The effects of low temperature thermo-mechanical treatment （LTTMT） on microstructures and mechanical properties of Ti-6Al-4V （TC4） alloy were studied by optical microscopy （OM）, tensile test, scanning electron m...The effects of low temperature thermo-mechanical treatment （LTTMT） on microstructures and mechanical properties of Ti-6Al-4V （TC4） alloy were studied by optical microscopy （OM）, tensile test, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. The experimental results confirm that the strength of TC4 alloy can be improved obviously by LTTMT processing, which combines strain strengthening with aging strengthening. The effect of LTTMT on the alloy depends on the microstructure of the refined and dispersed a＋fl phase on the basis of high dislocation density by pre-deformation below recrystallization temperature. The tensile strength decreases with the increase of pre-deformation reduction. The optimal processing parameters of LTTMT for TC4 alloy are as follows： solution treatment at 900 ℃ for 15 min, pre-deformation in the range of 600-700 ℃ with a reduction of 35%, finally aging at 540 ℃ for 4 h followed by air-cooling.展开更多
The influences of BaCu（B2O5） （BCB） addition on sintering, microstructure and microwave dielectric properties of Li2MgTi308 ceramics were investigated using X-ray diffractometry, scanning electron microscopy and mi...The influences of BaCu（B2O5） （BCB） addition on sintering, microstructure and microwave dielectric properties of Li2MgTi308 ceramics were investigated using X-ray diffractometry, scanning electron microscopy and microwave dielectric measurements. The experimental results show that a small amount of BaCu（B2O5） addition can effectively reduce the sintering temperature to 900℃, and induce only a limited degradation of the microwave dielectric properties. Typically, the best microwave dielectric properties of er24.5, Q×f =24 622 GHz, rf=4.2×10-6℃ -1 are obtained for 1.0% BCB-doped Li2MgTi3O8 ceramics sintered at 900℃ for 3 h. The BCB-doped Li2MgTi3O8 ceramics can be compatible with Ag electrode, which may be a strong candidate for low temperature co-fired ceramics applications.展开更多
Al-doped ZnO (ZAO) films were successfully deposited on the surface of common glasses by using low-temperature hydrothermal approach. In the reaction solution, the molar ratio of Al3+ to Zn2+ was 1∶100, the annealing...Al-doped ZnO (ZAO) films were successfully deposited on the surface of common glasses by using low-temperature hydrothermal approach. In the reaction solution, the molar ratio of Al3+ to Zn2+ was 1∶100, the annealing temperature and time were 200 ℃ and 2-6 h, respectively. The structure of the thin films was identified by X-ray diffraction (XRD), the surface morphology and thickness of the thin films were observed by scanning electron microscopy (SEM), and the electrical performance of the thin films was measured by four-point probes. It was shown that the films with an average particle size of 27.53 nm had a preferential orientation along (002), Al3+ had replaced the position of Zn2+ in the lattice without forming the Al2O3 phase and its thickness was 20-25 μm. With the increased annealing time, the intensity of diffraction peaks was decreased, the film exhibited irregular surface morphology gradually, and the resistivity of ZAO films was increased. The lowest resistivity obtained in this study was 3.45×10-5Ω·cm.展开更多
In order to investigate the effects of strain rate and temperature on the microstructure and texture evolution during warm deformation of wrought Mg alloy,AZ31 extruded rods were cut into cylinder samples with the dim...In order to investigate the effects of strain rate and temperature on the microstructure and texture evolution during warm deformation of wrought Mg alloy,AZ31 extruded rods were cut into cylinder samples with the dimension of d8 mm×12 mm.The samples were compressed using a Gleeble 1500D thermo-mechanical simulation machine at various strain rates(0.001,0.01,0.1,1 and 5 s- 1)and various temperatures(300,350,400 and 450℃).The microstructure and texture of the compressed samples at the same strain under different deformation conditions were studied and compared by electron backscatter diffraction(EBSD)in scanning electron microscope(SEM).The results show that the size of recrystallized grains in the deformed samples generally increases with the decrease of strain rate and the increase of temperature.After 50%reduction,most basal planes are aligned perpendicular to the compression direction at relatively high strain rate(>0.01 s- 1)or low temperature(<350℃).The optimized strain rate is 0.1 s- 1for uniaxial compression at 300℃,which produces about 80%of small grains(<5μm).展开更多
Photocatalytic activity of doped polyaniline nanopowders with different molar ratio of An/O （aniline^oxidizer） has been studied in the process of photocatalytic decolorization of aqueous solutions of methylene blue....Photocatalytic activity of doped polyaniline nanopowders with different molar ratio of An/O （aniline^oxidizer） has been studied in the process of photocatalytic decolorization of aqueous solutions of methylene blue. By means of scanning electron microscopy and low-temperature N2 adsorption method, it was found that doped PANI （polyaniline） nanopowders have the particles size of 30-50 nm with the specific surface area of 20-35 m2.g＂~. It was found that PANI photocatalytic activity essentially depends on molar ratio of An/O and adsorption interactions between the dye molecules and catalytic active centers on PANI surface and these interactions are greatly affected by pH of the solution 9.2. An optimum of the synergetic effect is found for an initial molar ratio of aniline to oxidizer equal to 0.8.展开更多
The BiOCI thin film with flower-like sphere structure was prepared at a low temperature by the alcoholysis-coating method using BiC13 as precursor. The obtained thin film was characterized by X-ray diffraction （XRD）...The BiOCI thin film with flower-like sphere structure was prepared at a low temperature by the alcoholysis-coating method using BiC13 as precursor. The obtained thin film was characterized by X-ray diffraction （XRD）, scanning electron microscopy （SEM）, electronic energy spectrum （EDS） and ultraviolet-visible diffuse reflectance spectroscopy （UV-vis DRS）. And the re- suits showed that the obtained BiOC1 film without calcination was composed of flower-like sphere structure with tetragonal phase and had a good absorption for ultraviolet. The photocatalytic activity of BiOC1 thin film was also evaluated by the deg- radation of methyl orange in water under UV light irradiation. The degradation experimental results confirmed that the film prepared at low temperature possessed a high photocatalytic activity and could achieve 97% degradation to 10 mg/L methyl orange solution after 150 min UV light irradiation. The stability of the obtained BLOC1 thin film was also good and its photo- catalytic activity still remained an above 94% removal of methyl orange after being used four times. In addition, a possible formation mechanism of BiOCI thin film was also inferred and the results suggested that the ethylene glycol solvent may con- tribute to the forming flower-like sphere structure.展开更多
文摘W962834 大麦发芽力估测方法的评价[告,英]/Parker,D.K.…∥HGCA Project Report.-London,UK:Home Grown Cereals Authority,1994,(100).-83p[WBTA,1996,13(1),674]W962835 利用热解重力法研究 ambiol 对大麦种子膨胀的影响[刊,英]/Voronina,S.S.…∥BiologyBulletin of the Russian Academy of Sciences.-1994,21(3).-363～365[WBTA,1996,13(1),675]W962836
基金Project(2008WK2005) supported by the Science and Technology Plan of Hunan Province, China
文摘The effects of low temperature thermo-mechanical treatment （LTTMT） on microstructures and mechanical properties of Ti-6Al-4V （TC4） alloy were studied by optical microscopy （OM）, tensile test, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. The experimental results confirm that the strength of TC4 alloy can be improved obviously by LTTMT processing, which combines strain strengthening with aging strengthening. The effect of LTTMT on the alloy depends on the microstructure of the refined and dispersed a＋fl phase on the basis of high dislocation density by pre-deformation below recrystallization temperature. The tensile strength decreases with the increase of pre-deformation reduction. The optimal processing parameters of LTTMT for TC4 alloy are as follows： solution treatment at 900 ℃ for 15 min, pre-deformation in the range of 600-700 ℃ with a reduction of 35%, finally aging at 540 ℃ for 4 h followed by air-cooling.
基金Project(2010GXNSFA013029) supported by the Natural Science Foundation of Guangxi Province,ChinaProject(101059529) supported by National Undergraduate Innovation Program of the Ministry of Education of China
文摘The influences of BaCu（B2O5） （BCB） addition on sintering, microstructure and microwave dielectric properties of Li2MgTi308 ceramics were investigated using X-ray diffractometry, scanning electron microscopy and microwave dielectric measurements. The experimental results show that a small amount of BaCu（B2O5） addition can effectively reduce the sintering temperature to 900℃, and induce only a limited degradation of the microwave dielectric properties. Typically, the best microwave dielectric properties of er24.5, Q×f =24 622 GHz, rf=4.2×10-6℃ -1 are obtained for 1.0% BCB-doped Li2MgTi3O8 ceramics sintered at 900℃ for 3 h. The BCB-doped Li2MgTi3O8 ceramics can be compatible with Ag electrode, which may be a strong candidate for low temperature co-fired ceramics applications.
文摘Al-doped ZnO (ZAO) films were successfully deposited on the surface of common glasses by using low-temperature hydrothermal approach. In the reaction solution, the molar ratio of Al3+ to Zn2+ was 1∶100, the annealing temperature and time were 200 ℃ and 2-6 h, respectively. The structure of the thin films was identified by X-ray diffraction (XRD), the surface morphology and thickness of the thin films were observed by scanning electron microscopy (SEM), and the electrical performance of the thin films was measured by four-point probes. It was shown that the films with an average particle size of 27.53 nm had a preferential orientation along (002), Al3+ had replaced the position of Zn2+ in the lattice without forming the Al2O3 phase and its thickness was 20-25 μm. With the increased annealing time, the intensity of diffraction peaks was decreased, the film exhibited irregular surface morphology gradually, and the resistivity of ZAO films was increased. The lowest resistivity obtained in this study was 3.45×10-5Ω·cm.
基金Project(2007CB613703)supported by the National Basic Research Program of ChinaProject(50890172)supported by the National Natural Science Foundation of China
文摘In order to investigate the effects of strain rate and temperature on the microstructure and texture evolution during warm deformation of wrought Mg alloy,AZ31 extruded rods were cut into cylinder samples with the dimension of d8 mm×12 mm.The samples were compressed using a Gleeble 1500D thermo-mechanical simulation machine at various strain rates(0.001,0.01,0.1,1 and 5 s- 1)and various temperatures(300,350,400 and 450℃).The microstructure and texture of the compressed samples at the same strain under different deformation conditions were studied and compared by electron backscatter diffraction(EBSD)in scanning electron microscope(SEM).The results show that the size of recrystallized grains in the deformed samples generally increases with the decrease of strain rate and the increase of temperature.After 50%reduction,most basal planes are aligned perpendicular to the compression direction at relatively high strain rate(>0.01 s- 1)or low temperature(<350℃).The optimized strain rate is 0.1 s- 1for uniaxial compression at 300℃,which produces about 80%of small grains(<5μm).
文摘Photocatalytic activity of doped polyaniline nanopowders with different molar ratio of An/O （aniline^oxidizer） has been studied in the process of photocatalytic decolorization of aqueous solutions of methylene blue. By means of scanning electron microscopy and low-temperature N2 adsorption method, it was found that doped PANI （polyaniline） nanopowders have the particles size of 30-50 nm with the specific surface area of 20-35 m2.g＂~. It was found that PANI photocatalytic activity essentially depends on molar ratio of An/O and adsorption interactions between the dye molecules and catalytic active centers on PANI surface and these interactions are greatly affected by pH of the solution 9.2. An optimum of the synergetic effect is found for an initial molar ratio of aniline to oxidizer equal to 0.8.
基金financially supported by the National Natural Science Foundation of China (20876104, 21176168)by the Science and Technology Foundation of Shanxi Province, China (20090311082)
文摘The BiOCI thin film with flower-like sphere structure was prepared at a low temperature by the alcoholysis-coating method using BiC13 as precursor. The obtained thin film was characterized by X-ray diffraction （XRD）, scanning electron microscopy （SEM）, electronic energy spectrum （EDS） and ultraviolet-visible diffuse reflectance spectroscopy （UV-vis DRS）. And the re- suits showed that the obtained BiOC1 film without calcination was composed of flower-like sphere structure with tetragonal phase and had a good absorption for ultraviolet. The photocatalytic activity of BiOC1 thin film was also evaluated by the deg- radation of methyl orange in water under UV light irradiation. The degradation experimental results confirmed that the film prepared at low temperature possessed a high photocatalytic activity and could achieve 97% degradation to 10 mg/L methyl orange solution after 150 min UV light irradiation. The stability of the obtained BLOC1 thin film was also good and its photo- catalytic activity still remained an above 94% removal of methyl orange after being used four times. In addition, a possible formation mechanism of BiOCI thin film was also inferred and the results suggested that the ethylene glycol solvent may con- tribute to the forming flower-like sphere structure.
