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天主圣三的奥理
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作者 李升 《中国天主教》 2016年第3期28-29,共2页
天主圣三,或天主三位一体的奥理,是天主的启示,是天主内在生活的启示。信奉基督圣教的教徒皆信天主有一性一体,这"性"是为三位所占有,即父、子、圣神三位。圣父即旧约所称的雅威,圣子即"圣言",即降生成人的耶稣基督,圣神为父及子所... 天主圣三,或天主三位一体的奥理,是天主的启示,是天主内在生活的启示。信奉基督圣教的教徒皆信天主有一性一体,这"性"是为三位所占有,即父、子、圣神三位。圣父即旧约所称的雅威,圣子即"圣言",即降生成人的耶稣基督,圣神为父及子所共发的神,即父、子共发的爱火。三者虽殊其位,但在本性上为一,是一个天主。有人说,天主圣三的奥理在旧约中只是准备,到新约才趋于明显。 展开更多
关键词 耶稣基督 圣教 雅威 一性 宗徒 天主圣父 新约圣经 天主圣子 傅油 子所
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基督徒的使命
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作者 夜莺 《中国天主教》 2015年第6期9-9,共1页
感谢天主赏赐我们每天的新生命,这份赏赐并非只为让我们"活下去",而是为让我们能够活得更加丰富而且更加属神。保禄宗徒告诉我们:我们有罪的肉身,是藉着基督的降生以及救赎而获得拯救的。在我们救主降生、救赎的整个过程中,... 感谢天主赏赐我们每天的新生命,这份赏赐并非只为让我们"活下去",而是为让我们能够活得更加丰富而且更加属神。保禄宗徒告诉我们:我们有罪的肉身,是藉着基督的降生以及救赎而获得拯救的。在我们救主降生、救赎的整个过程中,他用旧约中被主傅油的三种特殊身份来展示他的特殊使命,那即是:君王、司祭和先知。要想理解我们作为基督徒该当如何履行此三重职务,我们首先从基督身上来看。 展开更多
关键词 宗徒 保禄 活下去 救主 新生命 傅油 三重 耶稣基督 传中
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教友如何对待本国的丧葬和祭礼习俗
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作者 褚汉雨 《中国天主教》 1994年第3期37-38,共2页
中华民族视“尊敬长上”、“孝敬父母”为美德。它是一种本性的、自然的好行为,更由于儒家的推崇和宣扬,造成了一种经久不衰而遍及全国崇尚的风气,历代的君王也以此作为治理天下之本。 中国的孝道和天主教会的“孝敬父母”的诫命有相同... 中华民族视“尊敬长上”、“孝敬父母”为美德。它是一种本性的、自然的好行为,更由于儒家的推崇和宣扬,造成了一种经久不衰而遍及全国崇尚的风气,历代的君王也以此作为治理天下之本。 中国的孝道和天主教会的“孝敬父母”的诫命有相同之处。它包括对父母应有的一切责任义务:知恩、尊敬、服从、赡养、丧葬和祭祀; 展开更多
关键词 孝敬父母 天下之本 责任义务 傅油 教外 上主 古经 放鞭炮 敬拜 守斋
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第七期教区管理研讨班在京举办
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《中国天主教》 2015年第5期5 65-5,65,共2页
8月31日至9月4日,中国天主教第七期教区管理研讨班在"一会一团"举行,来自20多个教区的主教、教区负责人及"一会一团"的神父30人参加。本次研讨班"一会一团"特别邀请了澳大利亚圣神修院院长安多尼蒙席、... 8月31日至9月4日,中国天主教第七期教区管理研讨班在"一会一团"举行,来自20多个教区的主教、教区负责人及"一会一团"的神父30人参加。本次研讨班"一会一团"特别邀请了澳大利亚圣神修院院长安多尼蒙席、美国天主教华盛顿大学神学家尼各老神父、澳大利亚的肖恩教友和美国的亨利教友,与大家分享交流。31日上午研讨班在天主经的祈祷声中开幕。 展开更多
关键词 七期 中国天主教 天主经 圣神修院 美国天主教 安多 英林 日至 肖恩 傅油
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神父请告诉我,你究竟是谁
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作者 姜晓满 《中国天主教》 2016年第1期39-40,共2页
有一次,我到某个堂口做弥撒,有一个八九岁的小男孩来到我跟前并对我说:"神父请告诉我,你是谁?"我对那个小男孩说:"神父是基督第二,耶稣在世的代表。"有时默想,我也不断地问自己,我究竟是谁?
关键词 耶稣基督 对我说 告诉我 祝圣 傅油 这个世界 圣秩圣事 耶稣圣心 效法基督 保禄
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人,走向何方
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作者 崔鸿涛 《中国天主教》 2015年第1期16-18,共3页
在茫茫的人海中,人很可能在压力、挫折、徘徊、失落、欲望、情感等的困扰之下,前途迷茫而迷失人生的方向,人因而产生悲观,但与此同时人的心灵深处却发出追问:人,你将走向何方?那是人没有获悉至丰富的爱(若一4:8)没有寻觅到爱的化身——... 在茫茫的人海中,人很可能在压力、挫折、徘徊、失落、欲望、情感等的困扰之下,前途迷茫而迷失人生的方向,人因而产生悲观,但与此同时人的心灵深处却发出追问:人,你将走向何方?那是人没有获悉至丰富的爱(若一4:8)没有寻觅到爱的化身——耶稣。在古往今来的人生经历中,隐隐约约会发现藏在人生命中的秘密。当第一个男性亚当、女性厄娃偷吃禁果以后,被逐出了幸福之乡伊甸园,(创3:20-24)人,面临着严峻的问题:将走向何方? 展开更多
关键词 厄娃 主耶稣 心灵深处 中国天主教 傅油 上主 祝圣 刺青 满溢 立德
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广东省各地天主教会隆重庆祝重阳节
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《中国天主教》 2019年第5期31-31,共1页
农历九月初九重阳节是中华民族传统的敬老节,尊老敬老是中华民族的优良传统,也是天主教会的优良传统。在中国传统节日重阳节到来之际,广东各地天主教会纷纷举行庆祝活动。汕头教区主教座堂于10月6日(农历九月初八)举办第32届敬老节。黄... 农历九月初九重阳节是中华民族传统的敬老节,尊老敬老是中华民族的优良传统,也是天主教会的优良传统。在中国传统节日重阳节到来之际,广东各地天主教会纷纷举行庆祝活动。汕头教区主教座堂于10月6日(农历九月初八)举办第32届敬老节。黄炳章主教主持感恩弥撒,六百多位教友参加了感恩祭,弥撒中特别为近两百位70岁以上的长者施行傅油礼。 展开更多
关键词 天主教会 主教座堂 重阳节 傅油 中国传统节日 敬老节 庆祝活动 尊老敬老
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Properties of Bio-oil from Fast Pyrolysis of Rice Husk 被引量:14
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作者 郭秀娟 王树荣 +2 位作者 王琦 郭祚刚 骆仲泱 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第1期116-121,共6页
Physicochemical properties of bio-oil obtained from fast pyrolysis of rice husk were studied in the present work.Molecular distillation was used to separate the crude bio-oil into three fractions viz.light fraction,mi... Physicochemical properties of bio-oil obtained from fast pyrolysis of rice husk were studied in the present work.Molecular distillation was used to separate the crude bio-oil into three fractions viz.light fraction,middle fraction and heavy fraction.Their chemical composition was analyzed by gas chromatograph and mass spectrometer(GC-MS).The thermal behavior,including evaporation and decomposition,was investigated using thermogravimetric analyzer coupled with Fourier transform infrared spectrometer(TG-FTIR).The product distribution was significantly affected by contents of cellulose,hemicellulose and lignin.The bio-oil yield was 46.36%(by mass) and the yield of gaseous products was 27%(by mass).The chemicals in the bio-oil included acids,aldehydes,ketones,alcohols,phenols,sugars,etc.The light fraction was mainly composed of acids and compounds with lower boiling point temperature,the middle and heavy fractions were consisted of phenols and levoglucosan.The thermal stability of the bio-oil was determined by the interactions and intersolubility of compounds.It was found that the thermal stability of bio-oil was better than the light fraction,but worse than the middle and heavy fractions. 展开更多
关键词 biochemical engineering BIO-OIL fast pyrolysis DECOMPOSITION DISTILLATION
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Solvent Recovery from Soybean Oil/Hexane Miscella by PDMS Composite Membrane 被引量:11
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作者 CAI Weibin SUN Yanzhi PIAO Xianglan LI Jiding ZHU Shenlin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第4期575-580,共6页
Traditional solvent recovery in the extraction step of edible oil processing is distillation,which consumes large amounts of energy.If the distillation is replaced by membrane process,the energy consumption can be red... Traditional solvent recovery in the extraction step of edible oil processing is distillation,which consumes large amounts of energy.If the distillation is replaced by membrane process,the energy consumption can be reduced greatly.In this work,two kinds of membrane,PDMS(polydimethylsiloxane) composite membrane and Zeolite filled PDMS membrane were prepared,in which asymmetric microporous PVDF(polyvinylidenefluoride) membrane prepared with phase inversion method was functioned as the microporous supporting layer in the flat-plate composite membrane.The different function compositions of the PDMS/PVDF composite membranes were characterized by reflection Fourier transform infrared(FTIR) spectroscopy.The surface and section of PDMS/PVDF composite membranes were investigated by scanning electron microscope(SEM).The PDMS NF(nanofiltration) membranes were then applied in the recovery of hexane from soybean oil/hexane miscellas(1:3,mass ratio).The effects of pressure(0.5-1.5 MPa),cross-linking temperature and PDMS layer thickness on membrane performances were investigated.The results indicated that both two kinds of NF membranes were promising for solvent recovery,and zeolite filled in PDMS NF membrane could enhance the separation performance. 展开更多
关键词 PDMS composite membrane miscella ZEOLITE solvent recovery
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Green synthesis of nickel nanoparticles using Ocimum sanctum and their application in dye and pollutant adsorption 被引量:3
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作者 Chitra Jeyaraj Pandian Rameshthangam Palanivel Solairaj Dhananasekaran 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第8期1307-1315,共9页
Nickel nanoparticles as an eco-friendly adsorbent was biosynthesized using Ocimum sanctum leaf extract. The physiochemical properties of green synthesized nickel nanoparticles(Ni Gs) were characterized by UV–Vis spec... Nickel nanoparticles as an eco-friendly adsorbent was biosynthesized using Ocimum sanctum leaf extract. The physiochemical properties of green synthesized nickel nanoparticles(Ni Gs) were characterized by UV–Vis spectroscopy(UV–Vis), Fourier Transform Infrared Spectroscopy(FTIR), X-ray diffraction(XRD), Scanning Electron Microscope(SEM) and Transmission Electron Microscope(TEM). Ni Gs were used as adsorbent for the removal of dyes such as crystal violet(CV), eosin Y(EY), orange II(OR) and anionic pollutant nitrate(NO3-), sulfate(SO42-) from aqueous solution. Adsorption capacity of Ni Gs was examined in batch modes at different p H, contact time, Ni G dosage, initial dye and pollutant concentration. The adsorption process was p H dependent and the adsorption capacity increased with increase in contact time and with that of Ni G dosage, whereas the adsorption capacity decreased at higher concentrations of dyes and pollutants. Maximum percentage removal of dyes and pollutants were observed at 40, 20,30, 10 and 10 mg·L-1initial concentration of CV, EY, OR, NO3-and SO42-respectively. The maximum adsorption capacities in Langmuir isotherm were found to be 0.454, 0.615, 0.273, 0.795 and 0.645 mg·g-1at p H 8, 3, 3, 7and 7 for CV, EY, OR, NO3-and SO42-respectively. The higher coef ficients of correlation in Langmuir isotherm suggested monolayer adsorption. The mean energies(E), 2.23, 3.53, 2.50, 5.00 and 3.16 k J·mol-1for CV, EY, OR, NO3-and SO42-respectively, calculated from the Dubinin–Radushkevich isotherm showed physical adsorption of adsorbate onto Ni Gs. Adsorption kinetics data was better fitted to pseudo-second-order kinetics with R2 N 0.870 for all dyes and pollutants. Ni Gs were found to be an effective adsorbent for the removal of dyes and pollutants from aqueous solution and can be applied to treat textile and tannery ef fluents. 展开更多
关键词 Ocimum sanctum Nickel nanoparticles Adsorption Adsorbents Dyes Pollutants
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Desulfurization of Petroleum Coke by Calcination in Ammonia Atmosphere below 1000℃ 被引量:2
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作者 Zhong Qifan Xiao Jin +2 位作者 Huang Jindi Yuan Jie Yu Bailie 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2016年第4期41-50,共10页
The desulfurization efficiency and mechanism of the calcination of petroleum coke in ammonia atmosphere at lower than 1000 ℃ were investigated through a series of conditional experiments and comparison with other gas... The desulfurization efficiency and mechanism of the calcination of petroleum coke in ammonia atmosphere at lower than 1000 ℃ were investigated through a series of conditional experiments and comparison with other gases such as H_2. The topics of efficiency and reaction mechanism are usually discussed through investigation by means of the Fourier transform infrared spectroscopy(FT-IR), the Brunauer-Emmett-Teller(BET) technique, and the thermogravimetry coupled with the mass spectrometry(TG-MS). Results showed that in addition to H_2, ammonia not only could retain a high desulfurization rate but could also reduce coke loss during the desulfurization process of petroleum coke. The best desulfurization conditions covered a petroleum coke particle size of less than 0.1 mm, a calcination temperature of 800 ℃ in ammonia atmosphere with a flow rate of 10 L/h, and a heating duration of more than 120 min. Ammonia decomposition, H_2 generation, decline in the activation energy of the carbon–sulfur bonds, and petroleum coke with a largest specific surface area at 800 ℃ are the key goals of desulfurization studied thereby. As proved by TG-MS analysis, given a large quantity of H_2, ammonia can be decomposed at the same temperature to completely come into contact with the sulfur species in petroleum coke to generate H_2S. 展开更多
关键词 desulfurization petroleum coke ammonia calcination TG-MS
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Corn cob modified by lauric acid and ethanediol for emulsified oil adsorption
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作者 季振 林海 +2 位作者 陈月芳 董颖博 Muhammad Imran 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第6期2096-2105,共10页
Corn cob is a naturally renewable material with developed micropore and hydrophobic characteristics, which enables it to show good oil adsorption capacity. In order to improve oil adsorption capacity, corn cob was mod... Corn cob is a naturally renewable material with developed micropore and hydrophobic characteristics, which enables it to show good oil adsorption capacity. In order to improve oil adsorption capacity, corn cob was modified with lauric acid and ethanediol. The structure of raw and modified corn cob was investigated using Fourier transform infrared(FTIR) spectroscopy, scanning electron microscopy(SEM), Brunauer-Emmett-Teller(BET) method, thermogravimetric analysis(TGA) and Ze Ta potential analyzer. The effects of p H level, adsorption time, adsorbent dosage, and initial oil concentration on oil absorbency of corn cob were studied. The results indicate that the modification significantly improved the lipophilicity of corn cob, making the modified corn cob with much better adsorption capacity on oil absorbency. Compared with raw corn cob, the maximum saturated adsorption capacity of modified corn cob is 16.52 mg/g at p H 5, and the increasing percentage is found to be 141%, which indicates that the modification causes a better adsorption capacity for oil removal. In addition, due to high oil adsorption capacity, affordable price and low secondary pollution, the modified corn cob could be considered promising alternative for the traditional oil adsorbent to clean up the emulsified oily water. 展开更多
关键词 emulsified oil corn cob lauric acid ethanediol LIPOPHILICITY
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Characterization of Rapeseed Oil Using FTIR-ATR Spectroscopy
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作者 Lu Yuzhen Du Changwen Shao Yanqiu Zhou Jianmin 《Journal of Food Science and Engineering》 2014年第5期244-249,共6页
Fourier transform infrared attenuated total reflectance (FTIR-ATR) spectroscopy was employed to characterize rapeseed oils. The spectral features of rapeseed oils were first investigated. Spectral data was processed... Fourier transform infrared attenuated total reflectance (FTIR-ATR) spectroscopy was employed to characterize rapeseed oils. The spectral features of rapeseed oils were first investigated. Spectral data was processed using principal component analysis (PCA) and linear discriminant analysis (LDA) to discriminate the oils from three cultivars of rapeseeds. As a result, 100% discrimination accuracy was obtained by LDA. Furthermore, the applicability of FTIR-ATR spectroscopy to characterize the changes of rapeseed oils caused by thermal treatment was studied. The rapeseed oil at 60 ℃ was regularly subjected to spectral measurement, and the spectral changes induced by thermal treatment were analyzed and discussed. This study had demonstrated the good performance of FTIR-ATR spectroscopy in characterizing rapeseed oils. 展开更多
关键词 Rapeseed oil FTIR-ATR characterization.
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Preparation of Conjugated Linoleic Acid and Identification of Its Isomers 被引量:9
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作者 郭诤 张根旺 孙彦 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2003年第2期130-135,共6页
Conjugated linoleic acid (CLA) is a kind of fatty acid with physiological activities and potential application prospect. A synthesis method of conjugated linoleic acid and a purification technology were studied. CLA w... Conjugated linoleic acid (CLA) is a kind of fatty acid with physiological activities and potential application prospect. A synthesis method of conjugated linoleic acid and a purification technology were studied. CLA was prepared and purified by urea-complexation and conjugation using safflower oil as raw material. The purity of CLA and total recovery of the product was more than 95% and 48%, respectively. The main isomers produced in alkali-catalyzed conjugation were identified by gas chromatography (GC) linked to mass spectrometry (MS) and Fourier transform infrared spectroscopy (FTIR). The total amount of the two main isomers (9cis, 11trons-and 10trans, 12cis-CLA) determined by GC was more than 90% of the product. 展开更多
关键词 linoleic acid conjugated linoleic acid urea-complexation alkali-catalyzed conjugation IDENTIFICATION safflower oil
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Quantitative Analysis Using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry and Correlation between Mass Spectrometry Data and Sulfur Content of Crude Oils 被引量:4
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作者 Wang Wei Liu Yingrong +1 位作者 Liu Zelong Tian Songbai 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2015年第4期71-80,共10页
Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS) has become a powerful tool for analyzing the detailed composition of petroleum samples. However, the correlation between the numerous peaks obtain... Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS) has become a powerful tool for analyzing the detailed composition of petroleum samples. However, the correlation between the numerous peaks obtained by FT-ICR MS and bulk properties of petroleum samples is still a challenge. In this study, the internal standard method was applied for the quantitative analysis of four straight-run vacuum gas oils(VGO) by atmospheric pressure photoionization(APPI) FT-ICR MS. The heteroatom class distribution of these VGO samples turned to be different when the concentration changed. Linear relationship between the normalized abundance and the concentration of VGO samples was identified for the total aromatic compounds, aromatic hydrocarbons, S1 and N1 species. The differences of the response factors were also discussed. The sulfur contents of a series of crude oils were proved to be linear with the FT-ICR MS data calibrated by the response factor of S1 species. This study demonstrated the feasibility of the internal standard method in quantitative analysis with APPI FT-ICR MS, and the bulk properties of petroleum samples could be correlated directly with the FT-ICR MS data. 展开更多
关键词 FT-ICR MS APPI internal standard method response factor petroleomics
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Aminopropyl-containing ionic liquid based organosilica as a novel and efficient adsorbent for removal of crystal violet from wastewaters
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作者 Frood Shojaeipoor Bakhshali Masoumi +1 位作者 Mohammad Hossain Banakar Javad Rastegar 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第9期1294-1302,共9页
Herein a novel aminopropyl-containing ionic liquid based organosilica(ILOS-NH_2) is prepared, characterized and applied as effective adsorbent for removal of crystal violet(CV) dye from wastewater. The ILOS-NH2 materi... Herein a novel aminopropyl-containing ionic liquid based organosilica(ILOS-NH_2) is prepared, characterized and applied as effective adsorbent for removal of crystal violet(CV) dye from wastewater. The ILOS-NH2 material was synthesized by hydrolysis and co-condensation of 1,3-bis-(3-trimethoxysilylpropyl)-imidazolium chloride(BTMSPIC) under acidic conditions followed by treatment with 3-aminopropyl-trimethoxysilane in toluene under reflux conditions. This material was characterized using scanning electron microscopy(SEM), diffuse reflectance infrared Fourier transform spectroscopy(DRIFTS), thermal gravimetric analysis(TGA) and energy dispersive X-ray analysis(EDAX). The material was effectively used in the removal of crystal violet at ambient temperature and showed high capacity and stability under applied conditions. The efficacy of p H, contact time, adsorbent dose, initial dye concentration, temperature, and isotherm studies and the applicability of pseudo-first, second order and Elovich kinetic models have also been investigated. 展开更多
关键词 Ionic liquid based organosilica Aminopropyl-functionalized Crystal violet(CV) Isotherm Kinetic
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Oil spill sorption using raw and acetylated sugarcane bagasse
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作者 Reza Behnood Bagher Anvaripour +1 位作者 Nematollah Jaafarzadeh Masoome Farasati 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第7期1618-1625,共8页
In the recent decades oil spills in the aquatic environments are one of the major sources of environmental pollutions, which are steadily growing with the increase in oil consumption. Adsorption is a rapid and cost ef... In the recent decades oil spills in the aquatic environments are one of the major sources of environmental pollutions, which are steadily growing with the increase in oil consumption. Adsorption is a rapid and cost effective process to minimize the environmental impacts of oil spills and cleanup these pollutants. In this work, the crude oil sorption capacity was examined with raw sugarcane bagasse and acetylated sugarcane bagasse. Results show that the acetylated bagasse was significantly more oleophilic than the raw bagasse and acetylation reaction can increase bagasse oil sorption ability by about 90%. The maximum sorption capacities of acetylated bagasse were obtained about 11.3 g and 9.1 g in dry system(crude oil sorption) and oil layer sorption, respectively. The physicochemical characteristics of the sorbents such as composition, water solubility, moisture content and density were measured according to ASTM standard methods. Also Fourier transform infrared spectroscopy(FTIR) of raw and acetylated bagasse was performed to investigate the effect of acetylation on sugarcane bagasse structure. 展开更多
关键词 crude oil ADSORPTION natural sorbent: sugarcane bagasse acetylated bagasse
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畅享中华地道滋味——康师傅方便面“中华美食”各系列广告创意
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《声屏世界(广告人)》 2007年第5期88-90,共3页
背景说明在“传统饮食文化再创新”策略下,“康师傅方便面中华美食各地方系列”2006年步入了第三个发展年,也进入第三个传播阶段。在此传播阶段中,上海智得广告公司继续为各地方系列发想了一系列精彩的广告创意,在此共赏。
关键词 系列广告 传播阶段 广告公司 传统饮食文化 发想 酸菜牛肉 入第 私房菜 傅油 麻辣牛肉
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A reduced combustion kinetic model for the methanol-gasoline blended fuels on SI engines. 被引量:3
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作者 LING XinChen WU Feng YAO DongWei 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2016年第1期81-92,共12页
A reduced combustion kinetic model for the methanol-gasoline blended fuels for SI engines was developed. Sensitivity analysis and rate constant variation methods were used to optimize the kinetic model. Flame propagat... A reduced combustion kinetic model for the methanol-gasoline blended fuels for SI engines was developed. Sensitivity analysis and rate constant variation methods were used to optimize the kinetic model. Flame propagation, shock-tube and jet-stirred reactor systems were modeled in CHEMKIN. The laminar flame speed, ignition delay time and change in concentrations of species were simulated using the reduced kinetic model. The simulation results of reduced chemical mechanism agreed well with the relevant experimental data published in the literature. The experimental investigations on engine bench were also carried out. The in-cylinder pressure and exhaust emissions were obtained by using a combustion analyzer and an FTIR(Fourier transform infrared spectroscopy) spectrometer. Meanwhile, an engine in-cylinder CFD model was established in AVL FIRE and was coupled with the proposed reduced chemical mechanism to simulate the combustion process of methanol-gasoline blends. The simulated combustion process showed good agreement with the engine experimental results and the predicted emissions were found to be in accordance with the FTIR results. 展开更多
关键词 Methanol-gasoline chemical mechanism SI engine CFD simulation
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Petroleum heteroatom compounds in various commercial delayed coking liquids: characterized by FT-ICR MS and GC techniques 被引量:2
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作者 Miao Hu Chuang Guo +4 位作者 Linzhou Zhang Suoqi Zhao Keng H. Chung Chunming Xu Quan Shi 《Science China Chemistry》 SCIE EI CAS CSCD 2017年第2期284-292,共9页
Delayed coking is an important petroleum resid conversion process.The processability of coking liquids is known to be dependent on the heteroatom compounds present in the coking liquids.Eight commercial delayed coking... Delayed coking is an important petroleum resid conversion process.The processability of coking liquids is known to be dependent on the heteroatom compounds present in the coking liquids.Eight commercial delayed coking liquids were characterized by electrospray ionization(ESI)Fourier transform ion cyclotron resonance mass spectrometry(ESI FT-ICR MS)and gas chromatographic techniques.High relatively abundant heteroatom compounds in the coking liquids were 1-4 aromatic-ring pyridinic nitrogen compounds,carbazoles,benzocarbazoles,phenols,mercaptans,benzothiophenes,dibenzothiophenes,and naphthobenzothiophenes.Coking liquids derived from various feeds had similar compound class types,molecular weight distribution ranges,and double bond equivalents(DBE).However,the concentration of individual compounds and the distribution of DBE versus carbon number of heteroatom compounds varied.A comparison of heteroatom compounds in coker feeds and products revealed the various reaction mechanism of heteroatom compounds occurred during the coking process.The results suggested that molecular-level process models can be developed for optimization of unit operation to obtain desirable products that meet the environmental specifications and quality requirements. 展开更多
关键词 FT-ICR MS molecular composition heteroatom compounds petroleum delayed coking
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