0.5eV时H^++D_2(v=0,j=0)反应的微分、积分截面

基于ab initio势能面(KBNN PES)[1],用耦合通道超球坐标理论研究了碰撞能等于0.5 eV时H++D2(v=0,j=0)的积分,微分截面.对于反应性碰撞,计算的积分截面表明由于深势阱的存在使得这一绝热反应产物的分布表现出一种近似的统计行为.计算的微分截面反映该体系存在着长寿命的中间络合物;对于非反应性碰撞(传能过程),平动—平动传能过程更有效,且其积分截面随着转动量子数的增大而显著减少.通过反应性碰撞和非反应性碰撞积分截面的比较,发现在低能碰撞情况,非反应性碰撞更容易进行.

Convective Heat Transfer Enhancement of a Rectangular Flat Plate by an Impinging Jet in Cross Flow

Experiments were carried out to study the heat transfer performance of an impinging jet in a cross flow.Several parameters including the jet-to-cross-flow mass ratio(X=2%-8%), the Reynolds number(Red=1434-5735)and the jet diameter(d=2-4 mm) were explored. The heat transfer enhancement factor was found to increase with the jet-to-cross-flow mass ratio and the Reynolds number, but decrease with the jet diameter when other parameters maintain fixed. The presence of a cross flow was observed to degrade the heat transfer performance in respect to the effect of impinging jet to the target surface only. In addition, an impinging jet was confirmed to be capable of enhancing the heat transfer process in considerable amplitude even though the jet was not designed to impinge on the target surface.

The Pressure Gradient Elastic Wave： Energy Transfer Process for Compressible Fluids with Pressure Gradient

The temperature separation was discovered inside the short vortex chamber （H/D = 0.18）. Experiments revealed that the highest temperature of the periphery was 465 ℃, and the lowest temperature of the central zone was -45 ℃ （the compressed air was pumped into the chamber at room temperature）. The objective of this paper is to proof that this temperature separation effect cannot be explained by conventional heat transfer processes. To explain this phenomenon, the concept of PGEW （Pressure Gradient Elastic Waves） is proposed. PGEW are kind of elastic waves, which operate in compressible fluids with pressure gradients and density fluctuations. The result of PGEW propagation is a heat transfer from area of low pressure to high pressure zone. The physical model of a gas in a strong field of mass forces is proposed to substantiate the PGEW existence. This physical model is intended for the construction of a theory of PGEW. Understanding the processes associated with the PGEW permits the possibility of creating new devices for energy saving and low potential heat utilization, which have unique properties.

Stimuli-responsive Membranes： Smart Tools for Controllable Mass-transfer and Separation Processes

As emerging artificial biomimetic membranes, smart or intelligent membranes that are able to respond to environmental stimuli are attracting ever-increasing interests from various fields. Their permeation properties including hydraulic permeability and diffusional permeability can be dramatically controlled or adjusted self-regulatively in response to small chemical and/or physical stimuli in their environments. Such environmental stimuli-responsive smart membranes could find myriad applications in numerous fields ranging from controlled release to separations. Here the trans-membrane mass-transfer and membrane separation is introduced as the beginning to initiate the requirement of smart membranes, and then bio-inspired design of environmental stimuli-responsive smart membranes and four essential elements for smart membranes are introduced and discussed. Next, smart membrane types and their applications as smart tools for controllable mass-transfer in controlled release and separations are reviewed. The research tooics in the near future are also suggested.

Oscillation heat transfer dynamic model for new type oscillation looped heat pipe with double liquid slugs

In order to explain the oscillation heat transfer dynamics of closed loop oscillation heat pipe (CLOHP) with two liquid slugs,analysis on the forces and heat transfer process of the partial gas-liquid phase system involving multiple parameters was carried out,and a new type oscillation heat transfer dynamic model of the CLOHP was set up based on conservation laws of mass,momentum and energy.Application results indicate that its oscillation heat transfer dynamics features depend largely on the filling rate,pipe diameter and difference in temperature.Besides,oscillation intensity and transfer performance can be improved to a large extent by increasing the temperature difference properly and enlarging the pipe diameter within a certain range under a certain filling rate.

Numerical Simulation of Hot Spot Growth in Detonation with Regard to the Turbulent Mechanism of Energy Transfer

The paper presents the results of numerical modeling of hot spot growth process in detonation with account for turbulent mixing. The performed investigation has shown that large-scale HE （High explosives） particles mix up and split down to smaller sizes in the result of shock wave impact, instability development on the HE-EP （Explosion product） interface and vortex flow; at these sizes, due to the developed surface of the HE-EP contact, HE has enough time to get heated （energy transfer from EP）, and the decomposition reaction effectively continues. Numerical modeling make the calculation of the hot spot growth rate （about 100-200 m/s） possible. This has proved the hypothesis saying that at mechanical material transport the turbulence in the reaction zone plays an important role and it must be taken into account in the detonation theory.

Effects of Service Standards Communication and Servant Leadership on Strategic Competence and Customer Orientation

Service standards communication and servant leadership are both important mechanisms to improve an organization＇s service process. Therefore, they are likely to affect strategic competence and customer orientation skills of organizations. In this research, customer orientation and strategic competence are undertaken in relation with servant leadership and service standards communication, using a sample of 106 Turkish firms＇ executive assistants. The results prove that service standards communication and servant leadership have a strong positive relationship with both strategic competence and customer orientation.

Design and Implementation of Image Acquisition System Based on STM32

In order to solve the difficulty of reading inconvenience in the measurement process of digital track gauge, a kind of image data acquisition system with low cost and stable performance is designed. The system uses the Cortex-M4 as the core of the STM32F407ZGT6 as the control core, the use of OV2640 as an image sensor to collect images, and the collection of image files stored in the SD card for subsequent image processing to achieve the goal of rail adjustment to lay the foundation. The experimental results show that the image acquisition is stable and refiable and the collected images are clear and meet the design requirements.

高大空间空气载能辐射末端热环境与传能研究

本文以内设空气载能辐射空调系统的某火车站候车厅为研究对象,利用FLUENT数值模拟的方法,分析研究了房间人体活动区域内空气工况参数和系统传能过程。模拟结果显示,该房间室内空气温湿度分布较均匀,未出现结露现象。且在传能过程中,系统总冷负荷约为119 KW,空气载能辐射空调系统承担92%的冷负荷;其中,辐射换热占房间总负荷64.2%,对流换热占29.1%,由此可得系统以辐射换热为主;相较于金属平板辐射空调系统,该系统新增的对流换热量包括载能空气与辐射孔板间的对流换热量以及循环流动的交换能量;经计算,在相同模拟条件下,该系统总换热量较金属平板辐射空调系统超出约10%以上。综上,该系统在理论上基本符合高大空间建筑夏季负荷大,强调舒适节能的要求。

Progress of entransy analysis on the air-conditioning system in buildings

It is of great importance to improve the energy performance of the air-conditioning system for building energy conversation. Entransy provides a novel perspective to investigate the losses existing in the air-conditioning system. The progress of entransy analysis in the air-conditioning system is comprehensively investigated in the present study. Firstly missions and characteris- tics of the air-conditioning system are analyzed with emphasis on heat or mass transfer process. It is found that reducing the temperature difference, i.e. reducing the entransy dissipation helps to improve the performance. Entransy dissipations and thermal resistances of typical transfer processes in the air-conditioning system are presented. Characteristics of sensible heat transfer process and coupled heat and mass transfer processes are researched in terms of entransy dissipation analysis. Reasons leading to entransy dissipation are also clarified with the help of unmatched coefficient 4. Principles for reducing the entransy dissipation and constructing a high temperature cooling system are summarized on the basis of case studies in typical handling processes. It＇s recommended that reducing mixing process, improving match properties are main approaches to reduce the entransy dissipation. The present analysis is beneficial to casting light on the essence of the air-conditioning system and proposing novel approaches for performance optimization.

An Experimental Investigation on Heat Transfer Performance of Nanofluid Pulsating Heat Pipe

The effect of SiO2 particles on heat transfer performance of a pulsating heat pipe （PHP） was investigated experi- mentally. DI water was used as the base fluid and contrast medium for the PHP. In order to study and measure the character, there are SiO2/H20 nanofluids with different concentration and applying with various heating powers during the experiment investigation. According to the experimental result, the high fraction of SiO2/H20 will de- teriorate the performance of PHP compared with DI water, i.e. the thermal resistance and the temperature of evaporation section increases. It is in contrary in the case of low fraction of SiO2/H20. Finally, the comparison of the thermal performances between the normal operation system and the static settlement system is given. It is found that both the thermal resistance of nanofluid PHP and the temperature of the evaporation section increase after standing for a period, and it is the same trend for the temperature fluctuation at the identical heating power for PHP.

MgF_(2):Mn^(2+):novel material with mechanically-induced luminescence

Mechanoluminescent(ML)materials can directly convert external mechanical stimulation into light without the need for excitation from other forms of energy,such as light or electricity.This alluring characteristic makes ML materials potentially applicable in a wide range of areas,including dynamic imaging of force,advanced displays,information code,storage,and anti-counterfeiting encryption.However,current reproducible ML materials are restricted to sulfide-and oxide-based materials.In addition,most of the reported ML materials require pre-irradiation with ultraviolet(UV)lamps or other light sources,which seriously hinders their practical applications.Here,we report a novel ML material,MgF_(2):Mn^(2+),which emits bright red light under an external dynamic force without the need for pre-charging with UV light.The luminescence properties were systematically studied,and the piezophotonic application was demonstrated.More interestingly,unlike the well-known zinc sulfide ML complexes reported previously,a highly transparent ML film was successfully fabricated by incorporating MgF_(2):Mn^(2+)into polydimethylsiloxane(PDMS)matrices.This film is expected to find applications in advanced flexible optoelectronics such as integrated piezophotonics,artificial skin,athletic analytics in sports.

Natural convection heat transfer of molten salt in a single energy storage tank

Heat transfer in molten salt in a cylinder tank is studied via simulation and experiment to obtain its natural convection heat transfer in a single energy storage tank. Simulation and experimental results show that the natural convection heat transfer of water in a cylinder tank fits well with Garon＇s correlation. However, significant deviations occur when Garon＇s correlation is used to predict the natural convection heat transfer of molten salt because of its high viscosity and low thermal conductivity. However, the simulated data of the natural convection heat transfer of molten salt fit well with those of the experimental results Thus, a correlation that considers the effect of variable physical properties is proposed in this study to predict the natural con- vection heat transfer of molten salt. The deviation of the present data from the proposed correlation is less than ＋20%. The re- sults of this study can serve as a basis for the design of single energy storage tanks.

Mathematical Modeling of Heat Transfer Processes of Coal Waste Combustion in a Chamber of Automated Energy Generating Complex

The automated energy generating complex allows obtaining heat energy from waste coal-water slurry fuel （WCF） that is a mixture of fine coal particles from coal enrichment wastes with water. The mixture is blown into the swirl chamber under the pressure through the special sprayers. The received heat energy is used in different ways. One of the important issues is to estimate the heat losses through the walls of this chamber. In this paper we solved the boundary problem of mathematical physics to estimate the temperature fields in the walls of the swirl chamber. The obtained solution allows us to estimate the heat losses through the waUs of the swid chamber. The task of the mathematical physics has been solved by a numerical finite-difference method. The method for solving this prob- lem can be used in the calculation of temperature fields and evaluation of heat losses in other thermal power units.

White-light upconversion emission of lanthanide double-doped oxide nanoparticles via defect state luminescence of ZnO

The white upconversion luminescence （UCL） of upconversion nanoparticles （UCNPs） is mainly made up of the color red, green and blue. Interestingly, the white-light-emitting UCNPs can be obtained via a complex method of tridoping lanthanide ions such as Yb^3＋, Er^3＋, and Tm^3＋. We herein report that an excellent white UCL can be obtained from Yb/Tm double-doped ZnO. In this system, the blue and red UCL-emissions around 475 and 652 nm originate from ^1G4→^3H6 and ^1G4→^3F4 transition of Tm^3＋, respectively, and the green one can be attributed to the defect states （oxygen va- cancies） luminescence （DSL） of the ZnO host. Meanwhile, the fine nanostructure of ZnO：Yb/Tm is prepared by adjusting the concentration of OH-. Particularly, the one dimentional pencil-shaped nanorods with high aspect ratio achieve a strong green DSL emission due to the high concentration of oxygen vacancy. The oxygen vacancy defects play an irreplaceable role in affecting the intensities of blue and red UCL by acting as the intermediate state in the energy transfer process. More importantly, we demonstrate that the DSL and UCL can be combined into systems, paving a new road for obtaining the white UCL emission.

Investigation on thermophysical properties of reactive powder concrete

The thermophysical properties,such as thermal conductivity,thermal diffusivity,specific heat capacity and linear thermal expansion of reactive powder concrete(RPC) with different steel fiber volumetric fractions are investigated by means of high temperature tests. The thermophysical characteristics of RPC with different fiber volumes under different temperatures are analyzed and compared with those of the common high-strength concrete and high-performance concrete. The empirical relationships of thermophysical properties with temperature and fiber volume are identified. By the heat transfer and solid physics methods,the microscopic physical mechanism of heat transfer process and heat conduction properties of RPC are investigated,and the theoretical formulas of specific heat capacity and thermal expansion coefficient are derived,respectively. The effects of temperature and steel fibers on the specific heat capacity and the thermal expansion coefficient are quantitatively analyzed and the discriminant conditions are provided. It is shown that the experimental results are consistent with the theoretical prediction.

Broadband near-infrared luminescence and energy trans-fer in Bi singly-doped and Bi/Yb co-doped titanate glasses

Super-broadband near-infrared(NIR)emission from 1100 nm to 1600 nm is observed in Bi-doped titanate glasses at the excitation of 808 nm laser diode(LD).The effects of Bi content on the optical spectra are investigated.It is also found that the Bi-related emission intensity can be enhanced by Yb3+co-doping at the excitation of 980 nm LD.It should be ascribed to the energy transfer from Yb3+to active Bi ions.The energy transfer processes are studied based on the Inokuti-Hirayama(I-H)model,and the energy transfer of electric dipole-dipole interaction is confirmed to be dominant in Bi/Yb co-doped glasses.

Constraints on the Distortion of Area Objects in the Process of Map Objects Displacement

The displacement operator is an important and still a hot topic in map generalization. In the generalization product, symbols must be unambiguous and easily perceived and readily understood, which makes space competition among features an important obstacle in the process of map objects displacement. Space conflict between objects, through propagation process, may be spread and more objects may drift into it. In order to maintain symbols equilibrium and spatial relationship between objects, some unimportant symbols or parts of symbols should be distorted under constraints according to visual graphic resolution thresholds to figure out space competition among map features. Three constraints including position, legibility and characteristics are important for the maintenance of symbols equilibrium and spatial relationship, which are discussed in this paper. The skeleton is introduced to represent area objects figure characteristic, in which an area object can be separated to parts hierarchically according to their importance in the construction. Then, the finite element method is applied to the map objects’ displacement and distortion, in which a strategy for the parameters of finite element method is discussed.