Nanoindentation tests were conducted to investigate the near-surface mechanical properties of the individual components(fiber and matrix) for three-dimensional reinforced carbon/carbon composites(3D C/C).Optical micro...Nanoindentation tests were conducted to investigate the near-surface mechanical properties of the individual components(fiber and matrix) for three-dimensional reinforced carbon/carbon composites(3D C/C).Optical microscope and polarizing light microscope were used to characterize the microstructure of 3D C/C.The microscopy results show that large number of pores and cracks exist at both bundle/matrix interface and pitch carbon matrix.These defects have important effect on the mechanical behavior of 3D C/C.The in situ properties for components of 3D C/C were acquired by nanoindentation technique.Relative to the matrix sample,the fiber samples have more larger values for modulus,stiffness and hardness.However,there is no significant difference of modulus and stiffness among fiber samples with different directions.展开更多
As an important optical constant of optical properties for spectacle lens,the refractive index measurement is studied using V prism refractometer. In the experiment,according to various factors inducing measurement er...As an important optical constant of optical properties for spectacle lens,the refractive index measurement is studied using V prism refractometer. In the experiment,according to various factors inducing measurement error,the experimental results are analyzed,which include right angle deviation,contact liquid,curvature,and focusing accuracy. The study results show that focusing accuracy is the most important factor of influence for measurement,consists of contact liquid wettability,sample shape,and effective width of light transmission. In addition,the refractive index measurement is less affected by angle deviation of sample and the refractive index deviation of contact liquid. On the basis of the experimental data analysis,it is possible to relax the deviation of right angle of the sample to 1' or 2'.展开更多
Band offset is a dominant factor affecting the photocatalytic performance of heterostructure photocatalysts. Therefore, controlling the band gap structure of semiconductors is a key challenge in the development of eff...Band offset is a dominant factor affecting the photocatalytic performance of heterostructure photocatalysts. Therefore, controlling the band gap structure of semiconductors is a key challenge in the development of efficient photocatalysts. We used a typical in situ-method to prepare diverse graphite-phase carbon nitride(g-C_3N_4)samples from melamine, thiourea, and a mixture thereof,and found that they exhibited band gaps between2.3–2.8 e V. From UV–Vis spectra and X-ray photoelectron spectroscopy measurements, we determined that the g-C_3N_4 samples exhibited different band gap values and valence band positions. On this basis, we constructed g-C_3N_4/m-La VO_4 heterojunctions with different band offsets. UV–Vis spectra and X-ray photoelectron spectroscopy measurements revealed that the valence band offsets(VBOs) of the different heterojunctions were similar, but their conduction band offsets(CBOs) were significantly different. Photocatalytic experiments revealed that the reaction rate was enhanced with an increase in the CBO value. Furthermore, the three-phase g-C_3N_4/g-C_3N_4/mLa VO_4 heterojunction composed of m-La VO_4 and mixed g-C_3N_4 showed the highest photocatalytic activity, which was mainly due to the construction of a multilevel structure. This work investigates the influence of the band offset on heterojunction photoelectrochemical properties and provides a new strategy to improve the photocatalytic activity by constructing multilevel structures.展开更多
The performance of broadband polarizing beam splitters(PBSs) is sensitive to the incident angle.By taking account of the spectrum of the laser source and using the needle optimization method,a large acceptance angle P...The performance of broadband polarizing beam splitters(PBSs) is sensitive to the incident angle.By taking account of the spectrum of the laser source and using the needle optimization method,a large acceptance angle PBS for laser-based displays is designed.The average degrees of polarization in transmission and reflection can reach 0.989 and 0.980 for an acceptance angle of 13.6?in air using two materials,while better results of 0.993 and 0.989 for an acceptance angle of 14.8?in air are attained when three common materials are used.Both designs consist of 40 layers.展开更多
Linearly bonded triiodide chains with fairly small distance between the adjacent iodine ions feature a facile electron transfer and highly anisotropic properties.Here,we demonstrate a novel strategy towards a new one-...Linearly bonded triiodide chains with fairly small distance between the adjacent iodine ions feature a facile electron transfer and highly anisotropic properties.Here,we demonstrate a novel strategy towards a new one-dimensional linear triiodide DMEDA·I6,using chain-type N,N'-dimethylethanediamine(DMEDA)cation to coordinate triiodine ions.This triiodide has the shortest distance between adjacent I3^- and good linearity.An estimated electronic band gap of1.36 e V indicates its semiconducting properties.100 fold differences both in polarization-sensitive absorption and effective mass were achieved by simulation,with directions parallel and perpendicular to the a-axis of DMEDA·I6.The DMEDA·I6 single crystal-based photodetectors show a good switching characteristic and a distinct polarization-sensitive photoresponse with linear dichroic photodetection ratio of about 1.9.Strongly anisotropic features and semiconducting properties of DMEDA·I6 make this triiodide system an interesting candidate for polarization related applications.展开更多
基金Project(61391) supported by the National Security Basic Research Program of ChinaProject (91016029) supported by the National Natural Science Foundation of China
文摘Nanoindentation tests were conducted to investigate the near-surface mechanical properties of the individual components(fiber and matrix) for three-dimensional reinforced carbon/carbon composites(3D C/C).Optical microscope and polarizing light microscope were used to characterize the microstructure of 3D C/C.The microscopy results show that large number of pores and cracks exist at both bundle/matrix interface and pitch carbon matrix.These defects have important effect on the mechanical behavior of 3D C/C.The in situ properties for components of 3D C/C were acquired by nanoindentation technique.Relative to the matrix sample,the fiber samples have more larger values for modulus,stiffness and hardness.However,there is no significant difference of modulus and stiffness among fiber samples with different directions.
文摘As an important optical constant of optical properties for spectacle lens,the refractive index measurement is studied using V prism refractometer. In the experiment,according to various factors inducing measurement error,the experimental results are analyzed,which include right angle deviation,contact liquid,curvature,and focusing accuracy. The study results show that focusing accuracy is the most important factor of influence for measurement,consists of contact liquid wettability,sample shape,and effective width of light transmission. In addition,the refractive index measurement is less affected by angle deviation of sample and the refractive index deviation of contact liquid. On the basis of the experimental data analysis,it is possible to relax the deviation of right angle of the sample to 1' or 2'.
基金supported by the National Natural Science Foundation of China(21173131)the Taishan Scholar Project of Shandong Province
文摘Band offset is a dominant factor affecting the photocatalytic performance of heterostructure photocatalysts. Therefore, controlling the band gap structure of semiconductors is a key challenge in the development of efficient photocatalysts. We used a typical in situ-method to prepare diverse graphite-phase carbon nitride(g-C_3N_4)samples from melamine, thiourea, and a mixture thereof,and found that they exhibited band gaps between2.3–2.8 e V. From UV–Vis spectra and X-ray photoelectron spectroscopy measurements, we determined that the g-C_3N_4 samples exhibited different band gap values and valence band positions. On this basis, we constructed g-C_3N_4/m-La VO_4 heterojunctions with different band offsets. UV–Vis spectra and X-ray photoelectron spectroscopy measurements revealed that the valence band offsets(VBOs) of the different heterojunctions were similar, but their conduction band offsets(CBOs) were significantly different. Photocatalytic experiments revealed that the reaction rate was enhanced with an increase in the CBO value. Furthermore, the three-phase g-C_3N_4/g-C_3N_4/mLa VO_4 heterojunction composed of m-La VO_4 and mixed g-C_3N_4 showed the highest photocatalytic activity, which was mainly due to the construction of a multilevel structure. This work investigates the influence of the band offset on heterojunction photoelectrochemical properties and provides a new strategy to improve the photocatalytic activity by constructing multilevel structures.
基金supported by the National Natural Science Foundation of China (No.50802080)the Natural Science Foundation of Fujian Province (No.2010J01349)
文摘The performance of broadband polarizing beam splitters(PBSs) is sensitive to the incident angle.By taking account of the spectrum of the laser source and using the needle optimization method,a large acceptance angle PBS for laser-based displays is designed.The average degrees of polarization in transmission and reflection can reach 0.989 and 0.980 for an acceptance angle of 13.6?in air using two materials,while better results of 0.993 and 0.989 for an acceptance angle of 14.8?in air are attained when three common materials are used.Both designs consist of 40 layers.
基金financially supported by the National Natural Science Foundation of China (51761145048, 61725401 and 61704097)the Innovation Fund of WNLO and the 62th China Postdoctoral Science Foundation (2017M622418)
文摘Linearly bonded triiodide chains with fairly small distance between the adjacent iodine ions feature a facile electron transfer and highly anisotropic properties.Here,we demonstrate a novel strategy towards a new one-dimensional linear triiodide DMEDA·I6,using chain-type N,N'-dimethylethanediamine(DMEDA)cation to coordinate triiodine ions.This triiodide has the shortest distance between adjacent I3^- and good linearity.An estimated electronic band gap of1.36 e V indicates its semiconducting properties.100 fold differences both in polarization-sensitive absorption and effective mass were achieved by simulation,with directions parallel and perpendicular to the a-axis of DMEDA·I6.The DMEDA·I6 single crystal-based photodetectors show a good switching characteristic and a distinct polarization-sensitive photoresponse with linear dichroic photodetection ratio of about 1.9.Strongly anisotropic features and semiconducting properties of DMEDA·I6 make this triiodide system an interesting candidate for polarization related applications.
