Petrography and geochemistry of the altered and unaltered host rocks surrounding the Koktokay No.3 pegmatite revealed that the unaltered amphibolite is mainly composed of hornblende, plagioclase, and ilmenite.Beyond t...Petrography and geochemistry of the altered and unaltered host rocks surrounding the Koktokay No.3 pegmatite revealed that the unaltered amphibolite is mainly composed of hornblende, plagioclase, and ilmenite.Beyond these primary components, the altered host rocks contain a few newly formed minerals, including biotite,tourmaline, chlorine, and muscovite. The alteration zone surrounding the Koktokay No.3 pegmatite is limited to 2.0 m, characterized by biotitization, tourmalization, and chloritization. In the altered host rocks, the contents of SiO2, MgO, MnO, Na2O, and TiO2 did not vary greatly.However, Al2O3 showed a weak decreasing trend with the increasing distance from the pegmatite contact zone, while Fe2O3 and CaO showed an increasing trend. The contents of Li, Rb, and Cs in the altered host rocks were much higher than those in the unaltered host rocks, decreasing with distance from the contact. The chondrite-normalized rare earth element（REE） pattern of the altered and unaltered host rock was right-inclined from La to Lu, but enriched in light REEs over heavy REEs after hydrothermal alteration. An isocon plot shows that some oxides migrated in with an order of P2O5〉K2O 〉TiO2〉Al2O3〉SiO2〉MnO≥MgO, while others migrated out with an order of Na2O 〉CaO 〉Fe2O3. For REEs, the migration ratios are positive values withCs 〉Rb 〉Li 〉Nb 〉Ta 〉Be, signifying that all REEs migrated from the exsolved magmatic fluid into the altered host rocks. It was concluded that diffusion was the only mechanism for migration of ore-forming elements in the alteration zone. The effective diffusion coefficients（Deff）of LiF, RbF, and CsF were estimated under a fluid temperature of 500–550℃. Using a function of concentration（C（x,t）） and distance（x）, the order of migration distance was determined to be LiF 〉CsF 〉RbF, with diffusion times of （3.39 ± 0.35）× 10^6,（3.19 ± 0.28） × 10^5 and（6.33 ± 0.05） × 10^5 years, respectively.展开更多
In this study,the original tourmaline and beryl mineral samples have been collected from a Brazilian pegmatite.The objective of this study was to examine the adsorption behavior of Brazilian ciclosilicate samples,towa...In this study,the original tourmaline and beryl mineral samples have been collected from a Brazilian pegmatite.The objective of this study was to examine the adsorption behavior of Brazilian ciclosilicate samples,towards divalent metals(Pb 2+,Mn 2+,and Zn 2+) in ethanol solution has been studies by a batch technique.The ciclosilicate samples were characterized by elemental analysis,Fourier transform infrared spectroscopy,helium picnometry,mercury porosity,and nitrogen adsorption-desorption.The Langmuir expression for adsorption isotherm was applied in order to determine the adsorption capacity to form a monolayer and the constant related to the adsorption intensity.In aqueous solution there was a significant adsorption increase with the temperature and pronounced synergistic effects were observed.The maximum number of moles adsorbed was determined to be 12.48 and 11.49 mmol/g for systems Pb 2+ /beryl and Pb 2+ /tourmaline,respectively.The energetic effects caused by metal cations adsorption were determined through calorimetric titrations.Thermodynamics indicated the existence of favorable conditions for such Pb 2+-,Mn 2+-,and Zn 2+-OH interactions.展开更多
Hyalophane-rich pegmatites are identified from the Manjinggou high-pressure granulite terrain in the Central Zone of North China Craton. Based on field investigation, mineral assemblage and mineral geochemistry, two t...Hyalophane-rich pegmatites are identified from the Manjinggou high-pressure granulite terrain in the Central Zone of North China Craton. Based on field investigation, mineral assemblage and mineral geochemistry, two types of pegmatites can be defined, i.e., hyalophane pegmatite and hyalophane-rich pegmatite. The hyalophane pegmatite is composed of pure hyalophane with 18.7 mol%-19.4 mol% celsian, whereas the hyalophane-rich pegmatite consists of clinopyroxene + titanite + epidote + hyalophane with 11.9 mol%-12.5 mol% celsian. Hyalophane-rich pegmatite has typical magmatic zircons with oscillatory zoning and high Th/U ratios, implying that this type of pegmatite crystallized from special melt similar to magma. SIMS (Cameca 1280) zircon U-Pb dating shows that the crystallization age of the hyalophane-rich pegmatite is 1812±5 Ma, younger than the regional metamorphic age (peak of ca. 1.85 Ga). Zircon δ18O (8.0 ‰-9.3 ‰) and ?Hf (-7.0 to-2.7) values measured by SIMS suggest that the high-pressure granulite terrain was the source of these veins. Therefore, the hyalophane-rich pegmatite veins were likely to be generated by melting of the high-pressure granulite terrain during post collisional uplift. A quick tectonic uplifting process with a velocity of 0.4 to 0.6 mm/a has been estimated for the high-pressure granulite terrane from the Central Zone of North China Craton.展开更多
基金supported jointly by the Natural Science Foundation of China (Grant No.41372104)Research Project of Xinjiang Nonferrous Metals Industry (Group) Co.,Ltd.(Grant No.YSKY2011-02)
文摘Petrography and geochemistry of the altered and unaltered host rocks surrounding the Koktokay No.3 pegmatite revealed that the unaltered amphibolite is mainly composed of hornblende, plagioclase, and ilmenite.Beyond these primary components, the altered host rocks contain a few newly formed minerals, including biotite,tourmaline, chlorine, and muscovite. The alteration zone surrounding the Koktokay No.3 pegmatite is limited to 2.0 m, characterized by biotitization, tourmalization, and chloritization. In the altered host rocks, the contents of SiO2, MgO, MnO, Na2O, and TiO2 did not vary greatly.However, Al2O3 showed a weak decreasing trend with the increasing distance from the pegmatite contact zone, while Fe2O3 and CaO showed an increasing trend. The contents of Li, Rb, and Cs in the altered host rocks were much higher than those in the unaltered host rocks, decreasing with distance from the contact. The chondrite-normalized rare earth element（REE） pattern of the altered and unaltered host rock was right-inclined from La to Lu, but enriched in light REEs over heavy REEs after hydrothermal alteration. An isocon plot shows that some oxides migrated in with an order of P2O5〉K2O 〉TiO2〉Al2O3〉SiO2〉MnO≥MgO, while others migrated out with an order of Na2O 〉CaO 〉Fe2O3. For REEs, the migration ratios are positive values withCs 〉Rb 〉Li 〉Nb 〉Ta 〉Be, signifying that all REEs migrated from the exsolved magmatic fluid into the altered host rocks. It was concluded that diffusion was the only mechanism for migration of ore-forming elements in the alteration zone. The effective diffusion coefficients（Deff）of LiF, RbF, and CsF were estimated under a fluid temperature of 500–550℃. Using a function of concentration（C（x,t）） and distance（x）, the order of migration distance was determined to be LiF 〉CsF 〉RbF, with diffusion times of （3.39 ± 0.35）× 10^6,（3.19 ± 0.28） × 10^5 and（6.33 ± 0.05） × 10^5 years, respectively.
基金The authors are indebted to CNPq for fellowships and CAPES for financial support
文摘In this study,the original tourmaline and beryl mineral samples have been collected from a Brazilian pegmatite.The objective of this study was to examine the adsorption behavior of Brazilian ciclosilicate samples,towards divalent metals(Pb 2+,Mn 2+,and Zn 2+) in ethanol solution has been studies by a batch technique.The ciclosilicate samples were characterized by elemental analysis,Fourier transform infrared spectroscopy,helium picnometry,mercury porosity,and nitrogen adsorption-desorption.The Langmuir expression for adsorption isotherm was applied in order to determine the adsorption capacity to form a monolayer and the constant related to the adsorption intensity.In aqueous solution there was a significant adsorption increase with the temperature and pronounced synergistic effects were observed.The maximum number of moles adsorbed was determined to be 12.48 and 11.49 mmol/g for systems Pb 2+ /beryl and Pb 2+ /tourmaline,respectively.The energetic effects caused by metal cations adsorption were determined through calorimetric titrations.Thermodynamics indicated the existence of favorable conditions for such Pb 2+-,Mn 2+-,and Zn 2+-OH interactions.
基金supported by National Natural Science Foundation of China (Grant Nos. 40730315 and 41023009)State Key Laboratory of Lithospheric Evolution
文摘Hyalophane-rich pegmatites are identified from the Manjinggou high-pressure granulite terrain in the Central Zone of North China Craton. Based on field investigation, mineral assemblage and mineral geochemistry, two types of pegmatites can be defined, i.e., hyalophane pegmatite and hyalophane-rich pegmatite. The hyalophane pegmatite is composed of pure hyalophane with 18.7 mol%-19.4 mol% celsian, whereas the hyalophane-rich pegmatite consists of clinopyroxene + titanite + epidote + hyalophane with 11.9 mol%-12.5 mol% celsian. Hyalophane-rich pegmatite has typical magmatic zircons with oscillatory zoning and high Th/U ratios, implying that this type of pegmatite crystallized from special melt similar to magma. SIMS (Cameca 1280) zircon U-Pb dating shows that the crystallization age of the hyalophane-rich pegmatite is 1812±5 Ma, younger than the regional metamorphic age (peak of ca. 1.85 Ga). Zircon δ18O (8.0 ‰-9.3 ‰) and ?Hf (-7.0 to-2.7) values measured by SIMS suggest that the high-pressure granulite terrain was the source of these veins. Therefore, the hyalophane-rich pegmatite veins were likely to be generated by melting of the high-pressure granulite terrain during post collisional uplift. A quick tectonic uplifting process with a velocity of 0.4 to 0.6 mm/a has been estimated for the high-pressure granulite terrane from the Central Zone of North China Craton.
