In the environment of customization, disturbances such as rush orders and material shortages often occur in the manufacturing system, so rescheduling is necessary for the manufacturing system. The rescheduling methodo...In the environment of customization, disturbances such as rush orders and material shortages often occur in the manufacturing system, so rescheduling is necessary for the manufacturing system. The rescheduling methodology should be able to dispose of the disturbance efficiently so as to keep production going smoothly. This aims researching flow shop rescheduling problem (FSRP) necessitated by rush orders. Disjunctive graph is employed to demonstrate the FSRP. For a flow shop processing n jobs, after the original schedule has been made, and z out of n jobs have been processed in the flow shop, x rush orders come, so the original n jobs together with x rush orders should be rescheduled immediately so that the rush orders would be processed in the shortest time and the original jobs could be processed subject to some optimized criteria. The weighted mean flow time of both original jobs and rush orders is used as objective function. The weight for rush orders is much bigger than that of the original jobs, so the rush orders should be processed early in the new schedule. The ant colony optimization (ACO) algorithm used to solve the rescheduling problem has a weakness in that the search may fall into a local optimum. Mutation operation is employed to enhance the ACO performance. Numerical experiments demonstrated that the proposed algorithm has high computation repeatability and efficiency.展开更多
For the Fischer-Tropsch synthesis (FrS), this paper presents a numerical investigation in a 3D fiuidized bed reactor. The effect of the operation parameters such as bed temperature, superficial gas velocities, parti...For the Fischer-Tropsch synthesis (FrS), this paper presents a numerical investigation in a 3D fiuidized bed reactor. The effect of the operation parameters such as bed temperature, superficial gas velocities, particle size and bed heights is discussed. A 3D-CFD model coupled with FTS chemical kinetics was set up. The computational resuits are compared with experimental data in terms of the components production rates, etc. The analysis shows that the bed heights, the bed temperature, the superficial gas velocities and particle sizes affect the C5 + selectivity and the reaction rates. Product yields are dependent on the operating conditions especially the temperature.展开更多
This article has summarized the optimized measures relating to the loading of catalyst,and the sixth operating cycle of the residue hydrotreating unit at SINOPEC's Maoming Branch Company,and made a detailed compar...This article has summarized the optimized measures relating to the loading of catalyst,and the sixth operating cycle of the residue hydrotreating unit at SINOPEC's Maoming Branch Company,and made a detailed comparison on the impurities removal rate,hydrogen consumption and energy consumption of the sixth operating cycle with those achieved by the previous five cycles.Test results have revealed that the second-generation RHT series novel residue hydrotreating catalysts featured high activity,good stability,and long operating cycle and could remarkably reduce the hydrogen consumption and energy consumption of process unit.The hydrotreated AR product,having low Conradson carbon residue,low sulfur content,low metal content,high content of saturated hydrocarbons,and low content of asphaltenes and resins,is an excellent FCC feed.Judging from their overall property the second-generation RHT series of residue hydrotreating catalysts used in the sixth operating cycle have commanded a leading position among other catalysts used in previous operating cycles.展开更多
Deep hydrodesulfurization (HDS) is an important process to produce high quality liquid fuels with ultra-low sul- fur. Process intensification for deep HDS could be implemented by developing new active catalysts and/...Deep hydrodesulfurization (HDS) is an important process to produce high quality liquid fuels with ultra-low sul- fur. Process intensification for deep HDS could be implemented by developing new active catalysts and/or new types of reactors. In this work, the kinetics of dibenzothiophene (DBT) hydrodesulfurization over Ni-P/SBA-15/ cordierite catalyst was investigated at 340-380 ℃ and 3.0-5.0 MPa. The first-order reaction model with respect to both DBT and H2 was used to fit the kinetics data in a batch recycle operation system. It is found that both the activation energy and rate constant over the Ni-P monolithic catalyst under our operating conditions are close to those over conventionally used HDS catalysts. Comparative performance studies of two types of reactors, i.e., trickle bed reactor and monolithic reactor, were performed based on reactor modeling and simulation. The results indicate that the productivity of the monolithic reactor is 3 times higher than that of the trickle bed reactor on a catalyst weight basis since effective utilization of the catalyst is higher in the monolithic reactor, but the volumetric productivity of the monolithic reactor is lower for HDS of DBT. Based on simulation results, a two- reactor-in-series configuration for hydrodesulfurization is proposed, in which a monolithic reactor is followed by a tickled bed reactor so as to attain intensified performance of the system converting fuel oil of different sulfur-containing compounds. It is illustrated that the two reactor scheme outperforms the trickle bed reactor both on reactor volume and catalyst mass bases while the content of sulfur is reduced from 200 μg·g-1 to about 10 μ·g-1.展开更多
This paper deals with optimization of hard switching commutation mode for high-power, high-frequency consumer applications for selected power transistor. The experimental investigation of suitable settings is outgoing...This paper deals with optimization of hard switching commutation mode for high-power, high-frequency consumer applications for selected power transistor. The experimental investigation of suitable settings is outgoing from simulation analysis of hard switching for different transistor structures. For these purposes, the simulation models of power semiconductor switches with high level of validity have been used. After that, the experimental analysis for selected transistor was done with change of parameters that are influencing commutation process of transistor. Target of such kind of analysis was to reach as low switching losses as possible, achieving high power density and efficiency of power system, without utilization of improved switching techniques such as resonant switching. The results confirm that this task is realizable through use of progressive semiconductor devices such as SiC diodes and/or through latest families of MOSFET devices.展开更多
The reversible solid oxide cell(RSOC)is an attractive technology to mutually convert power and chemicals at elevated temperatures.However,its development has been hindered mainly due to the absence of a highly active ...The reversible solid oxide cell(RSOC)is an attractive technology to mutually convert power and chemicals at elevated temperatures.However,its development has been hindered mainly due to the absence of a highly active and durable fuel electrode.Here,we report a phase-transformed CoFe-Sr_(3)Fe_(1.25)Mo_(0.75)O_(7)-δ(CoFe-SFM)fuel electrode consisting of CoFe nanoparticles and Ruddlesden-Popper-layered Sr_(3)Fe_(1.25)Mo_(0.75)O_(7)-δ(SFM)from a Sr_(2)Fe_(7/6)Mo_(0.5)Co_(1/3)O_(6)-δ(SFMCo)perovskite oxide after annealing in hydrogen and apply it to reversible CO/CO_(2)conversion in RSOC.The CoFeSFM fuel electrode shows improved catalytic activity by accelerating oxygen diffusion and surface kinetics towards the CO/CO_(2)conversion as demonstrated by the distribution of relaxation time(DRT)study and equivalent circuit model fitting analysis.Furthermore,an electrolyte-supported single cell is evaluated in the 2:1 CO-CO_(2)atmosphere at 800℃,which shows a peak power density of 259 mW cm^(-2)for CO oxidation and a current density of-0.453 A cm^(-2)at 1.3 V for CO_(2)reduction,which correspond to 3.079 and3.155 m L min-1cm^(-2)for the CO and CO_(2)conversion rates,respectively.More importantly,the reversible conversion is successfully demonstrated over 20 cyclic electrolysis and fuel cell switching test modes at 1.3 and 0.6 V.This work provides a useful guideline for designing a fuel electrode through a surface/interface exsolution process for RSOC towards efficient CO-CO_(2)reversible conversion.展开更多
High refractive index(HRI,n>1.8)photonic structures offer strong light confinement and refractive efficiencies,cover the entire visible spectrum and can be tuned by designing geometric arrayed features.However,its ...High refractive index(HRI,n>1.8)photonic structures offer strong light confinement and refractive efficiencies,cover the entire visible spectrum and can be tuned by designing geometric arrayed features.However,its practical applications are still hindered by the applicability and material limitation of lithography-based micro/nano fabrication approaches.Herein,we demonstrate a fluid-guided printing process for preparing HRI selenium microarrays.The microstructured flexible template is replicated from the diced silicon wafer without any lithography-based methods.When heated above the glass transition temperature,the flow characteristics of selenium endows the structure downsizing and orientation patterning between the target substrate and the template.Near 10 times narrowing selenium microarrays(1.9μm width)are patterned from the non-lithography template(18μm width).HRI selenium microarrays offer high refractive efficiencies and strong optical confinement abilities,which achieve angledependent structurally coloration and polarization.Meanwhile,the color difference can be recognized under the one degree distinction of the angle between incident and refracted light.This printing platform will facilitate HRI optical metasurfaces in a variety of applications,ranging from photonic sensor,polarization modulation to light manipulation.展开更多
The rise of personalized flexible electronics has promoted the rapid development of flexible supercapacitors due to their long service life,fast charging-discharging rates and safe operation.Different from the traditi...The rise of personalized flexible electronics has promoted the rapid development of flexible supercapacitors due to their long service life,fast charging-discharging rates and safe operation.Different from the traditional flexible supercapacitors,the all-in-one integrated flexible supercapacitors are more resistant to deformation and lower interface resistance,which have a broader application prospect in the field of flexible electronics.This review briefly summarizes the preparation methods and electrochemical properties of some typical all-in-one supercapacitors,represented by planar and fibrous structures in recent years.Firstly,the basic understanding of traditional flexible supercapacitors and all-in-one integrated flexible supercapacitors,and the key parameters of the performance of flexible supercapacitors are introduced.Subsequently,the hydrogel matrix all-in-one supercapacitors with different functional characteristics(stretchable,self-healing and compressible)and the nonhydrogel matrix(separator,flexible membrane)all-in-one supercapacitors are discussed.Furthermore,the challenges and future development of flexible supercapacitors are considered.展开更多
文摘In the environment of customization, disturbances such as rush orders and material shortages often occur in the manufacturing system, so rescheduling is necessary for the manufacturing system. The rescheduling methodology should be able to dispose of the disturbance efficiently so as to keep production going smoothly. This aims researching flow shop rescheduling problem (FSRP) necessitated by rush orders. Disjunctive graph is employed to demonstrate the FSRP. For a flow shop processing n jobs, after the original schedule has been made, and z out of n jobs have been processed in the flow shop, x rush orders come, so the original n jobs together with x rush orders should be rescheduled immediately so that the rush orders would be processed in the shortest time and the original jobs could be processed subject to some optimized criteria. The weighted mean flow time of both original jobs and rush orders is used as objective function. The weight for rush orders is much bigger than that of the original jobs, so the rush orders should be processed early in the new schedule. The ant colony optimization (ACO) algorithm used to solve the rescheduling problem has a weakness in that the search may fall into a local optimum. Mutation operation is employed to enhance the ACO performance. Numerical experiments demonstrated that the proposed algorithm has high computation repeatability and efficiency.
基金Supported by the National High-Tech R&D Program of China[2011AA05A204]the Fundamental Research Funds for the Central Universities[222201717013]
文摘For the Fischer-Tropsch synthesis (FrS), this paper presents a numerical investigation in a 3D fiuidized bed reactor. The effect of the operation parameters such as bed temperature, superficial gas velocities, particle size and bed heights is discussed. A 3D-CFD model coupled with FTS chemical kinetics was set up. The computational resuits are compared with experimental data in terms of the components production rates, etc. The analysis shows that the bed heights, the bed temperature, the superficial gas velocities and particle sizes affect the C5 + selectivity and the reaction rates. Product yields are dependent on the operating conditions especially the temperature.
文摘This article has summarized the optimized measures relating to the loading of catalyst,and the sixth operating cycle of the residue hydrotreating unit at SINOPEC's Maoming Branch Company,and made a detailed comparison on the impurities removal rate,hydrogen consumption and energy consumption of the sixth operating cycle with those achieved by the previous five cycles.Test results have revealed that the second-generation RHT series novel residue hydrotreating catalysts featured high activity,good stability,and long operating cycle and could remarkably reduce the hydrogen consumption and energy consumption of process unit.The hydrotreated AR product,having low Conradson carbon residue,low sulfur content,low metal content,high content of saturated hydrocarbons,and low content of asphaltenes and resins,is an excellent FCC feed.Judging from their overall property the second-generation RHT series of residue hydrotreating catalysts used in the sixth operating cycle have commanded a leading position among other catalysts used in previous operating cycles.
基金Supported by the State Key Development Program for Basic Research of China(2006CB202503)
文摘Deep hydrodesulfurization (HDS) is an important process to produce high quality liquid fuels with ultra-low sul- fur. Process intensification for deep HDS could be implemented by developing new active catalysts and/or new types of reactors. In this work, the kinetics of dibenzothiophene (DBT) hydrodesulfurization over Ni-P/SBA-15/ cordierite catalyst was investigated at 340-380 ℃ and 3.0-5.0 MPa. The first-order reaction model with respect to both DBT and H2 was used to fit the kinetics data in a batch recycle operation system. It is found that both the activation energy and rate constant over the Ni-P monolithic catalyst under our operating conditions are close to those over conventionally used HDS catalysts. Comparative performance studies of two types of reactors, i.e., trickle bed reactor and monolithic reactor, were performed based on reactor modeling and simulation. The results indicate that the productivity of the monolithic reactor is 3 times higher than that of the trickle bed reactor on a catalyst weight basis since effective utilization of the catalyst is higher in the monolithic reactor, but the volumetric productivity of the monolithic reactor is lower for HDS of DBT. Based on simulation results, a two- reactor-in-series configuration for hydrodesulfurization is proposed, in which a monolithic reactor is followed by a tickled bed reactor so as to attain intensified performance of the system converting fuel oil of different sulfur-containing compounds. It is illustrated that the two reactor scheme outperforms the trickle bed reactor both on reactor volume and catalyst mass bases while the content of sulfur is reduced from 200 μg·g-1 to about 10 μ·g-1.
文摘This paper deals with optimization of hard switching commutation mode for high-power, high-frequency consumer applications for selected power transistor. The experimental investigation of suitable settings is outgoing from simulation analysis of hard switching for different transistor structures. For these purposes, the simulation models of power semiconductor switches with high level of validity have been used. After that, the experimental analysis for selected transistor was done with change of parameters that are influencing commutation process of transistor. Target of such kind of analysis was to reach as low switching losses as possible, achieving high power density and efficiency of power system, without utilization of improved switching techniques such as resonant switching. The results confirm that this task is realizable through use of progressive semiconductor devices such as SiC diodes and/or through latest families of MOSFET devices.
基金financially supported by the National Natural Science Foundation (52002249,51402093 and 21706162)Guangdong Basic and Applied Basic Research Foundation (2019A1515110025 and 2017A 030313289)+3 种基金the Research Grant for Scientific Platform and Project of Guangdong Provincial Education Office (2019KTSCX151)China Postdoctoral Science Foundation (2020M682872)Shenzhen Government’s Plan of Science and Technology (JCYJ201803005125247308)Technical support from the Instrumental Analysis Center of Shenzhen University (Xili Campus) is also appreciated。
文摘The reversible solid oxide cell(RSOC)is an attractive technology to mutually convert power and chemicals at elevated temperatures.However,its development has been hindered mainly due to the absence of a highly active and durable fuel electrode.Here,we report a phase-transformed CoFe-Sr_(3)Fe_(1.25)Mo_(0.75)O_(7)-δ(CoFe-SFM)fuel electrode consisting of CoFe nanoparticles and Ruddlesden-Popper-layered Sr_(3)Fe_(1.25)Mo_(0.75)O_(7)-δ(SFM)from a Sr_(2)Fe_(7/6)Mo_(0.5)Co_(1/3)O_(6)-δ(SFMCo)perovskite oxide after annealing in hydrogen and apply it to reversible CO/CO_(2)conversion in RSOC.The CoFeSFM fuel electrode shows improved catalytic activity by accelerating oxygen diffusion and surface kinetics towards the CO/CO_(2)conversion as demonstrated by the distribution of relaxation time(DRT)study and equivalent circuit model fitting analysis.Furthermore,an electrolyte-supported single cell is evaluated in the 2:1 CO-CO_(2)atmosphere at 800℃,which shows a peak power density of 259 mW cm^(-2)for CO oxidation and a current density of-0.453 A cm^(-2)at 1.3 V for CO_(2)reduction,which correspond to 3.079 and3.155 m L min-1cm^(-2)for the CO and CO_(2)conversion rates,respectively.More importantly,the reversible conversion is successfully demonstrated over 20 cyclic electrolysis and fuel cell switching test modes at 1.3 and 0.6 V.This work provides a useful guideline for designing a fuel electrode through a surface/interface exsolution process for RSOC towards efficient CO-CO_(2)reversible conversion.
基金the National Key R&D Program of China(2018YFA0208501)the National Natural Science Foundation of China(51803217,51773206,91963212,and 51961145102(BRICS Project))+3 种基金the Youth Innovation Promotion Association CAS(2020032)Beijing National Laboratory for Molecular Sciences(BNLMS-CXXM-202005)Russian Foundation for Basic Research(19-52-80036(BRICS Project))K.C.Wong Education Foundation。
文摘High refractive index(HRI,n>1.8)photonic structures offer strong light confinement and refractive efficiencies,cover the entire visible spectrum and can be tuned by designing geometric arrayed features.However,its practical applications are still hindered by the applicability and material limitation of lithography-based micro/nano fabrication approaches.Herein,we demonstrate a fluid-guided printing process for preparing HRI selenium microarrays.The microstructured flexible template is replicated from the diced silicon wafer without any lithography-based methods.When heated above the glass transition temperature,the flow characteristics of selenium endows the structure downsizing and orientation patterning between the target substrate and the template.Near 10 times narrowing selenium microarrays(1.9μm width)are patterned from the non-lithography template(18μm width).HRI selenium microarrays offer high refractive efficiencies and strong optical confinement abilities,which achieve angledependent structurally coloration and polarization.Meanwhile,the color difference can be recognized under the one degree distinction of the angle between incident and refracted light.This printing platform will facilitate HRI optical metasurfaces in a variety of applications,ranging from photonic sensor,polarization modulation to light manipulation.
基金supported by the National Key Research and Development Program of China(2017YFB0406301)the State Key Laboratory of Electrical Insulation and Power Equipment(EIPE19210)+1 种基金the 111 Project of China(B14040)the Fundamental Research Funds for the Central University。
文摘The rise of personalized flexible electronics has promoted the rapid development of flexible supercapacitors due to their long service life,fast charging-discharging rates and safe operation.Different from the traditional flexible supercapacitors,the all-in-one integrated flexible supercapacitors are more resistant to deformation and lower interface resistance,which have a broader application prospect in the field of flexible electronics.This review briefly summarizes the preparation methods and electrochemical properties of some typical all-in-one supercapacitors,represented by planar and fibrous structures in recent years.Firstly,the basic understanding of traditional flexible supercapacitors and all-in-one integrated flexible supercapacitors,and the key parameters of the performance of flexible supercapacitors are introduced.Subsequently,the hydrogel matrix all-in-one supercapacitors with different functional characteristics(stretchable,self-healing and compressible)and the nonhydrogel matrix(separator,flexible membrane)all-in-one supercapacitors are discussed.Furthermore,the challenges and future development of flexible supercapacitors are considered.