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载体特性对Pd-Cu/TiO_2催化剂催化脱氮性能的影响 被引量:3
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作者 陈立强 郑寿荣 +3 位作者 尹大强 江芳 郭照冰 范杰 《环境化学》 CAS CSCD 北大核心 2005年第5期502-505,共4页
以Pd-Cu/TiO_2为催化剂,采用催化加氢技术进行脱氮研究.结果表明:TiO_2载体的特性对催化活性及N_2选择性有显著影响,与773K和973K温度下焙烧得到的载体相比,以573K温度下焙烧得到的TiO2为载体制备的Pd(5wt%)-Cu(1·25wt%)/TiO_2催... 以Pd-Cu/TiO_2为催化剂,采用催化加氢技术进行脱氮研究.结果表明:TiO_2载体的特性对催化活性及N_2选择性有显著影响,与773K和973K温度下焙烧得到的载体相比,以573K温度下焙烧得到的TiO2为载体制备的Pd(5wt%)-Cu(1·25wt%)/TiO_2催化剂可显著提高催化效率及N_2选择性. 展开更多
关键词 Pd-Cu/TiO2催化 催化脱氮性能 载体特性 催化活性 催化效率 N2选择性 硝酸盐 环境水化学
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Photocatalytic Denitrogenation over Modified Waste FCC Catalyst
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作者 Zheng Liuping Lin Mei +3 位作者 Huang Yingying Yan Guiyang Zheng Binquan Li Ling 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2013年第3期33-37,共5页
The strontium modified waste FCC catalyst was prepared by magnetic stirring method and characterized by Xray diffractometry(XRD),UV-Vis diffuse reflectance spectrometry(DRS),X-ray photoelectron spectroscopy(XPS)and sc... The strontium modified waste FCC catalyst was prepared by magnetic stirring method and characterized by Xray diffractometry(XRD),UV-Vis diffuse reflectance spectrometry(DRS),X-ray photoelectron spectroscopy(XPS)and scanning electron microscopy(SEM).Meanwhile,its photocatalytic denitrogenation performance was evaluated in terms of its ability to degrade the N-containing simulation oil under visible light.A mixture of strontium nitrate solution(with a concentration of 0.5 mol/L)and waste FCC catalyst was calcined at 400℃for 5 h prior to taking part in the photocatalytic denitrogenation reaction.The test results showed that the photocatalytic degradation rate of pyridine contained in simulation oil in the presence of the strontium modified FCC catalyst could reach 92.0% under visible light irradiation for 2.5 h. 展开更多
关键词 waste FCC catalyst PHOTOCATALYSIS denitrogenation
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