The Zn(Ⅱ) phthalocyanine sensitized TiO2(ZnPc-TiO2) nanoparticles were prepared by hydrothermal method via impregnation with ZnPc.The as-prepared photocatalysts were characterized by X-ray diffractometry(XRD) and dif...The Zn(Ⅱ) phthalocyanine sensitized TiO2(ZnPc-TiO2) nanoparticles were prepared by hydrothermal method via impregnation with ZnPc.The as-prepared photocatalysts were characterized by X-ray diffractometry(XRD) and diffuse reflectance spectroscopy(DRS),and the surface photovoltage spectroscopy(SPS) and photocatalytic degradation of rhodamine B(RhB) were studied under illuminating.The experimental results indicate that TiO2 sensitized by ZnPc extends its absorption band into the visible region effectively,and the sensitized TiO2 has higher activity than TiO2(Degussa P-25) under the simulated solar light and the visible light.Based on the DRS and SPS results,the mechanism about the photogenerated carrier transfer between TiO2 and ZnPc is proposed.At a lower ZnPc content(≤0.20 μmol/g),ZnPc monomer acts as the electron donor,which provides the photoinduced electrons to the conduction band of TiO2.These photoinduced electrons can transfer to molecular oxygen(O2),leading to the formation of active species,such as superoxide/hydroxide radicals and singlet oxygen,which is beneficial to the photocatalytic reaction.While at a higher ZnPc content(>0.20 μmol/g),the formation of ZnPc dimer results in the decrease of photocatalytic activities of ZnPc-TiO2 photocatalyst.展开更多
The essential requirements of the end-effector of large space manipulator are capabilities of misalignment tolerance and soft capture.According to these requirements,an end-effector prototype combining the tendon-shea...The essential requirements of the end-effector of large space manipulator are capabilities of misalignment tolerance and soft capture.According to these requirements,an end-effector prototype combining the tendon-sheath transmission system with steel cable snaring mechanism was manufactured.An analysis method based on the coordinate transformation and the projection of key points of the mechanical interface was proposed,and it was a guideline of the end-effector design.Furthermore,the tendon-sheath transmission system was employed in the capture subassembly to reduce the inertia of the capture mechanism and enlarge the capture space.The capabilities of misalignment tolerance and soft capture were validated through the dynamic simulation in ADAMS software.The results of the capture simulation and experiment show that the end-effector has outstanding capabilities of misalignment tolerance and soft capture.The translation misalignments in radial directions are±100 mm,and angular misalignments about pitch and yaw are±15°.展开更多
Underwater wireless sensor networks(UWSNs) have attracted wide attention in recent years.The capacity research on it is still in the initial stage,lacking adequate performance evaluation for network construction.This ...Underwater wireless sensor networks(UWSNs) have attracted wide attention in recent years.The capacity research on it is still in the initial stage,lacking adequate performance evaluation for network construction.This paper will focus on this subject by theoretical analysis and simulation,aiming to provide some insights for the actual UWSNs construction.According to the structure features of cluster-based UWSNs and the propagation characteristics of underwater acoustic signal,with the combination of signal to interference plus noise ratio,we define some capacity performance metrics,such as outage probability and transmission capacity.Based on the theory of stochastic geometry,a network capacity analytical model used in the cluster-based UWSNs is presented.The simulation results verify the validity of the theoretical analysis,and the cause of error between theoretical and simulation results has also been clearly explained.展开更多
In order to save energy consumption of two-way amplifier forward(AF) relaying with channel estimation error, an energy efficiency enhancement scheme is proposed in this work. Firstly, through the analysis of two-way A...In order to save energy consumption of two-way amplifier forward(AF) relaying with channel estimation error, an energy efficiency enhancement scheme is proposed in this work. Firstly, through the analysis of two-way AF relaying mode with channel estimation error, the resultant instantaneous SNRs at end nodes is obtained. Then, by using a high SNR approximation, outage possibility is acquired and its simple closed-form expression is represented. Specially, for using the energy resource more efficiently, a low-complexity power allocation and transmission mode selection policy is proposed to enhance the energy efficiency of two-way AF relay system. Finally, relay priority region is identified in which cooperative diversity energy gain can be achieved. The computer simulations are presented to verify our analytical results, indicating that the proposed policy outperforms direct transmission by an energy gain of 3 dB at the relative channel estimation error less than 0.001. The results also show that the two-way AF relaying transmission loses the two-way AF relaying transmission loses its superiority to direct transmission in terms of energy efficiency when channel estimation error reaches 0.03.展开更多
A novel intelligent drug delivery system potential for the more effective therapy of the diabetics was proposed, and the composition of system was analyzed. Based on the design of micro-electro-mechanical systems (MEM...A novel intelligent drug delivery system potential for the more effective therapy of the diabetics was proposed, and the composition of system was analyzed. Based on the design of micro-electro-mechanical systems (MEMS), an iterative modeling process was introduced. Unified modeling language (UML) was em-ployed to describe the function requirement, and different diagrams were built up to explore the static model, the dynamic model and the employment model. The mapping analysis of different diagrams can simply verify the consistency and completeness of the system model.展开更多
Ceramic electrolytes are important in ceramic-liquid hybrid electrolytes(CLHEs),which can effectively solve the interfacial issues between the electrolyte and electrodes in solid-state batteries and provide a highly e...Ceramic electrolytes are important in ceramic-liquid hybrid electrolytes(CLHEs),which can effectively solve the interfacial issues between the electrolyte and electrodes in solid-state batteries and provide a highly efficient Li-ion transfer for solid–liquid Li metal batteries.Understanding the ionic transport mechanisms in CLHEs and the corresponding role of ceramic electrolytes is crucial for a rational design strategy.Herein,the Li-ion transfer in the ceramic electrolytes of CLHEs was confirmed by tracking the 6Li and 7Li substitution behavior through solid-state nuclear magnetic resonance spectroscopy.The ceramic and liquid electrolytes simultaneously participate in Li-ion transport to achieve highly efficient Li-ion transfer in CLHEs.A spontaneous Li-ion exchange was also observed between ceramic and liquid electrolytes,which serves as a bridge that connects the ceramic and liquid electrolytes,thereby greatly strengthening the continuity of Li-ion pathways in CLHEs and improving the kinetics of Li-ion transfer.The importance of an abundant solid–liquid interface for CLHEs was further verified by the enhanced electrochemical performance in LiFePO4/Li and LiNi0.8Co0.1Mn0.1O2/Li batteries from the generated interface.This work provides a clear understanding of the Li-ion transport pathway in CLHEs that serves as a basis to build a universal Li-ion transport model of CLHEs.展开更多
In this study,a porous inorganic/organic(ZnO/PEIE,where PEIE is polyethylenimine ethoxylated)(P-ZnO)hybrid material has been developed and adopted in the inverted organic solar cells(OSCs).The P-ZnO serving as the ele...In this study,a porous inorganic/organic(ZnO/PEIE,where PEIE is polyethylenimine ethoxylated)(P-ZnO)hybrid material has been developed and adopted in the inverted organic solar cells(OSCs).The P-ZnO serving as the electron transport layer(ETL)not only presents an ameliorative work function,but also forms the cratered surface with increased ohmic contact area,revealing suppressed charge recombination and enhanced charge extraction in devices.Particularly,P-ZnO-based OSCs show improved light trapping in the active layer compared with ZnO-based ones.The universality of P-ZnO serving as ETL for efficient OSCs is verified on three photovoltaic systems of PBDB-T/DTPPSe-2 F,PM6/Y6,and PTB7-Th/PC_(71)BM.The enhancements of 8%in power conversion efficiency(PCE)can be achieved in the state-of-the-art OSCs based on PBDB-T/DTPPSe-2F,PM6/Y6,and PTB7-Th/PC_(71)BM,delivering PCEs of 14.78%,16.57%,and 9.85%,respectively.Furthermore,a promising PCE of14.13%under air-processed condition can be achieved for PZnO/PBDB-T/DTPPSe-2F-based OSC,which is among the highest efficiencies reported for air-processed OSCs in the literature.And the P-ZnO/PBDB-T/DTPPSe-2F-based device also presents superior long-term storage stability whether in nitrogen or ambient air-condition without encapsulation,which can maintain over 85%of its initial efficiency.Our results demonstrate the great potential of the porous hybrid PZnO as ETL for constructing high-performance and air-stable OSCs.展开更多
基金Project(20431030) supported by the National Natural Science Foundation of ChinaProject(2006RFQXS096) supported by the Foundation for Science and Technology Innovation Talents of Harbin, China+1 种基金Project(1152Z002) supported by the Key Projects of Educational Department of Heilongjiang Province, ChinaProject(LBH-Q07111) supported by Heilongjiang Postdoctoral Funds for Scientific Research Initiation
文摘The Zn(Ⅱ) phthalocyanine sensitized TiO2(ZnPc-TiO2) nanoparticles were prepared by hydrothermal method via impregnation with ZnPc.The as-prepared photocatalysts were characterized by X-ray diffractometry(XRD) and diffuse reflectance spectroscopy(DRS),and the surface photovoltage spectroscopy(SPS) and photocatalytic degradation of rhodamine B(RhB) were studied under illuminating.The experimental results indicate that TiO2 sensitized by ZnPc extends its absorption band into the visible region effectively,and the sensitized TiO2 has higher activity than TiO2(Degussa P-25) under the simulated solar light and the visible light.Based on the DRS and SPS results,the mechanism about the photogenerated carrier transfer between TiO2 and ZnPc is proposed.At a lower ZnPc content(≤0.20 μmol/g),ZnPc monomer acts as the electron donor,which provides the photoinduced electrons to the conduction band of TiO2.These photoinduced electrons can transfer to molecular oxygen(O2),leading to the formation of active species,such as superoxide/hydroxide radicals and singlet oxygen,which is beneficial to the photocatalytic reaction.While at a higher ZnPc content(>0.20 μmol/g),the formation of ZnPc dimer results in the decrease of photocatalytic activities of ZnPc-TiO2 photocatalyst.
基金Project(2006AA04Z228) supported by National Hi-tech Research and Development Program of China
文摘The essential requirements of the end-effector of large space manipulator are capabilities of misalignment tolerance and soft capture.According to these requirements,an end-effector prototype combining the tendon-sheath transmission system with steel cable snaring mechanism was manufactured.An analysis method based on the coordinate transformation and the projection of key points of the mechanical interface was proposed,and it was a guideline of the end-effector design.Furthermore,the tendon-sheath transmission system was employed in the capture subassembly to reduce the inertia of the capture mechanism and enlarge the capture space.The capabilities of misalignment tolerance and soft capture were validated through the dynamic simulation in ADAMS software.The results of the capture simulation and experiment show that the end-effector has outstanding capabilities of misalignment tolerance and soft capture.The translation misalignments in radial directions are±100 mm,and angular misalignments about pitch and yaw are±15°.
基金supported by National Natural Science Foundation of China(No.61101164)
文摘Underwater wireless sensor networks(UWSNs) have attracted wide attention in recent years.The capacity research on it is still in the initial stage,lacking adequate performance evaluation for network construction.This paper will focus on this subject by theoretical analysis and simulation,aiming to provide some insights for the actual UWSNs construction.According to the structure features of cluster-based UWSNs and the propagation characteristics of underwater acoustic signal,with the combination of signal to interference plus noise ratio,we define some capacity performance metrics,such as outage probability and transmission capacity.Based on the theory of stochastic geometry,a network capacity analytical model used in the cluster-based UWSNs is presented.The simulation results verify the validity of the theoretical analysis,and the cause of error between theoretical and simulation results has also been clearly explained.
基金Project(IRT0852) supported by the Program for Changjiang Scholars and Innovative Research Team in University,ChinaProject(2012CB316100) supported by the National Basic Research Program of China+2 种基金Projects(61101144,61101145) supported by the National Natural Science Foundation of ChinaProject(B08038) supported by the "111" Project,ChinaProject(K50510010017) supported by the Fundamental Research Funds for the Central Universities,China
文摘In order to save energy consumption of two-way amplifier forward(AF) relaying with channel estimation error, an energy efficiency enhancement scheme is proposed in this work. Firstly, through the analysis of two-way AF relaying mode with channel estimation error, the resultant instantaneous SNRs at end nodes is obtained. Then, by using a high SNR approximation, outage possibility is acquired and its simple closed-form expression is represented. Specially, for using the energy resource more efficiently, a low-complexity power allocation and transmission mode selection policy is proposed to enhance the energy efficiency of two-way AF relay system. Finally, relay priority region is identified in which cooperative diversity energy gain can be achieved. The computer simulations are presented to verify our analytical results, indicating that the proposed policy outperforms direct transmission by an energy gain of 3 dB at the relative channel estimation error less than 0.001. The results also show that the two-way AF relaying transmission loses the two-way AF relaying transmission loses its superiority to direct transmission in terms of energy efficiency when channel estimation error reaches 0.03.
基金the National Natural Science Founda-tion of China (No. 50575145)
文摘A novel intelligent drug delivery system potential for the more effective therapy of the diabetics was proposed, and the composition of system was analyzed. Based on the design of micro-electro-mechanical systems (MEMS), an iterative modeling process was introduced. Unified modeling language (UML) was em-ployed to describe the function requirement, and different diagrams were built up to explore the static model, the dynamic model and the employment model. The mapping analysis of different diagrams can simply verify the consistency and completeness of the system model.
基金supported by the National Natural Science Foundation of China(U2001220)Key-Area Research and Development Program of Guangdong Province(2020B090919001)+2 种基金Shenzhen All-Solid-State Lithium Battery Electrolyte Engineering Research Center(XMHT20200203006)Shenzhen Technical Plan Project(RCJC20200714114436091,JCYJ20180508152210821JCYJ20180508152135822)。
文摘Ceramic electrolytes are important in ceramic-liquid hybrid electrolytes(CLHEs),which can effectively solve the interfacial issues between the electrolyte and electrodes in solid-state batteries and provide a highly efficient Li-ion transfer for solid–liquid Li metal batteries.Understanding the ionic transport mechanisms in CLHEs and the corresponding role of ceramic electrolytes is crucial for a rational design strategy.Herein,the Li-ion transfer in the ceramic electrolytes of CLHEs was confirmed by tracking the 6Li and 7Li substitution behavior through solid-state nuclear magnetic resonance spectroscopy.The ceramic and liquid electrolytes simultaneously participate in Li-ion transport to achieve highly efficient Li-ion transfer in CLHEs.A spontaneous Li-ion exchange was also observed between ceramic and liquid electrolytes,which serves as a bridge that connects the ceramic and liquid electrolytes,thereby greatly strengthening the continuity of Li-ion pathways in CLHEs and improving the kinetics of Li-ion transfer.The importance of an abundant solid–liquid interface for CLHEs was further verified by the enhanced electrochemical performance in LiFePO4/Li and LiNi0.8Co0.1Mn0.1O2/Li batteries from the generated interface.This work provides a clear understanding of the Li-ion transport pathway in CLHEs that serves as a basis to build a universal Li-ion transport model of CLHEs.
基金the National Natural Science Foundation of China(21905137)the Natural Science Foundation of Jiangsu Province(BK20180496)。
文摘In this study,a porous inorganic/organic(ZnO/PEIE,where PEIE is polyethylenimine ethoxylated)(P-ZnO)hybrid material has been developed and adopted in the inverted organic solar cells(OSCs).The P-ZnO serving as the electron transport layer(ETL)not only presents an ameliorative work function,but also forms the cratered surface with increased ohmic contact area,revealing suppressed charge recombination and enhanced charge extraction in devices.Particularly,P-ZnO-based OSCs show improved light trapping in the active layer compared with ZnO-based ones.The universality of P-ZnO serving as ETL for efficient OSCs is verified on three photovoltaic systems of PBDB-T/DTPPSe-2 F,PM6/Y6,and PTB7-Th/PC_(71)BM.The enhancements of 8%in power conversion efficiency(PCE)can be achieved in the state-of-the-art OSCs based on PBDB-T/DTPPSe-2F,PM6/Y6,and PTB7-Th/PC_(71)BM,delivering PCEs of 14.78%,16.57%,and 9.85%,respectively.Furthermore,a promising PCE of14.13%under air-processed condition can be achieved for PZnO/PBDB-T/DTPPSe-2F-based OSC,which is among the highest efficiencies reported for air-processed OSCs in the literature.And the P-ZnO/PBDB-T/DTPPSe-2F-based device also presents superior long-term storage stability whether in nitrogen or ambient air-condition without encapsulation,which can maintain over 85%of its initial efficiency.Our results demonstrate the great potential of the porous hybrid PZnO as ETL for constructing high-performance and air-stable OSCs.