Ionic liquids have negligibly low vapor pressure, high stability and polarity. They are regarded as green solvents. Enzymes, especially lipases, as well as whole-cell of microbe, are catalytically active in ionic liqu...Ionic liquids have negligibly low vapor pressure, high stability and polarity. They are regarded as green solvents. Enzymes, especially lipases, as well as whole-cell of microbe, are catalytically active in ionic liquids or aqueous-ionic liquid biphasic systems. Up to date, there have been many reports on enzyme-exhibited features and enzyme-mediated reactions in ionic liquids. In many cases, remarkable results with respect to yield, catalytic activity, stability and (enantio-, regio-) selectivity were obtained in ionic liquids in comparison with those observed in conventional media. Accordingly, ionic liquids provide new possibilities for the application of new type of solvent in biocatalytic reactions.展开更多
An inter-phasing pulse tube cooler (IPPTC) consists of two pulse tube units, which are connected to each other at hot ends of the pulse tubes through a needle valve. This paper presents the computational fluid dynamic...An inter-phasing pulse tube cooler (IPPTC) consists of two pulse tube units, which are connected to each other at hot ends of the pulse tubes through a needle valve. This paper presents the computational fluid dynamic (CFD) results of an IPPTC using a 2D axis-symmetrical model. General results such as the phase difference between pressure and velocity at cold end and hot end, the temperature profiles along the wall, the available lowest temperature as well as its oscillations and the coefficient of performance (COP) for IPPTC are presented. The formation of DC flow and its effects on the performance of the cooler are investigated and analyzed in detail. Turbulence, which is partially responsible for the poor overall performance of a single orifice pulse tube cooler (OPTC), is found to be much reduced in IPPTC and its performance is improved significantly compared with the single OPTC.展开更多
基金the Natural Science Foundation of Guangdong Province (No. 020839).
文摘Ionic liquids have negligibly low vapor pressure, high stability and polarity. They are regarded as green solvents. Enzymes, especially lipases, as well as whole-cell of microbe, are catalytically active in ionic liquids or aqueous-ionic liquid biphasic systems. Up to date, there have been many reports on enzyme-exhibited features and enzyme-mediated reactions in ionic liquids. In many cases, remarkable results with respect to yield, catalytic activity, stability and (enantio-, regio-) selectivity were obtained in ionic liquids in comparison with those observed in conventional media. Accordingly, ionic liquids provide new possibilities for the application of new type of solvent in biocatalytic reactions.
基金Project supported by the National Natural Science foundation of China (No. 50706042)the Science and Technology Department of Zhejiang Province (No. 2006C24G2010027)the Natural Science Foundation of Zhejiang Province (No. Y105519), China
文摘An inter-phasing pulse tube cooler (IPPTC) consists of two pulse tube units, which are connected to each other at hot ends of the pulse tubes through a needle valve. This paper presents the computational fluid dynamic (CFD) results of an IPPTC using a 2D axis-symmetrical model. General results such as the phase difference between pressure and velocity at cold end and hot end, the temperature profiles along the wall, the available lowest temperature as well as its oscillations and the coefficient of performance (COP) for IPPTC are presented. The formation of DC flow and its effects on the performance of the cooler are investigated and analyzed in detail. Turbulence, which is partially responsible for the poor overall performance of a single orifice pulse tube cooler (OPTC), is found to be much reduced in IPPTC and its performance is improved significantly compared with the single OPTC.
