We present a finite difference （FD） method for the simulation of seismic wave fields in fractured medium with an irregular （non-fiat） free surface which is beneficial for interpreting exploration data acquired in ...We present a finite difference （FD） method for the simulation of seismic wave fields in fractured medium with an irregular （non-fiat） free surface which is beneficial for interpreting exploration data acquired in mountainous regions. Fractures are introduced through the Coates-Schoenberg approach into the FD scheme which leads to local anisotropic properties of the media where fractures are embedded. To implement surface topography, we take advantage of the boundary-conforming grid and map a rectangular grid onto a curved one. We use a stable and explicit second-order accurate finite difference scheme to discretize the elastic wave equations （in a curvilinear coordinate system） in a 2D heterogeneous transversely isotropic medium with a horizontal axis of symmetry （HTI）. Efficiency tests performed by different numerical experiments clearly illustrate the influence of an irregular free surface on seismic wave propagation in fractured media which may be significant to mountain seismic exploration. The tests also illustrate that the scattered waves induced by the tips of the fracture are re-scattered by the features of the free surface topography. The scattered waves provoked by the topography are re-scattered by the fractures, especially Rayleigh wave scattering whose amplitudes are much larger than others and making it very difficult to identify effective information from the fractures.展开更多
The current-voltage（I-V） characteristics of cBN crystal sandwiched between two metallic electrodes are measured and found to be nonlinear. Over 20 samples are measured at room temperature with various electrodes, an...The current-voltage（I-V） characteristics of cBN crystal sandwiched between two metallic electrodes are measured and found to be nonlinear. Over 20 samples are measured at room temperature with various electrodes, and the resulting curves are all similar in shape. When a voltage of about 560V is applied to the cBN crystal, the emitted light is visible to the naked eye in a dark room. We explain these phenomena by the space charge limited current and the electronic transition between the X and Г valleys of the conduction band.展开更多
In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI（polyaniline）-WC（tungsten carbide） composite inert anodes were prepared on aluminum alloy substrate by...In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI（polyaniline）-WC（tungsten carbide） composite inert anodes were prepared on aluminum alloy substrate by double pulse electrodeposition（DPE） of PANI and WC particles with Pb2＋ from an original plating bath.Thereafter,anodic polarization curves,cyclic voltammetry curves and Tafel polarization curves for the composite inert anodes obtained under different PANI concentrations in the original plating bath were measured,and the microstructural features were also investigated by scanning electron microscopy（SEM）.The results show that Al/Pb-PANI-WC composite inert anode obtained under PANI concentration of 20 g/L in the original plating bath possesses uniform microstructures and composition distributions,higher electrocatalytic activity,better reversibility of electrode reaction and corrosion resistance in a synthetic zinc electrowinning electrolyte of 50 g/L Zn2＋,150 g/L H2SO4 at 35 °C.Compared with Pb-1%Ag alloy,the overpotential of oxygen evolutions for the composite inert anode are decreased by 185 mV and 166 mV,respectively,under 500 A/m2 and 1000 A/m2.展开更多
The electrochemical synthesis silicon wires by electrorefining metallurgical grade silicon in thermally dried and pre-electrolyzed molten KF-NaF eutectic were studied at temperatures 800-900 ℃ using cyclic voltammetr...The electrochemical synthesis silicon wires by electrorefining metallurgical grade silicon in thermally dried and pre-electrolyzed molten KF-NaF eutectic were studied at temperatures 800-900 ℃ using cyclic voltammetry and ac impedance. One oxidation peak at -0.14 V could be attributed to the reaction of Si to Si4＋. A cathodic peak occurred at -0.56 V in the cyclic voltammogram and one response semicircle in the ac impedance spectrum was observed, supporting a one-step electrochemical reduction process of Si4＋-→Si. The electrochemical reaction of silicon was controlled by the diffusion process. The purity of electrorefined silicon wires was up to 99.999% by ICP-MS analysis.展开更多
The problem of oblique wave （internal wave） propagation over a small deformation in a channel flow consisting of two layers was considered. The upper fluid was assumed to be bounded above by a rigid lid, which is an...The problem of oblique wave （internal wave） propagation over a small deformation in a channel flow consisting of two layers was considered. The upper fluid was assumed to be bounded above by a rigid lid, which is an approximation for the free surface, and the lower one was bounded below by an impermeable bottom surface having a small deformation; the channel was unbounded in the horizontal directions. Assuming irrotational motion, the perturbation technique was employed to calculate the first-order corrections of the velocity potential in the two fluids by using Green＇s integral theorem suitably with the introduction of appropriate Green＇s functions. Those functions help in calculating the reflection and transmission coefficients in terms of integrals involving the shape ftmction c（x） representing the bottom deformation. Three-dimensional linear water wave theory was utilized for formulating the relevant boundary value problem. Two special examples of bottom deformation were considered to validate the results. Consideration of a patch of sinusoidal ripples （having the same wave number） shows that the reflection coefficient is an oscillatory function of the ratio of twice the x-component of the wave number to the ripple wave number. When this ratio approaches one, the theory predicts a resonant interaction between the bed and the interface, and the reflection coefficient becomes a multiple of the number of ripples. High reflection of incident wave energy occurs if this number is large. Similar results were observed for a patch of sinusoidal ripples having different wave numbers. It was also observed that for small angles of incidence, the reflected energy is greater compared to other angles of incidence up to π/ 4. These theoretical observations are supported by graphical results.展开更多
An attempt was made to build up a thick and compact oxide layer rapidly by pre-treating the Pb-Ag-Nd anode in fluoride-containing H2SO4 solution. The passivation reaction of Pb-Ag-Nd anode during pre-treatment process...An attempt was made to build up a thick and compact oxide layer rapidly by pre-treating the Pb-Ag-Nd anode in fluoride-containing H2SO4 solution. The passivation reaction of Pb-Ag-Nd anode during pre-treatment process was investigated using cyclic voltammetry, linear scanning voltammetry, environmental scanning electron microscopy and X-ray diffraction analysis. The results show that Pb F2 and PbSO4 are formed near the potential of Pb/PbSO4 couple. The pre-treatment in fluoride-containing H2SO4 solution contributes to the formation of a thick, compact and adherent passive film. Furthermore, pre-treatment in fluoride-containing H2SO4 solution also facilitates the formation of PbO2 on the anodic layer, and the reason could be attributed to the formation of more PbF2 and PbSO4 during the pre-treatment which tend to transform to PbO2 during the following electrowinning process. In addition, the anodic layer on anode with pre-treatment in fluoride-containing H2SO4 solution is thick and compact, and its predominant composition is β-PbO2. In summary, the pre-treatment in fluoride-containing H2SO4 solution benefits the formation of a desirable protective layer in a short time.展开更多
The analysis of solar cell performance has been done by simulating the external I-V characteristics of n +/p/p + single crystal silicon solar cell under high light intensity and 1.5 air mass (AM). This method allows t...The analysis of solar cell performance has been done by simulating the external I-V characteristics of n +/p/p + single crystal silicon solar cell under high light intensity and 1.5 air mass (AM). This method allows the maximization of solar cell efficiency. To fabricate low-cost n +/p/p + single crystal silicon solar cells, solid source of doped phosphorous and boron was used.展开更多
基金sponsored by the Knowledge Innovation Program of the Chinese Academy of Sciences No.KZCX2-YW-132)the Important National Science and Technology Specific Projects(No.2008ZX05008-006)the National Natural Science Foundation of China Nos.41074033,40721003,40830315,and 40874041)
文摘We present a finite difference （FD） method for the simulation of seismic wave fields in fractured medium with an irregular （non-fiat） free surface which is beneficial for interpreting exploration data acquired in mountainous regions. Fractures are introduced through the Coates-Schoenberg approach into the FD scheme which leads to local anisotropic properties of the media where fractures are embedded. To implement surface topography, we take advantage of the boundary-conforming grid and map a rectangular grid onto a curved one. We use a stable and explicit second-order accurate finite difference scheme to discretize the elastic wave equations （in a curvilinear coordinate system） in a 2D heterogeneous transversely isotropic medium with a horizontal axis of symmetry （HTI）. Efficiency tests performed by different numerical experiments clearly illustrate the influence of an irregular free surface on seismic wave propagation in fractured media which may be significant to mountain seismic exploration. The tests also illustrate that the scattered waves induced by the tips of the fracture are re-scattered by the features of the free surface topography. The scattered waves provoked by the topography are re-scattered by the fractures, especially Rayleigh wave scattering whose amplitudes are much larger than others and making it very difficult to identify effective information from the fractures.
文摘The current-voltage（I-V） characteristics of cBN crystal sandwiched between two metallic electrodes are measured and found to be nonlinear. Over 20 samples are measured at room temperature with various electrodes, and the resulting curves are all similar in shape. When a voltage of about 560V is applied to the cBN crystal, the emitted light is visible to the naked eye in a dark room. We explain these phenomena by the space charge limited current and the electronic transition between the X and Г valleys of the conduction band.
基金Project (51004056) supported by the National Natural Science Foundation of ChinaProject (KKZ6201152009) supported by the Opening Foundation of Key Laboratory of Inorganic Coating Materials, ChinaProjects (2011239, 2011240) supported by Analysis and Measurement Research Fund of Kunming University of Science and Technology,China
文摘In order to search for a suitable anode material used in zinc electrowinning in place of Pb-Ag alloy,Al/Pb-PANI（polyaniline）-WC（tungsten carbide） composite inert anodes were prepared on aluminum alloy substrate by double pulse electrodeposition（DPE） of PANI and WC particles with Pb2＋ from an original plating bath.Thereafter,anodic polarization curves,cyclic voltammetry curves and Tafel polarization curves for the composite inert anodes obtained under different PANI concentrations in the original plating bath were measured,and the microstructural features were also investigated by scanning electron microscopy（SEM）.The results show that Al/Pb-PANI-WC composite inert anode obtained under PANI concentration of 20 g/L in the original plating bath possesses uniform microstructures and composition distributions,higher electrocatalytic activity,better reversibility of electrode reaction and corrosion resistance in a synthetic zinc electrowinning electrolyte of 50 g/L Zn2＋,150 g/L H2SO4 at 35 °C.Compared with Pb-1%Ag alloy,the overpotential of oxygen evolutions for the composite inert anode are decreased by 185 mV and 166 mV,respectively,under 500 A/m2 and 1000 A/m2.
文摘The electrochemical synthesis silicon wires by electrorefining metallurgical grade silicon in thermally dried and pre-electrolyzed molten KF-NaF eutectic were studied at temperatures 800-900 ℃ using cyclic voltammetry and ac impedance. One oxidation peak at -0.14 V could be attributed to the reaction of Si to Si4＋. A cathodic peak occurred at -0.56 V in the cyclic voltammogram and one response semicircle in the ac impedance spectrum was observed, supporting a one-step electrochemical reduction process of Si4＋-→Si. The electrochemical reaction of silicon was controlled by the diffusion process. The purity of electrorefined silicon wires was up to 99.999% by ICP-MS analysis.
文摘The problem of oblique wave （internal wave） propagation over a small deformation in a channel flow consisting of two layers was considered. The upper fluid was assumed to be bounded above by a rigid lid, which is an approximation for the free surface, and the lower one was bounded below by an impermeable bottom surface having a small deformation; the channel was unbounded in the horizontal directions. Assuming irrotational motion, the perturbation technique was employed to calculate the first-order corrections of the velocity potential in the two fluids by using Green＇s integral theorem suitably with the introduction of appropriate Green＇s functions. Those functions help in calculating the reflection and transmission coefficients in terms of integrals involving the shape ftmction c（x） representing the bottom deformation. Three-dimensional linear water wave theory was utilized for formulating the relevant boundary value problem. Two special examples of bottom deformation were considered to validate the results. Consideration of a patch of sinusoidal ripples （having the same wave number） shows that the reflection coefficient is an oscillatory function of the ratio of twice the x-component of the wave number to the ripple wave number. When this ratio approaches one, the theory predicts a resonant interaction between the bed and the interface, and the reflection coefficient becomes a multiple of the number of ripples. High reflection of incident wave energy occurs if this number is large. Similar results were observed for a patch of sinusoidal ripples having different wave numbers. It was also observed that for small angles of incidence, the reflected energy is greater compared to other angles of incidence up to π/ 4. These theoretical observations are supported by graphical results.
基金Projects(51204208,51374240)supported by the National Natural Science Foundation of ChinaProject(2014zzts028)supported by the Fundamental Research Funds for the Central Universities of Central South University,China
文摘An attempt was made to build up a thick and compact oxide layer rapidly by pre-treating the Pb-Ag-Nd anode in fluoride-containing H2SO4 solution. The passivation reaction of Pb-Ag-Nd anode during pre-treatment process was investigated using cyclic voltammetry, linear scanning voltammetry, environmental scanning electron microscopy and X-ray diffraction analysis. The results show that Pb F2 and PbSO4 are formed near the potential of Pb/PbSO4 couple. The pre-treatment in fluoride-containing H2SO4 solution contributes to the formation of a thick, compact and adherent passive film. Furthermore, pre-treatment in fluoride-containing H2SO4 solution also facilitates the formation of PbO2 on the anodic layer, and the reason could be attributed to the formation of more PbF2 and PbSO4 during the pre-treatment which tend to transform to PbO2 during the following electrowinning process. In addition, the anodic layer on anode with pre-treatment in fluoride-containing H2SO4 solution is thick and compact, and its predominant composition is β-PbO2. In summary, the pre-treatment in fluoride-containing H2SO4 solution benefits the formation of a desirable protective layer in a short time.
文摘The analysis of solar cell performance has been done by simulating the external I-V characteristics of n +/p/p + single crystal silicon solar cell under high light intensity and 1.5 air mass (AM). This method allows the maximization of solar cell efficiency. To fabricate low-cost n +/p/p + single crystal silicon solar cells, solid source of doped phosphorous and boron was used.
