Distribution of metals on Pd-SnO2/D3520 catalysts and state of the catalystswere studied with SEM, XRD. The interactlbn between metals and supped or between Pd and Sn or Ph were studied by IR, XPS. In addition, the re...Distribution of metals on Pd-SnO2/D3520 catalysts and state of the catalystswere studied with SEM, XRD. The interactlbn between metals and supped or between Pd and Sn or Ph were studied by IR, XPS. In addition, the relationship ofthe activity for catalytic hydrogenation of the olefins and outer layer valence electrondensity of Pd was discussed. The results showed that these catalysts had suitablesurface state, the metals were uniformly dispersed on the surface layer of the suppnd. There were not obvious interaction between the metals and the supal. Therewas strong interaction between Pd and Sn (or Ph) in the catalysts. The catalytic activity for hydrogenation was related to outer layer valence electron density of Pd.展开更多
文摘Distribution of metals on Pd-SnO2/D3520 catalysts and state of the catalystswere studied with SEM, XRD. The interactlbn between metals and supped or between Pd and Sn or Ph were studied by IR, XPS. In addition, the relationship ofthe activity for catalytic hydrogenation of the olefins and outer layer valence electrondensity of Pd was discussed. The results showed that these catalysts had suitablesurface state, the metals were uniformly dispersed on the surface layer of the suppnd. There were not obvious interaction between the metals and the supal. Therewas strong interaction between Pd and Sn (or Ph) in the catalysts. The catalytic activity for hydrogenation was related to outer layer valence electron density of Pd.
