鸡胚心电位场衰减与液态媒质电导率关系的研究

目的 研究鸡胚心电位场的衰减与液态媒质电导率之间的关系。方法 在电导率不同的5种液态媒质中，采集60个5 d龄鸡胚心脏相同方向上若干离场源不同距离的测试点心电图，分别比较不同液态媒质中相同测试点心电图R（r）的振幅。结果 液态媒质的电导率越高，相同距离测试点记录的心电图R（r）波振幅越小，且差异具显著性（P<0.05）。结论 液态媒质的电导率越高，对心电位场传播的衰减幅度就越大。这表明正常情况下，将心脏周围组织简单地等效为电导率与生理盐水相仿的容积导体传统的容积导体学说［1］确有商榷之处。

Effect of MnO_4^- and silver content on electrochemical behaviour of Pb-Ag alloy anodes during potential decay periods

The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay periods. When the anodes were immersed into acid zinc sulphate electrolyte without MnO4- ions, the Pb-0.72%Ag anode entered complete passivation state in the shortest time among the five anodes, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by measurement of open circuit potential. During immersion of the anodes, MnO4 ions accelerated the passivation and increased the corrosion current density of the anodes. After immersion in zinc electrolyte with MnO4-, the anode Pb-0.72%Ag had the best corrosion resistance, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, then the close anodes Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by the electrochemical impedance spectroscopy （EIS） analysis.

Study on Methanol Oxidation at Pt and PtRu Electrodes by Combining in situ Infrared Spectroscopy and Differential Electrochemical Mass Spectrometry

Methanol oxidation reaction （MOR） at Pt and Pt electrode surface deposited with various amounts of Ru （denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML） in 0.1 mol/L HClO4＋0.5 mol/L MeOH has been studied under potentiostatic conditions by in situ FTIR spectroscopy in attenuated-total-reflection con guration and di erential electro-chemical mass spectrometry under controlled flow conditions. Results reveal that （i） CO is the only methanol-related adsorbate observed by IR spectroscopy at all the Pt and PtRu electrodes examined at potentials from 0.3 V to 0.6 V （vs. RHE）; （ii） at Pt0.56Ru0.44, two IR bands, one from CO adsorbed at Ru islands and the other from COL at Pt substrate are detected, while at other electrodes, only a single band for COL adsorbed at Pt is observed; （iii） MOR activity decreases in the order of Pt0.73Ru0.27〉Pt0.56Ru0.44〉Pt0.83Ru0.17〉Pt; （iv） at 0.5 V, MOR at Pt0.73Ru0.27 reaches a current e ciency of 50% for CO2 production, the turn-over frequency from CH3OH to CO2 is ca. 0.1 molecule/（site sec）. Suggestions for further improving of PtRu catalysts for MOR are provided.

Adsorption behavior of heptyl xanthate on surface of ZnO and Cu(Ⅱ) activated ZnO using continuous online in situ ATR-FTIR technology

A continuous online in situ attenuated total reflection Fourier-transform infrared(ATR-FTIR)spectroscopic technique was used to investigate the adsorption and desorption kinetics of heptyl xanthate(KHX)on the surface of ZnO and Cu(Ⅱ)activated ZnO.The results showed that Cu(Ⅱ)facilitated the xanthate adsorption process on the surface,and led to the formation of cuprous xanthate(CuX),dixanthogen(X_(2))and xanthate aggregates.The adsorption of xanthate on the surface of ZnO and Cu(Ⅱ)activated ZnO was found to both follow the pseudo-first-order kinetic model.When the NaOH solution was used as a desorption agent,the adsorbed xanthate can largely be removed due to the competition between OH^(−)and HX−.However,for Cu(Ⅱ)activated ZnO,the peak intensities at 1197 and 1082 cm^(−1) had no obvious weakening,and the absorption intensities at 1261 and 1026 cm^(−1) increased in the first 5 min,indicating an ion-exchange reaction between OH^(−)and surface zinc bonded xanthate HX−and the reorganization of adsorbed xanthate.

制造与创造(外二篇)

制造正成为工业化社会的主旋律,它以繁忙然而单调,拥挤然而缺乏个性为基本素质,从而使我们看到的每一件新生事物都可能似曾相识。制造是机械的,或说它是机械自然铺陈的结果。制造的产品以大众口味的趋同湮没在五光十色中,在城市的霓虹闪烁里为大众所追逐欣赏。明星、箱包、电器。

Amplitude phase control for electro-hydraulic servo system based on normalized least-mean-square adaptive filtering algorithm

The electro-hydraulic servo system was studied to cancel the amplitude attenuation and phase delay of its sinusoidal response,by developing a network using normalized least-mean-square (LMS) adaptive filtering algorithm.The command input was corrected by weights to generate the desired input for the algorithm,and the feedback was brought into the feedback correction,whose output was the weighted feedback.The weights of the normalized LMS adaptive filtering algorithm were updated on-line according to the estimation error between the desired input and the weighted feedback.Thus,the updated weights were copied to the input correction.The estimation error was forced to zero by the normalized LMS adaptive filtering algorithm such that the weighted feedback was equal to the desired input,making the feedback track the command.The above concept was used as a basis for the development of amplitude phase control.The method has good real-time performance without estimating the system model.The simulation and experiment results show that the proposed amplitude phase control can efficiently cancel the amplitude attenuation and phase delay with high precision.

Tests of new in-situ seabed acoustic measurement system in Qingdao

A new in-situ seabed acoustic measurement system is developed for direct in-situ measurement of sediment geoacoustic properties （compressional wave velocity and attenuation）. The new in-situ system consists of two parts： the deck control unit and the underwater measurement unit. The underwater measurement unit emits sonic waves that propagate through the seafloor sediment, receives the returning signals, and transmits them to the deck control unit for waveform display and analysis. The entire operation is controlled and monitored in real time by the deck control unit on the research vessel and can provide recording of full waveforms to determine the sound velocity and attenuation. This paper outlines the design of the system, the measurement process, and demonstrates its application in tests carded out on seabed sediment off the Qingdao coast, China. The test results show that the system performed well and rapidly provided accurate in-situ acoustic velocity and attenuation estimates of the seafloor sediment.

Electrochemical Performance and Capacity Fading Mechanism of LiFePO4 at Different pH Aqueous Electrolyte Solutions

The electrochemical stability of LiFePO4 in a Li＋-containing aqueous electrolyte solution is critically dependent on the pH value of the aqueous solution. It shows a considerable decay in capacity of LiFePO4 upon cycling when the pH value is increased to 11. The mechanism responsible for the capacity fading is extensively investigated by means of cyclic voltammogram, ac impedance, charge/discharge, ex situ X-ray diffraction, and chemical analysis. LiFePO4 is relatively electrochemically stable in LiNO3 aqueous solution with pH=7. But the electrochemical performance of LiFePO4 in aqueous electrolyte is inferior to that in organic electrolyte. It is attributed to the loss of Li and the Fe, P dissolution during prolonged charge-discharge in aqueous medium. A precipitate is formed on the surface of LiFePO4 electrodes. It results in the change of crystalline structure, a large electrode polarization, and capacity fading.

Development of Design Response Spectra Based on Various Attenuation Relationships at Specific Location

Peninsular Malaysia is located and lies in a low seismic region. Although Malaysia is not located in the active fault seismic area, it is closed to the Sumatran active seismic zones. Tall building are fIequently felt the tremor generated fTom Sumatran subduction and fault zones especially in the west cost of Peninsular Malaysia such as Johor Bahru, Kuala Lumpur and Penang. Existing design response spectra was developed based on attenuation relationship for each subduction and fault zone. In this study, the design response spectra were developed based on various attenuation relationships for selected location in Kuala Lumpur area, namely, Mutiara Damansara, Bandar Petaling Jaya and Bandar Puteri Puchong. The development of design response spectra based on various attenuation relationships is more reliable in selecting the appropriate attenuation relationship for the study area. Seven attenuations have been chosen and results show that Megawati et al. are the most appropriate attenuation relation for fault zone, where the predicted PGA （peak ground acceleration） is 0.0187 g which is the proposed PGA value for this study area. This study also found that most of soil in the study area can be categorized into SD （stiff soil） according to site classification in the NEHRP 2000 Provision/UBC 97. Bandar petaling Jaya was found to be highest AF （amplification factor） of 3.74 for stiff soil and Mutiara Damansara with AF of 2.67 for very dense soil or soft rock. The proposed design response spectra for each location were developed based on UBC 1997 （Uniform Building Code 1997）. The peak RSA （response spectrum acceleration） of 0.30 g for soil type SD for Bandar Petaling Jaya is the maximum level of acceleration on the soil surface with a period range of 0.10 to 0.52 seconds. All these values can be used for the seismic safety evaluation of existing structures and as a guideline in designing new structures to resist future earthquake, within the study area.

Numerical Modeling of the Effect of Crack Parameters on Attenuation Anisotropy

Propagation through stress-aligned fluid-filled cracks and other inclusions have been claimed to be the cause of azimuthal anisotropy observed in the crust and upper mantle.This paper examines the behavior of seismic waves attenuation caused by the internal structure of rock mass,and in particular,the internal geometry of the distribution of fluid-filled openings Systematic research on the effect of crack parameters,such as crack density,crack aspect ratio(the ratio of crack thickness to crack diameter),pore fluid properties(particularly pore fluid velocity),VP/VS ratio of the matrix material and seismic wave frequency on attenuation anisotropy has been conducted based on Hudson's crack theory.The result shows that the crack density,aspect ratio,material filler,seismic wave frequency,and P-wave and shear wave velocity in the background of rock mass,and especially frequency has great effect on attenuation curves.Numerical research can help us know the effect of crack parameters and is a good supplement for laboratory modeling.However,attenuation is less well understood because of the great sensitivity of attenuation to details of the internal geometry.Some small changes in the characteristics of pore fluid viscosity,pore fluids containing gas and liquid phases and pore fluids containing clay can each alter attenuation coefficients by orders of magnitude.Some parameters controlling attenuation are therefore necessary to make reasonable estimations,and anisotropic attenuation is worth studying further.

Suppression dampens unpleasant emotion faster than reappraisal:Neural dynamics in a Chinese sample

The timing dynamics of regulating negative emotion with expressive suppression and cognitive reappraisal were investigated in a Chinese sample. Event-Related Potentials were recorded while subjects were required to view, suppress emotion expression to, or reappraise emotional pictures. The results showed a similar reduction in self-reported negative emotion during both strategies. Additionally, expressive suppression elicited larger amplitudes than reappraisal in central-frontal P3 component(340–480 ms). More importantly, the Late Positive Potential(LPP) amplitudes were decreased in each 200 ms of the 800–1600 ms time intervals during suppression vs. viewing conditions. In contrast, LPP amplitudes were similar for reappraisal and viewing conditions in all the time windows, except for the decreased amplitudes during reappraisal in the 1400–1600 ms. The LPP(but not P3) amplitudes were positively related to negative mood ratings, whereas the amplitudes of P3, rather than LPP, predict self-reported expressive suppression. These results suggest that expressive suppression decreases emotion responding more rapidly than reappraisal, at the cost of greater cognitive resource involvements in Chinese individuals.

Cathodic Zn underpotential deposition:an evitable degradation mechanism in aqueous zinc-ion batteries

Aqueous zinc-ion batteries(AZIBs)are promising for large-scale energy storage,but their development is plagued by inadequate cycle life.Here,for the first time,we reveal an unusual phenomenon of cathodic underpotential deposition(UPD)of Zn,which is highly irreversible and considered the origin of the inferior cycling stability of AZIBs.Combining experimental and theoretical simulation approaches,we propose that the UPD process agrees with a two-dimensional nucleation and growth model,following a thermodynamically feasible mechanism.Furthermore,the universality of Zn UPD is identified in systems,including VO_(2)//Zn,TiO_(2)//Zn,and SnO_(2)//Zn.In practice,we propose and successfully implement removing cathodic Zn UPD and substantially mitigate the degradation of the battery by controlling the end-ofdischarge voltage.This work provides new insights into AZIBs degradation and brings the cathodic UPD behavior of rechargeable batteries into the limelight.

Infrared spectroscopic study on chemical and phase equilibrium in triethylammonium acetate

Protic ionic liquid (PIL) triethylammonium acetate was prepared by mixing equimolar amounts of acetic acid and triethylamine, and then studied using the combination of the Attenuated Total Reflection Fourier Transform Infrared spectroscopy, in-situ infrared spectroscopy, pH, and conductivity titration measurements. It was found that the equimolar synthesized triethylammonium acetate was separated into two layers, which suggesting that there were both chemical and phase equilibrium in this solution. Molecular species could be directly observed in the IR spectra over the range of 1200-1800 cm-1 and also checked by 1H NMR. Based on analysis, the upper layer was rich in amine with little acid and PIL, and the down layer was rich in PIL with residual acetic acid and amine. And single PIL-rich layer could be separated into two layers again when the mole ratio of newly added triethyamine to the theoretical produced triethylammonium acetate reached 0.12.

Real-time in situ TEM studying the fading mechanism of tin dioxide nanowire electrodes in lithium ion batteries

Fading mechanism of tin dioxide （SnO2） electrodes in lithium ion batteries has attracted much attentions, which is of great importance for the battery applications. In this paper, electrochemical lithiation-delithiation cycles of individual SnO2 nanowires were conducted in situ in a high-resolution transmission electron microscopy （TEM）. Major changes in volume with expan- sions of 170%~300% on SnO2 nanowire electrodes were observed during the first lithiation process in electrochemical cycling, including conversion reaction of SnO2 precursor to Li20 matrix and active lithium host Sn, and alloying of Sn with Li to form brittle Li-Sn alloy. SnO2 nanowire electrodes were inclined to suffer from thermal runaway condition in the first two cycles. During cycling, morphology and composition evolution of SnO2 nanowire electrodes were recorded. Cyclic lithiation and del- ithiation of the electrode demonstrated the phase transition between Lii3Sn5 and Sn. Metallic Sn clusters were formed and their sizes enlarged with increasing cycle times. Detrimental aggregation of Sn clusters caused pulverization in SnO2 nanowire elec- trodes, which broke the conduction and transport path for electrons and lithium ions. The real-time in situ TEM revealed fading mechanism provides important guidelines for the viable design of the SnO2 nanowire electrodes in lithium ion batteries.

An Isoratio Method and an Isoratio Scaling Phenomenon in Heavy-Ion Collisions

An isoratio method is proposed to study the chemical potential of neutrons(protons) from the yield ratio of isotopes(isotones) differing in neutron-excess(I = N- Z). The measured fragments in the 140 A MeV ^(40),^(48) Ca and^(58),^(64) Ni +~9Be reactions, as well as those in the simulated^(58),^(64) Ni +~9Be reactions by using the antisymmetric molecular dynamics(AMD) model plus the secondary decay model gemini, have been adopted to perform the isoratio analysis.The results of the isoratio method verify that they are similar to that of the well known isoscaling method. The isoratio scaling phenomenon suggested by the isoratio method has also been found in the measured data and the fragments simulated by the AMD + gemini models.