The oxidation process of low-grade vanadium slag in the presence of Na2CO3 was investigated by XRD,SEM/EDS and TG-DSC techniques.The results show that the vanadium slag is oxidized in a temperature range from 273 to 7...The oxidation process of low-grade vanadium slag in the presence of Na2CO3 was investigated by XRD,SEM/EDS and TG-DSC techniques.The results show that the vanadium slag is oxidized in a temperature range from 273 to 700 °C.Olivine phases and spinel phases are completely decomposed at 500 and 600 °C,respectively.Most of water-soluble sodium vanadates are formed between 500 and 600 °C.When roasting temperature reaches above 700 °C,the vanadium-rich phases of sodium vanadates can be obviously observed.However,at temperature above 800 °C,the samples are sintered.Most of the vanadium is enwrapped by glassy phase compounds which lead to the decrease of the leaching rate of vanadium.At the same time,the effect of roasting temperature on extraction of vanadium and characterization of leach residues were discussed.展开更多
In this study, the benefication of low-grade Espey -10 mm. colemanite stocks of more than 30,000 tons, which have been waiting for longer years, can not be evaluated in any way in Emet Boron Works in order to get sala...In this study, the benefication of low-grade Espey -10 mm. colemanite stocks of more than 30,000 tons, which have been waiting for longer years, can not be evaluated in any way in Emet Boron Works in order to get salable product. Chemical, physical, mineralogical and thermal characterization of low-grade colemanite stock, in the sizes of 10 mm, are located in Espey region primarily conducted. Grades of 10 mm size of Espey used in this study is 28.87% B203. In the microwave experiments, a concentrate of 50.82% B203 was obtained with the efficiency of 88.13%. Evaluating colemanite concentrate by microwave technology may have great importance in solving environmental problem.展开更多
基金Project (2008AA031104) supported by the National High-tech Research and Development Program of China Project (2010063003) supported by the Sharing Fund of Large-scale Equipment of Chongqing University,China
文摘The oxidation process of low-grade vanadium slag in the presence of Na2CO3 was investigated by XRD,SEM/EDS and TG-DSC techniques.The results show that the vanadium slag is oxidized in a temperature range from 273 to 700 °C.Olivine phases and spinel phases are completely decomposed at 500 and 600 °C,respectively.Most of water-soluble sodium vanadates are formed between 500 and 600 °C.When roasting temperature reaches above 700 °C,the vanadium-rich phases of sodium vanadates can be obviously observed.However,at temperature above 800 °C,the samples are sintered.Most of the vanadium is enwrapped by glassy phase compounds which lead to the decrease of the leaching rate of vanadium.At the same time,the effect of roasting temperature on extraction of vanadium and characterization of leach residues were discussed.
文摘In this study, the benefication of low-grade Espey -10 mm. colemanite stocks of more than 30,000 tons, which have been waiting for longer years, can not be evaluated in any way in Emet Boron Works in order to get salable product. Chemical, physical, mineralogical and thermal characterization of low-grade colemanite stock, in the sizes of 10 mm, are located in Espey region primarily conducted. Grades of 10 mm size of Espey used in this study is 28.87% B203. In the microwave experiments, a concentrate of 50.82% B203 was obtained with the efficiency of 88.13%. Evaluating colemanite concentrate by microwave technology may have great importance in solving environmental problem.
