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低吸附量煤岩和页岩等温吸附实验的负吸附原因 被引量:7
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作者 田文广 邓泽 +6 位作者 王红岩 刘洪林 李贵中 刘学军 陈振宏 陈浩 李亚男 《天然气工业》 EI CAS CSCD 北大核心 2018年第6期19-26,共8页
低吸附样品等温吸附实验经常出现反"V"形先升后降"负吸附"现象,成为困扰相关实验的测试难题。为此,基于前人的研究成果,引入大样量重量法等温吸附仪,分析了大样量重量法的测试原理和操作流程,对比了体积法、磁悬浮... 低吸附样品等温吸附实验经常出现反"V"形先升后降"负吸附"现象,成为困扰相关实验的测试难题。为此,基于前人的研究成果,引入大样量重量法等温吸附仪,分析了大样量重量法的测试原理和操作流程,对比了体积法、磁悬浮重量法和大样量重量法3种方法的优缺点,进而选取大样量重量法等温吸附仪对内蒙古二连盆地吉尔噶朗图凹陷吉煤2井低煤阶煤岩和川南地区某井下志留统龙马溪组页岩样品进行了等温吸附实验,以期在消除系统累计误差影响之后,探究出现"负吸附"现象的根本原因。实验结果表明:(1)大样量重量法测试中未出现"负吸附"现象,其对低煤阶煤岩和页岩样品的测试结果可靠,拟合度高(R^2>0.99);(2)电子传感器误差(天平、压力和温度等采集器件)、系统累计误差、吸附相密度取值差异等不会导致吸附曲线形态的反转性变化;(3)样品缸空体积误差是引起"负吸附"的根本原因。结论认为,在等温吸附解释算法中增加体积校正参数,可以提高测试的准确性。 展开更多
关键词 低吸附量 煤岩 页岩 等温吸附实验 吸附 体积法 样品缸 空体积误差 吸附相密度
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Synergistic Multilayer Adsorption for Low Concentration Dyestuffs by Biomass 被引量:1
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作者 Keith Kim Hung Choy Gordon Mckay 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第3期560-566,共7页
Due to the high cost of adsorbents and their thermal regeneration in recent years, much research has fo- cused on the search for cheaper adsorbents for treating wastewater from textile industry. The single component a... Due to the high cost of adsorbents and their thermal regeneration in recent years, much research has fo- cused on the search for cheaper adsorbents for treating wastewater from textile industry. The single component ad-sorption of an acidic dye, Acid Yellow 117, and a basic dye, Methylene Blue, onto several adsoroents-bamooo, waste wood, bamboo char, waste wood char, bamboo activated carbon, wood activated carbon and active carbon F400 were conducted. Based on a Langmuir analysis, the monolayer adsorption capacities were determined. Three of the adsorbents were selected for binary layer adsorption to check the multilayer concept and the potential application for better adsorbent usage. The two cheapest adsorbents, bamboo and wood are compared with the commer-cial activated carbon F400, and all three systems were successful. 展开更多
关键词 MULTILAYER ADSORPTION BIOMASS dyestuffs
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Removal of Cypermethrin with Seaweed Gracilaria lemaneiformis 被引量:1
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作者 WANG Zhaohui YUE Wenjie 《Journal of Ocean University of China》 SCIE CAS 2015年第5期858-864,共7页
Abstract The removal of cypermethrin with a red macroalga, Gracilaria lemaneiformis, was studied under laboratory conditions. Results showed that the residue contents with G. lemaneiformis were significantly lower tha... Abstract The removal of cypermethrin with a red macroalga, Gracilaria lemaneiformis, was studied under laboratory conditions. Results showed that the residue contents with G. lemaneiformis were significantly lower than those corresponding groups without the algal thalli after 96 h treatment. The removal rates decreased with increasing concentrations, which were about 50% without G. lemaneiformis after 96h exposure, and increased to 89%, 73%, and 66% in flasks with G. lemaneiformis at the concentrations of 10, 100, and 1000 gg L-1, respectively. The amount of biosorption (absorption and adsorption) by G. lemaneiformis increased with the increasing concentration and exposure time. Adsorption was the main process for the removal by G. lemaneiformis, which accounted for 75%-97% of the total biosorption. However, biosorption only contributed 0.5%-19.3% to the total losses of cypermethrin, which was more efficient under the low concentration. Natural losses contributed the largest portion of losses, which was over 65% in all treatments during the experiment. The unknown pathway of removal, which might be the bio-decomposed by microorganisms attaching the algal thalli, also contributed a lot to the total removal. The results suggested that cultivation of G. lemaneiformis could significantly remove cypermethrin, especially at low concentrations, and large-scale cultivation of G. lemaneiformis has considerable potential of biorestoration of eutrophic and cypermethrin-poUuted coastal sea areas. 展开更多
关键词 CYPERMETHRIN Gracilaria lemaneiformis REMOVAL BIOSORPTION marine environment
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