SBR工艺对低碳量城市污水的反硝化除磷研究

广州地区的城市污水含碳量低,碳、氮、磷浓度比例失调,采用传统工艺处理很难达到理想的脱氮除磷效果,为此采用SBR工艺对其进行处理,考察了该工艺的反硝化除磷效果。结果表明,在厌氧/缺氧/好氧的运行模式下,采用逐步增加缺氧段运行时间的方法可有效提高污泥的反硝化除磷性能;在试验进水水质条件下,反应器厌氧运行30 min、缺氧运行3 h、好氧运行1 h可保证对磷的稳定高效去除,出水TP<1 mg/L;ORP值无法指示缺氧反硝化与吸磷过程,pH值可作为缺氧吸磷结束的指示参数,而ORP和pH值均可作为好氧吸磷结束的控制参数。

低掺量碳纤维混凝土试验研究

研究了低掺量短切碳纤混凝土的力学和断裂性能，碳纤分散技术和与钢纤混掺效应．碳纤能有效地提高混凝土初裂强度和韧性；碳纤与钢纤混掺更能发挥各自优势，能配制出一种高性能复合材料．

Strategic deliberation on development of low-carbon energy system in China

In recent years, there have been considerable developments in energy provision with the growing improvements in energy supply security and support systems in China. However, China's energy system continues to retain a high-carbon feature where coal dominates energy production and consumption, which has led to the rapid growth of greenhouse gas emissions and associated serious environmental pollution. It has therefore become an important task for China to consider how to promote the low-carbon development of energy system. This paper summarized the basic trends and challenges for development of low-carbon energy system in China and studied the primary energy consumption and carbon emissions in different scenarios at 10-year intervals between 2010 and 2050. The analysis showed that controlling coal consumption will have an important influence on the control of total carbon emissions and of carbon emission peaking; promotion of non-fossil fuel energies will offer a growing contribution to a low-carbon transition in the medium and long term; the development of carbon capture, utilization, and storage will play a key role in realizing a deep decarbonization pathway, particularly after 2030; and the establishment of a low-carbon power system is crucial for the achievement of low-carbon energy transition. Finally, the strategic considerations and policy suggestions on the development of low-carbon energy systems in China are explored.

Influence of fly ash on early-age cracking behavior of high-flowing concrete

The effects of quality and content of fly ash on the early-age cracking behavior of high-flowing concrete （HFC） were investigated. The early-age cracking behavior of the HFC was analyzed by combining the tests of evaporation capacity and electrical resistivity of the HFC. In these tests, a modified flat-type specimen was adopted. The results show that the HFC will have a lower evaporation capacity when it is mixed with fine fly ash, while it will have a higher evaporation capacity when grade II! fly ash is used as mineral admixture. And the electrical resistivity rate of HFC reduces with the increase of the content of fly ash. A nonlinear relationship exists between the cracking time of HFC and the minimum electrical resistivity. The early-age cracking behavior of HFC with fly ash can be enhanced by appropriately increasing the fine particle content and MgO, K2O, and SO3 contents of fly ash. The optimal content of fly ash, which makes a satisfied early-age cracking behavior of HFC, is obtained. And when the content of fly ash exceeds a critical value, the early-age cracking behavior of HFC will rapidly decrease.

Copper and platinum dual-single-atoms supported on crystalline graphitic carbon nitride for enhanced photocatalytic CO_(2) reduction

Single-atom Pt catalysts are designed to promote efficient atom utilization,whereas effective decrease of Pt loading and improvement of photocatalytic activity in monoatomic Pt-deposited systems is still ongoing.Atomically dispersed metal species in crystalline carbon nitride are still challenging owing to their high crystallization and structural stability.In this study,we developed a novel single-atomic Pt-Cu catalyst for reducing noble metal loading by combining Pt with earth-abundant Cu atoms and enhancing photocatalytic CO_(2)reduction.N-vacancy-rich crystalline carbon nitride was used as a fine-tuning ligand for isolated Pt-Cu atom dispersion based on its accessible functional N vacancies as the seeded centers.The synthesized dimetal Pt-Cu atoms on crystalline carbon nitride(Pt Cu-cr CN)exhibited high selectivity and activity for CO_(2)conversion without the addition of any cocatalyst or sacrificial agent.In particular,we demonstrated that the diatomic Pt-Cu exhibited high mass activity with only 0.32 wt% Pt loading and showed excellent photocatalytic selectivity toward CH_(4)generation.The mechanism of CO_(2)photoreduction for Pt Cu-cr CN was proposed based on the observations and analysis of aberration-corrected high-angle annular dark-field scanning transmission electron microscopy images,in situ irradiated X-ray photoelectron spectroscopy,and in situ diffuse reflectance infrared Fourier transform spectroscopy.The findings of this work provide insights for abrogating specific bifunctional atomic metal sites in noble metal-based photocatalysts by reducing noble metal loading and maximizing their effective mass activity.

Coalification and coal alteration under mild thermal conditions

Coalification temperatures are often considered to be approximately 100-170 ℃ for bituminous coal and 170-275 ℃ for anthracite. However, our micropetrographic observations, solid state ^27Al magic-angle spinning nuclear magnetic resonance measurements, interpretation of δ^13C values for whewellite in pelosiderite concretions from Carboniferous sediments, and assessment of whewellite thermal stability show that coalification temperatures can be significantly lower. Also the temperatures of coal alteration may be substantially lower than is stated. Ordinarily, high- temperature alteration is reported, but microthermometric measurements of fluids temperatures and micropetrographic observations show that the coal alteration can take place at low temperatures. For this reason, coals from the Kladno- Rakovnik Basin, part of Late Paleozoic continental basins of the Czech Republic, were analyzed. Regarding coalification, micropetrographic characterizations of unaltered coals, the presence of thermally unstable Al complexes in the coal organic mass documented using ^27Al MAS NMR method, and proven occurrence of whewellite in pelosiderite concretions suggest a lower coalification temperature, max. -70 ℃. Regarding coal alteration, micropetrographic observations revealed （a） the weaker intensity of fluorescence of liptinite, （b） mylonitic structures and microbreccia with carbonate fluid penetration, and （c） high oxygen content in coals （37-38 wt.%）. These phenomena are typical for thermal and oxidative alteration of coal. As the temperature of carbonate fluids inferred from fluid inclusion analysis was evaluated as -100-113 ℃, the temperature of coal alteration was suggested as -113℃; the alteration was caused by hot hydrothermal fluids.

2,3,5-Triphenyl-2H-tetrazolium Chloride and 2,4,6-Tri（2-pyridyl）-s-triazine on the Corrosion of Mild Steel in HCl

Electrochemical measurement, quantum chemical method, and scanning electron microscopy （SEM） were performed to investigate the inhibitive effect of 2,3,5-triphenyl-2H-tetrazolium chloride （TTC） and 2,4,6-tri（2-pyridyl） -s-triazine（TPT） on the corrosion of mild steel in lmol.L^-1 HCl at room temperature. Impedance spectroscopy measurement showed that the polarization resistance increased and that double layer capacitance decreased with the increase in the inhibitive concentration, and the results of potentiodynamic polarization showed that the inhibitors suppressed both cathodic and anodic processes of steel corrosion without change in the mecha-nism. Higher the orbital density distribution strength of the lowest unoccupied molecular orbital, higher is the molecule dipole, and lower energy gap between the energy of the highest occupied molecular orbital and the energy of the lowest unoccupied molecular orbital resulted in higher inhibitory efficiency. The results of SEM analysis showed that the metal-was protected from aggressive corrosion by the addition of TTC and TPT.

LARGE VOLUME IONIZATION CHAMBER USED AS LABORATORY REFERENCE FOR LOW ENERGY X－RAY MEASUREMENT

A large volume spherical ionization chamber of 195 mm diameter and 0.36 mg/cm2wall thickness made from conducting carbon-fibre epoxy composite material has been developed. The mechanical intensity of the chamber is satisfactory for a good longterm volume stability. Owing to its large volume and thin wall, the chamber is sensitive to low energy photon beams and has excellent energy-response characteristics. This ionization chamber is suitable not only for a laboratory reference but also for measurement of low energy photon beam exposure rates at protection-level.

Development of Low Carbon Aquaculture System by Using Zeolite

Ammonia volatilization is a major process of N （nitrogen） loss that affects the environment. The best way of capturing volatilized ammonia-N could be using zeolite as a good ion exchange medium before it gets either volatilized or nitrified. Thus, captured ammonia-N could be used as a source of inorganic nitrogen in ponds to promote algal production without adding additional organic carbon and BOD （biochemical oxygen demand）. The zeolite used for the study was a commercially available zeolite, （CLINZEX） which was a fine powder （CEC （cation exchange capacity） 3.9-4 meq/g）. The experiment was conducted to assess the difference between manure loaded system and zeolite loaded system in terms of water quality, TAN （total ammoniacal nitrogen） release and algal productivity. The difference between the BOD values recorded in both the controls and treatments utilizing chicken manure as source of manure-N remained mostly above 10 ppm. Similarly, the difference between mean COD （chemical oxygen demand） values of control and treatment tanks always remained above 7 ppm. All the experimental tanks loaded with zeolite samples from chicken manure showed range of variation in TAN values （0.018-0.08 mg/1）. The range of values of chlorophyll a （1,029-5,150 mg/m~） recorded in the treatment tanks was higher than the values （54.6-1347 mg/m3） of chlorophyll a in the control tanks. F-test analysis done using highest mean values of BOD, COD, TAN and chlorophyll a showed a highly significant （P 〈 0.01） variation between the treatment and control tanks and at the same time no significant variation was found between time intervals.

Seafarers＇ Current Awareness, Knowledge, Motivation and Ideas towards Low Carbon-Energy Efficient Operations

International and national concern about detrimental climate change has generated pressure for the shipping industry to play its＇ role in reducing the 3.3% of global carbon emission it emits. On the 1st January, 2013, the IMO （International Maritime Organisation） enforced regulations to support the reduction of shipping carbon emissions by improving energy efficiency. These measures directly and indirectly affect the daily operations of seafarers and onshore performance and managerial personnel. Whilst the industry has made efforts to raise the awareness of many stakeholders and research has been undertaken to investigate energy efficiency barriers, little has been done to capture the opinions, needs and knowledge of seafarers. A questionnaire was distributed in the last quarter of 2011 to investigate seafarers＇ awareness, knowledge and motivation towards carbon emissions in general and towards shipping carbon emissions. It also investigated opinions as to which personnel have the most influence over carbon reductions and what are the most important operational improvements that can be made. The authors have collected 317 questionnaire responses. The primary benefit of this study is to support the identification of an operational strategy to improve energy efficiency, including the development of LC-EE （low carbon-energy efficiency） MET （maritime education and training）, which is shown to be needed.

Apply of Low-Carbon Technology in Building Energy Conservation in Hot Summer and Cold Winter Area

Building energy conservation is the basis for carbon emission reduction, through elaborating the relationship between low carbon and energy efficient building. It points out that the construction of energy-saving emission reduction is an effective means to solve the problems of high energy consumption of the building, and it is also an important measure for China＇s carbon emission reduction. According to the climate characteristics in hot summer and cold winter area, low carbon technology suitable for the construction of energy-efficient hot summer and cold winter area is proposed which is based on the analysis of the current main building energy-saving technical measures.

Low Carbon Society in China: Research and Practice

This paper aims to provide an overall image in terms of low carbon society （LCS） and its development in China. It mainly introduced and analyzed low carbon development which was addressed as crucial initiative for implementation of LCS in China. A comparative analysis was carried out on concepts and experiences of LCS between China and developed countries. The trends and characteristics of CO2 emissions in China have also been analyzed. Because of large amount of CO2 emissions generated in the production process and relatively small amount of CO2 emissions in the consumption process, China is facing a severe challenge of imbalance in economic growth and CO2 emissions. If the consumption and production pattern of developed countries are duplicated, China is very likely to experience a development pattern of boosting economic growth and improving living standards significantly but meanwhile risking and suffering by large amount of resources consumption and CO2 emissions. Thus, a comprehensive, systematic and scientific scheme for implementing a low carbon society is urgently needed in China. Through literature research, mainstream perspectives of scholars with respect to development of LCS are concluded. In the meantime, CO2 emissions reduction target, carbon taxation and different debated issues are also presented. The achievements, China has rflade, consist of concrete actions taken by local governments, some new policies and regulations for carbon reduction at national level, in particular energy-saving and renewable energy policies proposed in the l lth Five-Year Plan （2005-2010）. Carbon trading markets and carbon capture and starage technology have also made progress in China. There are still many limitations and barriers remaining and in need to be solved in the next steps.

Low-carbon scenario and technologies in modern city——Case study of Shenyang

From a multi-dimensional perspective of economic development,carbon dioxide and industrial pollutant emission and resource consumption in the case study of Shenyang,this paper analyzes the resource consumption and environmental impact in the process of urban economic development and low-carbon transition and evaluates the emission reduction potential and scenario of various technologies. The results show that city plays a key role in global low-carbon economic construction,and it is pointed out that emission reduction technology in urban scale can reduce total amount of carbon emission to substantial extent. From the aspect of future development,the input of technology and economic growth pattern should be strengthened so as to realize economic development as well as the total amount reduction of pollutant emission.

Discussion on the Construction of low-carbon electricity technology innovation system

With the issue of climate change increasingly restricting the sustainable development of society, people must realize that we must control atmospheric concentrations of greenhouse gases at a certain level. However, the traditional model of economic development will lead to human demand for energy continuing to grow, followed by a growth in emissions of carbon dioxide. Obviously we must ensure that there is rapid economic development, but also to protect the human living environment, which is a very sharp contradiction. A good solution to this conflict is to take a new model of development --- a low-carbon economy. The so-called low-carbon economy refers to the reduction of greenhouse gas emissions, the application of new technologies, new materials and new practices, etc., through improvements, optimization or innovative production and business activities, to achieve the maximum degree of reduction of greenhouse gas emissions, and the formation of a new economic development model, the goal is to mitigate climate change and promote sustainable human development. On how to develop a low-carbon economy, domestic and foreign scholars have been studied from many angles, one of which is a consensus to reduce greenhouse gas emissions through the development and use of low-carbon technologies.

China's Voluntary Mitigation Target and Road of Low-carbon Development

China is going through a rapid development stage of industrialization and urbanization.Although tremendous achievements have been made in the aspects of energy conservation,improvement of energy effectiveness and development of new and renewable energies,because of the rapid development of economy,it is difficult to change the huge total amount and fast increase of CO2 emission in the near future.China has to confront the tough challenge to address global climate change.China plans to reduce carbon intensity,that is,CO2 emissions per unit GDP,by 40 to 45% by 2020 compared with the 2005 level.It is a strategic option to coordinate domestic sustainable development with coping with global climate change on the basis of China's national circumstances,representing the core content and key measures for transforming development pattern and realizing low-carbon development.To achieve the target,more capital and technology inputs are required for energy conservation and low-carbon development during the twelfth and Thirteenth Five Year Plan period than in the Eleventh Five Year Plan period.In addition,energy conservation achieved by structural adjustment,industrial upgrading and product value-added improvement is also expected to play a greater role.Therefore,China should strengthen technological innovation,make greater efforts to transform the development pattern,take advantage of the synergistic effect of policies and measures while coping with global climate change and building a domestic tow-oriented society.China should also establish an industrial system characterized by low-carbon emission.Then China will ultimately achieve a win-win situation in both domestic sustainable development and coping with global climate change.

Soil organic carbon pool along different altitudinal level in the Sygera Mountains, Tibetan Plateau

Labile organic carbon（LOC） is one of the most important indicators of soil organic matter quality and dynamics elevation and plays important function in the Tibetan Plateau climate. However, it is unknown what the sources and causes of LOC contamination are. In this study, soil organic carbon（SOC）, total nitrogen（TN）, microbial biomass carbon（MBC）, microbial biomass nitrogen（MBN） and LOC were analyzed based on different soil horizons and elevations using turnover time in an experimental site（3700 m to 4300 m area） in Sygera. SOC and LOC in higher-elevation vegetation types were higher than that of in lower-elevation vegetation types. Our results presented that the soil microbial biomass carbon（SMBC） and soil microbial biomass nitrogen（SMBN）were positively correlated with SOC. The content of easily oxidized carbon（EOC）, particulate organic carbon（POC） and light fraction organic carbon（LFOC） decreased with depth increasing and the content were the lowest in the 60 cm to 100 cm depth.The total SOC, ROC and POC contents decreased with increasing soil horizons. The SOC, TN, MBC and MBN contents increased with increasing altitude in the Sygera Mountains. The MBC and MBN contents weredifferent with the changes of SOC（p＆lt;0.05）,meanwhile, both LFOC and POC were related to total SOC（p＆lt;0.05）. The physical and chemical properties of soil, including temperature, humidity, and altitude,were involved in the regulation of SOC, TN, MBC,MBN and LFOC contents in the Sygera Mountains,Tibetan Plateau.

China’s Transition to a Low-Carbon Economy:2006-2010

China achieved major progress in low-carbon development during the period of the 11th Five Year Plan (2006-2010). The increasing trend of energy intensity and carbon intensity of the economy as seen prior to 2005 was reversed to a sharp decreasing trend, leading to a 19% decrease in energy intensity and 21% decrease in carbon intensity in five years. The enhanced energy efficiency, mostly due to efficiency improvement in power and manufacturing sector, is the major driver of the decrease in carbon intensity of the economy. The development of renewable energy, despite its impressive growth rate, played a minor role because of its small share in the energy mix of the country. Energy con-sumption and energy-related carbon emissions per unit of area in building continued to grow at a lesser rate, which, combined with the fast growth of total building volume, led to fast growth in total energy consumption and carbon emissions in the sector. Similar trend is observed in the transportation sector whose total energy use and carbon emissions continued to grow fast despite slight improvement in energy efficiency. Agricultural energy use experienced a slight change and forestry made a major contribution to carbon sinks. Policy and institutional innovations helped build a solid system of rules for low-carbon development. Improving cost effectiveness of the system remains a major challenge for the next five year plan period.

Understanding the discrepancy between the quality and yield in the synthesis of carbon nanotubes

High-quality carbon nanotubes （CNTs） are promising materials in many applications. However, current chemical vapor deposition （CVD） methods for CNT synthesis suffer from the discrepancy between the quality and yield of CNTs： Low-quality CNTs can be synthesized with high yield, while high-quality CNTs can only be synthesized with low yield. Here a CVD method has been designed to synthesize both high-quality and low-quality CNTs using the same combination of catalyst and precursor. As a result, we were able to understand the reasons for the low yield in high-quality CNT synthesis and a method was derived to improve their yield. This understanding is an important step towards high- yield synthesis of high-quality CNTs.

Evaluation of Smart Low-carbon Development in Major Chinese Cities

This study chose major Chinese cities and used the creative model of Smart Low-carbon Strength Quo- tient （SLSQ） to investigate the level and state of urban smart low-carbon development. The results show that： （1） three main categories of smart low-carbon cities are found; namely, leaders with high SLSQ, steady ones with av- erage SLSQ and lagging ones with low SLSQ; （2） the SLSQ level shows a spatial change trend of diminishing from the southeast to the northwest and differing within regions; （3） the SLSQ level indicates an urban scale change trend of decreasing from the big to the small and differing within each scale; （4） the SLSQ level suggests an ad- ministrative hierarchy change trend of descending from the high to the low and differing within each class; （5） based on the SLSQ, three dynamic patterns were identified： leading mode, steady mode and preparing mode, among which the steady mode accounts for the vast majority of smart low-carbon development in major Chinese cities.