Soluble phosphate fertilizers have been preferably used in plant crop production. The cost of applying conventional water soluble phosphate fertilizer is high in developing countries since their manufacturing requires...Soluble phosphate fertilizers have been preferably used in plant crop production. The cost of applying conventional water soluble phosphate fertilizer is high in developing countries since their manufacturing requires importing high grade rock phosphate （RP）. As a result, the use of indigenously available low-grade RP is gaining importance globally. In this study, experiments were carried out using clayey loamy alkaline soil to evaluate the agronomic efficiency of fine sized low grade RP with inorganic nitrogen fertilizers and it was further compared with that of soluble phosphate fertilizer （di-ammonium phosphate）, Cicer arietinum was the test crops subjected to treatments of absolute control, di-ammonium phosphate and low grade RP with varying concentrations of ammonium sulphate or ammonium nitrate. The experiments were conducted during 2012-2013 in the bid to study the growth rate and the biomass of the crop. Tests were also performed to determine the residual effects of the fertilizers on the crops. The results revealed that the combined use of low grade RP and ammonium sulphate or ammonium nitrate, at 16 kg N/ha, resulted in an agronomic efficiency, in terms of biomass of plants, comparable to that of di-ammonium phosphate and was found to be a more attractive management option for resource-poor farmers.展开更多
In this paper, the growth characteristics of Acidithiobacillus ferrooxidans （At.f） and Acidithiobacillus thiooxidans （At. f） in mixed culture has been studied, explored mixed bacteria phosphate solubilization effe...In this paper, the growth characteristics of Acidithiobacillus ferrooxidans （At.f） and Acidithiobacillus thiooxidans （At. f） in mixed culture has been studied, explored mixed bacteria phosphate solubilization effect, from a kind of low-grade phosphate rock. The results show that mixed bacteria has strong ability to produce acid, and have stronger oxidation activity to energy source -Fe^2＋. Mixed bacteria can significantly increase the rate of phosphate solubilization from phosphate rock in low concentration pulp. It goes against mixed bacteria reproduction when pulp concentration increased, makes phosphate solubilization rate decreased.展开更多
Electrolytic manganese residue leachate(EMRL)contains plenty of Mn^(2+) and NH_(4)^(+)-N,and phosphogypsum leachate(PGL)contains large amounts of PO_(4)^(3-)-P and F^(-).Traditional methods of EMRL and PGL discharge c...Electrolytic manganese residue leachate(EMRL)contains plenty of Mn^(2+) and NH_(4)^(+)-N,and phosphogypsum leachate(PGL)contains large amounts of PO_(4)^(3-)-P and F^(-).Traditional methods of EMRL and PGL discharge could seriously damage the ecological environment.In this study,an innovative method for cooperative removal Mn^(2+),NH_(4)^(+)-N,PO_(4)^(3-)-P,F^(-)from PG and POFT was studied.The result showed that Mn^(2+),PO_(4)^(3-)-P and F^(-)were mainly removed in forms of Mg_(3)Si_(4)O_(10)(OH)_(2),Mn_(3)O_(4),Mn_(3)(PO_(4))_(2),Mg_(3)(PO_(4))_(2),CaSO_(4)·2H_(2)O,MnF_(2),MnOOH and Ca_(2)P_(2)O_(7)·2H_(2)O,when LG-MgO was used to adjust the pH value of the system to 9.5,and the volume ratio of EMRL and PGL was 1:4,as well as reaction for 1 h at 25℃.NH_(4)^(+)-N was mainly removed by struvite precipitate,when the molar ratio of N:Mg:P was 1:3:2.4.The concentrations of Mn^(2+),NH_(4)^(+)-N and F^(-)were lower than the integrated wastewater discharge standard.The concentration of PO_(4)^(3-)-P decreased from 254.20 mg/L to 3.21 mg/L.This study provided a new method for EMRL and PGL cooperative harmless treatment.展开更多
文摘Soluble phosphate fertilizers have been preferably used in plant crop production. The cost of applying conventional water soluble phosphate fertilizer is high in developing countries since their manufacturing requires importing high grade rock phosphate （RP）. As a result, the use of indigenously available low-grade RP is gaining importance globally. In this study, experiments were carried out using clayey loamy alkaline soil to evaluate the agronomic efficiency of fine sized low grade RP with inorganic nitrogen fertilizers and it was further compared with that of soluble phosphate fertilizer （di-ammonium phosphate）, Cicer arietinum was the test crops subjected to treatments of absolute control, di-ammonium phosphate and low grade RP with varying concentrations of ammonium sulphate or ammonium nitrate. The experiments were conducted during 2012-2013 in the bid to study the growth rate and the biomass of the crop. Tests were also performed to determine the residual effects of the fertilizers on the crops. The results revealed that the combined use of low grade RP and ammonium sulphate or ammonium nitrate, at 16 kg N/ha, resulted in an agronomic efficiency, in terms of biomass of plants, comparable to that of di-ammonium phosphate and was found to be a more attractive management option for resource-poor farmers.
文摘In this paper, the growth characteristics of Acidithiobacillus ferrooxidans （At.f） and Acidithiobacillus thiooxidans （At. f） in mixed culture has been studied, explored mixed bacteria phosphate solubilization effect, from a kind of low-grade phosphate rock. The results show that mixed bacteria has strong ability to produce acid, and have stronger oxidation activity to energy source -Fe^2＋. Mixed bacteria can significantly increase the rate of phosphate solubilization from phosphate rock in low concentration pulp. It goes against mixed bacteria reproduction when pulp concentration increased, makes phosphate solubilization rate decreased.
基金Project(2018YFC1903500)supported by the National Key Research and Development Program of ChinaProject(52174386)supported by the National Natural Science Foundation of ChinaProject(2021YFH0058)supported by the Science and Technology Plan Project of Sichuan Province,China。
文摘Electrolytic manganese residue leachate(EMRL)contains plenty of Mn^(2+) and NH_(4)^(+)-N,and phosphogypsum leachate(PGL)contains large amounts of PO_(4)^(3-)-P and F^(-).Traditional methods of EMRL and PGL discharge could seriously damage the ecological environment.In this study,an innovative method for cooperative removal Mn^(2+),NH_(4)^(+)-N,PO_(4)^(3-)-P,F^(-)from PG and POFT was studied.The result showed that Mn^(2+),PO_(4)^(3-)-P and F^(-)were mainly removed in forms of Mg_(3)Si_(4)O_(10)(OH)_(2),Mn_(3)O_(4),Mn_(3)(PO_(4))_(2),Mg_(3)(PO_(4))_(2),CaSO_(4)·2H_(2)O,MnF_(2),MnOOH and Ca_(2)P_(2)O_(7)·2H_(2)O,when LG-MgO was used to adjust the pH value of the system to 9.5,and the volume ratio of EMRL and PGL was 1:4,as well as reaction for 1 h at 25℃.NH_(4)^(+)-N was mainly removed by struvite precipitate,when the molar ratio of N:Mg:P was 1:3:2.4.The concentrations of Mn^(2+),NH_(4)^(+)-N and F^(-)were lower than the integrated wastewater discharge standard.The concentration of PO_(4)^(3-)-P decreased from 254.20 mg/L to 3.21 mg/L.This study provided a new method for EMRL and PGL cooperative harmless treatment.
