The interaction potential index IPI(X) of 16 Br, C1, I, NO2, CN, CHO, COOH, CH3, CH: kinds of substituents X (X---OH, SH, NH2, :CH2, C-CH, Ph, COCH3, COOCH3) were proposed, which are derived from the experimenta...The interaction potential index IPI(X) of 16 Br, C1, I, NO2, CN, CHO, COOH, CH3, CH: kinds of substituents X (X---OH, SH, NH2, :CH2, C-CH, Ph, COCH3, COOCH3) were proposed, which are derived from the experimental enthalpies of formation △fHФ (g) values of monosubstituted straight-chain alkanes. Based on the IPI(X) and polarizability effect index, a simple and effective model was constructed to estimate the △fHФ (g) values of monosubstituted alkanes RX (including the branched derivatives). The present model takes into account not only the contributions of the alkyl R and the substituent X, but also the contribution of the interaction between R and X. Its stability and prediction ability was confirmed by the results of leave-one-out method. Compared with previous reported studies, the obtained equation can be used to estimate enthalpies of formation for much more kinds of monosubstituted alkanes with less parameters. Thus, it is recommended for the calculation of the △fHФ(g) for the RX.展开更多
The fraction of photosynthetically active radiation (FPAR) is a key variable in the assessment of vegetation productivity and land ecosystem carbon cycles. Based on ground-measured corn hyperspectral reflectance and...The fraction of photosynthetically active radiation (FPAR) is a key variable in the assessment of vegetation productivity and land ecosystem carbon cycles. Based on ground-measured corn hyperspectral reflectance and FPAR data over Northeast China, the correlations between corn-canopy FPAR and hyperspectral reflectance were analyzed, and the FPAR estimation performances using vegetation index (VI) and neural network (NN) methods with different two-band-combination hyperspectral reflectance were investigated. The results indicated that the corn-canopy FPAR retained almost a constant value in an entire day. The negative correlations between FPAR and visible and shortwave infrared reflectance (SWIR) bands are stronger than the positive correlations between FPAR and near-infrared band re- flectance (NIR). For the six VIs, the normalized difference vegetation index (NDVI) and simple ratio (SR) performed best for estimating corn FPAR (the maximum R2 of 0.8849 and 0.8852, respectively). However, the NN method esti- mated results (the maximum Rz is 0.9417) were obviously better than all of the VIs. For NN method, the two-band combinations showing the best corn FPAR estimation performances were from the NIR and visible bands; for VIs, however, they were from the SWIR and NIR bands. As for both the methods, the SWIR band performed exceptionally well for corn FPAR estimation. This may be attributable to the fact that the reflectance of the SWIR band were strongly controlled by leaf water content, which is a key component of corn photosynthesis and greatly affects the absorption of photosynthetically active radiation (APAR), and makes further impact on corn-canopy FPAR.展开更多
In this paper,the explicit estimates of central moments for one kind of exponential-type operators are derived.The estimates play an essential role in studying the explicit approximation properties of this family of o...In this paper,the explicit estimates of central moments for one kind of exponential-type operators are derived.The estimates play an essential role in studying the explicit approximation properties of this family of operators.Using the proposed method,the results of Ditzian and Totik in 1987,Guo and Qi in 2007,and Mahmudov in 2010 can be improved respectively.展开更多
This article describes a proposal for a double index to estimate the isotropic components of unitary errors in a quantum computation circuit. In the context of this work the error is considered isotropic if it has sph...This article describes a proposal for a double index to estimate the isotropic components of unitary errors in a quantum computation circuit. In the context of this work the error is considered isotropic if it has spherical symmetry about the state of interest. The theoretical definition is given, as well the numerical approximation for practical purposes. The index is tested in some simple examples and the geometric distortion of the propagated error is studied for an inaccurate Shor 9-qubits correcting code.展开更多
Soil salinity is one of the most severe environmental problems worldwide. It is necessary to develop a soil-salinity-estimation model to project the spatial distribution of soil salinity. The aims of this study were t...Soil salinity is one of the most severe environmental problems worldwide. It is necessary to develop a soil-salinity-estimation model to project the spatial distribution of soil salinity. The aims of this study were to use remote sensed images and digital elevation model(DEM) to develop quantitative models for estimating soil salinity and to investigate the influence of vegetation on soil salinity estimation. Digital bands of Landsat Thematic Mapper(TM) images, vegetation indices, and terrain indices were selected as predictive variables for the estimation. The generalized additive model(GAM) was used to analyze the quantitative relationship between soil salt content, spectral properties, and terrain indices. Akaike's information criterion(AIC) was used to select relevant predictive variables for fitted GAMs. A correlation analysis and root mean square error between predicted and observed soil salt contents were used to validate the fitted GAMs. A high ratio of explained deviance suggests that an integrated approach using spectral and terrain indices with GAM was practical and efficient for estimating soil salinity. The performance of the fitted GAMs varied with changes in vegetation cover.Salinity in sparsely vegetated areas was estimated better than in densely vegetated areas. Visible red and near-infrared bands, and the second and third components of the tasseled cap transformation were the most important spectral variables for the estimation. Variable combinations in the fitted GAMs and their contribution varied with changes in vegetation cover. The contribution of terrain indices was smaller than that of spectral indices, possibly due to the low spatial resolution of DEM. This research may provide some beneficial references for regional soil salinity estimation.展开更多
With the development of the global economy, interaction among different economic entities from one region is intensifying, which makes it significant to consider such interaction when constructing composite index for ...With the development of the global economy, interaction among different economic entities from one region is intensifying, which makes it significant to consider such interaction when constructing composite index for each country from one region. Recent advances in signal extraction and time series analysis have made such consideration feasible and practical. Singular spectrum analysis (SSA) is a well-developed technique for time series analysis and proven to be a powerful tool for signal extraction. The present study aims to introduce the usage of the SSA technique for multi-country business cycle analysis. The multivariate SSA (MSSA) is employed to construct a model-based composite index and the two dimensional SSA (2D-SSA) is employed to establish the multi-country composite index. Empirical results performed on Chinese economy demonstrate the accuracy and stability of MSSA-based composite index, and the 2D-SSA based composite indices for Asian countries confirm the efficiency of the technique in capturing the interaction among different countries.展开更多
基金This work was supported by the National Natural Science Foundation of China (No.21072053 and No.20772028) and the Scientific Research Fund of Hunan Provincial Education Department (No.10K025 and No.09C386).
文摘The interaction potential index IPI(X) of 16 Br, C1, I, NO2, CN, CHO, COOH, CH3, CH: kinds of substituents X (X---OH, SH, NH2, :CH2, C-CH, Ph, COCH3, COOCH3) were proposed, which are derived from the experimental enthalpies of formation △fHФ (g) values of monosubstituted straight-chain alkanes. Based on the IPI(X) and polarizability effect index, a simple and effective model was constructed to estimate the △fHФ (g) values of monosubstituted alkanes RX (including the branched derivatives). The present model takes into account not only the contributions of the alkyl R and the substituent X, but also the contribution of the interaction between R and X. Its stability and prediction ability was confirmed by the results of leave-one-out method. Compared with previous reported studies, the obtained equation can be used to estimate enthalpies of formation for much more kinds of monosubstituted alkanes with less parameters. Thus, it is recommended for the calculation of the △fHФ(g) for the RX.
基金Under the auspices of National Key Research Program of Global Change Research (No.2010CB951302)National Natural Science Fundation of China (No.40771146)China Postdoctoral Science Foundation Funded Project (No.07Z7601MZ1)
文摘The fraction of photosynthetically active radiation (FPAR) is a key variable in the assessment of vegetation productivity and land ecosystem carbon cycles. Based on ground-measured corn hyperspectral reflectance and FPAR data over Northeast China, the correlations between corn-canopy FPAR and hyperspectral reflectance were analyzed, and the FPAR estimation performances using vegetation index (VI) and neural network (NN) methods with different two-band-combination hyperspectral reflectance were investigated. The results indicated that the corn-canopy FPAR retained almost a constant value in an entire day. The negative correlations between FPAR and visible and shortwave infrared reflectance (SWIR) bands are stronger than the positive correlations between FPAR and near-infrared band re- flectance (NIR). For the six VIs, the normalized difference vegetation index (NDVI) and simple ratio (SR) performed best for estimating corn FPAR (the maximum R2 of 0.8849 and 0.8852, respectively). However, the NN method esti- mated results (the maximum Rz is 0.9417) were obviously better than all of the VIs. For NN method, the two-band combinations showing the best corn FPAR estimation performances were from the NIR and visible bands; for VIs, however, they were from the SWIR and NIR bands. As for both the methods, the SWIR band performed exceptionally well for corn FPAR estimation. This may be attributable to the fact that the reflectance of the SWIR band were strongly controlled by leaf water content, which is a key component of corn photosynthesis and greatly affects the absorption of photosynthetically active radiation (APAR), and makes further impact on corn-canopy FPAR.
基金Supported by National Natural Science Foundation of China(No.60872161,No.10971251)
文摘In this paper,the explicit estimates of central moments for one kind of exponential-type operators are derived.The estimates play an essential role in studying the explicit approximation properties of this family of operators.Using the proposed method,the results of Ditzian and Totik in 1987,Guo and Qi in 2007,and Mahmudov in 2010 can be improved respectively.
文摘This article describes a proposal for a double index to estimate the isotropic components of unitary errors in a quantum computation circuit. In the context of this work the error is considered isotropic if it has spherical symmetry about the state of interest. The theoretical definition is given, as well the numerical approximation for practical purposes. The index is tested in some simple examples and the geometric distortion of the propagated error is studied for an inaccurate Shor 9-qubits correcting code.
基金financially supported by the National Natural Science Foundation of China (Nos. 41001363 and 41471335)the Ocean Public Welfare Scientific Research Project, China (No. 201305021)
文摘Soil salinity is one of the most severe environmental problems worldwide. It is necessary to develop a soil-salinity-estimation model to project the spatial distribution of soil salinity. The aims of this study were to use remote sensed images and digital elevation model(DEM) to develop quantitative models for estimating soil salinity and to investigate the influence of vegetation on soil salinity estimation. Digital bands of Landsat Thematic Mapper(TM) images, vegetation indices, and terrain indices were selected as predictive variables for the estimation. The generalized additive model(GAM) was used to analyze the quantitative relationship between soil salt content, spectral properties, and terrain indices. Akaike's information criterion(AIC) was used to select relevant predictive variables for fitted GAMs. A correlation analysis and root mean square error between predicted and observed soil salt contents were used to validate the fitted GAMs. A high ratio of explained deviance suggests that an integrated approach using spectral and terrain indices with GAM was practical and efficient for estimating soil salinity. The performance of the fitted GAMs varied with changes in vegetation cover.Salinity in sparsely vegetated areas was estimated better than in densely vegetated areas. Visible red and near-infrared bands, and the second and third components of the tasseled cap transformation were the most important spectral variables for the estimation. Variable combinations in the fitted GAMs and their contribution varied with changes in vegetation cover. The contribution of terrain indices was smaller than that of spectral indices, possibly due to the low spatial resolution of DEM. This research may provide some beneficial references for regional soil salinity estimation.
基金supported by the National Science Foundation of China under Grant No.71101142Presidential Award of Chinese Academy of Sciences
文摘With the development of the global economy, interaction among different economic entities from one region is intensifying, which makes it significant to consider such interaction when constructing composite index for each country from one region. Recent advances in signal extraction and time series analysis have made such consideration feasible and practical. Singular spectrum analysis (SSA) is a well-developed technique for time series analysis and proven to be a powerful tool for signal extraction. The present study aims to introduce the usage of the SSA technique for multi-country business cycle analysis. The multivariate SSA (MSSA) is employed to construct a model-based composite index and the two dimensional SSA (2D-SSA) is employed to establish the multi-country composite index. Empirical results performed on Chinese economy demonstrate the accuracy and stability of MSSA-based composite index, and the 2D-SSA based composite indices for Asian countries confirm the efficiency of the technique in capturing the interaction among different countries.