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Pt/Ba-Al-O催化剂储存NO_x的性能和机理研究 被引量:8
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作者 李新刚 孟明 +1 位作者 林培琰 汪文栋 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2001年第4期501-506,共6页
采用共沉淀法制备了Pt/Ba -Al-O样品。用XRD、NO -TPD以及NOx 储存量测量等手段对样品进行了表征 ,并对NOx 的储存机理进行了探讨。结果表明 ,样品中的主要成分是BaAl2 O4 ,有少量BaCO3存在。在催化剂表面的Pt有两种吸附位 ,吸附位 1为N... 采用共沉淀法制备了Pt/Ba -Al-O样品。用XRD、NO -TPD以及NOx 储存量测量等手段对样品进行了表征 ,并对NOx 的储存机理进行了探讨。结果表明 ,样品中的主要成分是BaAl2 O4 ,有少量BaCO3存在。在催化剂表面的Pt有两种吸附位 ,吸附位 1为NO提供了吸附位 ,对应低温区的NO脱附峰 ;吸附位 2使NO和O2 在催化剂表面反应生成硝酸盐和亚硝酸盐 ,对应高温区的NO脱附峰。当吸附温度为 30 0℃、O2 的体积分数为 1.3%时 ,NO的脱附量达到了最大值。经过还原处理样品的NO吸附能力比经过氧化预处理的样品强得多。样品储存NOx 的最佳温区为 30 0~ 4 5 0℃。 展开更多
关键词 氧化氮 储存 催化剂 PT BaAl2O3 储存机理 钡铝氧化物 汽车尾气治理 吸附
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Corrosion behavior of 2A97 Al-Cu-Li alloys in different thermomechanical conditions by quasi-in-situ analysis
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作者 You Lü Xiang-zhe MENG +2 位作者 Yan-yan LI Ze-hua DONG Xin-xin ZHANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期2772-2786,共15页
As a promising material in the aircraft industry,2A97 Al-Cu-Li alloy exhibits high corrosion susceptibility that may limit its application.In the present work,to illustrate the influences of precipitate and grain-stor... As a promising material in the aircraft industry,2A97 Al-Cu-Li alloy exhibits high corrosion susceptibility that may limit its application.In the present work,to illustrate the influences of precipitate and grain-stored energy on localized corrosion evolution in 2A97 Al-Cu-Li alloy,cold working and artificial aging were carried out to produce 2A97 Al-Cu-Li alloys under different thermomechanical conditions.Quasi-in-situ analysis,traditional immersion test and electrochemical measurement were then conducted to examine the corrosion behavior of 2A97 alloys.It is revealed that precipitate significantly affects Cu enrichment at corrosion fronts,which determines corrosion susceptibility of alloys,whereas grain-stored energy distribution is closely associated with localized corrosion propagation.It is also indicated that quasi-in-situ analysis exhibits a consistent corrosion evolution with traditional immersion tests,which is regarded as a proper method to explore localized corrosion mechanisms by providing local microstructural information with enhanced time and spatial resolutions. 展开更多
关键词 Al−Cu−Li alloy corrosion behavior quasi-in situ analysis grain-stored energy thermomechanical treatment
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Ni_(2)Co-LDHs作为超级电容器电极材料的电化学性能研究 被引量:1
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作者 周芳 刘强 +1 位作者 吕天喜 胡伟康 《浙江师范大学学报(自然科学版)》 CAS 2022年第3期300-307,共8页
通过化学共沉淀法制备了不同组分镍钴层状双氢氧化物(Ni_(x)Co_(y)-LDHs),并通过X射线衍射、扫描电镜、透射电镜、循环伏安法、恒电流充放电及电化学交流阻抗等测试手段进一步研究了Ni_(2)Co-LDHs材料的物相结构、表面形貌和电化学性能... 通过化学共沉淀法制备了不同组分镍钴层状双氢氧化物(Ni_(x)Co_(y)-LDHs),并通过X射线衍射、扫描电镜、透射电镜、循环伏安法、恒电流充放电及电化学交流阻抗等测试手段进一步研究了Ni_(2)Co-LDHs材料的物相结构、表面形貌和电化学性能,探究电荷储存机理及计算扩散系数.结果表明:当镍钴物质的量之比为2∶1时,其组分Ni_(2)Co-LDHs与其他2个组分(NiCo_(0.2)-LDHs和NiCo-LDHs)相比,比容量最大;纳米片状形貌的Ni_(2)Co-LDHs作为超级电容器电极材料表现出极好的电化学性能,其比容量最大值为2037 F/g,较小的阻抗(0.21Ω/cm^(2))和良好的循环稳定性,经过近4000周循环,比容量衰减约10%;Ni_(2)Co-LDHs电极的还原反应过程为扩散控制电荷储存,扩散系数D为8.0×10^(-11) cm^(2)/s,其氧化反应过程为混合储存机理,扩散系数D为4.2×10^(-10)cm^(2)/s.由于此类二元镍钴双层氢氧化物电极材料具有良好的氧化还原动力学性能,因此,在超级电容器领域具有极其广阔的应用前景. 展开更多
关键词 镍钴层状双氢氧化物 电极材料 电荷储存机理 扩散系数 超级电容器
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基于电石渣—三乙烯四胺的多孔凝胶矿化固碳研究 被引量:1
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作者 陆伟 吴明跃 +5 位作者 吕茂云 李金亮 梁运涛 张茜 王昌祥 路瑶 《矿业安全与环保》 北大核心 2022年第4期87-94,共8页
为有效矿化封存CO_(2)、提高煤矿防灭火效果,提出了一种通过添加催化CO_(2)转化物质(三乙烯四胺溶液,TETA)和增加气固接触面积(多孔凝胶)协同提升矿化反应速率的方法。通过单因素试验确定了TETA的质量分数和CO_(2)初始压力,借助高温高... 为有效矿化封存CO_(2)、提高煤矿防灭火效果,提出了一种通过添加催化CO_(2)转化物质(三乙烯四胺溶液,TETA)和增加气固接触面积(多孔凝胶)协同提升矿化反应速率的方法。通过单因素试验确定了TETA的质量分数和CO_(2)初始压力,借助高温高压反应釜研究了多孔凝胶对CO_(2)矿化效率的影响规律,利用扫描电镜和密度泛函理论研究了TETA储存和转化CO_(2)机理。研究结果表明:添加CaO能增大反应釜内CO_(2)压降值,TETA的最佳质量分数为2.5%~7.5%,CO_(2)初始压力为0.4~0.8 MPa;单位质量的多孔凝胶在温度20、30、40℃条件下固定CO_(2)的质量分别为0.070、0.077、0.110 g。 展开更多
关键词 煤自燃 CO_(2)矿化封存 三乙烯四胺 CaO 多孔凝胶 单因素试验 储存—转化—矿化CO_(2)机理
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Quantitative analysis of Boehm' s GC 被引量:2
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作者 GUAN Xue-tao ZHANG Yuan-rui +1 位作者 GOU Xiao-gang CHENG Xu 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2003年第3期259-264,共6页
The term garbage collection describes the automated process of finding previously allocated memorythatis no longer in use in order to make the memory available to satisfy subsequent allocation requests. Wehave reviewe... The term garbage collection describes the automated process of finding previously allocated memorythatis no longer in use in order to make the memory available to satisfy subsequent allocation requests. Wehave reviewed existing papers and implementations of GC, and especially analyzed Boehm' s C codes, which isa real-time mark-sweep GC running under Linux and ANSI C standard. In this paper, we will quantitatively an-alyze the performance of different configurations of Boehm' s collector subjected to different workloads. Reportedmeasurements demonstrate that a refined garbage collector is a viable alternative to traditional explicit memorymanagement techniques, even for low-level languages. It is more a trade-off for certain system than an all-or-nothing proposition. 展开更多
关键词 CONSERVATIVE garbage collection INCREMENTAL mark-sweep REAL-TIME
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The MMU Implementation of Unity-1 Microprocessor 被引量:2
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作者 宋传华 Cheng +2 位作者 Xu Zhu Dexin 《High Technology Letters》 EI CAS 2003年第4期27-32,共6页
Virtual memory management is always a very essential issue of the modern microprocessor design. A memory management unit (MMU) is designed to implement a virtual machine for user programs, and provides a management me... Virtual memory management is always a very essential issue of the modern microprocessor design. A memory management unit (MMU) is designed to implement a virtual machine for user programs, and provides a management mechanism between the operating system and user programs. This paper analyzes the tradeoffs considered in the MMU design of Unity 11 CPU of Peking University, and introduces in detail the solution of pure hardware table walking with two level page table organization. The implementation takes care of required operations and high performances needed by modern operating systems and low costs needed by embedded systems. This solution has been silicon proven, and successfully porting the Linux 2.4.17 kernel, the XWindow system, GNOME and most application software onto the Unity platform. 展开更多
关键词 Unity 1 MMU TLB table walking MICROPROCESSOR
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South Africa's Nuclear Forensics Response Plan Step 1 - in Support of Nuclear Security Investigations
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作者 Phuti Reuben Mogafe Banyana Kokwane Precious Tshidada AmosL Matshiga JJHancket 《Journal of Physical Science and Application》 2015年第3期183-190,共8页
In South Africa, the nuclear forensics approach and its functions hosted and managed by Necsa, in support of any nuclear security investigations, start from the incident scene when the nuclear or radioactive material ... In South Africa, the nuclear forensics approach and its functions hosted and managed by Necsa, in support of any nuclear security investigations, start from the incident scene when the nuclear or radioactive material (that is out of regulatory control) is being handled and handed over to Necsa Emergency Control Centre by the South African law enforcement agencies in the presence of NOMS Department official. The main objective of this approach is to increase the credibility status of the chain of custody on the handling of the material during incident (crime) scene management process (for both nuclear forensics and traditional forensic evidence collection) and its transportation from the scene to the suitable storage facility at Necsa. Aspects to be looked into during the response process include interactions between law enforcement agencies, Necsa relevant departments and the National Nuclear Regulator of South Africa. This paper focuses on the entire whole response process and associated prior arrangements, in order to show and provide a set of requirements attached to the material, the scope of critical relevant technical and law enforcement information that to be acquired by all parties involving and participating in the nuclear/radiological incident or event response process before the material is authorized for storage at a suitably qualified Necsa's nuclear forensics, which is dedicated storage facility on Pelindaba site. 展开更多
关键词 Response plan nuclear incidents.
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The Efficiency Improving of Traction Drive Test Bench with Supercapacitor Energy Storage System
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作者 Genadijs Zaleskis Viesturs Brazis 《Journal of Mathematics and System Science》 2012年第9期570-575,共6页
For development of passenger electrical transport, it is necessary to use energy more rationally. One of methods of vehicle power efficiency increase is installation of on-board energy storage systems. For studying of... For development of passenger electrical transport, it is necessary to use energy more rationally. One of methods of vehicle power efficiency increase is installation of on-board energy storage systems. For studying of system operation, it is necessary to carry out a lot of experiments, therefore it is favorable to use the test bench and its computer model for reduction of the number of physical experiments. In this article, the results of computer modeling for the optimization of traction drive test bench by adjusting of the operation parameters of supercapacitor energy storage are described. Test bench operation is considered in cases of the energy storage system working at various selected supercapacitor initial voltages. Maximal increase of possibility of vehicle test bench regenerative braking with minimal decrease of autonomous power supply mode possibility is investigated. There is estimated the energy storage system efficiency improving measures dependence from supercapacitor operational voltage ranges. Parameters at which the minimum losses of energy are observed are revealed. Dependence of energy storage system discharge power on the most admissible supercapacitor current is established. 展开更多
关键词 Energy storage SUPERCAPACITOR test bench computer modeling passenger electrical transport.
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钠离子电池用碳负极材料研究进展 被引量:14
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作者 张思伟 张俊 +3 位作者 吴思达 吕伟 康飞宇 杨全红 《化学学报》 SCIE CAS CSCD 北大核心 2017年第2期163-172,共10页
相较于目前主流的锂离子电池,钠离子电池成本相对较低,因而有望在未来大规模储能系统中获得重要应用,然而其实用化进程仍受制于缺少合适的正负极材料,特别是性能优异且实用化的负极材料.钠离子电池与锂离子电池具有相似的工作原理,但钠... 相较于目前主流的锂离子电池,钠离子电池成本相对较低,因而有望在未来大规模储能系统中获得重要应用,然而其实用化进程仍受制于缺少合适的正负极材料,特别是性能优异且实用化的负极材料.钠离子电池与锂离子电池具有相似的工作原理,但钠离子和锂离子在碳负极材料中的储存行为却有着很大的不同.总体而言,碳材料仍是目前最有望促进钠离子电池实用化的关键负极材料.本文系统总结并分析了目前已有碳材料中钠离子的储存机制,对负极材料的设计思路和研究进展进行了概述,着重阐述了商用化碳分子筛在钠离子电池中的实用化前景.最后,本文对钠离子电池中碳负极材料的未来发展方向进行了展望. 展开更多
关键词 碳材料 钠离子电池 储存机理 碳分子筛
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Recent development of studies on the mechanism of resistive memories in several metal oxides 被引量:2
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作者 TIAN XueZeng WANG LiFen +5 位作者 LI XiaoMin WEI JiaKe YANG ShiZe XU Zhi WANG WenLong BAI XueDong 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2013年第12期2361-2369,共9页
Resistive switching random access memories(RRAM)have been considered to be promising for future information technology with applications for non-volatile memory,logic circuits and neuromorphic computing.Key performanc... Resistive switching random access memories(RRAM)have been considered to be promising for future information technology with applications for non-volatile memory,logic circuits and neuromorphic computing.Key performances of those resistive devices are approaching the realistic levels for production.In this paper,we review the progress of valence change type memories,including relevant work reported by our group.Both electrode engineering and in-situ transmission electron microscopy(TEM)high-resolution observation have been implemented to reveal the influence of migration of oxygen anions/vacancies on the resistive switching effect.The understanding of resistive memory mechanism is significantly important for device applications. 展开更多
关键词 resistive switching effect valence change memory electrode engineering in-situ TEM
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