Based on the magnetic interaction energy, using derivative of the magnetic energy density, a model is proposed to compute the magnetic-induced shear modulus of magnetorheological elastomers. Taking into account the in...Based on the magnetic interaction energy, using derivative of the magnetic energy density, a model is proposed to compute the magnetic-induced shear modulus of magnetorheological elastomers. Taking into account the influences of particles in the same chain and the particles in all adjacent chains, the traditional magnetic dipole model of the magnetorheological elastomers is modified. The influence of the ratio of the distance etween adjacent chains to the distance between adjacent particles in a chain on the magnetic induced shear odulus is quantitatively studied. When the ratio is large, the multi-chain model is compatible with the single chain model, but when the ratio is small, the difference of the two models is significant and can not be neglected. Making certain the size of the columns and the distance between adjacent columns, after constructing the computational model of BCT structures, the mechanical property of the magnetorheological elastomers composed of columnar structures is analyzed. Results show that, conventional point dipole model has overrated the magnetic-induced shear modulus of the magnetorheological elastomers. From the point of increasing the magnetic-induced shear modulus, when the particle volume fraction is small, the chain-like structure exhibits better result than the columnar structure, but when the particle volume fraction is large,the columnar structure will be better.展开更多
Home THX系统的技术要求 Home THX的主要目的在于将以Dolby技术录制、用THX标准重放的电影声音真实地在家用视听室中重现,让人们足不出户就可欣赏到身临其境的电影效果。THX家庭影院除对室内声学环境有一定要求外,对于整个THX音响系统...Home THX系统的技术要求 Home THX的主要目的在于将以Dolby技术录制、用THX标准重放的电影声音真实地在家用视听室中重现,让人们足不出户就可欣赏到身临其境的电影效果。THX家庭影院除对室内声学环境有一定要求外,对于整个THX音响系统也有如下要求: 1.展开更多
The anisotropy of a geologic formation can reflect the direction of fractures and ground stress, which is an important metric that guides the exploration and development of oil and gas reservoirs. Cross-dipole acousti...The anisotropy of a geologic formation can reflect the direction of fractures and ground stress, which is an important metric that guides the exploration and development of oil and gas reservoirs. Cross-dipole acoustic logging is the main method used to detect anisotropy with borehole geophysics. In this paper, a stepwise inversion method for three anisotropy parameters in a horizontal transversely isotropic(HTI) formation is proposed, which turns one 3D operation of simultaneous inversion into three 1D operations. The scheme’s stability and reliability were tested by numerically simulated data using a f inite-difference method, and by f ield logging data. The inversion results of the simulated data show that the stepwise inversion method can stably obtain the fast shear azimuth and the anisotropy parameters in both fast and slow formations with strong and weak anisotropy, and it performed well even with noisy data. In particular, the results of the fast shear azimuth inversion were very stable and reliable. The inversion results of f ield logging data were consistent with those given by existing commercial software, which used simultaneous inversion, for both fast and slow formations. Where large difference was observed between our stepwise method and the commercial software, our analysis suggests that the fast shear azimuth of our inversion was more reasonable, which reinforces its superior performance and practicality.展开更多
Umpolung reactions of C=X bonds(X=O,N)are valuable ways of constructing new C–C bonds,which are sometimes difficult to be constructed using traditional synthetic pathways.Classical polarity inversion of C=X bonds(X=O...Umpolung reactions of C=X bonds(X=O,N)are valuable ways of constructing new C–C bonds,which are sometimes difficult to be constructed using traditional synthetic pathways.Classical polarity inversion of C=X bonds(X=O,N)usually requires air or moisture‐sensitive and strong reducing agents,which limit the feasibility of substrate scope.Herein we describe a photo‐induced reductive cross‐coupling reaction of aldehydes,ketones and imines with electron‐deficient arenes(aromatic nitriles)using fac‐Ir(ppy)3as a photocatalyst and diisopropylethylamine(DIPEA)as a terminal reductant under visible light irradiation.Mild conditions and high yields mean that this new polarity inversion strategy can be used with aryl‐substituted alcohols and amines.Spectroscopic studies and control experiments have demonstrated the oxidative quenching of Ir(ppy)3*by electron‐deficient arenes involved in the key step for the C–C bond formation.展开更多
In this paper, a co-polarized, co-located electric and magnetic dipoles(CCEMD) with high isolation is presented. The antenna consists of a loop based on segmented line and two independent feeding ports. Two modes of t...In this paper, a co-polarized, co-located electric and magnetic dipoles(CCEMD) with high isolation is presented. The antenna consists of a loop based on segmented line and two independent feeding ports. Two modes of the antenna are exited separately, the first one has a radiation pattern equivalent to an electric dipole by exciting anti-phase current with symmetric distribution, and the second one is like a magnetic dipole by exciting uniform and in-phase currents along the loop. The antenna is fabricated and tested. Its measured common-10 d B impedance bandwidth at two ports is 280 MHz(2.32-2.6 GHz) with isolation better than 41 d B. Its MIMO performance in terms of capacity gain(CG) over the SISO system is investigated in a multipath rich environment containing two parallel PEC planes by both measurements and image theory based simulations. Results show that, in free space, the CG results are just slightly larger than 1, however, in the multipath rich channel, the CG values are very close to 2, which indicates that two separate subchannels can be achieved by the proposed CCEMD. The measured results of CG agree well with that obtained by simulation.展开更多
Magnetorheological elastomer (MRE) is a new kind of smart materials, the rheological properties can be controlled rapidly by the external magnetic field. It is mainly composed of rubber and micron-sized ferromagneti...Magnetorheological elastomer (MRE) is a new kind of smart materials, the rheological properties can be controlled rapidly by the external magnetic field. It is mainly composed of rubber and micron-sized ferromagnetic particles, which forms a chain-like structure. Therefore its mechanical, electric, and magnetic properties can be changed by the applied magnetic field, which is called as the magneto-induced effect. But this effect is not remarkable enough currently for the engineering application. So it is important for material preparation to optimize parameters to enhance the magneto-induced effect. In this work, based on chain-like model, some factors influencing the magneto-induced effect of MRE were analyzed theoretically by using dipole method with the normal distribution of chain's angle introduced. The factors included the oblique angle of particles chains, magnetic field intensity, and shear strain, etc. Some experiments were also carried out.展开更多
In this study, using the Geophysical Fluid Dynamics Laboratory Climate Model version 2pl (GFDL CM2pl) coupled model, the winter predictability barrier (WPB) is found to exist in the model not only in the growing p...In this study, using the Geophysical Fluid Dynamics Laboratory Climate Model version 2pl (GFDL CM2pl) coupled model, the winter predictability barrier (WPB) is found to exist in the model not only in the growing phase but also the Indian Ocean dipole (IOD) decaying phase of positive events due to the effect of initial errors. In particular, the WPB is stronger in the growing phase than in the decaying phase. These results indicate that initial errors can cause the WPB. The domi- nant patterns of the initial errors that cause the occurrence of the WPB often present an eastern-western dipole both in the surface and subsurface temperature components. These initial errors tend to concentrate in a few areas, and these areas may represent the sensitive areas of the predictions of positive IOD events. By increasing observations over these areas and eliminating initial errors here, the WPB phenomenon may be largely weakened and the forecast skill greatly improved.展开更多
A wideband dipole signal is required for dipole dispersion correction and nearborehole imaging. To obtain the broadband flexural wave dispersion, we use a nonlinear frequency modulation (NLFM) signal and propose a s...A wideband dipole signal is required for dipole dispersion correction and nearborehole imaging. To obtain the broadband flexural wave dispersion, we use a nonlinear frequency modulation (NLFM) signal and propose a segment linear frequency modulation (SLFM) signal as the dipole excitation signal to compensate for the excitation intensity. The signal-to-noise ratio (SNR) of the signal over the entire frequency band is increased. The finite-difference method is used to simulate the responses from a Ricker wavelet, a linear frequency modulation (LFM) signal, an NLFM signal, and an SLFM signal in two borehole models of a homogeneously hard formation and a radially stratified formation. The dispersion and radial tomography results at low SNR of the sound source signals are compared. Numerical modeling suggests that the energy of the flexural waves excited by the Ricker wavelet source is concentrated near the Airy phase. In this case, the dispersion is incomplete and information regarding the formation near or far from the borehole cannot be obtained. The LFM signal yields dispersion information near the Airy phase and the high-frequency range but not in the low-frequency range. Moreover, the information regarding the formation far from the borehole is not accurate. The NLFM signal extends the frequency range of the flexural waves by compensating for the excitation intensity and yields information regarding the formation information, but it is not easy to obtain. The SLFM signal yields the same results as the NLFM signal and is easier to implement. Consequently, the dipole detection range expands and the S-wave velocity calculation accuracy improves.展开更多
We theoretically investigate the response of nonlinear absorption and population dynamics in optically dense media of four-level atoms driven by a single-mode probe laser, via taking the density-dependent near dipoled...We theoretically investigate the response of nonlinear absorption and population dynamics in optically dense media of four-level atoms driven by a single-mode probe laser, via taking the density-dependent near dipoledipole (NDD) interactions into consideration. The influence of the NDD effects on the absorption of the probe field and population dynamics is predicted via numerical calculations. It is shown that the NDD effects can reduce gradually to transient absorption with the increase of the strengths of the NDD interactions, and transient amplification can be achieved. In the steady-state limit, the probe field exhibits transparency for strong NDD interactions. Alternatively, the population entirely remains at the ground state due to the NDD effects.展开更多
On the basis of Wilson's work in which the vertical electric dipole is centrally located in GHz Transverse ElectroMagnetic (GTEM) cell, we deduce the expression for the field distribution excited by an electric di...On the basis of Wilson's work in which the vertical electric dipole is centrally located in GHz Transverse ElectroMagnetic (GTEM) cell, we deduce the expression for the field distribution excited by an electric dipole in the case that the dipole is not centrally located. It will be useful for EMC measurements using GTEM cell.展开更多
For the first time, we derive the dispersion energy for a molecule which involves the anisotropic dipole interaction by virtue of the invariant eigen-operator method, which greatly simplifies the usual calculation if ...For the first time, we derive the dispersion energy for a molecule which involves the anisotropic dipole interaction by virtue of the invariant eigen-operator method, which greatly simplifies the usual calculation if one uses the Schroedinger equation.展开更多
We study the one-loop contribution of the effective flavor changing neutral couplings (FCNC) tcZ on the charm quark electric dipole moment. Using the known limits on the top and charm quarks electric dipole moments,...We study the one-loop contribution of the effective flavor changing neutral couplings (FCNC) tcZ on the charm quark electric dipole moment. Using the known limits on the top and charm quarks electric dipole moments, we place limits on these FCNC anomalous couplings.展开更多
The mechanism and regioselectivity of 1,3-dipolar cycloaddition of N-[methyl]-C-[5-nitro-2-furyl] nitrilimine with dimethyl 7-oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylate were investigated using activation energ...The mechanism and regioselectivity of 1,3-dipolar cycloaddition of N-[methyl]-C-[5-nitro-2-furyl] nitrilimine with dimethyl 7-oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylate were investigated using activation energy calculations and density functional theory-based reactivity indexes. The reaction proceeds by an asynchronous concerted mechanism. The calculations are performed at the B3LYP/6-31G(d) level of theory and the obtained results are in agreement with experimental outcome.展开更多
Taking the density-dependent near dipole-dipole (NDD) interaction into consideration, we theoretically investigate the response of nonlinear absorption and dispersion in optically dense media of three-level atoms dr...Taking the density-dependent near dipole-dipole (NDD) interaction into consideration, we theoretically investigate the response of nonlinear absorption and dispersion in optically dense media of three-level atoms driven by a single-mode probe laser. The influence of the NDD effects on the absorption and dispersion spectra of the probe field is predicted via numerical calculations. It is shown that the NDD effects reduce gradually to transient absorption and amplification with the increase of the strengths of the NDD interaction, but do not change the steady-state behavior. Due to the presence of the NDD effects, steady-state absorption spectra exhibit asymmetric double-peak structure and overall shifts when a continuous-wave (cw) probe field is applied. However, frequency dispersion spectra are insensitive to them near the zero detuning.展开更多
In this paper the anomalous magnetic dipole moment ofmuon in the littlest Higgs (LH) model is studied at one-loop level. We discuss the dependence of the contributions on the global symmetry breaking scale f, mizing...In this paper the anomalous magnetic dipole moment ofmuon in the littlest Higgs (LH) model is studied at one-loop level. We discuss the dependence of the contributions on the global symmetry breaking scale f, mizing angles c` and , and the Higgs triplet vacuum expectation value v' in the electroweak precision data preferring ranges. We find that the LH model can give a relatively small, but non-negligible extra weak contribution to the muon anomalous magnetic moment and can reduce the deviation of △aμ from 2.6σ for the SM to 2.5σ for the LH model.展开更多
Within the framework of the U<SUB>sdpf</SUB>(16) interacting boson model (IBM), the effects of strong correlations of the dipole (p<SUP>?</SUP>-boson) and the octupole (f<SUP>?</SUP>...Within the framework of the U<SUB>sdpf</SUB>(16) interacting boson model (IBM), the effects of strong correlations of the dipole (p<SUP>?</SUP>-boson) and the octupole (f<SUP>?</SUP>-boson) degree of freedom on the positive-parity states of even-even nuclei in SU(3) limit are discussed. It is shown that configurations of an even number of many p- and f-bosons can not only be incorporated into the usual low-lying collective rotational bands, such as the ground state band, β- and γ-vibrational bands, but also naturally form the rotational bands, etc. These results are similar to that of U<SUB>sdg</SUB>(15)-IBM and in good agreement with the experimental data of the nucleus. Besides, several intraband E2 transition probabilities are given, which are consistent with that of U<SUB>sd</SUB>(6)-IBM.展开更多
Enantiomer separation is one of the most important prerequisites for the investigation of environmental enantioselective behavior for chiral pesticides.The enantiomeric separation of three chiral pesticides,indoxacarb...Enantiomer separation is one of the most important prerequisites for the investigation of environmental enantioselective behavior for chiral pesticides.The enantiomeric separation of three chiral pesticides,indoxacarb,lambda-cyhalothrin,and simeconazole,were studied on cellulose tris-(3,5-dimethylphenyl-carbamate)-coated chiral stationary phase(CDMPC-CSP) using high-performance liquid chromatography under normal phase condition.The effects of chromatographic conditions,such as the mobile phase composition including the concentration and type of alcohol modifiers in hexane,flow rate and column temperature,on enantiomer separation were examined.The thermodynamical mechanism of enantioseparation and chiral recognition mechanism were discussed.Better separation were achieved using 20% n-propanol for indoxacarb,2% iso-butanol for lambda-cyhalothrin,and 20% iso-propanol for simeconazole as modifiers in hexane at 25℃ with the selectivity factor(a) of 1.69,1.82 and 1.70,respectively.The resolution factor(Rs) decreased as the flow rate increased from 0.4 to 1.1 ml·min-1.The retention factor(k') and selectivity factor for the enantiomers of analytes decreased as temperature increased.The lna-1/T plots for racemic chiral pesticides were linear in the range of 15-35℃ in hexane/iso-propanol and the chiral separation was controlled by enthalpy.Hydrogen bonding,π-π and dipole-dipole interactions between enantiomers and CDMPC-CSP play an important role in chiral identification,and the fitting of the asymmetric portion of solutes in a chiral cavity or channel of the CSP is also important.展开更多
We have investigated the magnetism of one-dimensional dipolar-interaction spin chains with perpendicular anisotropy by simulation. The behaviors of the magnetizations and the orientation correlations change dramatical...We have investigated the magnetism of one-dimensional dipolar-interaction spin chains with perpendicular anisotropy by simulation. The behaviors of the magnetizations and the orientation correlations change dramatically as the anisotropy increases to the critical value. The domain length can be controlled by adjusting the temperature and the external field as well as the anisotropy. These properties are interesting and arise from the competition between the anisotropy and the interaction along the chain.展开更多
文摘Based on the magnetic interaction energy, using derivative of the magnetic energy density, a model is proposed to compute the magnetic-induced shear modulus of magnetorheological elastomers. Taking into account the influences of particles in the same chain and the particles in all adjacent chains, the traditional magnetic dipole model of the magnetorheological elastomers is modified. The influence of the ratio of the distance etween adjacent chains to the distance between adjacent particles in a chain on the magnetic induced shear odulus is quantitatively studied. When the ratio is large, the multi-chain model is compatible with the single chain model, but when the ratio is small, the difference of the two models is significant and can not be neglected. Making certain the size of the columns and the distance between adjacent columns, after constructing the computational model of BCT structures, the mechanical property of the magnetorheological elastomers composed of columnar structures is analyzed. Results show that, conventional point dipole model has overrated the magnetic-induced shear modulus of the magnetorheological elastomers. From the point of increasing the magnetic-induced shear modulus, when the particle volume fraction is small, the chain-like structure exhibits better result than the columnar structure, but when the particle volume fraction is large,the columnar structure will be better.
基金supported by the National Natural Science Foundation of China(Grant Nos.11574347,11774373,11734017 and 91630309)the Petro China Innovation Foundation(No.2016D-5007-0304)
文摘The anisotropy of a geologic formation can reflect the direction of fractures and ground stress, which is an important metric that guides the exploration and development of oil and gas reservoirs. Cross-dipole acoustic logging is the main method used to detect anisotropy with borehole geophysics. In this paper, a stepwise inversion method for three anisotropy parameters in a horizontal transversely isotropic(HTI) formation is proposed, which turns one 3D operation of simultaneous inversion into three 1D operations. The scheme’s stability and reliability were tested by numerically simulated data using a f inite-difference method, and by f ield logging data. The inversion results of the simulated data show that the stepwise inversion method can stably obtain the fast shear azimuth and the anisotropy parameters in both fast and slow formations with strong and weak anisotropy, and it performed well even with noisy data. In particular, the results of the fast shear azimuth inversion were very stable and reliable. The inversion results of f ield logging data were consistent with those given by existing commercial software, which used simultaneous inversion, for both fast and slow formations. Where large difference was observed between our stepwise method and the commercial software, our analysis suggests that the fast shear azimuth of our inversion was more reasonable, which reinforces its superior performance and practicality.
文摘Umpolung reactions of C=X bonds(X=O,N)are valuable ways of constructing new C–C bonds,which are sometimes difficult to be constructed using traditional synthetic pathways.Classical polarity inversion of C=X bonds(X=O,N)usually requires air or moisture‐sensitive and strong reducing agents,which limit the feasibility of substrate scope.Herein we describe a photo‐induced reductive cross‐coupling reaction of aldehydes,ketones and imines with electron‐deficient arenes(aromatic nitriles)using fac‐Ir(ppy)3as a photocatalyst and diisopropylethylamine(DIPEA)as a terminal reductant under visible light irradiation.Mild conditions and high yields mean that this new polarity inversion strategy can be used with aryl‐substituted alcohols and amines.Spectroscopic studies and control experiments have demonstrated the oxidative quenching of Ir(ppy)3*by electron‐deficient arenes involved in the key step for the C–C bond formation.
基金supported by the National Natural Science Foundations of China (61771435)
文摘In this paper, a co-polarized, co-located electric and magnetic dipoles(CCEMD) with high isolation is presented. The antenna consists of a loop based on segmented line and two independent feeding ports. Two modes of the antenna are exited separately, the first one has a radiation pattern equivalent to an electric dipole by exciting anti-phase current with symmetric distribution, and the second one is like a magnetic dipole by exciting uniform and in-phase currents along the loop. The antenna is fabricated and tested. Its measured common-10 d B impedance bandwidth at two ports is 280 MHz(2.32-2.6 GHz) with isolation better than 41 d B. Its MIMO performance in terms of capacity gain(CG) over the SISO system is investigated in a multipath rich environment containing two parallel PEC planes by both measurements and image theory based simulations. Results show that, in free space, the CG results are just slightly larger than 1, however, in the multipath rich channel, the CG values are very close to 2, which indicates that two separate subchannels can be achieved by the proposed CCEMD. The measured results of CG agree well with that obtained by simulation.
基金This work was supported by the National Natural Science Foundation of China (No.50830202 and No.60804018) and the Plan of the Excellent Talent for the New Century (NCET-07-0910). The authors also appreciate the help in the experimental instruments of Professor Xing-long Gong of University of Science and Technology of China deeply.
文摘Magnetorheological elastomer (MRE) is a new kind of smart materials, the rheological properties can be controlled rapidly by the external magnetic field. It is mainly composed of rubber and micron-sized ferromagnetic particles, which forms a chain-like structure. Therefore its mechanical, electric, and magnetic properties can be changed by the applied magnetic field, which is called as the magneto-induced effect. But this effect is not remarkable enough currently for the engineering application. So it is important for material preparation to optimize parameters to enhance the magneto-induced effect. In this work, based on chain-like model, some factors influencing the magneto-induced effect of MRE were analyzed theoretically by using dipole method with the normal distribution of chain's angle introduced. The factors included the oblique angle of particles chains, magnetic field intensity, and shear strain, etc. Some experiments were also carried out.
基金sponsored by the National Basic Research Program of China (Grant No. 2012CB955202)the National Public Benefit (Meteorology) Research Foundation of China (Grant No. GYHY201306018)
文摘In this study, using the Geophysical Fluid Dynamics Laboratory Climate Model version 2pl (GFDL CM2pl) coupled model, the winter predictability barrier (WPB) is found to exist in the model not only in the growing phase but also the Indian Ocean dipole (IOD) decaying phase of positive events due to the effect of initial errors. In particular, the WPB is stronger in the growing phase than in the decaying phase. These results indicate that initial errors can cause the WPB. The domi- nant patterns of the initial errors that cause the occurrence of the WPB often present an eastern-western dipole both in the surface and subsurface temperature components. These initial errors tend to concentrate in a few areas, and these areas may represent the sensitive areas of the predictions of positive IOD events. By increasing observations over these areas and eliminating initial errors here, the WPB phenomenon may be largely weakened and the forecast skill greatly improved.
基金This work was supported by the National Natural Science Foundation of China (Nos. 11574347, 11734017, 91630308, and 11374322), the Youth Talent Project of the Institute of Acoustics of Chinese Academy of Sciences (No. QNYC201619), and the PetroChina Innovation Foundation (No. 2016D-5007-0304).
文摘A wideband dipole signal is required for dipole dispersion correction and nearborehole imaging. To obtain the broadband flexural wave dispersion, we use a nonlinear frequency modulation (NLFM) signal and propose a segment linear frequency modulation (SLFM) signal as the dipole excitation signal to compensate for the excitation intensity. The signal-to-noise ratio (SNR) of the signal over the entire frequency band is increased. The finite-difference method is used to simulate the responses from a Ricker wavelet, a linear frequency modulation (LFM) signal, an NLFM signal, and an SLFM signal in two borehole models of a homogeneously hard formation and a radially stratified formation. The dispersion and radial tomography results at low SNR of the sound source signals are compared. Numerical modeling suggests that the energy of the flexural waves excited by the Ricker wavelet source is concentrated near the Airy phase. In this case, the dispersion is incomplete and information regarding the formation near or far from the borehole cannot be obtained. The LFM signal yields dispersion information near the Airy phase and the high-frequency range but not in the low-frequency range. Moreover, the information regarding the formation far from the borehole is not accurate. The NLFM signal extends the frequency range of the flexural waves by compensating for the excitation intensity and yields information regarding the formation information, but it is not easy to obtain. The SLFM signal yields the same results as the NLFM signal and is easier to implement. Consequently, the dipole detection range expands and the S-wave velocity calculation accuracy improves.
基金The project supported in part by National Natural Science Foundation of China under Grant Nos. 60478029 and 10575040The authors would like to thank Dr, Ying Wu for helpful discussions.
文摘We theoretically investigate the response of nonlinear absorption and population dynamics in optically dense media of four-level atoms driven by a single-mode probe laser, via taking the density-dependent near dipoledipole (NDD) interactions into consideration. The influence of the NDD effects on the absorption of the probe field and population dynamics is predicted via numerical calculations. It is shown that the NDD effects can reduce gradually to transient absorption with the increase of the strengths of the NDD interactions, and transient amplification can be achieved. In the steady-state limit, the probe field exhibits transparency for strong NDD interactions. Alternatively, the population entirely remains at the ground state due to the NDD effects.
基金Supported by the Innovation Project of Chinese Academy of Sciences
文摘On the basis of Wilson's work in which the vertical electric dipole is centrally located in GHz Transverse ElectroMagnetic (GTEM) cell, we deduce the expression for the field distribution excited by an electric dipole in the case that the dipole is not centrally located. It will be useful for EMC measurements using GTEM cell.
基金The project supported by the President Foundation of the Chinese Academy of Sciences and National Natural Science Foundation of China under Grant No. 10475056.
文摘For the first time, we derive the dispersion energy for a molecule which involves the anisotropic dipole interaction by virtue of the invariant eigen-operator method, which greatly simplifies the usual calculation if one uses the Schroedinger equation.
文摘We study the one-loop contribution of the effective flavor changing neutral couplings (FCNC) tcZ on the charm quark electric dipole moment. Using the known limits on the top and charm quarks electric dipole moments, we place limits on these FCNC anomalous couplings.
文摘The mechanism and regioselectivity of 1,3-dipolar cycloaddition of N-[methyl]-C-[5-nitro-2-furyl] nitrilimine with dimethyl 7-oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylate were investigated using activation energy calculations and density functional theory-based reactivity indexes. The reaction proceeds by an asynchronous concerted mechanism. The calculations are performed at the B3LYP/6-31G(d) level of theory and the obtained results are in agreement with experimental outcome.
基金The projects supported in part by National Natural Science Foundation of China under Grant Nos. 10575040 and 90503010
文摘Taking the density-dependent near dipole-dipole (NDD) interaction into consideration, we theoretically investigate the response of nonlinear absorption and dispersion in optically dense media of three-level atoms driven by a single-mode probe laser. The influence of the NDD effects on the absorption and dispersion spectra of the probe field is predicted via numerical calculations. It is shown that the NDD effects reduce gradually to transient absorption and amplification with the increase of the strengths of the NDD interaction, but do not change the steady-state behavior. Due to the presence of the NDD effects, steady-state absorption spectra exhibit asymmetric double-peak structure and overall shifts when a continuous-wave (cw) probe field is applied. However, frequency dispersion spectra are insensitive to them near the zero detuning.
基金The project supported in part by National Natural Science Foundation of China and Special Fund sponsored by the Chinese Academy of Sciences
文摘In this paper the anomalous magnetic dipole moment ofmuon in the littlest Higgs (LH) model is studied at one-loop level. We discuss the dependence of the contributions on the global symmetry breaking scale f, mizing angles c` and , and the Higgs triplet vacuum expectation value v' in the electroweak precision data preferring ranges. We find that the LH model can give a relatively small, but non-negligible extra weak contribution to the muon anomalous magnetic moment and can reduce the deviation of △aμ from 2.6σ for the SM to 2.5σ for the LH model.
文摘Within the framework of the U<SUB>sdpf</SUB>(16) interacting boson model (IBM), the effects of strong correlations of the dipole (p<SUP>?</SUP>-boson) and the octupole (f<SUP>?</SUP>-boson) degree of freedom on the positive-parity states of even-even nuclei in SU(3) limit are discussed. It is shown that configurations of an even number of many p- and f-bosons can not only be incorporated into the usual low-lying collective rotational bands, such as the ground state band, β- and γ-vibrational bands, but also naturally form the rotational bands, etc. These results are similar to that of U<SUB>sdg</SUB>(15)-IBM and in good agreement with the experimental data of the nucleus. Besides, several intraband E2 transition probabilities are given, which are consistent with that of U<SUB>sd</SUB>(6)-IBM.
基金Supported by China Postdoctoral Science Fund (20090461007)Postdoctoral Research Funding Special Plans of Hunan(2010RC4025)Graduate Innovation Research Project of Hunan (CX2010B295)
文摘Enantiomer separation is one of the most important prerequisites for the investigation of environmental enantioselective behavior for chiral pesticides.The enantiomeric separation of three chiral pesticides,indoxacarb,lambda-cyhalothrin,and simeconazole,were studied on cellulose tris-(3,5-dimethylphenyl-carbamate)-coated chiral stationary phase(CDMPC-CSP) using high-performance liquid chromatography under normal phase condition.The effects of chromatographic conditions,such as the mobile phase composition including the concentration and type of alcohol modifiers in hexane,flow rate and column temperature,on enantiomer separation were examined.The thermodynamical mechanism of enantioseparation and chiral recognition mechanism were discussed.Better separation were achieved using 20% n-propanol for indoxacarb,2% iso-butanol for lambda-cyhalothrin,and 20% iso-propanol for simeconazole as modifiers in hexane at 25℃ with the selectivity factor(a) of 1.69,1.82 and 1.70,respectively.The resolution factor(Rs) decreased as the flow rate increased from 0.4 to 1.1 ml·min-1.The retention factor(k') and selectivity factor for the enantiomers of analytes decreased as temperature increased.The lna-1/T plots for racemic chiral pesticides were linear in the range of 15-35℃ in hexane/iso-propanol and the chiral separation was controlled by enthalpy.Hydrogen bonding,π-π and dipole-dipole interactions between enantiomers and CDMPC-CSP play an important role in chiral identification,and the fitting of the asymmetric portion of solutes in a chiral cavity or channel of the CSP is also important.
基金Supported by the Doctorial Start-up Fund of Bohai University under Grant No.KYC-BSQD200901
文摘We have investigated the magnetism of one-dimensional dipolar-interaction spin chains with perpendicular anisotropy by simulation. The behaviors of the magnetizations and the orientation correlations change dramatically as the anisotropy increases to the critical value. The domain length can be controlled by adjusting the temperature and the external field as well as the anisotropy. These properties are interesting and arise from the competition between the anisotropy and the interaction along the chain.