A series of functionalized ionic liquids （ILs） containing ester-group were synthesized and their tribological prop- erties as lubricants for steel-steel contact were studied and compared with a non-functionalized io...A series of functionalized ionic liquids （ILs） containing ester-group were synthesized and their tribological prop- erties as lubricants for steel-steel contact were studied and compared with a non-functionalized ionic liquid and perfluo- ropolyethers （PFPE）. The morphology and chemical composition of the worn scars were analyzed by scanning electron mi- croscopy and X-ray photoelectron spectroscopy, respectively, and the possible lubrication mechanism of ILs was discussed. As a result, all ILs demonstrated a better lubricity and a much higher load-carrying capacity than PFPE used as lubricants for the steel-steel tribomates system. The functionalized ILs with ester-group showed slightly worse friction reducing abil- ity than their nonfunctionalized counterparts at relatively lower loads owing to their higher viscosity, but then exhibited better antiwear ability because the ester group they contained had not only physical but also strong chemical reactions with the freshly exposed steel surface and formed chemical adsorption boundary films on the worn surface during friction pro- cess. Under high loads, some triboehemical reactions took place between the active elements, such as fluorine which were released from the ILs, and fresh metal surfaces of rubbing pairs to form the admixture reaction films, which were mainly composed of ferric fluoride mixed with ferric oxide, leading to lower friction coefficients and good wear resistance.展开更多
In this paper, we conduct research on the development of mechanical and electrical integration of system function principle and related technologies. Along with the rapid and continuous development of modem science an...In this paper, we conduct research on the development of mechanical and electrical integration of system function principle and related technologies. Along with the rapid and continuous development of modem science and technology, it ＇ s for the penetration and cross of different subjects great push, the more important is caused by technological revolution in the field of engineering and mechanical engineering field under the rapid development of computer technology and microelectronic technology and penetration to the mechanical and electrical integration, which is formed by the mechanical industry lead to trigger a particularly large changes in the mechanical industry management system and mode of production, product and technical structure, composition and function, thus result in industrial production from the previous mechanical electrification progressively electromechanical integration which lead the trend of the current technology.展开更多
基金the Natural Science Foundation Project of CQ CSTC, 2010BB0201
文摘A series of functionalized ionic liquids （ILs） containing ester-group were synthesized and their tribological prop- erties as lubricants for steel-steel contact were studied and compared with a non-functionalized ionic liquid and perfluo- ropolyethers （PFPE）. The morphology and chemical composition of the worn scars were analyzed by scanning electron mi- croscopy and X-ray photoelectron spectroscopy, respectively, and the possible lubrication mechanism of ILs was discussed. As a result, all ILs demonstrated a better lubricity and a much higher load-carrying capacity than PFPE used as lubricants for the steel-steel tribomates system. The functionalized ILs with ester-group showed slightly worse friction reducing abil- ity than their nonfunctionalized counterparts at relatively lower loads owing to their higher viscosity, but then exhibited better antiwear ability because the ester group they contained had not only physical but also strong chemical reactions with the freshly exposed steel surface and formed chemical adsorption boundary films on the worn surface during friction pro- cess. Under high loads, some triboehemical reactions took place between the active elements, such as fluorine which were released from the ILs, and fresh metal surfaces of rubbing pairs to form the admixture reaction films, which were mainly composed of ferric fluoride mixed with ferric oxide, leading to lower friction coefficients and good wear resistance.
文摘In this paper, we conduct research on the development of mechanical and electrical integration of system function principle and related technologies. Along with the rapid and continuous development of modem science and technology, it ＇ s for the penetration and cross of different subjects great push, the more important is caused by technological revolution in the field of engineering and mechanical engineering field under the rapid development of computer technology and microelectronic technology and penetration to the mechanical and electrical integration, which is formed by the mechanical industry lead to trigger a particularly large changes in the mechanical industry management system and mode of production, product and technical structure, composition and function, thus result in industrial production from the previous mechanical electrification progressively electromechanical integration which lead the trend of the current technology.
