The experiment of ultrasonic treatment of roll casting aluminum strip on plane twin-roll cast-roller with double-heads ultrasonic tools was carried out, and the metallographic structure of the roll casting aluminum st...The experiment of ultrasonic treatment of roll casting aluminum strip on plane twin-roll cast-roller with double-heads ultrasonic tools was carried out, and the metallographic structure of the roll casting aluminum strip treated by ultrasonic was studied. The results show that ultrasonic treatment can refine the grain of the roll casting aluminum strips and make the structure of the strips more homogeneous. The effect is the best when the power of ultrasonic is 300 W and the incident angle of the guide rod is 45、. The mechanism of acoustic cavitations and acoustic flow on grain refinement was also discussed. The heat effect of intensity ultrasonic was studied. The present problems during ultrasonic roll casting process, such as the imperfect cooling system, the inaccurate calculation of ultrasonic energy, and the shape and position of the guide rod to be improved were pointed out.展开更多
Three types of semi-cry stalline photovoltaic polymers were synthesized by incorporating a siloxane-terminated organic/inorganic hybrid side-chain and changing the number of fluorine substituents.A branch point away f...Three types of semi-cry stalline photovoltaic polymers were synthesized by incorporating a siloxane-terminated organic/inorganic hybrid side-chain and changing the number of fluorine substituents.A branch point away from a polymer main backbone in the siloxane-containing side-chains and the intra-and/or interchain noncovalent coulombic interactions enhance a chain planarity and facile interchain organization.The resulting polymers formed strongly agglomerated films with high roughness,suggesting strong intermolecular interactions.The optical band gap of ca.1.7 eV was measured for all polymers with a pronounced shoulder peak due to tight π-π stacking.With increasing the fluorine substituents,the frontier energy levels decreased and preferential face-on orientation was observed.The siloxane-terminated side-chains and fluorine substitution promoted the intermolecular packing,showing well resolved lamellar scatterings up to(300) for this series of polymers in the grazing incidence wide angle X-ray scattering measurements.The PPsiDTBT,PPsiDTFBT and PPsiDT2 FBT devices showed a power conversion efficiency of 3.16%,4.40%and 5.65%,respectively,by blending with PC_(71)BM.Langevin-type bimolecular charge recombination was similar for three polymeric solar cells.The main loss in the photocurrent generation for PPsiDTBT:PC_(71)BM was interpreted to originate from the trap assisted charge recombination by measuring light-intensity dependent short-circuit current density(J_(SC)) and open-circuit voltage(V_(Oc)).Our results provide a new insight into the rational selection of solubilizing substituents for optimizing crystalline interchain packing with appropriate miscibility with PC71 BM for further optimizing polymer solar cells.展开更多
基金Projects(IRT0549) supported by Program for Changjiang Scholars and Innovative Research Team in University, China
文摘The experiment of ultrasonic treatment of roll casting aluminum strip on plane twin-roll cast-roller with double-heads ultrasonic tools was carried out, and the metallographic structure of the roll casting aluminum strip treated by ultrasonic was studied. The results show that ultrasonic treatment can refine the grain of the roll casting aluminum strips and make the structure of the strips more homogeneous. The effect is the best when the power of ultrasonic is 300 W and the incident angle of the guide rod is 45、. The mechanism of acoustic cavitations and acoustic flow on grain refinement was also discussed. The heat effect of intensity ultrasonic was studied. The present problems during ultrasonic roll casting process, such as the imperfect cooling system, the inaccurate calculation of ultrasonic energy, and the shape and position of the guide rod to be improved were pointed out.
基金supported by the National Research Foundation of Korea 2015R1A2A1A15055605,2015M1A2A2057506,2015R1D1A1A09056905,2016M1A2A2940911)
文摘Three types of semi-cry stalline photovoltaic polymers were synthesized by incorporating a siloxane-terminated organic/inorganic hybrid side-chain and changing the number of fluorine substituents.A branch point away from a polymer main backbone in the siloxane-containing side-chains and the intra-and/or interchain noncovalent coulombic interactions enhance a chain planarity and facile interchain organization.The resulting polymers formed strongly agglomerated films with high roughness,suggesting strong intermolecular interactions.The optical band gap of ca.1.7 eV was measured for all polymers with a pronounced shoulder peak due to tight π-π stacking.With increasing the fluorine substituents,the frontier energy levels decreased and preferential face-on orientation was observed.The siloxane-terminated side-chains and fluorine substitution promoted the intermolecular packing,showing well resolved lamellar scatterings up to(300) for this series of polymers in the grazing incidence wide angle X-ray scattering measurements.The PPsiDTBT,PPsiDTFBT and PPsiDT2 FBT devices showed a power conversion efficiency of 3.16%,4.40%and 5.65%,respectively,by blending with PC_(71)BM.Langevin-type bimolecular charge recombination was similar for three polymeric solar cells.The main loss in the photocurrent generation for PPsiDTBT:PC_(71)BM was interpreted to originate from the trap assisted charge recombination by measuring light-intensity dependent short-circuit current density(J_(SC)) and open-circuit voltage(V_(Oc)).Our results provide a new insight into the rational selection of solubilizing substituents for optimizing crystalline interchain packing with appropriate miscibility with PC71 BM for further optimizing polymer solar cells.
