in the perovskites.Therefore,using spin polarizations can present a new design to control the photovoltaic loss in perovskites-based photovoltaic devices.Also,we found that introducing D:A interface can largely affect the bulk charge dissociation and recombination in perovskite solar cells.This indicates that the interfacial and bulk photovoltaic processes are internally coupled in developing photovoltaic actions in perovskite devices.Clearly,these magneto-optical measurements show a great potential to unravel the deeper photovoltaic processes occurring at D:A and E:A interfaces in both organic bulk-heterojunction and perovskite solar cells under device-operating conditions.展开更多
We demonstrated an efficient solar photovoltaic-powered electrochemical CO_(2) reduction device with a high-pressure CO_(2)-captured liquid feed.In an“air-to-barrel”picture,this device holds promise to avoid both hi...We demonstrated an efficient solar photovoltaic-powered electrochemical CO_(2) reduction device with a high-pressure CO_(2)-captured liquid feed.In an“air-to-barrel”picture,this device holds promise to avoid both high-temperature gaseous CO_(2) regeneration and high energy-cost gas product separation steps,while these steps are necessary for devices with a gaseous CO_(2) feed.To date,solar fuel production with a CO_(2)-saturated liquid feed suffers from high over-potential to suppress the hydrogen evolution reaction and consequently,low solar-to-chemical(STC)energy conversion efficiency.Here,we presented a distinct high-pressure operando strategy,i.e.,we took extra advantage of the high pressure in catalyst synthesis besides in the period of the CO_(2) reduction reaction(CO_(2)RR).The power of this strategy was demonstrated by a proof-of-concept device in which a representative copper catalyst was first synthesized in operando in a high-pressure(50 bar)CO_(2)-saturated KHCO3 solution,and then this high-pressure CO_(2)-captured liquid was converted to solar fuel using the operando synthesized Cu catalyst.This Cu catalyst achieved 95%CO_(2)RR selectivity at the recorded low potential of−0.3 V vs.RHE enabled by the combination of operando facet engineering and oxide derivation.Furthermore,this device achieved a record-high STC efficiency of 21.6%under outdoor illumination,superior to other CO_(2)-saturated liquid-fed devices,and compared favorably to gaseous CO_(2)-fed devices.展开更多
To date, extensive research has been carried out,with considerable success, on the development of highperformance perovskite solar cells(PSCs). Owing to its wide absorption range and remarkable thermal stability, the ...To date, extensive research has been carried out,with considerable success, on the development of highperformance perovskite solar cells(PSCs). Owing to its wide absorption range and remarkable thermal stability, the mixedcation perovskite FAxMA1-xPbI3(formamidinium/methylammonium lead iodide) promises high performance. However, the ratio of the mixed cations in the perovskite film has proved difficult to control with precursor solution. In addition, the FAxMA1-xPbI3 films contain a high percentage of MA+and suffer from serious phase separation and high trap states, resulting in inferior photovoltaic performance. In this study, to suppress phase separation, a post-processing method was developed to partially nucleate before annealing, by treating the as-prepared intermediate phase FAI-Pb I2-DMSO(DMSO: dimethylsulfoxide) with mixed FAI/MAI solution. It was found that in the final perovskite, FA0.92MA0.08 PbI3, defects were substantially reduced because the analogous molecular structure initiated ion exchange in the post-processed thin perovskite films, which advanced partial nucleation. As a result, the increased light harvesting and reduced trap states contributed to the enhancement of open-circuit voltage and short-circuit current. The PSCs produced by the post-processing method presented reliable reproducibility, with a maximum power conversion efficiency of 20.80% and a degradation of ~30% for 80 days in standard atmospheric conditions.展开更多
基金The National Natural Science Foundation of China(No.52171274).
文摘The floating photovoltaic membrane prototype developed by Ocean Sun was selected as a reference object,and a 1∶40 scale laboratory model was designed and produced to further explore the impact of inflow conditions on the hydrodynamic properties of the membrane structure.By conducting free attenuation tests,results showed that the inflow has only a slight effect on the natural frequencies of the heave,pitch,and surge of the membrane structure.This finding shows that the dynamic properties of the membrane structure remain essentially stable under different inflow conditions.The results of further regular and irregular wave hydrodynamic experiments show that,compared with the control group,the response of the membrane structure under inflow conditions in terms of heave,pitch,surge,and heave acceleration motions is relatively gentle,whereas the response of the membrane structure to the mooring force is strong.Especially when the waves are irregular,the inflow conditions have a more significant impact on the membrane structure,which may lead to more complex response changes in the structure.Therefore,in the actual engineering design process,the impact of inflow conditions on the behavior of the membrane structure must be fully considered,and appropriate engineering measures must be taken to ensure the safety and stability of the structure.
基金financially supported by the National High Technology Research and Development Program of China(No.2012AA09A20105)the National Science Foundation Network(No.41574127)
文摘We studied finite-element-method-based two-dimensional frequency-domain acoustic FWI under rugged topography conditions. The exponential attenuation boundary condition suitable for rugged topography is proposed to solve the cutoff botmdary problem as well as to consider the requirement of using the same subdivision grid in joint multifrequency inversion. The proposed method introduces the attenuation factor, and by adjusting it, acoustic waves are sufficiently attenuated in the attenuation layer to minimize the cutoff boundary effect. Based on the law of exponential attenuation, expressions for computing the attenuation factor and the thickness of attenuation layers are derived for different frequencies. In multifrequency-domain FWI, the conjugate gradient method is used to solve equations in the Gauss-Newton algorithm and thus minimize the computation cost in calculating the Hessian matrix. In addition, the effect of initial model selection and frequency combination on FWI is analyzed. Examples using numerical simulations and FWI calculations are used to verify the efficiency of the proposed method.
基金funded by the Ministry of Science and Technology of China (Grant No. 2011BAK12B02)the National Natural Science Foundation of China (Grant No. 41190084)+2 种基金the National Key Technology R&D Program (Grant No 2012 BAK10B04)the Non-Profit Industry Financial Program of MWR (Grant No. 201301058)the Changjiang River Scientific Research Institute of Sciences Innovation Team Project (Grant No. CKSF2012052/TB)
文摘This paper describes a study on the combined impacts of antecedent earthquakes and droughts on disastrous debris flows.This is a novel attempt in quantifying such impacts using the effective peak acceleration(EPA)(to represent earthquakes) and standardized precipitation index(SPI)(to represent droughts).The study is based on the analysis of 116 disastrous debris flow events occurred in China's Mainland in the last 100 years covering a wide spectrum of climate types and landforms.It has been found that the combined impacts from earthquakes and droughts on disastrous debris flows do exist and vary from low to very high according to different climate conditions and terrains.The impacts from earthquakes increase with the increased terrain relief,and the impacts from droughts are strongest in semi-humid climate condition(with reduced impacts in humid and semi-arid /arid climate conditions).Hypothetical explanations on the study discoveries have been proposed.This study reveals the possible reasons for the disastrous debris flow distributions around the world and has significant implications in paleo-climate-seismicanalysis and disastrous debris flow risk management.
基金supported by the National Science Foundation of the United States(ECCS-1102011,ECCS-0644945,and CBET-1438181)the support from Sustainable Energy Education and Research Center and Center for Materials Processing at the University of Tennessee+1 种基金This research was partially conducted at the Center for Nanophase Materials Sciences based on user project(CNMS2012-106,CNMS2012-107,CNMS-2012-108),which is sponsored at Oak Ridge National Laboratory by the Division of Scientific User Facilities,U.S.Department of Energythe University of Tennessee also acknowledge the project support from the National Natural Science Foundation of China(21161160445,61077020)
文摘This article presents our experimental studies to unravel the dynamic photovoltaic processes occurring at donor:acceptor(D:A)and electrode:active layer(E:A)interfaces under device-operating conditions by using two unique magneto-optical measurements,namely photo-induced capacitance and magnetic field effect measurement.First,we have found that a higher surface polarization of dielectric thin film can decrease the surface charge accumulation at E:A interface.The photo-induced capacitance results indicate that dielectric thin film plays a crucial role in the charge collection in generating photocurrent in organic solar cells.Second,our experimental results from magnetic field effect show that the binding energies of charge transfer(CT)states at D:A interface can be evaluated by using the critical bias required to completely dissociate the CT states.This is the first experimental demonstration that the binding energies of CT states can be measured under deviceoperating conditions.Furthermore,we use our measurement of magnetic field effect to investigate the most popular organic photovoltaic solar cells,organometal halide perovskite photovoltaic devices.The results of magneto-photoluminescence show that the photogenerated electrons and holes are inevitably recombined into electron–hole pairs through a spin-dependent process in the perovskites.Therefore,using spin polarizations can present a new design to control the photovoltaic loss in perovskites-based photovoltaic devices.Also,we found that introducing D:A interface can largely affect the bulk charge dissociation and recombination in perovskite solar cells.This indicates that the interfacial and bulk photovoltaic processes are internally coupled in developing photovoltaic actions in perovskite devices.Clearly,these magneto-optical measurements show a great potential to unravel the deeper photovoltaic processes occurring at D:A and E:A interfaces in both organic bulk-heterojunction and perovskite solar cells under device-operating conditions.
基金supported by the National Natural Science Foundation of China(51888103,52006103,51976090,and 52006101)Scientific and Technological Innovation Project of Carbon Emission Peak and Carbon Neutrality of Jiangsu Province(BE2022024)+1 种基金Natural Science Foundation of Jiangsu Province(BK20200072,BK20200491,and BK20200500)China Postdoctoral Science Foundation(2020M681603)。
文摘We demonstrated an efficient solar photovoltaic-powered electrochemical CO_(2) reduction device with a high-pressure CO_(2)-captured liquid feed.In an“air-to-barrel”picture,this device holds promise to avoid both high-temperature gaseous CO_(2) regeneration and high energy-cost gas product separation steps,while these steps are necessary for devices with a gaseous CO_(2) feed.To date,solar fuel production with a CO_(2)-saturated liquid feed suffers from high over-potential to suppress the hydrogen evolution reaction and consequently,low solar-to-chemical(STC)energy conversion efficiency.Here,we presented a distinct high-pressure operando strategy,i.e.,we took extra advantage of the high pressure in catalyst synthesis besides in the period of the CO_(2) reduction reaction(CO_(2)RR).The power of this strategy was demonstrated by a proof-of-concept device in which a representative copper catalyst was first synthesized in operando in a high-pressure(50 bar)CO_(2)-saturated KHCO3 solution,and then this high-pressure CO_(2)-captured liquid was converted to solar fuel using the operando synthesized Cu catalyst.This Cu catalyst achieved 95%CO_(2)RR selectivity at the recorded low potential of−0.3 V vs.RHE enabled by the combination of operando facet engineering and oxide derivation.Furthermore,this device achieved a record-high STC efficiency of 21.6%under outdoor illumination,superior to other CO_(2)-saturated liquid-fed devices,and compared favorably to gaseous CO_(2)-fed devices.
基金support from the National Key Research and Development Program of China (2016YFA0202401)the 111 Project (B16016)+2 种基金the National Natural Science Foundation of China (51702096 and U1705256)the Fundamental Research Funds for the Central Universities (2018ZD07)Metatest Scan Pro Laser Scanning System
文摘To date, extensive research has been carried out,with considerable success, on the development of highperformance perovskite solar cells(PSCs). Owing to its wide absorption range and remarkable thermal stability, the mixedcation perovskite FAxMA1-xPbI3(formamidinium/methylammonium lead iodide) promises high performance. However, the ratio of the mixed cations in the perovskite film has proved difficult to control with precursor solution. In addition, the FAxMA1-xPbI3 films contain a high percentage of MA+and suffer from serious phase separation and high trap states, resulting in inferior photovoltaic performance. In this study, to suppress phase separation, a post-processing method was developed to partially nucleate before annealing, by treating the as-prepared intermediate phase FAI-Pb I2-DMSO(DMSO: dimethylsulfoxide) with mixed FAI/MAI solution. It was found that in the final perovskite, FA0.92MA0.08 PbI3, defects were substantially reduced because the analogous molecular structure initiated ion exchange in the post-processed thin perovskite films, which advanced partial nucleation. As a result, the increased light harvesting and reduced trap states contributed to the enhancement of open-circuit voltage and short-circuit current. The PSCs produced by the post-processing method presented reliable reproducibility, with a maximum power conversion efficiency of 20.80% and a degradation of ~30% for 80 days in standard atmospheric conditions.