Toprovide a theoretical basis for optimizing the pervaporation procedure, a mass transfer model for pervaporation for binary mixtures was developed basedon the multi-fields synergy theory. This model used the mechanis...Toprovide a theoretical basis for optimizing the pervaporation procedure, a mass transfer model for pervaporation for binary mixtures was developed basedon the multi-fields synergy theory. This model used the mechanism of sorption-diffusion-desorption and introduced a diffusion coefficient, which was dependent on the feed concentration and temperature. Regarding the strong coupling effect in the mass transfer, the concentration distribution in membrane was predicted using the Flory-Huggins thermodynamic theory. The batch experiments and other experiments with constant composition-were conducted-using a modified chitosan pervaporatioffmembrane to separate tert-butyl alcohol （TBA）-water mixtures. The parameters of the mass transfer model were obtained from the flux of the experiments with a constant composition and the activity coefficients available through phase equilibrium equation, using the Willson equation in the feed side and the Flory-Huggins thermodynamic theory within the membrane The simulation results of the experiments .are in good agreement with the results, of the experiments.展开更多
This paper presents a study on the criterion of crack initiation and propagation under creep conditions, which were investigated using specimens collected from outcropped sandstone rock formations. Beam specimens unde...This paper presents a study on the criterion of crack initiation and propagation under creep conditions, which were investigated using specimens collected from outcropped sandstone rock formations. Beam specimens under three points bending were used in this investigation. The experimental result shows that due to creep deformation, rock crack will inevitably initiate and propagate after a time interval of sustained loading under a load of K I , which is less than fracture toughness K IC but not less than a constant marked as K IC2 . K IC2 indicates the ability of rock to resist crack initiation and propagation under creep conditions and it is defined as creep fracture toughness.展开更多
基金Supported by the Key Project of National Natural Science Foundation of China （No.20436040）, and the National Natural Science Foundation of China （No.20476084, No.20776117）.
文摘Toprovide a theoretical basis for optimizing the pervaporation procedure, a mass transfer model for pervaporation for binary mixtures was developed basedon the multi-fields synergy theory. This model used the mechanism of sorption-diffusion-desorption and introduced a diffusion coefficient, which was dependent on the feed concentration and temperature. Regarding the strong coupling effect in the mass transfer, the concentration distribution in membrane was predicted using the Flory-Huggins thermodynamic theory. The batch experiments and other experiments with constant composition-were conducted-using a modified chitosan pervaporatioffmembrane to separate tert-butyl alcohol （TBA）-water mixtures. The parameters of the mass transfer model were obtained from the flux of the experiments with a constant composition and the activity coefficients available through phase equilibrium equation, using the Willson equation in the feed side and the Flory-Huggins thermodynamic theory within the membrane The simulation results of the experiments .are in good agreement with the results, of the experiments.
文摘This paper presents a study on the criterion of crack initiation and propagation under creep conditions, which were investigated using specimens collected from outcropped sandstone rock formations. Beam specimens under three points bending were used in this investigation. The experimental result shows that due to creep deformation, rock crack will inevitably initiate and propagate after a time interval of sustained loading under a load of K I , which is less than fracture toughness K IC but not less than a constant marked as K IC2 . K IC2 indicates the ability of rock to resist crack initiation and propagation under creep conditions and it is defined as creep fracture toughness.
