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dppm与CH_2Cl_2在Pd(OAc)_2作用下反应stopped-flow动态学研究 被引量:1
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作者 韦凤萍 黄永仁 汪汉卿 《化学研究与应用》 CAS CSCD 1998年第4期392-395,共4页
dppm与CH2Cl2在Pd(OAc)2作用下反应stopped_flow动态学研究韦凤萍黄永仁(华东师范大学分析测试中心上海200061)汪汉卿(中国科学院物理研究所兰州730000关键词动态学Pd(OAc)2dp... dppm与CH2Cl2在Pd(OAc)2作用下反应stopped_flow动态学研究韦凤萍黄永仁(华东师范大学分析测试中心上海200061)汪汉卿(中国科学院物理研究所兰州730000关键词动态学Pd(OAc)2dppmCH2Cl2停-流中图分类号O... 展开更多
关键词 动态学 PD(OAC)2 DPPM 停-流 二氯甲烷 钯配合物
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Effects of sequential decay on collective flows and nuclear stopping power in heavy-ion collisions at intermediate energies 被引量:1
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作者 Kui Xiao Peng-Cheng Li +2 位作者 Yong-Jia Wang Fu-Hu Liu Qing-Feng Li 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第4期175-184,共10页
In this study, the rapidity distribution, collective flows, and nuclear stopping power in ^(197)Au+^(197)Au collisions at intermediate energies were investigated using the ultrarelativistic quantum molecular dynamics(... In this study, the rapidity distribution, collective flows, and nuclear stopping power in ^(197)Au+^(197)Au collisions at intermediate energies were investigated using the ultrarelativistic quantum molecular dynamics(UrQMD) model with GEMINI++ code. The UrQMD model was adopted to simulate the dynamic evolution of heavy-ion collisions, whereas the GEMINI++ code was used to simulate the decay of primary fragments produced by UrQMD. The calculated results were compared with the INDRA and FOPI experimental data. It was found that the rapidity distribution, collective flows, and nuclear stopping power were affected to a certain extent by the decay of primary fragments, especially at lower beam energies. Furthermore, the experimental data of the collective flows and nuclear stopping power at the investigated beam energies were better reproduced when the sequential decay effect was included. 展开更多
关键词 Heavy-ion collisions Sequential decay effect Collective flow Nuclear stopping power
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用Stopped-flow光散射方法研究NaCl浓度对CTAB棒状胶束形态转变的影响
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作者 高建伟 潘皖江 +2 位作者 刘和文 诸致远 刘世勇 《纳米科技》 2006年第1期48-50,共3页
用Stopped-flow光散射方法研究NaCl浓度对CTAB(十六烷基三甲基溴化铵)棒状胶束形态转变的影响。对同一CTAB溶液体系增加盐浓度,或者保持盐浓度恒定条件下增加CTAB浓度,胶束形态都出现显著的从球状到棒状转变过程。
关键词 stopped-flow 光散射 CTAB 十六烷基三甲基溴化铵 表面净性剂
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Stopped-Flow技术应用于烯烃聚合的研究
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作者 叶朝阳 王立 《合成树脂及塑料》 CAS 2002年第1期45-49,共5页
对Stopped-Flow技术应用于MgCl_2负载Ziegler催化体系的研究结果进行了综述,该技术能够将烯烃聚合反应控制在极短时间内(约0.1s),并且对于催化剂活性中心的研究有着十分重要的意义。
关键词 stopped-flow技术 烯烃聚合 MgCl2负载 Ziegler催化剂
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Simultaneous Determination of Samarium and Gadolinium by a Automated Stopped-flow Analyzer 被引量:1
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作者 Yang Yi, Cai Ruxiu and Zeng Yun’ e (Department of Chemistry, Wuhan University, Wuhan) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1991年第2期79-83,共5页
The present paper contains the reaction mechanism of the rare earth complex with 2-(2-arsenophenylazo)-7-(2, 6-dichloro-4-fluoro-phenylazo)- 1, 8-dihydroxynaphthalene-3, 6-disulfonic acid (DCF-arsenazo) studied prelim... The present paper contains the reaction mechanism of the rare earth complex with 2-(2-arsenophenylazo)-7-(2, 6-dichloro-4-fluoro-phenylazo)- 1, 8-dihydroxynaphthalene-3, 6-disulfonic acid (DCF-arsenazo) studied preliminarily with a fully automated stopped-flow analyzer. A method with a high sensitivity and selectivity is proposed for the simultaneous determination of samarium and gadolinium based on the differential kinetic reaction of the rare earth complex with DCF-arsenazo. Sm and Gd in their concentrated oxides were determined with the relative errors less than 6%. 展开更多
关键词 KINETIC SAMARIUM GADOLINIUM stopped-flow
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Kinetic-spectrophotometric determination of free cyanide by stopped-flow reversed flow injection analysis
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《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1993年第3期367-372,共6页
A stopped-flow reversed flow injection method for the determination of free cyanide is proposed. Pyridine-barbituric acid mixture is injected in the flow system as reagent to form the colour species with cyanide. The ... A stopped-flow reversed flow injection method for the determination of free cyanide is proposed. Pyridine-barbituric acid mixture is injected in the flow system as reagent to form the colour species with cyanide. The flow is stopped when the reagent zone comes in the flow cell, where absorbance-time data are collected at 580nm wavelength. The linear range of the determination is 0.1 -10μg/ml CN-. The sampling rate is 60h-1 and the relative standard deviation is 1.6% (n=16) at 5.0 μg/ml CN-1 level. With satisfactory results, the proposed method was applied to the determination of free cyanide in wastewater without sample pretreatment. 展开更多
关键词 kinetic analysis stopped-flow reversed flow injection system free cyanide wastewater.
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New Approach to Detecting Phenoxyl Free Radicals Generated in Enzyme Reaction by Stopped-flow Spectrophotometry
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作者 Jing XU Lan Hua ZHAO +2 位作者 Xin Guo WU Hong Mei WANG Ru Xiu CAI 《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第7期949-952,共4页
A highly sensitive stopped-flow spectrophotometry kinetic method was proposed for quantification phenoxyl radicals based on their accelerating effect on the oxidation of nicotinamide adenine dinucleotide (NADH). Phe... A highly sensitive stopped-flow spectrophotometry kinetic method was proposed for quantification phenoxyl radicals based on their accelerating effect on the oxidation of nicotinamide adenine dinucleotide (NADH). Phenoxyl radicals generated from as low as 1×10^-8 mol/L 2,4-DCP can be readily detected with the proposed method and the detecting limit was 2.5×10^-9 mol/L. 展开更多
关键词 Phenoxyl radicals moleculary probe stopped-flow spectrophotometry.
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Mixed traffic flow modeling near Chinese bus stops and its applications 被引量:5
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作者 杨小宝 四兵锋 环梅 《Journal of Central South University》 SCIE EI CAS 2012年第9期2697-2704,共8页
To determine how bus stop design influences mixed traffic operation near Chinese bus stops,a new theoretical method was developed by using additive-conflict-flows procedure.The procedure was extended from homogeneous ... To determine how bus stop design influences mixed traffic operation near Chinese bus stops,a new theoretical method was developed by using additive-conflict-flows procedure.The procedure was extended from homogeneous traffic flow to mixed traffic flow.Based on the procedure and queuing theory,car capacity and speed models were proposed for three types of bus stops including curbside,bus bay and bicycle detour.The effects of various combinations of bus stop type,traffic volume,bus dwell time,and berth number on traffic operations were investigated.The results indicate that traffic volume,bus dwell time and berth number have negative effects on traffic operations for any type of bus stops.For different types of bus stops,at car volumes above approximately 200 vehicles per hour,the bus bay and bicycle detour designs provide more benefits than the curbside design.As traffic volume increases,the benefit firstly increases in uncongested conditions and then decreases in congested conditions.It reaches the maximum at car volumes nearly 1 100 vehicles per hour.The results can be used to aid in the selection of a preferred bus stop design for a given traffic volume in developing countries. 展开更多
关键词 mixed traffic flow bus stop road capacity SPEED bicycles
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Collective flow and nuclear stopping in heavy ion collisions in Fermi energy domain 被引量:5
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作者 Peng-Cheng Li Yong-Jia Wang +1 位作者 Qing-Feng Li Hong-Fei Zhang 《Nuclear Science and Techniques》 SCIE CAS CSCD 2018年第12期54-61,共8页
The effects of the in-medium nucleon-nucleon(NN) elastic cross section on the observables in heavy ion collisions in the Fermi energy domain are investigated within the framework of the ultrarelativistic quantum molec... The effects of the in-medium nucleon-nucleon(NN) elastic cross section on the observables in heavy ion collisions in the Fermi energy domain are investigated within the framework of the ultrarelativistic quantum molecular dynamics model. The results simulated using medium correction factors of F=σ_(NN)^(in-medium)/σ_(NN)^(free)=0.2,0.3,0.5,and the density-and momentum-dependent factor obtained from the FU3 FP1 parametrization are compared with the FOPI and INDRA experimental data. It is found that the calculations using the correction factors F=0.2 and 0.5 reproduce the experimental data(i.e.,collective flow and nuclear stopping) at 40 and 150 MeV/nucleon, respectively. Calculations with the FU3 FP1 parametrization can best fit these experimental data. These conclusions can be confirmed in both^(197)Au+^(197)Au and^(129)Xe+^(120)Sn. 展开更多
关键词 重离子碰撞 原子 精力 流动 集体 修正因素 动力学模型 试验性
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Mechanism of Flowing Stop of Al-Si Alloys in EPC Process
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作者 魏尊杰 安阁英 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 1995年第2期60-63,共4页
The effect of several casting parameters on flowability of aluminium alloys is studied.It is found that fluidity increases linearly with the increase of pouring temperature and casting section thickness;the latent hea... The effect of several casting parameters on flowability of aluminium alloys is studied.It is found that fluidity increases linearly with the increase of pouring temperature and casting section thickness;the latent heat of vaporization is one of the most important properties of polystyrene which influences the molten metal flow.Also the mechanism of metal flowing stop is studied by means of dumping tests.The results show that for pure aluminium and aluminium alloys with narrow freezing range the molten metal flowing is stopped when a solidification shell which has enough strength to resist the effective pressure head is formed at the flowing metal front.The mechanism of flowing stop is much different from that in the traditional green sand casting. 展开更多
关键词 ss:Evaporative pattern CASTING flowABILITY flowing stop
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A New Macro Model for Traffic Flow on a Highway with Bus Stop
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作者 唐铁桥 史彦锋 +1 位作者 黄海军 尚华艳 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第6期1113-1118,共6页
Based on the difference between the online bus stop and the offline bus stop, two macro models are developed to describe the two types of bus stops. The numerical results show that the two models can qualitatively rep... Based on the difference between the online bus stop and the offline bus stop, two macro models are developed to describe the two types of bus stops. The numerical results show that the two models can qualitatively reproduce some complex phenomena resulted by the two types of bus stops and that the otttine bus stop is more effective than the online bus stop when the initial density is relatively low. 展开更多
关键词 traffic flow bus stop STABILITY
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公交站点区域行人与非机动车交互行为建模与仿真
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作者 魏中华 马厚强 +1 位作者 王铭乾 黄文佳 《科学技术与工程》 北大核心 2024年第1期397-407,共11页
为研究公交站点区域行人和非机动车的冲突行为,在元胞自动机模型的基础上,首先,考虑激进型行人和混合非机动车流,通过行人穿越决策规则和非机动车避让规则耦合行人运动模型和非机动车运动模型,采用双向行人Blue模型模拟进出站行人的运... 为研究公交站点区域行人和非机动车的冲突行为,在元胞自动机模型的基础上,首先,考虑激进型行人和混合非机动车流,通过行人穿越决策规则和非机动车避让规则耦合行人运动模型和非机动车运动模型,采用双向行人Blue模型模拟进出站行人的运动行为,采用改进的NaSch模型模拟非机动车的运动行为,建立公交站点区域行人与非机动车交互模型。然后,在北京市西单商场公交站B站台开展观测实验,微观层面展现行人和非机动车之间的交互作用,分析在不同流量构成下二者冲突演化规律以及进出站行人到达率、非机动车到达率对延误和冲突数的影响。研究结果表明,非机动车堵塞多发生在非机动车与行人刚开始的交互处,并向来车方向延伸。与进出站行人到达率相比,行人和非机动车延误受非机动车到达率影响更显著;在进出站行人比例为0.5时,行人和非机动车延误达到峰值;进站行人比例为1时,行人和非机动车延误比出站行人比例为1时延误小;在行人到达率一定时,冲突数随着非机动车达到率的增大而增加,当行人到达率较小时,冲突数呈缓慢地增长趋势,随着行人到达率的增大,冲突数增长率呈现先增大后减小的趋势。 展开更多
关键词 公交站点区域 混合交通流 元胞自动机 交通流特征
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全球经济政策不确定性对国际资本异常流动的影响
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作者 杨继梅 邱雨佳 《西部论坛》 北大核心 2024年第3期9-23,共15页
全球经济政策不确定性上升会提高国际投资的风险和成本,加上“外国劣势”的影响,投资者会减少对外投资,从而使国际资本出现本土化倾向的异常流动。采用24个发达经济体、25个新兴和发展中经济体2005年第三季度至2022年第四季度的跨国面... 全球经济政策不确定性上升会提高国际投资的风险和成本,加上“外国劣势”的影响,投资者会减少对外投资,从而使国际资本出现本土化倾向的异常流动。采用24个发达经济体、25个新兴和发展中经济体2005年第三季度至2022年第四季度的跨国面板数据,将国际资本异常流动分为外逃、撤回、激增、中断4种类型,运用Probit模型分析发现:在样本期间,发达经济体的资本异常流动少于新兴和发展中经济体;全球经济政策不确定性上升会降低资本外逃和激增的概率,并增加资本撤回和中断的概率;全球经济政策不确定性对发达经济体4种异常流动的影响都显著,而对新兴和发展中经济体只显著影响了资本外逃和激增;全球经济政策不确定性会显著影响其他投资的4种异常流动,并显著影响直接投资的外逃和激增、证券投资的外逃和撤回;金融开放水平较低时,金融开放会强化全球经济政策不确定性对国际资本异常流动的影响,但当金融开放水平较高时,全球经济政策不确定性的影响不再显著。因此,应建立国际资本异常流动监测平台,完善国际投资监管机制,并积极推进高水平金融开放。 展开更多
关键词 经济政策不确定性 国际资本流动 资本外逃 资本激增 资本撤回 资本中断
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Study on compressibility of traffic flow 被引量:1
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作者 王殿海 梁春岩 +1 位作者 程瑶 姚荣涵 《Journal of Southeast University(English Edition)》 EI CAS 2009年第2期262-266,共5页
In order to describe the compressibility of traffic flows and determine the compression factors, the Mach number of gas dynamics is introduced, and the concept and the formula of the compression factor are obtained. A... In order to describe the compressibility of traffic flows and determine the compression factors, the Mach number of gas dynamics is introduced, and the concept and the formula of the compression factor are obtained. According to the concept of the compression factor and its differential equation, a stop-wave model is built. The theoretical value and the observed one are obtained by the survey data in Changchun city. The relative error between the two values is 20. 3%. The accuracy is improved 39% compared with the result from the traditional stop-wave model. The results show that the traffic flow is compressible, and the methods of research on gas compressibility is also applicable to the traffic flow. The stop-wave model obtained by the compression factor can better describe the phenomenon of the stop wave at a signalized intersection when compared with the traditional stop-wave model. 展开更多
关键词 compressibility of traffic flow Mach number compression factor stop wave
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椰油酰胺丙基甜菜碱防聚剂对管输体系中水合物团聚的影响
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作者 张书炜 徐加放 +3 位作者 潘振 王博闻 王健 陈杰 《石油化工》 CAS CSCD 北大核心 2024年第5期686-693,共8页
针对高含水率下防聚剂失效问题,研究了新型防聚剂椰油酰胺丙基甜菜碱(CAB-35)对不同含水率及初始流量的油水乳液体系流动稳定性的影响。实验结果表明,含水率和初始流量的增加均会使水合物颗粒平均粒径弦长减小,推迟水合物堵管时间。CAB... 针对高含水率下防聚剂失效问题,研究了新型防聚剂椰油酰胺丙基甜菜碱(CAB-35)对不同含水率及初始流量的油水乳液体系流动稳定性的影响。实验结果表明,含水率和初始流量的增加均会使水合物颗粒平均粒径弦长减小,推迟水合物堵管时间。CAB-35在纯水中的抗凝聚效果也较好,它的椰油酰胺基为长烷基链,能降低颗粒间内聚力,通过影响气体水合物颗粒之间的液桥从而使水合物颗粒凝聚力失稳。在倾斜管道中CAB-35仍具有较好的抗凝聚作用。添加CAB-35可在第一次停输再启动后保证水合物浆液的流动时间延长,但第二次停输后仍不能通过再启动泵使流量恢复正常。研究结果为防聚剂选择、高含水率体系下的水合物抗凝聚及非常规管段停启系统中水合物浆液流动提供理论支持。 展开更多
关键词 水合物 流动保障 防聚剂 倾斜管道 停输再启动
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顺序注射停留分光光度法测定磺胺乙酰钠 被引量:1
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作者 过治军 冯素玲 樊静 《分析试验室》 CAS CSCD 北大核心 2005年第6期72-74,共3页
在HCl浓度为5.0×10-4mol/L时,磺胺乙酰钠-NaNO2-1-萘胺的重氮化偶合反应,生成不稳定的红色产物,利用顺序注射停留技术在473nm波长处检测该不稳定产物,建立了快速自动测定磺胺乙酰钠的新方法。该方法线性范围为5~2500μg/mL,检出限... 在HCl浓度为5.0×10-4mol/L时,磺胺乙酰钠-NaNO2-1-萘胺的重氮化偶合反应,生成不稳定的红色产物,利用顺序注射停留技术在473nm波长处检测该不稳定产物,建立了快速自动测定磺胺乙酰钠的新方法。该方法线性范围为5~2500μg/mL,检出限为0.018μg/mL,进样频率为62个/h。应用于药物中磺胺乙酰钠的测定,并与药典规定方法进行对照。 展开更多
关键词 顺序注射分析 停留技术 分光光度法 磺胺乙酰钠 1-萘胺
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基于中间气压罐和罐前逆止阀的浮船泵站水锤防护
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作者 洪智 周暄礼 刘志勇 《中国农村水利水电》 北大核心 2024年第4期182-186,共5页
以云南省元谋县金沙江光伏提水工程的第一级浮船泵站供水系统为例,开展了浮船泵站水锤防护的研究。在参考相关设计规范的基础上,确定了停泵水锤防护标准;通过比较不同水源水位和停泵台数对过渡过程的影响,确定水锤防护的控制工况为水源... 以云南省元谋县金沙江光伏提水工程的第一级浮船泵站供水系统为例,开展了浮船泵站水锤防护的研究。在参考相关设计规范的基础上,确定了停泵水锤防护标准;通过比较不同水源水位和停泵台数对过渡过程的影响,确定水锤防护的控制工况为水源水位最低、运行机组全部停泵的工况;根据管道沿线地形和浮船泵站的特点,在分析泵出口阀关闭程序、中间气压罐防护效果、罐前逆止阀作用的基础上,提出了“泵出口轴流式逆止阀+中间气压罐+罐前逆止阀”的水锤防护方案。该方案通过泵出口轴流式逆止阀完全防止机组倒转,通过中间气压罐控制管线中的正负水锤压力,通过罐前逆止阀防止倒泄水流对浮船和摇臂联络管的冲击。该防护措施对类似工程有较好的参考意义。 展开更多
关键词 浮船泵站 轴流式逆止阀 中间气压罐 罐前逆止阀 停泵水锤防护
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基于3DPIV技术的煤矿模拟巷道烟气流动实验研究
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作者 邹永洺 王银辉 +1 位作者 田富超 赵岳然 《煤矿安全》 CAS 北大核心 2024年第8期72-79,共8页
为研究煤矿井下发生火灾时烟气流动的特征,进而准确分析烟气流动状态,模拟了自然状态下烟气在10 s的流动状态,确定发火产烟的大致阶段;利用三维粒子图像测速(3-dimensional Particle Image Velocimetry,3DPIV)技术分别拍摄巷道敞口、密... 为研究煤矿井下发生火灾时烟气流动的特征,进而准确分析烟气流动状态,模拟了自然状态下烟气在10 s的流动状态,确定发火产烟的大致阶段;利用三维粒子图像测速(3-dimensional Particle Image Velocimetry,3DPIV)技术分别拍摄巷道敞口、密闭以及密闭启封3种状态下固定风速1 m/s风机的启停控制,研究不同条件下烟流的运动情况。结果表明:巷道敞口烟流流动比较简单,而巷道一旦密闭,导致烟气无法扩散,高浓度烟气将会出现复杂的流动变化,如层流、过度流、湍流、逆流以及烟流分叉等现象,巷道密闭启封时会发生烟流“涌出”,此刻烟流流动状态复杂多变,但经过一定时间都会保持烟流稳定。 展开更多
关键词 矿井火灾 烟气流动 模拟巷道 3DPIV 密闭启封
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结合道路信息的HEV发动机起停触发系统设计
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作者 高爱云 张兴源 付主木 《重庆交通大学学报(自然科学版)》 CAS CSCD 北大核心 2024年第7期121-128,136,共9页
现有的发动机起停系统只要发动机满足怠速停止的基本条件发动机就会停止,造成车辆频繁起停,这样不仅会加剧发动机部件磨损,还会增加整车油耗。为解决这一问题,设计了一种结合道路信息的混合动力汽车发动机起停触发系统(HEV-EST)。根据HE... 现有的发动机起停系统只要发动机满足怠速停止的基本条件发动机就会停止,造成车辆频繁起停,这样不仅会加剧发动机部件磨损,还会增加整车油耗。为解决这一问题,设计了一种结合道路信息的混合动力汽车发动机起停触发系统(HEV-EST)。根据HEV发动机怠速和重起油耗图,确定HEV-EST起停条件;利用BP神经网络数字识别算法和颜色识别算法构建交通信号灯识别模型;运用统筹学的排队论对交通流进行分析计算,构建交通流分析模型;最后结合交通信号灯识别模型和交通流分析模型,设计了HEV-EST;并进行了MATLAB仿真验证。结果表明:该系统明显降低了车辆无效起停的次数,提高了整车燃油经济性。 展开更多
关键词 车辆工程 混合动力汽车 交通信号灯识别 交通流 发动机起停
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基于运营成本的城际铁路列车编组和停站方案综合优化研究
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作者 何红 《铁道运输与经济》 北大核心 2024年第3期36-42,共7页
针对城际铁路开通初期客流时空分布不均衡导致的单一列车编组模式造成运能浪费的问题,从列车运营成本出发,研究多种停站模式的大小编组列车开行方案。以列车运营成本最小化为目标函数,以大小编组列车的开行列数、列车停站方案为决策变量... 针对城际铁路开通初期客流时空分布不均衡导致的单一列车编组模式造成运能浪费的问题,从列车运营成本出发,研究多种停站模式的大小编组列车开行方案。以列车运营成本最小化为目标函数,以大小编组列车的开行列数、列车停站方案为决策变量,综合考虑列车区间断面满载率、OD服务频率等约束条件,构建大小编组列车开行方案模型;采用遗传算法求解,得到全日大小编组列车开行方案。以广清城际铁路和广州东环城际铁路为例,与现行列车开行方案相比,多停站模式的大小编组列车开行方案可使列车运营成本减少59%,日断面满载率平均值由0.288 8提高到0.866 5,说明采用多停站模式的大小编组列车开行方案能够有效降低列车运营成本,提高断面满载率。 展开更多
关键词 城际铁路 客流特征 停站方案 运营成本 大小编组
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