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不耦合装药爆炸作用下燃料空气炸药的近区抛散 被引量:7
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作者 张奇 白春华 +1 位作者 刘庆明 王仲琦 《弹道学报》 CSCD 北大核心 2000年第2期22-25,共4页
通过建立的力学模型 ,分析中心不耦合装药爆炸载荷下燃料空气炸药近区抛散速度分布的规律 .得到燃料抛散最大速度的计算方法 ,为中、远区抛散分析奠定了基础 .计算值与实验结果是一致的 .研究结果表明 :中心不耦合装药爆炸载荷作用与耦... 通过建立的力学模型 ,分析中心不耦合装药爆炸载荷下燃料空气炸药近区抛散速度分布的规律 .得到燃料抛散最大速度的计算方法 ,为中、远区抛散分析奠定了基础 .计算值与实验结果是一致的 .研究结果表明 :中心不耦合装药爆炸载荷作用与耦合装药相比 ,燃料的抛速变小 . 展开更多
关键词 燃料空气炸药 爆炸作用 抛散过程 不耦合装药
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核反应堆严重事故中燃料与冷却剂相互作用粗混合过程的数值模型验证
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作者 曹学武 飞田吉春 《核动力工程》 EI CAS CSCD 北大核心 2003年第S2期1-4,12,共5页
熔融燃料与冷却剂相互作用的粗混合过程是核反应堆严重事故机理研究中很重要的物理现象。在粗混合过程中,由于冷却剂的局部蒸发,高温燃料粒子或熔融燃料液滴被一层蒸汽膜包裹,形成了特殊的复合结构。但是在目前的数值模拟研究中,高温燃... 熔融燃料与冷却剂相互作用的粗混合过程是核反应堆严重事故机理研究中很重要的物理现象。在粗混合过程中,由于冷却剂的局部蒸发,高温燃料粒子或熔融燃料液滴被一层蒸汽膜包裹,形成了特殊的复合结构。但是在目前的数值模拟研究中,高温燃料粒子或熔融燃料液滴在冷却剂中的阻力系数大多数是采用Ishii的模型,并非针对此特殊复合结构开发的。作者基于此特殊复合结构开发出了一个新的阻力系数模型。通过应用Ishii的模型和新开发的模型分别模拟粗混合实验QUEOS以比较和验证新开发的阻力系数模型。结果表明,新开发的模型改善了粗混合阶段的数值模拟模型中的阻力系数与实验的差异。 展开更多
关键词 数值模拟 多相流 燃料与冷却剂相互作用 阻力系数
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熔融不锈钢与液态钠相互作用的瞬态换热特性研究
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作者 刘雅鹏 张大林 +5 位作者 陈宇彤 林悦 张熙司 田文喜 秋穗正 苏光辉 《原子能科学技术》 EI CAS CSCD 北大核心 2024年第9期1893-1901,I0001,共10页
钠冷快堆严重事故下,堆芯熔融物会与液态金属钠发生相互作用,如果导致堆芯区域内出现钠沸腾的现象,可能会导致堆芯的再临界,从而导致堆芯的进一步熔化。在重定位过程中,堆芯熔融物与液态钠的换热会导致钠出现沸腾,从而影响熔融物射流碎... 钠冷快堆严重事故下,堆芯熔融物会与液态金属钠发生相互作用,如果导致堆芯区域内出现钠沸腾的现象,可能会导致堆芯的再临界,从而导致堆芯的进一步熔化。在重定位过程中,堆芯熔融物与液态钠的换热会导致钠出现沸腾,从而影响熔融物射流碎裂与碎片形成。因此,采用严重事故分析程序ACENA对COSA实验平台上开展的熔融不锈钢与液态钠的相互作用的实验进行分析,验证程序对熔融不锈钢与液态钠相互作用过程的瞬态换热特性的分析能力。验证结果表明:程序会高估熔融不锈钢射流与钠池接触时的换热,且不考虑熔融不锈钢外侧凝固形成的硬壳对换热的影响会导致对换热速率的高估。 展开更多
关键词 钠冷快堆 熔融燃料与冷却剂相互作用 ACENA程序
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低熔点金属与冷却剂相互作用的数值模拟 被引量:4
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作者 张熙司 薛方元 +2 位作者 胡文军 刘鹏飞 喻宏 《科技创新导报》 2020年第15期118-120,共3页
为了更好的验证钠冷快堆堆芯解体事故分析程序,需要对熔融燃料与冷却剂的相互作用(FCI)现象进行模拟与验证。对于钠冷快堆而言,采用钠作为冷却剂的FCI实验较难开展,对实验条件要求极高。因此本研究利用锡-水相互作用实验进行机理研究和... 为了更好的验证钠冷快堆堆芯解体事故分析程序,需要对熔融燃料与冷却剂的相互作用(FCI)现象进行模拟与验证。对于钠冷快堆而言,采用钠作为冷却剂的FCI实验较难开展,对实验条件要求极高。因此本研究利用锡-水相互作用实验进行机理研究和程序验证。本文通过对实验的模拟来研究发生在核反应堆严重事故情况下的燃料与冷却剂相互作用过程。采用基于泰勒不稳定性的水力学细粒化模型,对低熔点金属与冷却剂相互作用过程进行数值计算和预测。计算结果表明,水力学模型较好地模拟了低熔点金属与冷却剂相互作用过程。 展开更多
关键词 低熔点金属与冷却剂 燃料与冷却剂相互作用 数值模拟
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熔融液柱与冷却剂作用中液柱碎化预测
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作者 李爽岚 刘鹏飞 +1 位作者 贺隆坤 匡波 《原子能科学技术》 EI CAS CSCD 北大核心 2023年第5期988-997,共10页
液柱碎化是熔融物和冷却剂相互作用(FCI)粗混合阶段的关键物理现象,在安全分析时需建立液柱碎化模型。本文将实验验证和理论分析相结合,开展了高温熔融液柱与冷却剂相互作用实验;建立了不同沸腾条件下的液柱表面膜态沸腾模型和液柱表面... 液柱碎化是熔融物和冷却剂相互作用(FCI)粗混合阶段的关键物理现象,在安全分析时需建立液柱碎化模型。本文将实验验证和理论分析相结合,开展了高温熔融液柱与冷却剂相互作用实验;建立了不同沸腾条件下的液柱表面膜态沸腾模型和液柱表面不稳定波生长模型;再考虑不稳定波断裂和熔融物的脱离,构建起完整的熔融液柱水力学碎化模型。用该水力学碎化模型对不同沸腾条件下的熔融液柱碎化行为进行了预测。预测结果表明,实验得到的碎片中位直径和碎裂长度与模型预测结果符合较好,且能进一步应用于典型反应堆原型材料FCI实验的液柱碎化预测。 展开更多
关键词 液柱碎化 膜态沸腾 不稳定波断裂 燃料和冷却剂相互作用
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压水堆核电厂堆腔内蒸汽爆炸风险分析研究
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作者 张航 杨小磊 +2 位作者 段永强 关仲华 张丹 《科技视界》 2024年第11期84-88,共5页
在核电厂严重事故中,压力容器失效后熔融物和冷却剂相互作用,可能引发蒸汽爆炸现象,威胁堆腔完整性,增加裂变产物释放到环境中的风险。保守计算分析显示爆炸后果严重。文章采用风险分析进行评价,考虑事故后果和发生频率。通过概率论与... 在核电厂严重事故中,压力容器失效后熔融物和冷却剂相互作用,可能引发蒸汽爆炸现象,威胁堆腔完整性,增加裂变产物释放到环境中的风险。保守计算分析显示爆炸后果严重。文章采用风险分析进行评价,考虑事故后果和发生频率。通过概率论与确定论相结合分析堆腔的失效概率。根据影响参数的概率分布进行抽样计算,获得了爆炸载荷的概率分布。将载荷的概率分布结合堆腔混凝土失效曲线,得到可能导致堆腔损坏的概率为1.03%。 展开更多
关键词 蒸汽爆炸 燃料-冷却剂作用 堆腔失效 敏感性分析
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Study on Near Field Dispersal of Fuel Air Explosive 被引量:8
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作者 张奇 白春华 +3 位作者 刘庆明 王仲琦 梁慧敏 肖绍清 《Journal of Beijing Institute of Technology》 EI CAS 1999年第2期2-7,共6页
Aim To study fuel dispersion in fuel air explosive(FAE) and computational ways of fuel dispersion velocity in the near area. Methods\ The dispersion process of fuel in FAE was analyzed by the use of results measured ... Aim To study fuel dispersion in fuel air explosive(FAE) and computational ways of fuel dispersion velocity in the near area. Methods\ The dispersion process of fuel in FAE was analyzed by the use of results measured with KODAK EKTAPRO EM Motion Analyzer and setting up mechanical models. Results\ Computational methods for fuel dispersion velocity in the acceleration stage is given and taken as a base for the study of fuel dispersion in the intermediate and the far area. Conclusion\ When the fuel flow velocity is higher than that of the explosion gas in the center cavity, the fuel divides with the explosion gas and its velocity of flow reaches a maximum. The acceleration stage ends at that time. The fuel dispersion velocity at this time is the initial conditions for numeral analyses of dispersion process in the intermediate and far areas. 展开更多
关键词 fuel air explosive explosion action dispersal process
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熔融金属液滴热细粒化过程研究 被引量:3
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作者 林千 佟立丽 +2 位作者 曹学武 Alexander VOROBYEV VladimirK RIVENTSEV 《原子能科学技术》 EI CAS CSCD 北大核心 2009年第7期604-608,共5页
熔融液滴的细粒化是决定燃料与冷却剂相互作用破坏后果的关键过程,它决定最终的热能与动能的转化比,是预测事故后果的重要因素之一。然而目前对该过程中基于本身内能的热细粒化机理尚不清楚。本工作通过单个熔融金属液滴与水相互作用的... 熔融液滴的细粒化是决定燃料与冷却剂相互作用破坏后果的关键过程,它决定最终的热能与动能的转化比,是预测事故后果的重要因素之一。然而目前对该过程中基于本身内能的热细粒化机理尚不清楚。本工作通过单个熔融金属液滴与水相互作用的实验,借助高速摄像系统对熔融液滴的热细粒化现象进行拍摄,观察发现熔融金属液滴与水的相互作用经历了若干次加速膨胀细粒化过程,测量到熔融液滴的细粒化时间为0.8 ms,两次细粒化的时间间隔为0.8 ms,细粒化加速膨胀时间仅为0.4 ms。根据实验观察和分析,提出了一种由熔融液滴与水接触面不稳定沸腾效应引起的热细粒化机理。 展开更多
关键词 燃料与冷却剂相互作用 熔融液滴 热细粒化
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快堆组件盒壁破损机理模型的建立与验证
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作者 赵树峰 罗锐 +2 位作者 王洲 石晓波 杨献勇 《原子能科学技术》 EI CAS CSCD 北大核心 2007年第4期448-452,共5页
快堆内发生超设计基准事故后,故障组件盒会发展到沸腾池,事故下一步的传播取决于池壁破损。文章采用机理建模方法,对3种主要盒壁破损机理建立模型,并在法国SCARABEE堆内实验中的BE+3和PV-A实验以及堆外GEYSER实验上进行了模型验证,模型... 快堆内发生超设计基准事故后,故障组件盒会发展到沸腾池,事故下一步的传播取决于池壁破损。文章采用机理建模方法,对3种主要盒壁破损机理建立模型,并在法国SCARABEE堆内实验中的BE+3和PV-A实验以及堆外GEYSER实验上进行了模型验证,模型计算结果与实验结果吻合较好。根据模型计算结果,对PV-A实验的池壁破损给予了合理解释,总结出快堆池壁破损的相关结论,并对堆内发生燃料-冷却剂相互作用(FCI)的可能性进行分析,给出了相关结论。 展开更多
关键词 快堆 沸腾池 燃料-冷却剂相互作用
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钠冷快堆堆芯熔融物射流碎裂特性理论研究
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作者 葛魁 张亚培 +2 位作者 田文喜 苏光辉 秋穗正 《原子能科学技术》 EI CAS CSCD 北大核心 2023年第2期251-263,共13页
在钠冷快堆严重事故下,堆芯熔融物可能掉入冷却剂中并与液态金属钠相互作用,导致熔融物的碎裂及凝固,并在堆芯捕集器或下封头内重定位形成堆芯碎片床。熔融物的射流碎裂特性直接关乎堆芯碎片床的冷却及再临界行为。本文基于线性稳定性... 在钠冷快堆严重事故下,堆芯熔融物可能掉入冷却剂中并与液态金属钠相互作用,导致熔融物的碎裂及凝固,并在堆芯捕集器或下封头内重定位形成堆芯碎片床。熔融物的射流碎裂特性直接关乎堆芯碎片床的冷却及再临界行为。本文基于线性稳定性理论、运动学方程和交界面修正拉普拉斯定律,推导出考虑沸腾和凝固效应的熔融物射流表面不稳定性增长方程,建立了液态金属钠中熔融物射流碎裂模型,并提出了典型环境中熔融物射流碎裂准则。随后使用熔融物射流碎裂模型对COSA实验结果进行了对比分析。本研究结果将为钠冷快堆严重事故的评估论证提供可靠工具,对严重事故缓解措施的设计也具有重要的指导意义和参考价值。 展开更多
关键词 钠冷快堆 熔融燃料与冷却剂相互作用 射流碎裂 COSA实验
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Simulation of the mixing process in FCIs with hydrodynamic fragmentation model
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作者 LIN Qian CAO Xuewu 《Nuclear Science and Techniques》 SCIE CAS CSCD 2007年第4期242-246,共5页
Fuel Coolant Interactions (FCIs) are important issues in nuclear reactor severe accident analysis. In FCIs, fragmentation model of molten droplets is a key factor to estimate degree of possible damage. In this paper, ... Fuel Coolant Interactions (FCIs) are important issues in nuclear reactor severe accident analysis. In FCIs, fragmentation model of molten droplets is a key factor to estimate degree of possible damage. In this paper, the mixing process in FCIs is studied by the simulation of MIXA experiment with hydrodynamic fragmentation model. The result shows that hydrodynamic fragmentation model underestimates the fragmentation rate of high temperature molten droplets under the condition of low Weber numbers. It is concluded that models based on thermal fragmentation mechanism should be adopted to analyze the FCI process and its consequence. 展开更多
关键词 核反应堆 燃料冷冻作用 事故 燃料熔化
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Experimental study of high temperature particle dropping in coolant liquid
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作者 LI Tianshu YANG Yanhua LI Xiaoyan HU Zhihua 《Nuclear Science and Techniques》 SCIE CAS CSCD 2007年第4期252-256,共5页
A series of experiments of the premixing stage of fuel-coolant interactions (FCI), namely the particles falling into water, were carried out. The force on the particles during the course of falling has been studied. T... A series of experiments of the premixing stage of fuel-coolant interactions (FCI), namely the particles falling into water, were carried out. The force on the particles during the course of falling has been studied. The dropping character of hot particle was influenced by three main parameters, i.e., particle temperature, particle diameter and coolant subcooling that varied over a wide range. A high-speed camera recorded the falling speed of the particle and the moving curves were obtained. The experimental results showed that for the film boiling on the surface of particle and water, the temperature increase of either particle or coolant would slow down the particle falling velocity. The falling velocity of particle in small diameter is lower than that of the bigger particle. The present work can provide an experimental foundation for further investigation of high-speed transient evaporation heat transfer. 展开更多
关键词 蒸汽爆炸 燃料冷却作用 高温粒子 热力学
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The Biomarker Changes of a Heavy Fuel Oil After Different Weathering Times
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作者 MA Qimin NI Zhanglin YU Zhigang 《Journal of Ocean University of China》 SCIE CAS 2009年第1期51-56,共6页
This paper presents the experimental results of composition changes of heavy fuel oil by stmulating weathering in static seawater under natural environmental conditions. The results indicate: n-C10 to n-C15 were lost... This paper presents the experimental results of composition changes of heavy fuel oil by stmulating weathering in static seawater under natural environmental conditions. The results indicate: n-C10 to n-C15 were lost gradually in 24 weeks and the relative abundance of alkanes with long chains (〉n-C19) increased markedly. The aromatic compounds with less than two tings (except C4N) were completely lost in 24 weeks and CnP and CnD became the main aromatics in the heavy fuel oil after 24 weeks. The ratios of n- C1/Pristane (Pr) and n-C18 Phytane (Ph) were suitable for identifying lightly weathered (3 weeks) heavy fuel oil. The ratios of n-ClT/n-C18 and Pr/Ph were suitable for identifying moderately weathered heavy fuel oil (12 weeks); the ratios of C2D/C2P and C3D/C3P did not change significantly in 24 weeks and were more suitable for identifying moderately weathered heavy fuel oil (24 weeks). 展开更多
关键词 heavy fuel oil WEATHERING GC/MS
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Vapor-Liquid Equilibrium of Ethylene + Mesitylene System and Process Simulation for Ethylene Recovery
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作者 GUO Jing WU Xianghong JING Shuhong ZHANG Qian ZHENG Danxing 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第4期543-548,共6页
The amount of ethylene in refinery off-gas is high with a mass fraction of 20%,but the refinery off-gas is usually used as fuel gas in most refineries.The separation and recovery of ethylene is of remarkable significa... The amount of ethylene in refinery off-gas is high with a mass fraction of 20%,but the refinery off-gas is usually used as fuel gas in most refineries.The separation and recovery of ethylene is of remarkable significance for saving energy and reducing carbon dioxide emission.The aim of this paper is to use a novel absorbent mesitylene for the ethylene absorption process and assess its application feasibility through the ethylene + mesitylene vapor-liquid equilibrium data measurement and its binary interaction parameter correlation,as well as the simulation for ethylene separation process. 展开更多
关键词 ETHYLENE MESITYLENE vapor-liquid equilibrium process simulation
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An approach for IC engine coolant energy recovery based on low-temperature organic Rankine cycle 被引量:1
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作者 付建勤 刘敬平 +2 位作者 徐政欣 邓帮林 刘琦 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第2期727-734,共8页
To promote the fuel utilization efficiency of IC engine, an approach was proposed for IC engine coolant energy recovery based on low-temperature organic Rankine cycle(ORC). The ORC system uses IC engine coolant as hea... To promote the fuel utilization efficiency of IC engine, an approach was proposed for IC engine coolant energy recovery based on low-temperature organic Rankine cycle(ORC). The ORC system uses IC engine coolant as heat source, and it is coupled to the IC engine cooling system. After various kinds of organic working media were compared, R124 was selected as the ORC working medium. According to IC engine operating conditions and coolant energy characteristics, the major parameters of ORC system were preliminary designed. Then, the effects of various parameters on cycle performance and recovery potential of coolant energy were analyzed via cycle process calculation. The results indicate that cycle efficiency is mainly influenced by the working pressure of ORC, while the maximum working pressure is limited by IC engine coolant temperature. At the same working pressure, cycle efficiency is hardly affected by both the mass flow rate and temperature of working medium. When the bottom cycle working pressure arrives at the maximum allowable value of 1.6 MPa, the fuel utilization efficiency of IC engine could be improved by 12.1%.All these demonstrate that this low-temperature ORC is a useful energy-saving technology for IC engine. 展开更多
关键词 IC engine waste heat recovery organic Rankine cycle cycle efficiency coolant energy
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Biodiesel from Algae
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作者 Mladen Bosnjakovie 《Journal of Mechanics Engineering and Automation》 2013年第3期179-188,共10页
Fossil fuels are non-renewable, and their quantities have been reducing because of pumping. On the other hand, the traffic is still developing and needs for fuels are growing. As a consequence people are forced to loo... Fossil fuels are non-renewable, and their quantities have been reducing because of pumping. On the other hand, the traffic is still developing and needs for fuels are growing. As a consequence people are forced to look for other sources of getting fuel. Additional reason for this has been steadily boosting the prices of crude oil and gas. Diesel, as fuel that is often used, is possible to produce from different feedstock (oil rape, soybean, sunflower, palm, waste animal fats, algae, etc). In this paper, the author analyzes the possibility of obtaining biodiesel from algae and the feasibility of such a method of producing biodiesel. Algae for biodiesel production are analyzed and the systems in which they are growing are described. Experience in this area is described as well as opportunities for further development of technology for getting biodiesel from algae. Algae are very resistant and can grow virtually anywhere in the desert, in salt and fresh water and even in the waste water. Algae can reproduce quickly; they use C02 for photosynthesis and less water than other crops. Bio fuel from algae is biodegradable and contains no sulphur and it is not toxic. 展开更多
关键词 BIODIESEL ALGAE photobioreactor.
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Improvements of evaporation drag model
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作者 LIXiao-Yan XUJi-Jun 《Nuclear Science and Techniques》 SCIE CAS CSCD 2004年第5期317-320,共4页
A special visible experiment facility has been designed and built, and an observable experiment is per- formed by pouring one or several high-temperature particles into a water pool in the facility. The experiment res... A special visible experiment facility has been designed and built, and an observable experiment is per- formed by pouring one or several high-temperature particles into a water pool in the facility. The experiment result has verified Yang’s evaporation drag model, which holds that the non-symmetric profile of the local evaporation rate and the local density of vapor would bring about a resultant force on the hot particle so as to resist its motion. How- ever, in Yang’s evaporation drag model, radiation heat transfer is taken as the only way to transfer heat from hot par- ticle to the vapor-liquid interface, and all of the radiation energy is deposited on the vapor-liquid interface and con- tributed to the vaporization rate and mass balance of the vapor film. In improved model heat conduction and heat convection are taken into account. This paper presents calculations of the improved model, putting emphasis on the effect of hot particle’s temperature on the radiation absorption behavior of water. 展开更多
关键词 优化蒸发牵引模型 燃料冷却剂作用 热传送 放射性热交换
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严重事故工况下大质量碎片床形成的实验研究
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作者 房芳芳 韩昆 +2 位作者 王增辉 陈炼 何旭道 《原子能科学技术》 EI CAS CSCD 北大核心 2023年第11期2210-2217,共8页
碎片床形成实验作为评估碎片床可冷却性、再熔化可能性以及冷却措施的前期输入条件,具有非常高的研究价值。本文进行了大质量碎片床形成实验研究,以氧化锆为工质开展了不同熔融物质量、射流直径、水池深度、水过冷度等因素组合条件下的... 碎片床形成实验作为评估碎片床可冷却性、再熔化可能性以及冷却措施的前期输入条件,具有非常高的研究价值。本文进行了大质量碎片床形成实验研究,以氧化锆为工质开展了不同熔融物质量、射流直径、水池深度、水过冷度等因素组合条件下的实验。基于4组实验工况,获取了碎片床结构、碎片形态及尺寸分布、碎片床孔隙率等参数。结果表明:随着熔融物质量增加及水过冷度的减小,形成的碎片床中大尺寸碎片所占份额增加;在本实验装置条件下,碎片床平均孔隙率为0.345。本文结果可对碎片床的可冷却性及再熔化研究提供支持。 展开更多
关键词 严重事故 熔融物 燃料冷却剂相互作用 射流破碎 碎片床
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Modelling the Hydrogen Inhibition Effect on Ammonia Decomposition
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作者 Denver Cheddie 《Journal of Energy and Power Engineering》 2014年第4期663-670,共8页
Recently ammonia has been investigated as a fuel for SOFCs (solid oxide fuel cells). Ammonia is widely produced and transported globally, and stores hydrogen in its bonds making it an excellent fuel for fuel cells. ... Recently ammonia has been investigated as a fuel for SOFCs (solid oxide fuel cells). Ammonia is widely produced and transported globally, and stores hydrogen in its bonds making it an excellent fuel for fuel cells. The high temperature of SOFCs allows for internal decomposition of ammonia. Previous models of ammonia-fed SOFCs treat ammonia decomposition as having first order dependence on ammonia partial pressure, and ignore the effect of hydrogen inhibition. However, research has shown that at low temperatures (≤ 600 ℃) and low ammonia partial pressures, the rate of ammonia decomposition is inhibited by the presence of hydrogen. This hydrogen inhibition effect was studied and implemented in a model of an ammonia decomposition reactor. Results showed that it may significantly decrease the rate of hydrogen generation. This work sets the foundation for more accurate modelling of intermediate temperature ammonia-fed SOFCs. 展开更多
关键词 Temkin-pyzhev model hydrogen inhibition ammonia decomposition solid oxide fuel cells.
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Coacervation of oxidized glutathione with a cationic surfactant and the application in dye removal
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作者 Yue Zhang Yu Liu +2 位作者 Li Zhao Ce Wang Baocai Xu 《日用化学工业(中英文)》 CAS 2024年第12期1423-1430,共8页
Coacervation of oxidized glutathione(GSSG)and a cationic surfactant,didodecyldimethylammonium bromide(DDAB),was constructed mainly driven by the electrostatic and hydrophobic interactions.The pH-dependent coacervate o... Coacervation of oxidized glutathione(GSSG)and a cationic surfactant,didodecyldimethylammonium bromide(DDAB),was constructed mainly driven by the electrostatic and hydrophobic interactions.The pH-dependent coacervate of GSSG-DDAB(1∶4,mol/mol)was analyzed.Under acidic and neutral conditions,a turbid suspension of droplets is observed,and alkaline pH results in the phase separation of coacervates as the top phase.The coacervate phase exhibits good performance(extraction efficiency>85%)in extracting several dyes from water,including brilliant yellow,acid red 13,cresyl violet acetate,eriochrom blue SE,and 4-hydroxyazobenzene.The dyes are added into the suspension in acidic conditions.Then,the dyes are enriched and extracted along with the coacervates as the top phase when pH is adjusted to~10.Coacervation of GSSG with DDAB provides a simple approach to extract organic pollutants in wastewater treatment. 展开更多
关键词 coacervation oxidized glutathione dye removal electrostatic interaction hydrophobic effect
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