We investigated the effects of supports (CMK-3, SiO2ZrO2, MgO, Al2O3) and promoters (Cu, Ce, Fe) on textual properties of Ni based catalysts. o-Cresol was used as a probe to test the activity of these catalysts un...We investigated the effects of supports (CMK-3, SiO2ZrO2, MgO, Al2O3) and promoters (Cu, Ce, Fe) on textual properties of Ni based catalysts. o-Cresol was used as a probe to test the activity of these catalysts under the condition of 230 ℃ and nitrogen pres-sure of 0.1 MPa. The catalysts were characterized by X-ray diffraction, H2 temperature programmed reduction ammonium programmed desorption, and N2 adsorption-desorption isotherms. The results showed that the catalytic performance of Ni/CMK-3 (the conversion of o-cresol reached 45.4%) was significantly better than the other three kinds of supports. The modification of Ni/CMK-3 was also investigated and over 60% conversion of o-cresol was obtained after the addition of Ce (64.6%)and Cu (66.8%) in Ni/CMK-3, whereas the addition of Fe led to a decrease of conversion. In the meantime, Cu changed the products dis-tribution. The appearance of toluene indicated that another pathway existed in the reaction.Accompanied by the ascension of conversion in both sides, side effects also occurred and got more serious. The apparent order of activity for all the tested catalysts was NiCe/CMK-3〉NiCu/CMK-3〉Ni/CMK-3〉NiFe/CMK-3〉Ni/Al2O3Ni/SiO2ZrO2〉Ni/MgO. The reac-tion pathway, involving three routes, was also mentioned in this study.展开更多
In order to reveal the changing law of the mechanical response of asphalt pavements under the action of vehicle load and provide references for the design of durable pavements,three typical asphalt pavement structures...In order to reveal the changing law of the mechanical response of asphalt pavements under the action of vehicle load and provide references for the design of durable pavements,three typical asphalt pavement structures with flexible base(S1),combined base(S2),and semi-rigid base(S3)were selected to perform field strain tests under static and dynamic load using the fiber Bragg grating optical sensing technology.The changing characteristics of the strain field along the horizontal and depth directions of pavements were analyzed.The results indicate that the most unfavorable asphalt pavement layers were the upper-middle surface layer and the lower base layer.In addition,the most unfavorable loading positions on the surface layer and the base layer were the center of wheel load and the gap center between two wheels,respectively.The most unfavorable layer of the surface layers gradually moved from the lower layer to the upper layer with the increase of base layer modulus.The power function relationships between structural layer strain and vehicle speed were revealed.The semi-rigid base asphalt pavement was the most durable pavement type,since its strain value was lower compared to those of the other structures.展开更多
When subjected to shear loading condition,a steel rock bolt will become bent in the field close to the loading point in situ.The bolt is deformed as the joint displacement increases,which can mobilize a normal load an...When subjected to shear loading condition,a steel rock bolt will become bent in the field close to the loading point in situ.The bolt is deformed as the joint displacement increases,which can mobilize a normal load and a shear load on the bolt accordingly.In this work,the relationship analysis between the displacing angle and loading angle is carried out.By considering elastic andplastic states of rock bolt during shearing,the rotation of bolt extremity can be calculated analytically.Thus,the loading angle isobtained from displacing angle.The verification of analytical results and laboratory results from reference research implies that theanalytical method is correct and working.In terms of in-situ condition,the direction of the load acting on steel bolt can be predictedwell according to the direction of the deformed rock bolt with respect to original bolt axis.展开更多
The loading tides are calculated by means of the Green's function method based on a high-resolution regional ocean tide model, the TOPO7.0 global ocean tide model, and the Gutenberg-Bullen A Earth model. The resul...The loading tides are calculated by means of the Green's function method based on a high-resolution regional ocean tide model, the TOPO7.0 global ocean tide model, and the Gutenberg-Bullen A Earth model. The results show that the maximal amplitude of M2 vertical displacement loading (VDL) tide in the Bohai, Yellow, and East China Seas exceeding 28mm appears 150km off the Zhejiang coast; the second maximum exceeding 20mm appears in Inchon Bay; and the third maximum exceeding 14mm is located in the northeast of the North Yellow Sea. The maximal amplitudes of S2 VDL tide at the above three locations exceed 10, 8, and 4mm, respectively. The maximal amplitudes of the K1 and O1 VDL tides, exceeding 13 and 10 mm respectively, appear near the central and north Ryukyu Islands; the amplitudes tend to decease toward the inward areas. The phases of semidiurnal VDL tides are basically opposite to those of corresponding ocean tides. The phases of diurnal VDL tides are basically opposite to those of corresponding ocean tides in the most part of the East China Sea and the eastern part of the South Yellow Sea. This anti-phase relationship generally does not hold in the rest parts of the Bohai and Yellow Seas. The distribution patterns of self-attraction and loading (SAL) tides are very similar to those of VDL tides. The SAL tides have amplitudes about 1.2-1.7 times of the corresponding VDL tides and their phases are basically opposite to the corresponding VDL tides. The maximal amplitude of M2 SAL tide also appears off the Zhejiang coast, with a magnitude exceeding 42mm.展开更多
The longitudinal resistance performance of a granular ballast bed under cyclic symmetric displacement loading was studied based on a full-scale test model of ballast track structures. The change law of the longitudina...The longitudinal resistance performance of a granular ballast bed under cyclic symmetric displacement loading was studied based on a full-scale test model of ballast track structures. The change law of the longitudinal resistance characteristics of the ballast bed under variable displacement amplitudes was analyzed. The results show that: the resistance-displacement curves of a granular ballast bed are a set of closed hysteretic curves, indicating obvious energy consumption; a granular ballast bed softens gradually during the cyclic process with constant displacement amplitude, and the residual deformation rate increases nonlinearly with increasing cycle number; the peak value of the longitudinal resistance of lines decreases with increasing cycle number; the cyclic softening of a granular ballast bed is dependent on the displacement amplitude-the higher the displacement, the more severe the cyclic softening will become; after cyclic displacement loading is applied several times, the longitudinal resistance of the bed will degenerate obviously, and the higher the displacement amplitude, the higher the longitudinal resistance attenuation rate of the ballast bed will become.展开更多
To study the deformability and ductility of an innovative precast shear wall joined by bolted connections,experimental tests were conducted on two test walls under monotonic and cyclic loading,respectively;subsequentl...To study the deformability and ductility of an innovative precast shear wall joined by bolted connections,experimental tests were conducted on two test walls under monotonic and cyclic loading,respectively;subsequently,theoretical analysis was performed on the deformation performance of the shear wall assembly.The test results confirmed the favorable deformability and ductility of the specimens.The top displacement of the shear wall assembly was analytically decomposed into several constituent parts,the theoretical formulae of which were subsequently deduced.The compositional analysis demonstrated that the top displacement of the test wall was primarily induced by the elastic deformation of the upper wall panel(UWP),the relative slippages within the bolted connections,and the flexural deformation within the plastic region of the UWP,while the constituent part contributed by the deformation in the connecting steel frame can be neglected.展开更多
Softening behavior of lath martensitic steels is related to the coarsening of laths and dislocation evolution during cyclic deformation.Involving the physical mechanism,we developed a dislocation-based model to study ...Softening behavior of lath martensitic steels is related to the coarsening of laths and dislocation evolution during cyclic deformation.Involving the physical mechanism,we developed a dislocation-based model to study the cyclic plastic response for lath martensitic steels.For a block,we proposed an interfacial dislocation evolution model to physically present the interaction between mobile dislocations in the block and interfacial dislocations by considering the coarsening mechanism of the laths.Moreover,the evolution behavior of backstress caused by dislocation pile up at the block boundary has been considered.Then,a hierarchical model based on the elastic-viscoplastic self-consistent(EVPSC)theory is developed,which can realize the scale transition among representative volume element(RVE),prior austenite grains(PAGs)and blocks.According to the proposed model,the effective mechanical responses including the cyclic hysteretic loop and peak stress at different cycles for lath martensitic steel have been theoretically predicted and investigated.展开更多
基金This work was supported by the National Natural Science Foundation of China (No.51036006 and No.51106108) and the Key Program of the Chinese Academy of Sciences (No.KGZD-EW-304-3).
文摘We investigated the effects of supports (CMK-3, SiO2ZrO2, MgO, Al2O3) and promoters (Cu, Ce, Fe) on textual properties of Ni based catalysts. o-Cresol was used as a probe to test the activity of these catalysts under the condition of 230 ℃ and nitrogen pres-sure of 0.1 MPa. The catalysts were characterized by X-ray diffraction, H2 temperature programmed reduction ammonium programmed desorption, and N2 adsorption-desorption isotherms. The results showed that the catalytic performance of Ni/CMK-3 (the conversion of o-cresol reached 45.4%) was significantly better than the other three kinds of supports. The modification of Ni/CMK-3 was also investigated and over 60% conversion of o-cresol was obtained after the addition of Ce (64.6%)and Cu (66.8%) in Ni/CMK-3, whereas the addition of Fe led to a decrease of conversion. In the meantime, Cu changed the products dis-tribution. The appearance of toluene indicated that another pathway existed in the reaction.Accompanied by the ascension of conversion in both sides, side effects also occurred and got more serious. The apparent order of activity for all the tested catalysts was NiCe/CMK-3〉NiCu/CMK-3〉Ni/CMK-3〉NiFe/CMK-3〉Ni/Al2O3Ni/SiO2ZrO2〉Ni/MgO. The reac-tion pathway, involving three routes, was also mentioned in this study.
基金Projects(51908071,51708071)supported by National Natural Science Foundation of ChinaProject(2020JJ5975)supported by the Natural Science Foundation of Hunan Province,China+1 种基金Project(18C0194)supported by the Scientific Research Project of Education Department of Hunan Province,ChinaProject(kfj190301)supported by Open Fund of Key Laboratory of Road Structure and Material of Ministry of Transport(Changsha University of Science&Technology),China。
文摘In order to reveal the changing law of the mechanical response of asphalt pavements under the action of vehicle load and provide references for the design of durable pavements,three typical asphalt pavement structures with flexible base(S1),combined base(S2),and semi-rigid base(S3)were selected to perform field strain tests under static and dynamic load using the fiber Bragg grating optical sensing technology.The changing characteristics of the strain field along the horizontal and depth directions of pavements were analyzed.The results indicate that the most unfavorable asphalt pavement layers were the upper-middle surface layer and the lower base layer.In addition,the most unfavorable loading positions on the surface layer and the base layer were the center of wheel load and the gap center between two wheels,respectively.The most unfavorable layer of the surface layers gradually moved from the lower layer to the upper layer with the increase of base layer modulus.The power function relationships between structural layer strain and vehicle speed were revealed.The semi-rigid base asphalt pavement was the most durable pavement type,since its strain value was lower compared to those of the other structures.
基金Projects(51604299,51274249,51474252)supported by the National Natural Science Foundation of ChinaProject(2016YFC0600706)supported by the State Key Research Development Program of China+4 种基金Project(2015CX005)supported by the Innovation Driven Plan of Central South University,ChinaProject(2016M600636)supported by China Postdoctoral Science FoundationProject supported by the Postdoctoral Science Foundation of Central South University,China
文摘When subjected to shear loading condition,a steel rock bolt will become bent in the field close to the loading point in situ.The bolt is deformed as the joint displacement increases,which can mobilize a normal load and a shear load on the bolt accordingly.In this work,the relationship analysis between the displacing angle and loading angle is carried out.By considering elastic andplastic states of rock bolt during shearing,the rotation of bolt extremity can be calculated analytically.Thus,the loading angle isobtained from displacing angle.The verification of analytical results and laboratory results from reference research implies that theanalytical method is correct and working.In terms of in-situ condition,the direction of the load acting on steel bolt can be predictedwell according to the direction of the deformed rock bolt with respect to original bolt axis.
基金supported by National Natural Science Foundation of China (Grant Nos. 40676009 and 40606006)Qingdao Science and Technology Basic Research Program (Grant No. 11-1-4-98-JCH)
文摘The loading tides are calculated by means of the Green's function method based on a high-resolution regional ocean tide model, the TOPO7.0 global ocean tide model, and the Gutenberg-Bullen A Earth model. The results show that the maximal amplitude of M2 vertical displacement loading (VDL) tide in the Bohai, Yellow, and East China Seas exceeding 28mm appears 150km off the Zhejiang coast; the second maximum exceeding 20mm appears in Inchon Bay; and the third maximum exceeding 14mm is located in the northeast of the North Yellow Sea. The maximal amplitudes of S2 VDL tide at the above three locations exceed 10, 8, and 4mm, respectively. The maximal amplitudes of the K1 and O1 VDL tides, exceeding 13 and 10 mm respectively, appear near the central and north Ryukyu Islands; the amplitudes tend to decease toward the inward areas. The phases of semidiurnal VDL tides are basically opposite to those of corresponding ocean tides. The phases of diurnal VDL tides are basically opposite to those of corresponding ocean tides in the most part of the East China Sea and the eastern part of the South Yellow Sea. This anti-phase relationship generally does not hold in the rest parts of the Bohai and Yellow Seas. The distribution patterns of self-attraction and loading (SAL) tides are very similar to those of VDL tides. The SAL tides have amplitudes about 1.2-1.7 times of the corresponding VDL tides and their phases are basically opposite to the corresponding VDL tides. The maximal amplitude of M2 SAL tide also appears off the Zhejiang coast, with a magnitude exceeding 42mm.
基金Project supported by the National Natural Science Foundation of China (Nos. 51425804, U1234201, and 1334203), and the Doctorial Innovation Fund of Southwest Jiaotong University (No. 2014310016), China
文摘The longitudinal resistance performance of a granular ballast bed under cyclic symmetric displacement loading was studied based on a full-scale test model of ballast track structures. The change law of the longitudinal resistance characteristics of the ballast bed under variable displacement amplitudes was analyzed. The results show that: the resistance-displacement curves of a granular ballast bed are a set of closed hysteretic curves, indicating obvious energy consumption; a granular ballast bed softens gradually during the cyclic process with constant displacement amplitude, and the residual deformation rate increases nonlinearly with increasing cycle number; the peak value of the longitudinal resistance of lines decreases with increasing cycle number; the cyclic softening of a granular ballast bed is dependent on the displacement amplitude-the higher the displacement, the more severe the cyclic softening will become; after cyclic displacement loading is applied several times, the longitudinal resistance of the bed will degenerate obviously, and the higher the displacement amplitude, the higher the longitudinal resistance attenuation rate of the ballast bed will become.
基金supported by the National Natural Science Foundation of China(Grant No.51078077)
文摘To study the deformability and ductility of an innovative precast shear wall joined by bolted connections,experimental tests were conducted on two test walls under monotonic and cyclic loading,respectively;subsequently,theoretical analysis was performed on the deformation performance of the shear wall assembly.The test results confirmed the favorable deformability and ductility of the specimens.The top displacement of the shear wall assembly was analytically decomposed into several constituent parts,the theoretical formulae of which were subsequently deduced.The compositional analysis demonstrated that the top displacement of the test wall was primarily induced by the elastic deformation of the upper wall panel(UWP),the relative slippages within the bolted connections,and the flexural deformation within the plastic region of the UWP,while the constituent part contributed by the deformation in the connecting steel frame can be neglected.
基金supported by the National Natural Science Foundation of China(Grant Nos.11988102,12002005,11632001,11521202)the Science Challenge Project(Grant No.TZ2018001).
文摘Softening behavior of lath martensitic steels is related to the coarsening of laths and dislocation evolution during cyclic deformation.Involving the physical mechanism,we developed a dislocation-based model to study the cyclic plastic response for lath martensitic steels.For a block,we proposed an interfacial dislocation evolution model to physically present the interaction between mobile dislocations in the block and interfacial dislocations by considering the coarsening mechanism of the laths.Moreover,the evolution behavior of backstress caused by dislocation pile up at the block boundary has been considered.Then,a hierarchical model based on the elastic-viscoplastic self-consistent(EVPSC)theory is developed,which can realize the scale transition among representative volume element(RVE),prior austenite grains(PAGs)and blocks.According to the proposed model,the effective mechanical responses including the cyclic hysteretic loop and peak stress at different cycles for lath martensitic steel have been theoretically predicted and investigated.