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高振动激发态吡嗪碰撞传能的QCT计算研究
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作者 周建华 马万勇 +3 位作者 姜海辉 张纪明 王少坤 顾月姝 《物理化学学报》 SCIE CAS CSCD 北大核心 2005年第4期388-391,共4页
用准经典轨线(QCT)方法计算了高振动激发态吡嗪(C4N2H4)与N2、O2、NH3、基态吡嗪之间的碰撞传能.C4N2H4通过计算发现,高振动激发态C4N2H4与N2、O2碰撞发生的主要是V鄄V传能,与NH3碰撞发生的主要是V鄄R传能,与基态C4N2H4碰撞发生的主要是... 用准经典轨线(QCT)方法计算了高振动激发态吡嗪(C4N2H4)与N2、O2、NH3、基态吡嗪之间的碰撞传能.C4N2H4通过计算发现,高振动激发态C4N2H4与N2、O2碰撞发生的主要是V鄄V传能,与NH3碰撞发生的主要是V鄄R传能,与基态C4N2H4碰撞发生的主要是V鄄V(R)传能.通过比较高振动激发态C4N2H4、C6F6、C6H6与其基态分子的碰撞传能,发现此类碰撞传能中,若分子的对称性高,则V鄄V传能更容易实现. 展开更多
关键词 吡嗪 高振动激发态 碰撞传能 QCT计算 传能机理
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Numerical Simulation of Hot Spot Growth in Detonation with Regard to the Turbulent Mechanism of Energy Transfer
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作者 Yury Vasilyevich Yanilkin Vitaly Grigoryevich Morozov Irina Isorevna Karpenko Olga Nikolaevna Chernyshova 《Journal of Physical Science and Application》 2015年第3期226-237,共12页
The paper presents the results of numerical modeling of hot spot growth process in detonation with account for turbulent mixing. The performed investigation has shown that large-scale HE (High explosives) particles ... The paper presents the results of numerical modeling of hot spot growth process in detonation with account for turbulent mixing. The performed investigation has shown that large-scale HE (High explosives) particles mix up and split down to smaller sizes in the result of shock wave impact, instability development on the HE-EP (Explosion product) interface and vortex flow; at these sizes, due to the developed surface of the HE-EP contact, HE has enough time to get heated (energy transfer from EP), and the decomposition reaction effectively continues. Numerical modeling make the calculation of the hot spot growth rate (about 100-200 m/s) possible. This has proved the hypothesis saying that at mechanical material transport the turbulence in the reaction zone plays an important role and it must be taken into account in the detonation theory. 展开更多
关键词 Hot spot DETONATION turbulent mixing numerical simulation.
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铱(Ir^Ⅲ)-稀土(Ln^Ⅲ)异核配合物发光性能研究 被引量:1
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作者 禹钢 卞祖强 +1 位作者 刘志伟 黄春辉 《中国科学:化学》 CSCD 北大核心 2014年第2期267-276,共10页
稀土离子(LnⅢ)丰富的4f电子跃迁能级,使稀土发光材料获得重要而广泛的应用.稀土配合物中天线基团的引入,弥补了稀土离子f-f跃迁禁阻而导致吸收较低的不足.而具有三重态吸收的过渡金属配合物作为天线基团,更使稀土离子的激发窗口红移.... 稀土离子(LnⅢ)丰富的4f电子跃迁能级,使稀土发光材料获得重要而广泛的应用.稀土配合物中天线基团的引入,弥补了稀土离子f-f跃迁禁阻而导致吸收较低的不足.而具有三重态吸收的过渡金属配合物作为天线基团,更使稀土离子的激发窗口红移.相关研究具有重要的理论意义和实际应用价值.本文主要综述近年来有关铱(IrⅢ)-稀土(LnⅢ)异核发光配合物方面的研究进展. 展开更多
关键词 稀土发光 异核配合物 传能机理
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High mixing effectiveness lobed nozzles and mixing mechanisms 被引量:3
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作者 SHENG ZhiQiang CHEN ShiChun +1 位作者 WU Zhe HUANG PeiLin 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2015年第7期1218-1233,共16页
For a circular lobed nozzle with the exit plane displaced from the center body,adding a central plug at exit or replacing the nozzle with an alternating-lobe nozzle can improve the mixing effectiveness.In this study,n... For a circular lobed nozzle with the exit plane displaced from the center body,adding a central plug at exit or replacing the nozzle with an alternating-lobe nozzle can improve the mixing effectiveness.In this study,numerical investigations of jet mixing in the lobed nozzles with a central plug and alternating-lobe nozzles in pumping operation were conducted.The effects of the central plugs with the wake ranging from attached to separated flow on the mixing were analyzed,along with the mechanism of improving the mixing performance in a"sword"alternating-lobe nozzle.The simulation results reveal that the large-scale mixing rate,which is dominated by streamwise vortices,is related to the intensity of the attainable heat and mass transfer in the streamwise vortices.The effects of the streamwise vortices on the normal vortex ring are virtually a manifestation of the heat and mass transfer/mixing process of the streamwise vortices.The simulation results also show that the central plug with the attached rear-flow performs better in improving the mixing effectiveness and pumping performance;on the contrary,if the rear-flow is separated,more pressure loss will be induced.In particular,a completely separated flow over the rear of the central plug will severely degrade the attainable heat and mass transfer in the streamwise vortices.For the sword alternating-lobe nozzle,wider sword deep troughs help to increase the flux of the secondary stream around the core region and delay the confluence of the primary stream in the region between the deep and shallow troughs.Thus,the mixing is improved in the middle and posterior segments.Compared to the lobed nozzle with a central plug,the improved sword alternating-lobe nozzle can achieve a higher mixing effectiveness with much less pressure loss,which is preferred in situations when the power loss of the engine is restricted. 展开更多
关键词 jet mixing lobed nozzle mixing effectiveness streamwise vortices heat and mass transfer
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