喷涂聚脲保护面层的选择

重点阐述了芳香族聚脲涂层几种常用的脂肪族聚脲保护面层的材料特点,并对其优缺点作了对比;指出聚天冬氨酸酯聚脲作聚脲保护面漆,各项性能指标都能满足相关技术要求。

Aspects of surface and environment protection in German mining areas

Hard coal mining in the German Ruhr district has a tradition of more than 200 years. Starting in the south near the river Ruhr with mining of seams near to the surface, mining wandered to the north with coal seams deeper and deeper. In the same way all environmental effects of mining wandered from south to north, as there are abandoned mining sites, contaminated areas, burning mining dumps, subsided areas and gas accesses at day ground. This all happened in a very high populated area with more than four million inhabitants. Therefore Germany has a long tradition in solving environmental problems of mining activities. The very good interaction of mine authority, mining companies and the mine workers’ union is the main reason why the problems of decreasing mining activities in Germany were solved without economic, environmental or social hazards.

Fracture evolution and pressure relief gas drainage from distant protected coal seams under an extremely thick key stratum

When an extremely thick rock bed exists above a protected coal seam in the bending zone given the condition of a mining protective seam, this extremely thick rock bed controls the movement of the entire overlying stratum. This extremely thick rock bed, called a ＂main key stratum＂, will not subside nor break for a long time, causing lower fractures and bed separations not to close and gas can migrate to the bed separation areas along the fractures. These bed separations become gas enrichment areas. By analyzing the rule of fracture evolution and gas migration under the main key stratum after the deep protective coal seam has been mined, we propose a new gas drainage method which uses bore holes, drilled through rock and coal seams at great depths for draining pressure relief gas. In this method, the bores are located at a high level suction roadway （we can also drill them in the drilling field located high in an air gateway）. Given the practice in the Haizi mine, the gas drainage rate can reach 73% in the middie coal group, with a gas drainage radius over 100 m.

透水生态钢渣混凝土路面施工技术

结合某公路施工建设项目,基于环保利用,对该公路路面采用透水生态钢渣混凝土,提出合理的钢渣混凝土配合比设计,针对各个施工环节提出可行的施工控制技术措施,为同类工程提供参考借鉴。

Evaluation of long-term corrosion durability and self-healing ability of scratched coating systems on carbon steel in a marine environment

Defects in protective-coating systems on steel surfaces are inevitable in practical engineering applications. A composite coating system, including a primer, middle coat and topcoat, were used to protect carbon steel from corrosion in a marine environment. Two environmental additives, glass fibers and thiourea, were applied in the middle coat to modify the coating system. The long-term corrosion durability and self-healing ability of the scratched coating system were evaluated by multiple methods. Results of the electrochemical technologies indicated that the coating system that contained 0.5 wt.% fibers and 0.5 wt.% thiourea presented good corrosion protection and self-healing for carbon steel when immersed in 3.5% NaCl for 120 d. Evolution of localized corrosion factors with time, as obtained from the current distribution showed that fibers combined with thiourea could inhibit the occurrence of local corrosion in scratched coating systems and retarded the corrosion development significantly. Surface characterization suggested that adequate thiourea could be absorbed tmiformly on fibers for a long time to play an important role in protecting the carbon steel. Finally, schematic models were established to demonstrate the action of fibers and thiourea on the exposed surface of the carbon steel and the scratched coating system in the entire deterioration process.

Rational concrete cover of prestressed concrete beams and slabs for fire resistance

As the influence of the ratio of the characteristic value of structural resistance to that of frequent combination effect, K, on the thickness of concrete cover of prestressed concrete （PC） beams and slabs for fire resistance is not considered sufficiently in design criteria for concrete structures in China and other countries at present, numerical analyses were carried out by ANSYS software on unbonded prestressed concrete （UPC） oneway simply-supported and continuous slabs and beams, and bonded PC simply-supported and continuous beams subjected to fire in 186 cases. In the analysis, K, section dimensions and the thickness of concrete cover are regarded as independent variables and some calculation parameters determined by trial and error based on test resuits. Calculation formula for fire endurance of UPC simply-supported and continuous slabs was proposed, and the recommended thicknesses of cover of PC beams and slabs was presented in consideration of the influence of K and section dimensions as well as fire endurance requirements. Comparison analysis of relevant design criterions in China and other countries was performed to verify the rationale of the proposed values.

Hollow-in-hollow carbon spheres with hollow foam-like cores for lithium-sulfur batteries

Lithium-sulfur batteries have attracted increasing attention because of their high theoretical capadty. Using sulfur/carbon composites as the cathode materials has been demonstrated as an effective strategy to optimize sulfur utilization and enhance cycle stability as well. In this work hollow-in-hollow carbon spheres with hollow foam-like cores （HCSF@C） are prepared to improve both capability and cycling stability of lithium-sulfur batteries. With high surface area and large pore volumes, the loading of sulfur in HCSF@C reaches up to 70 wt.%. In the resulting S/HCSF@C composites, the outer carbon shell serves as an effective protection layer to trap the soluble polysulfide intermediates derived from the inner component. Consequently, the S/HCSF@C cathode retains a high capacity of 780 mAh/g after 300 cycles at a high charge/discharge rate of 1 A/g.