Mg-based Mg-TiO2 composite powder was prepared by arc plasma evaporation of the Mg+5%TiO2 mixture followed by passivation in air. ICP, XRD and SEM techniques were used to characterize the composition, phase component...Mg-based Mg-TiO2 composite powder was prepared by arc plasma evaporation of the Mg+5%TiO2 mixture followed by passivation in air. ICP, XRD and SEM techniques were used to characterize the composition, phase components and microstructure of the composite powder. The hydrogen sorption properties of the composite powder were investigated by DSC and PCT techniques. According to the data from PCT measurements, the hydrogenation enthalpy and entropy changes of the composite powder are calculated to be-71.5 kJ/mol and-130.1 J/(K·mol), respectively. Besides, the hydrogenation activation energy is determined to be 77.2 kJ/ mol. The results indicate that TiO2 added into Mg by arc plasma method can act as a catalyst to improve the hydrogen sorption kinetic properties of Mg.展开更多
With the growing deployment of smart distribution grid,it has become urgent to investigate the smart distribution grid behavior during transient faults and improve the system stability.The feasibility of segmenting la...With the growing deployment of smart distribution grid,it has become urgent to investigate the smart distribution grid behavior during transient faults and improve the system stability.The feasibility of segmenting large power grids and multiple smart distribution grids interconnections using energy storage technology for improving the system dynamic stability was studied.The segmentation validity of the large power grids and smart distribution grid inverter output interconnections power system using energy storage technology was proved in terms of theoretical analysis.Then,the influences of the energy storage device location and capacity on the proposed method were discussed in detail.The conclusion is obtained that the ESD optimal locations are allocated at the tie line terminal buses in the interconnected grid,respectively.The effectiveness of the proposed method was verified by simulations in an actual power system.展开更多
Ion conductive membranes(ICMs)are frequently used as separators for energy conversion and storage technologies of fuel cells,flow battery,and hydrogen pump,because of their good ion-selective conduction and low electr...Ion conductive membranes(ICMs)are frequently used as separators for energy conversion and storage technologies of fuel cells,flow battery,and hydrogen pump,because of their good ion-selective conduction and low electronic conductivity.Firstly,this feature article reviews the recent studies on the development of new nonfluorinated ICMs with low cost and their macro/micro-structure control.In general,these new nonfluorinated ICMs have lower conductivity than commercial perfluorinated ones,due to their poor ion transport channels.Increasing ion exchange capacity(IEC)would create more continuous hydrophilic channels,thus enhancing the conductivity.However,high IEC also expands the overall hydrophilic domains,weakens the interaction between polymer chains,enhances the mobility of polymer chains,and eventually induces larger swelling.The micro-scale expansion and macro-scale swelling of the ICMs with high IEC could be controlled by limiting the mobility of polymer chains.Based on this strategy,some ef ficient techniques have been developed,including covalent crosslinking,semi-interpenatrating polymer network,and blending.Secondly,this review introduces the optimization of macro/microstructure of both perfluorinated and nonfluorinated ICMs to improve the performance.Macro-scale multilayer composite is an ef ficient way to enhance the mechanical strength and the dimensional stability of the ICMs,and could also decrease the content of per fluorosulfonic acid resin in the membrane,thereby reducing the cost of the perfluorinated ICMs.Long side chain,multiple functionalization,small molecule inducing micro-phase separation,electrospun nano fiber,and organic–inorganic hybrid could construct more ef ficient ion transport channels,improving the ion conductivity of ICMs.展开更多
In this paper, we apply the split-platform automated storage/retrieval systems (SP-AS/RSs) (Hu et al., 2005) to store containers in the yard to improve the yard performance and to increase the utilization of the yard ...In this paper, we apply the split-platform automated storage/retrieval systems (SP-AS/RSs) (Hu et al., 2005) to store containers in the yard to improve the yard performance and to increase the utilization of the yard space. The layout of an SP-AS/RS based yard is described in detail. To achieve an efficient operation, we present a novel yard space allocation policy called the ‘second-carrier-based allocation policy’, which can help to alleviate the out-of-sequence problem of containers and the congestion of vehicles at the AS/RS racks. Different allocation policies are compared by an integrated container terminal simulation system. The simulation results show that the second-carrier-based policy is very efficient and has the potential to offer high terminal performance.展开更多
we have developed ferroelectric capacitor fabrication technique to realize low-voltage and high-density ferroelectric random access memory (FRAM). High temperature deposited IrOxtop electrode reveals high crystallin...we have developed ferroelectric capacitor fabrication technique to realize low-voltage and high-density ferroelectric random access memory (FRAM). High temperature deposited IrOxtop electrode reveals high crystalline quality which drastically reduces the degradation of ferroelectric film by preventing hydrogen diffusion into ferroelectric film. This improvement enables us to commercialize highly-reliable 1T 1C FRAM with memory density of 4 Mb or larger.展开更多
The current need to fasten the implementation of renewable energies greatly depends on the development of competitive storage devices, and while there is not a single technology which is likely capable to competitivel...The current need to fasten the implementation of renewable energies greatly depends on the development of competitive storage devices, and while there is not a single technology which is likely capable to competitively cover the wide range of possible demands, electrochemical technologies are one of the most promising for many of them. For the realization of this promise, new materials fulfilling criteria such as high energy density, high power density, competitive cost, reliability, and environmental compatibility need to be developed in the near future. Electrochemical energy storage devices can be classified into two main technologies: supercapacitors and batteries (including redox flow batteries). Materials and applications for these technologies are discussed and compared, listing current status, technical and strategic challenges.展开更多
Porous materials such as metal-organic frameworks(MOFs)with high theoretical volumetric gas uptake capacity are promising materials for gas storage and separation,but the structuring for practical applications is chal...Porous materials such as metal-organic frameworks(MOFs)with high theoretical volumetric gas uptake capacity are promising materials for gas storage and separation,but the structuring for practical applications is challenging.Herein,we report a general and feasible strategy to combine electrospinning with a phase conversion method to decorate polyacrylonitrile nanofibers(PAN NFs)with CuMOF(HKUST-1).The strategy is based on the combination of surface pretreatment of the NFs with Cu(OH)_(2) and a subsequent phase conversion into HKUST-1 crystals(PCHKUST-1).A significant higher loading of HKUST-1 in the PAN NF matrix was achieved by the phase conversion method compared with direct electrospinning of MOF slurries or insitu growth of MOF crystals on NFs.As a result,the hierarchical structured PC(phase conversion)-HKUST-1 NFs revealed the highest gravimetric storage capacity of 86 cm^(3) g^(-1)(STP)at 3500 kPa and 298 K for methane(CH_(4)),which is higher than other HKUST-1 NFs reported previously.The improved CH_(4) uptake can be explained by the high loading of HKUST-1 due to the high availability of Cu-ions localized on the surface of the NFs during the phase conversion process,resulting in high surface area and excellent gas access of the phase converted HKUST-1.Thus,the developed strategy of structuring MOFs could be of interest for the fabrication of tailor-made MOF NF architectures for other energy and environmental applications.展开更多
Currently, carbon materials, such as graphene,carbon nanotubes, activated carbon, porous carbon, have been successfully applied in energy storage area by taking advantage of their structural and functional diversity. ...Currently, carbon materials, such as graphene,carbon nanotubes, activated carbon, porous carbon, have been successfully applied in energy storage area by taking advantage of their structural and functional diversity. However, the development of advanced science and technology has spurred demands for green and sustainable energy storage materials.Biomass-derived carbon, as a type of electrode materials, has attracted much attention because of its structural diversities,adjustable physical/chemical properties, environmental friendliness and considerable economic value. Because the nature contributes the biomass with bizarre micro structures,the biomass-derived carbon materials also show naturally structural diversities, such as OD spherical, 1D fibrous, 2D lamellar and 3D spatial structures. In this review, the structure design of biomass-derived carbon materials for energy storage is presented. The effects of structural diversity, porosity and surface heteroatom doping of biomass-derived carbon materials in supercapacitors, lithium-ion batteries and sodium-ion batteries are discussed in detail. In addition, the new trends and challenges in biomass-derived carbon materials have also been proposed for further rational design of biomass-derived carbon materials for energy storage.展开更多
基金Project(11ZR1417600)supported by Shanghai Natural Science Foundation from Science and Technology Committee of Shanghai,ChinaProject(11PJ1406000)supported by‘Pujiang’Project from the Science and Technology Committee of Shanghai+1 种基金Project(12ZZ017)supported by Shanghai Education Commission,ChinaProject(20100073120007)supported by China Education Commission
文摘Mg-based Mg-TiO2 composite powder was prepared by arc plasma evaporation of the Mg+5%TiO2 mixture followed by passivation in air. ICP, XRD and SEM techniques were used to characterize the composition, phase components and microstructure of the composite powder. The hydrogen sorption properties of the composite powder were investigated by DSC and PCT techniques. According to the data from PCT measurements, the hydrogenation enthalpy and entropy changes of the composite powder are calculated to be-71.5 kJ/mol and-130.1 J/(K·mol), respectively. Besides, the hydrogenation activation energy is determined to be 77.2 kJ/ mol. The results indicate that TiO2 added into Mg by arc plasma method can act as a catalyst to improve the hydrogen sorption kinetic properties of Mg.
基金Project(N110404031)supported by the Fundamental Research Funds for the Central Universities,China
文摘With the growing deployment of smart distribution grid,it has become urgent to investigate the smart distribution grid behavior during transient faults and improve the system stability.The feasibility of segmenting large power grids and multiple smart distribution grids interconnections using energy storage technology for improving the system dynamic stability was studied.The segmentation validity of the large power grids and smart distribution grid inverter output interconnections power system using energy storage technology was proved in terms of theoretical analysis.Then,the influences of the energy storage device location and capacity on the proposed method were discussed in detail.The conclusion is obtained that the ESD optimal locations are allocated at the tie line terminal buses in the interconnected grid,respectively.The effectiveness of the proposed method was verified by simulations in an actual power system.
基金Supported by the National Science Fund for Distinguished Young Scholars of China(Grant No.21125628)the Major National Scienti fic Instrument Development Project(Grant No.21527812)+3 种基金the National Natural Science Foundation of China(Grant Nos.21406031 and 21476044)the State Key Laboratory of Fine Chemicals(KF1507)the Fundamental Research Funds for the Central Universities(Grant Nos.DUTPJ14RC(3)003)State Key Laboratory of fine chemicals(Panjin)project(Grant No.JH2014009)
文摘Ion conductive membranes(ICMs)are frequently used as separators for energy conversion and storage technologies of fuel cells,flow battery,and hydrogen pump,because of their good ion-selective conduction and low electronic conductivity.Firstly,this feature article reviews the recent studies on the development of new nonfluorinated ICMs with low cost and their macro/micro-structure control.In general,these new nonfluorinated ICMs have lower conductivity than commercial perfluorinated ones,due to their poor ion transport channels.Increasing ion exchange capacity(IEC)would create more continuous hydrophilic channels,thus enhancing the conductivity.However,high IEC also expands the overall hydrophilic domains,weakens the interaction between polymer chains,enhances the mobility of polymer chains,and eventually induces larger swelling.The micro-scale expansion and macro-scale swelling of the ICMs with high IEC could be controlled by limiting the mobility of polymer chains.Based on this strategy,some ef ficient techniques have been developed,including covalent crosslinking,semi-interpenatrating polymer network,and blending.Secondly,this review introduces the optimization of macro/microstructure of both perfluorinated and nonfluorinated ICMs to improve the performance.Macro-scale multilayer composite is an ef ficient way to enhance the mechanical strength and the dimensional stability of the ICMs,and could also decrease the content of per fluorosulfonic acid resin in the membrane,thereby reducing the cost of the perfluorinated ICMs.Long side chain,multiple functionalization,small molecule inducing micro-phase separation,electrospun nano fiber,and organic–inorganic hybrid could construct more ef ficient ion transport channels,improving the ion conductivity of ICMs.
基金the Agency for Science, Technology and Research, the Maritime and Port Authority,and Nanyang Technological University, Singapore
文摘In this paper, we apply the split-platform automated storage/retrieval systems (SP-AS/RSs) (Hu et al., 2005) to store containers in the yard to improve the yard performance and to increase the utilization of the yard space. The layout of an SP-AS/RS based yard is described in detail. To achieve an efficient operation, we present a novel yard space allocation policy called the ‘second-carrier-based allocation policy’, which can help to alleviate the out-of-sequence problem of containers and the congestion of vehicles at the AS/RS racks. Different allocation policies are compared by an integrated container terminal simulation system. The simulation results show that the second-carrier-based policy is very efficient and has the potential to offer high terminal performance.
文摘we have developed ferroelectric capacitor fabrication technique to realize low-voltage and high-density ferroelectric random access memory (FRAM). High temperature deposited IrOxtop electrode reveals high crystalline quality which drastically reduces the degradation of ferroelectric film by preventing hydrogen diffusion into ferroelectric film. This improvement enables us to commercialize highly-reliable 1T 1C FRAM with memory density of 4 Mb or larger.
文摘The current need to fasten the implementation of renewable energies greatly depends on the development of competitive storage devices, and while there is not a single technology which is likely capable to competitively cover the wide range of possible demands, electrochemical technologies are one of the most promising for many of them. For the realization of this promise, new materials fulfilling criteria such as high energy density, high power density, competitive cost, reliability, and environmental compatibility need to be developed in the near future. Electrochemical energy storage devices can be classified into two main technologies: supercapacitors and batteries (including redox flow batteries). Materials and applications for these technologies are discussed and compared, listing current status, technical and strategic challenges.
基金supported by the Grande Solution Project“HiGradeGas”(48279)Innovation Fund Denmark,exploring NFs-based adsorbents for biogas upgrading and storage+1 种基金the Danish Research Council to provide funding to support fundamental research on electrospinning(8022-00237B)for investigating NFs structures for enzyme immobilization(6111-00232B)。
文摘Porous materials such as metal-organic frameworks(MOFs)with high theoretical volumetric gas uptake capacity are promising materials for gas storage and separation,but the structuring for practical applications is challenging.Herein,we report a general and feasible strategy to combine electrospinning with a phase conversion method to decorate polyacrylonitrile nanofibers(PAN NFs)with CuMOF(HKUST-1).The strategy is based on the combination of surface pretreatment of the NFs with Cu(OH)_(2) and a subsequent phase conversion into HKUST-1 crystals(PCHKUST-1).A significant higher loading of HKUST-1 in the PAN NF matrix was achieved by the phase conversion method compared with direct electrospinning of MOF slurries or insitu growth of MOF crystals on NFs.As a result,the hierarchical structured PC(phase conversion)-HKUST-1 NFs revealed the highest gravimetric storage capacity of 86 cm^(3) g^(-1)(STP)at 3500 kPa and 298 K for methane(CH_(4)),which is higher than other HKUST-1 NFs reported previously.The improved CH_(4) uptake can be explained by the high loading of HKUST-1 due to the high availability of Cu-ions localized on the surface of the NFs during the phase conversion process,resulting in high surface area and excellent gas access of the phase converted HKUST-1.Thus,the developed strategy of structuring MOFs could be of interest for the fabrication of tailor-made MOF NF architectures for other energy and environmental applications.
基金supported by the National Natural Science Foundation of China (51702117,51672055)Major Research Projects Fund of Jilin Institute of Chemical Technology (2016006)Natural Science Foundation of Heilongjiang Province of China (E201416)
文摘Currently, carbon materials, such as graphene,carbon nanotubes, activated carbon, porous carbon, have been successfully applied in energy storage area by taking advantage of their structural and functional diversity. However, the development of advanced science and technology has spurred demands for green and sustainable energy storage materials.Biomass-derived carbon, as a type of electrode materials, has attracted much attention because of its structural diversities,adjustable physical/chemical properties, environmental friendliness and considerable economic value. Because the nature contributes the biomass with bizarre micro structures,the biomass-derived carbon materials also show naturally structural diversities, such as OD spherical, 1D fibrous, 2D lamellar and 3D spatial structures. In this review, the structure design of biomass-derived carbon materials for energy storage is presented. The effects of structural diversity, porosity and surface heteroatom doping of biomass-derived carbon materials in supercapacitors, lithium-ion batteries and sodium-ion batteries are discussed in detail. In addition, the new trends and challenges in biomass-derived carbon materials have also been proposed for further rational design of biomass-derived carbon materials for energy storage.