The tidal current duration (TCD) and velocity (TCV) and suspended sediment concentration (SSC) were measured in the dry season in December, 2011 and in the flood season in June, 2012 at the upper part of the Nor...The tidal current duration (TCD) and velocity (TCV) and suspended sediment concentration (SSC) were measured in the dry season in December, 2011 and in the flood season in June, 2012 at the upper part of the North Channel of Changjiang Estuary. They were assimilated with the measured data in 2003, 2004, 2006 and 2007, using the tidal range's proportion conversion. Variations in TCD and TCV, preferential flow and SSC have been calculated. Influences of typical engineering projects such as Qingcaosha fresh water reservoir, Yangtze River Bridge, and land reclamation on the ebb and flood TCD, TCV and SSC in the North Channel for the last 10 years are discussed. The results show that: (1) currently, in the upper part of North Channel, the ebb tide dominates; after the construction of the typical projects, ebb TCD and TCV tends to be larger and the vertical average ebb and flood SSC decrease during the flood season while SSC increases during the dry season; (2) changes in the vertical average TCV are mainly contributed by seasonal runoff variation during the flood season, which is larger in the flood season than that in the dry season; the controlling parameters of increasing ebb TCD and TCV are those large-scale engineering projects in the North Channel; variation in SSC may result mainly from the reduction of basin annual sediment loads, large-scale nearshore projects and so on.展开更多
The general layout of 6th generation semi-submersible drilling platforms is the main factor impacting the efficiency of their drilling operations. This paper provides a compound/integrated algorithm based on process f...The general layout of 6th generation semi-submersible drilling platforms is the main factor impacting the efficiency of their drilling operations. This paper provides a compound/integrated algorithm based on process flow that is aimed at improving efficiency, while giving attention to stability and safety at the same time. The paper describes the process flow of dual drilling centers and a hierarchical division of rigs based on the different modes of transportation of various drilling support systems. The general layout-centripetal overall arrangement spatially was determined based on drilling efficiency. We derived our modules according to drilling functionality; the modules became our basic layout units. We applied different layout algorithm to mark out the upper and lower decks. That is, the upper deck was designed based on the lowest transportation cost while the lower deck's calculations were based on the best-fit scope. Storage configurations in columns and pontoons were also considered for the layout design. Finally the center of gravity was taken into consideration and the general layout was adjusted accordingly, to result in an optimal center of gravity. The methodology of the general layout can provide a reference for implementation of domestic designs of semi-submersible rigs.展开更多
A new 18-lump kinetic model for naphtha catalytic reforming reactions is discussed. By developing this model as a user module, a whole industrial continuous catalytic reforming process is simulated on Aspen plus plat-...A new 18-lump kinetic model for naphtha catalytic reforming reactions is discussed. By developing this model as a user module, a whole industrial continuous catalytic reforming process is simulated on Aspen plus plat-form. The technique utilizes the strong databases, complete sets of modules, and flexible simulation tools of the Aspen plus system and retains the characteristics of the proposed kinetic model. The calculated results are in fair agreement with the actual operating data. Based on the model of the whole reforming process, the process is opti-mized and the optimization results are tested in the actual industrial unit for about two months. The test shows that the process profit increases about 1000yuan·h-1 averagely, which is close to the calculated result.展开更多
The central composite process optimization was performed by response surface methodology technique using a design for the treatment of methyltin mercaptide with modified semi-coke. The semi-coke from the coal industry...The central composite process optimization was performed by response surface methodology technique using a design for the treatment of methyltin mercaptide with modified semi-coke. The semi-coke from the coal industry was suitably modified by treating it with phosphoric acid, with a thermal activation process. The objective of the process optimization is to reduce the chemical oxygen demand (COD) and NH4+-N in the methyltin mercaptide industrial effluent. The process variables considered for process optimization are the semi-coke dosage, adsorption time and effluent pH. The optimized process conditions are identified to be a semi-coke dosage of 80 g/L, adsorption time of 90 min and a pH value of 8.34. The ANOVA results indicate that the adsorbent dosage and pH are the significant parameters, while the adsorption time is insignificant, possibly owing to the large range of adsorption time chosen. The textural characteristics of modified semi-coke were analyzed using scanning electron microscopy and nitrogen adsorption isotherm. The average BET surface area of modified semi-coke is estimated to be 915 mE/g, with the average pore volume of 0.71 cm3/g and a average pore diameter of 3.09 nm, with micropore volume contributing to 52.36%.展开更多
This paper addresses the application of stochastic optimization approaches to the synthesis of heatintegrated complex distillation system, which is characterized by large-scale combinatorial feature. Conventionaland c...This paper addresses the application of stochastic optimization approaches to the synthesis of heatintegrated complex distillation system, which is characterized by large-scale combinatorial feature. Conventionaland complex columns, thermally coupled (linked) side strippers and side rectifiers as well as heat integration betweenthe different columns are simultaneously considered. The problem is formulated as an MINLP (mixed-integernonlinear programming) problem. A simulated annealing algorithm is proposed to deal with the MINLP problemand a shortcut method is applied to evaluate all required design parameters as well as the total cost function. Twoillustrating examples are presented.展开更多
To improve the dust removal performance of the wet electrostatic precipitator(WESP), a flow field optimization scheme was proposed via CFD simulation in different scales. The simplified models of perforated and collec...To improve the dust removal performance of the wet electrostatic precipitator(WESP), a flow field optimization scheme was proposed via CFD simulation in different scales. The simplified models of perforated and collection plates were determined firstly. Then the model parameters for the resistance of perforated and collection plates, obtained by small-scale flow simulation, were validated by medium-scale experiments. Through the comparison of the resistance and velocity distribution between simulation results and experimental data, the simplified model is proved to present the resistance characteristics of perforated and collection plates accurately. Numerical results show that after optimization, both the flow rate and the pressure drop in the upper room of electric field regions are basically equivalent to those of the lower room, and the velocity distribution in flue inlet of WESP becomes more uniform. Through the application in practice, the effectiveness and reliability of the optimization scheme are proved, which can provide valuable reference for further optimization of WESP.展开更多
In this paper,we investigate a streamline diffusion finite element approxi- mation scheme for the constrained optimal control problem governed by linear con- vection dominated diffusion equations.We prove the existenc...In this paper,we investigate a streamline diffusion finite element approxi- mation scheme for the constrained optimal control problem governed by linear con- vection dominated diffusion equations.We prove the existence and uniqueness of the discretized scheme.Then a priori and a posteriori error estimates are derived for the state,the co-state and the control.Three numerical examples are presented to illustrate our theoretical results.展开更多
For complex chemical processes,process optimization is usually performed on causal models from first principle models.When the mechanism models cannot be obtained easily,restricted model built by process data is used ...For complex chemical processes,process optimization is usually performed on causal models from first principle models.When the mechanism models cannot be obtained easily,restricted model built by process data is used for dynamic process optimization.A new strategy is proposed for complex process optimization,in which latent variables are used as decision variables and statistics is used to describe constraints.As the constraint condition will be more complex by projecting the original variable to latent space,Hotelling T^2 statistics is introduced for constraint formulation in latent space.In this way,the constraint is simplified when the optimization is solved in low-dimensional space of latent variable.The validity of the methodology is illustrated in pH-level optimal control process and practical polypropylene grade transition process.展开更多
According to the Wide Area Network model, we formulate Internet flow control as a constrained convex programming problem, where the objective is to maximize the total utility of all sources over their transmission rat...According to the Wide Area Network model, we formulate Internet flow control as a constrained convex programming problem, where the objective is to maximize the total utility of all sources over their transmission rates. Based on this formulation, flow control can be converted to a normal unconstrained optimization problem through the barrier function method, so that it can be solved by means of a gradient projection algorithm with properly rate iterations. We prove that the algorithm converges to the global optimal point, which is also a stable proportional fair rate allocation point, provided that the step size is properly chosen. The main difficulty facing the realization of iteration algorithm is the distributed computation of congestion measure. Fortunately, Explicit Congestion Notification (ECN) is likely to be used to improve the performance of TCP in the near future. By using ECN, it is possible to realize the iteration algorithm in IP networks. Our algorithm is divided into two parts, algorithms in the router and in the source. The router marks the ECN bit with a probability that varies as its buffer occupancy varies, so that the congestion measure of links can be communicated to the source when the marked ECN bits are reflected back from its destination. Source rates are then updated by all sessions according to the received congestion measure. The main advantage of our scheme is its fast convergence ability and robustness; it can also provide the network with zero packet loss by properly choosing the queue threshold and provide differentiated service to users by applying different utility functions.展开更多
Butyl-levulinate has been identified as a promising fuel candidate with high oxygen content. Its com- bustion in diesel engines yields very low soot and NOx emissions. It can be produced by the esterification of butan...Butyl-levulinate has been identified as a promising fuel candidate with high oxygen content. Its com- bustion in diesel engines yields very low soot and NOx emissions. It can be produced by the esterification of butanol and levulinic acid, which themselves are platform chemicals in a biorenewables-based chemical supply chain. Since the equilibrium of esterification limits the conversion in a conventional reactor, reactive distillation can be applied to overcome this limitation. The presence of the high-boiling catalyst sulfuric acid requires a further separation step downstream of the reactive distillation column to recover the catalyst for recycle. Optimal design specifications and an optimal operating point are determined using rigorous flowsheet optimization. The challenging optimization problem is solved by a favorable initialization strategy and continuous reformulation. The design identified has the potential to produce a renewable transportation fuel at reasonable cost.展开更多
Operation optimization is an effective method to explore potential economic benefits for existing plants. The m.aximum potential benefit from operationoptimization is determined by the distances between current operat...Operation optimization is an effective method to explore potential economic benefits for existing plants. The m.aximum potential benefit from operationoptimization is determined by the distances between current operating point and process constraints, which is related to the margins of design variables. Because of various ciisturbances in chemical processes, some distances must be reserved for fluctuations of process variables and the optimum operating point is not on some process constraints. Thus the benefit of steady-state optimization can not be fully achied(ed while that of dynamic optimization can be really achieved. In this study, the steady-state optimizationand dynamic optimization are used, and the potential benefit-is divided into achievable benefit for profit and unachievable benefit for control. The fluid catalytic cracking unit (FCCU) is used for case study. With the analysis on how the margins of design variables influence the economic benefit and control performance, the bottlenecks of process design are found and appropriate control structure can be selected.展开更多
文摘The tidal current duration (TCD) and velocity (TCV) and suspended sediment concentration (SSC) were measured in the dry season in December, 2011 and in the flood season in June, 2012 at the upper part of the North Channel of Changjiang Estuary. They were assimilated with the measured data in 2003, 2004, 2006 and 2007, using the tidal range's proportion conversion. Variations in TCD and TCV, preferential flow and SSC have been calculated. Influences of typical engineering projects such as Qingcaosha fresh water reservoir, Yangtze River Bridge, and land reclamation on the ebb and flood TCD, TCV and SSC in the North Channel for the last 10 years are discussed. The results show that: (1) currently, in the upper part of North Channel, the ebb tide dominates; after the construction of the typical projects, ebb TCD and TCV tends to be larger and the vertical average ebb and flood SSC decrease during the flood season while SSC increases during the dry season; (2) changes in the vertical average TCV are mainly contributed by seasonal runoff variation during the flood season, which is larger in the flood season than that in the dry season; the controlling parameters of increasing ebb TCD and TCV are those large-scale engineering projects in the North Channel; variation in SSC may result mainly from the reduction of basin annual sediment loads, large-scale nearshore projects and so on.
基金Supported by the National High Technology Research and Development Program of China (863 Program) under Grant No.2006AA09A104
文摘The general layout of 6th generation semi-submersible drilling platforms is the main factor impacting the efficiency of their drilling operations. This paper provides a compound/integrated algorithm based on process flow that is aimed at improving efficiency, while giving attention to stability and safety at the same time. The paper describes the process flow of dual drilling centers and a hierarchical division of rigs based on the different modes of transportation of various drilling support systems. The general layout-centripetal overall arrangement spatially was determined based on drilling efficiency. We derived our modules according to drilling functionality; the modules became our basic layout units. We applied different layout algorithm to mark out the upper and lower decks. That is, the upper deck was designed based on the lowest transportation cost while the lower deck's calculations were based on the best-fit scope. Storage configurations in columns and pontoons were also considered for the layout design. Finally the center of gravity was taken into consideration and the general layout was adjusted accordingly, to result in an optimal center of gravity. The methodology of the general layout can provide a reference for implementation of domestic designs of semi-submersible rigs.
基金Supported by the National Natural Science Foundation of China (No.60421002).
文摘A new 18-lump kinetic model for naphtha catalytic reforming reactions is discussed. By developing this model as a user module, a whole industrial continuous catalytic reforming process is simulated on Aspen plus plat-form. The technique utilizes the strong databases, complete sets of modules, and flexible simulation tools of the Aspen plus system and retains the characteristics of the proposed kinetic model. The calculated results are in fair agreement with the actual operating data. Based on the model of the whole reforming process, the process is opti-mized and the optimization results are tested in the actual industrial unit for about two months. The test shows that the process profit increases about 1000yuan·h-1 averagely, which is close to the calculated result.
基金Projects(5114703,51004059/E041601)supported by the National Natural Science Foundation of China
文摘The central composite process optimization was performed by response surface methodology technique using a design for the treatment of methyltin mercaptide with modified semi-coke. The semi-coke from the coal industry was suitably modified by treating it with phosphoric acid, with a thermal activation process. The objective of the process optimization is to reduce the chemical oxygen demand (COD) and NH4+-N in the methyltin mercaptide industrial effluent. The process variables considered for process optimization are the semi-coke dosage, adsorption time and effluent pH. The optimized process conditions are identified to be a semi-coke dosage of 80 g/L, adsorption time of 90 min and a pH value of 8.34. The ANOVA results indicate that the adsorbent dosage and pH are the significant parameters, while the adsorption time is insignificant, possibly owing to the large range of adsorption time chosen. The textural characteristics of modified semi-coke were analyzed using scanning electron microscopy and nitrogen adsorption isotherm. The average BET surface area of modified semi-coke is estimated to be 915 mE/g, with the average pore volume of 0.71 cm3/g and a average pore diameter of 3.09 nm, with micropore volume contributing to 52.36%.
基金Supported by the National Fundamental Research Development Program of China (No. 2000026308).
文摘This paper addresses the application of stochastic optimization approaches to the synthesis of heatintegrated complex distillation system, which is characterized by large-scale combinatorial feature. Conventionaland complex columns, thermally coupled (linked) side strippers and side rectifiers as well as heat integration betweenthe different columns are simultaneously considered. The problem is formulated as an MINLP (mixed-integernonlinear programming) problem. A simulated annealing algorithm is proposed to deal with the MINLP problemand a shortcut method is applied to evaluate all required design parameters as well as the total cost function. Twoillustrating examples are presented.
文摘To improve the dust removal performance of the wet electrostatic precipitator(WESP), a flow field optimization scheme was proposed via CFD simulation in different scales. The simplified models of perforated and collection plates were determined firstly. Then the model parameters for the resistance of perforated and collection plates, obtained by small-scale flow simulation, were validated by medium-scale experiments. Through the comparison of the resistance and velocity distribution between simulation results and experimental data, the simplified model is proved to present the resistance characteristics of perforated and collection plates accurately. Numerical results show that after optimization, both the flow rate and the pressure drop in the upper room of electric field regions are basically equivalent to those of the lower room, and the velocity distribution in flue inlet of WESP becomes more uniform. Through the application in practice, the effectiveness and reliability of the optimization scheme are proved, which can provide valuable reference for further optimization of WESP.
基金supported by the National Basic Research Program under the Grant 2005CB321701the National Natural Science Foundation of China under the Grants 60474027 and 10771211.
文摘In this paper,we investigate a streamline diffusion finite element approxi- mation scheme for the constrained optimal control problem governed by linear con- vection dominated diffusion equations.We prove the existence and uniqueness of the discretized scheme.Then a priori and a posteriori error estimates are derived for the state,the co-state and the control.Three numerical examples are presented to illustrate our theoretical results.
基金Supported by the National Natural Science Foundation of China(61174114)the Research Fund for the Doctoral Program of Higher Education in China(20120101130016)+1 种基金the Natural Science Foundation of Zhejiang Province(LQ15F030006)the Educational Commission Research Program of Zhejiang Province(Y201431412)
文摘For complex chemical processes,process optimization is usually performed on causal models from first principle models.When the mechanism models cannot be obtained easily,restricted model built by process data is used for dynamic process optimization.A new strategy is proposed for complex process optimization,in which latent variables are used as decision variables and statistics is used to describe constraints.As the constraint condition will be more complex by projecting the original variable to latent space,Hotelling T^2 statistics is introduced for constraint formulation in latent space.In this way,the constraint is simplified when the optimization is solved in low-dimensional space of latent variable.The validity of the methodology is illustrated in pH-level optimal control process and practical polypropylene grade transition process.
文摘According to the Wide Area Network model, we formulate Internet flow control as a constrained convex programming problem, where the objective is to maximize the total utility of all sources over their transmission rates. Based on this formulation, flow control can be converted to a normal unconstrained optimization problem through the barrier function method, so that it can be solved by means of a gradient projection algorithm with properly rate iterations. We prove that the algorithm converges to the global optimal point, which is also a stable proportional fair rate allocation point, provided that the step size is properly chosen. The main difficulty facing the realization of iteration algorithm is the distributed computation of congestion measure. Fortunately, Explicit Congestion Notification (ECN) is likely to be used to improve the performance of TCP in the near future. By using ECN, it is possible to realize the iteration algorithm in IP networks. Our algorithm is divided into two parts, algorithms in the router and in the source. The router marks the ECN bit with a probability that varies as its buffer occupancy varies, so that the congestion measure of links can be communicated to the source when the marked ECN bits are reflected back from its destination. Source rates are then updated by all sessions according to the received congestion measure. The main advantage of our scheme is its fast convergence ability and robustness; it can also provide the network with zero packet loss by properly choosing the queue threshold and provide differentiated service to users by applying different utility functions.
基金funded by the Excellence Initiative of the German federal and state governments to promote science and research at German universities
文摘Butyl-levulinate has been identified as a promising fuel candidate with high oxygen content. Its com- bustion in diesel engines yields very low soot and NOx emissions. It can be produced by the esterification of butanol and levulinic acid, which themselves are platform chemicals in a biorenewables-based chemical supply chain. Since the equilibrium of esterification limits the conversion in a conventional reactor, reactive distillation can be applied to overcome this limitation. The presence of the high-boiling catalyst sulfuric acid requires a further separation step downstream of the reactive distillation column to recover the catalyst for recycle. Optimal design specifications and an optimal operating point are determined using rigorous flowsheet optimization. The challenging optimization problem is solved by a favorable initialization strategy and continuous reformulation. The design identified has the potential to produce a renewable transportation fuel at reasonable cost.
基金Supported by the National Natural Science Foundation of China(21006127)the National Basic Research Program of China(2012CB720500)the Science Foundation of China University of Petroleum(KYJJ2012-05-28)
文摘Operation optimization is an effective method to explore potential economic benefits for existing plants. The m.aximum potential benefit from operationoptimization is determined by the distances between current operating point and process constraints, which is related to the margins of design variables. Because of various ciisturbances in chemical processes, some distances must be reserved for fluctuations of process variables and the optimum operating point is not on some process constraints. Thus the benefit of steady-state optimization can not be fully achied(ed while that of dynamic optimization can be really achieved. In this study, the steady-state optimizationand dynamic optimization are used, and the potential benefit-is divided into achievable benefit for profit and unachievable benefit for control. The fluid catalytic cracking unit (FCCU) is used for case study. With the analysis on how the margins of design variables influence the economic benefit and control performance, the bottlenecks of process design are found and appropriate control structure can be selected.