芳胺重氮盐对蚕丝偶合染色的构效关系研究

芳胺重氮盐对蚕丝织物的偶合染色因受限于发色体结构,难以获得深色系列染色织物。文章以染色蚕丝织物的K/S值曲线为衡量指标,分别采用具有供吸电性基团、大共轭体系或磺酸基团的芳胺重氮盐对蚕丝进行偶合染色,研究并揭示了芳胺结构的影响规律。结果表明,供电性基团的助色作用较弱,吸电性基团的助色效果更为显著;芳胺重氮盐的共轭体系越大,K/S值曲线越红移;含磺酸基的芳胺重氮盐也能够进行偶合染色,并实现了具有大共轭体系的芳伯胺染料重氮盐对蚕丝的偶合染色。各类芳胺重氮盐所染蚕丝织物的耐皂洗和耐摩擦色牢度均能达到4级以上。

羊毛偶合染色新方法的探讨

羊毛偶合反应染色新方法系使重氮化羊毛与色酚的偶合染色,或使预处理羊毛与重氮化色基的偶合染色。研究了羊毛预处理及偶合染色工艺对染色效果和物理机械性能的影响,指出该方法在染色成本和染色牢度方面具有的优势。

羊毛偶合染色新方法的探讨

本文探讨了羊毛偶合反应染色新方法，即重氮化羊毛与色酚的偶合染色以及预处理羊 毛与重氮化色基的偶合染色。研究了羊毛预处理及偶合染色工艺对染色效果和物理机械性能的影 响。指出该方法在染色成本和染色牢度方面具有显著优势。

羊毛染色新方法

本文探讨了羊毛偶合反应染色新方法,即重氮化羊毛与色酚的偶合染色以及预处理羊毛与重氮化色基的偶合染色。研究了羊毛预处理及偶合染色工艺对染色效果和物理机械性能的影响,指出该方法在降低染色成本和提高染色牢度方面具有显著优势。

Preparation and Characterization of Polyimide Attached with Azo-dye Chromophore Side Chain

In order to improve the nonlinear optical property and stability of azo-dye chromophore, the nonlinear optical polyimide (NLOPI) attached with azo chromophore side chain is synthesized by diazo coupling reaction of 4-nitrobenzenediazonium tetrafloroborate. The designed chemical structure of production can be proved in the infrared spectrum and ultraviolet-visible absorption spectrum. The NLOPI exhibited UV-Vis absorption of the azobenzene chromophore in the vicinity of the wavelengths of 330 and 490 nm. The broad amorphous peak proved that the NLOPI was amorphous with a little periodical structure along the side chain. According to transmission electron microscope, the NLOPI film was homogeneous. NLOPI only displayed a decrease in mass of about 5% at the temperature of 400 ℃ through thermogravimetric analysis.