The coordination reactions of Cu(Ⅱ) and Ni(Ⅱ) with acid alizarine blue B (AABB) in the presence of cetyltrimethylammonium bromide (CTAB) micelle were investigated using the microsurface adsorptionspectral co...The coordination reactions of Cu(Ⅱ) and Ni(Ⅱ) with acid alizarine blue B (AABB) in the presence of cetyltrimethylammonium bromide (CTAB) micelle were investigated using the microsurface adsorptionspectral correction technique (MSASC). The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu(Ⅱ) or Ni(Ⅱ)and AABB. The binding ratio of AABB to CTAB was 1:2.5, and monomeric aggregate, AABB2CTAB5, was formed with an adsorption constant of 5.95×10^5 at 20 ℃ or 2.48×10^5 at 40 ℃. In the ternary complexation, the ratio of AABB:Cu and AABB:Ni were 1:1 and 1:2.5, respectively. Two types of aggregates, Cu2.AABB2·CTAB80 and Ni5.AABB2.CTAB80, were formed.展开更多
Infectious bursal disease virus (IBDV) was inactivated by two different chemicals—formaldehyde and binary ethylenimine (BEI). Formaldehyde was used at 0.1% and 0.2%, while BEI was used at concentrations of 0.001 and ...Infectious bursal disease virus (IBDV) was inactivated by two different chemicals—formaldehyde and binary ethylenimine (BEI). Formaldehyde was used at 0.1% and 0.2%, while BEI was used at concentrations of 0.001 and 0.002 mol/L. These four vaccines were tested for their efficiency in generating humoral immune response in different groups of broiler chicks. Both BEI-inactivated vaccines gave relatively higher antibody titers and were almost twice as efficient as formaldehyde-inactivated ones.展开更多
The vapor-liquid equilibrium (VLE) data for the dimethyl carbonate-n-butyl acetate binary system were measured by an Ellis equilibrated distillator. The experimental data were checked for their thermodynamic consisten...The vapor-liquid equilibrium (VLE) data for the dimethyl carbonate-n-butyl acetate binary system were measured by an Ellis equilibrated distillator. The experimental data were checked for their thermodynamic consistency through statistical methods. The VLE data was correlated with Wilson and NRTL activity coefficient models and also with the calculation of the vapor phase fugacity coefficient by the modified Peng-Robinson equation of state.展开更多
Viscosities and densities for 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) and N, N-dimethylformamide (DMF) binary mixtures have been measured at the temperature range from 293.15 K to 318.15 K. ...Viscosities and densities for 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) and N, N-dimethylformamide (DMF) binary mixtures have been measured at the temperature range from 293.15 K to 318.15 K. It is shown that the viscosities and densities decrease monotonously with temperature and the content of DMF. Various correlation methods including Arrhenius-like equation, Sedclon et al.'s equation, Redlich-Kister equation with four parameters, and other empirical equations were applied to evaluate these experimental data. A model based on an equation of state Ior estimating the viscosity of mixtures containing ionic liquids were proposed by coupling with the excess Gibbs free energy model of viscosity, which can synchronously calculate the viscosity and the molar volume. The results show that the model gives a deviation of 8.29% for the viscosity, and a deviation of 1.05% for the molar volume when only one temperature-independent adjustable parameter is adopted. The correlation accuracy is further improved when two parameters or one temperature-dependent parameter is used.展开更多
This work proved that biomass-based polyols (sorbitol, xylitol, erythritol, glycerol and ethanediol) were able to be converted into high-value chemical (p-xylene) by catalytic cracking of polyols, alkylation of aromat...This work proved that biomass-based polyols (sorbitol, xylitol, erythritol, glycerol and ethanediol) were able to be converted into high-value chemical (p-xylene) by catalytic cracking of polyols, alkylation of aromatics, and the isomerization of xylenes over the SiO2-modified zeolites. Compared to the conventional HZSM-5 zeolite, the SiO2-containing zeolites considerably increased the selectivity and yield of p-xylene due to the reduction of external surface acidity and the narrowing of pore entrance. The influences of the methanol additive, reaction temperature, and types of polyols on the selectivity and yield of p-xylene were investigated in detail. Catalytic cracking of polyols with methanol significantly enhanced the production of p-xylene by the alkylation of toluene with methanol. The highest p-xylene yield of 10.9 C-mol% with a p-xylene/xylenes ratio of 91.1% was obtained over the 15wt%SiO2/HZSM-5 catalyst. The reaction pathway for the formation of p-xylene was addressed according to the study of the key reactions and the characterization of catalysts.展开更多
Liquid-liquid equilibrium (LLE) data for the ternary system 2-methoxy-2-methylpropane (methyl tert-butyl ether) + p-cresol + water was measured at atmospheric pressure and temperatures of 298.15 K and 313.15 K. ...Liquid-liquid equilibrium (LLE) data for the ternary system 2-methoxy-2-methylpropane (methyl tert-butyl ether) + p-cresol + water was measured at atmospheric pressure and temperatures of 298.15 K and 313.15 K. From the distribution coefficients and selectivity, it was found that 2-methoxy-2-methylpropane is an efficient solvent to extract p-cresol from wastewater. The consistency of the experimental tie-line data was verified with the Hand and Bachman equations. These data were also correlated with the non-random two liquid (NRTL) and universal quasi-chemical correlation activity coefficient (UN1QUAC) models to yield binary interac- tion parameters for p-cresol extraction process evaluation. Both models agreed with experiments very well, yet the NRTL model showed even smaller average deviation than the UNIQUAC model.展开更多
Vapor-liquid equilibrium (VLE) for a ternary system of methyldichlorosilane + methylvinyldichlorosi-lane + toluene and constituent binary systems were measured at 101.3kPa using a new type of magnetical pump-ebulliome...Vapor-liquid equilibrium (VLE) for a ternary system of methyldichlorosilane + methylvinyldichlorosi-lane + toluene and constituent binary systems were measured at 101.3kPa using a new type of magnetical pump-ebulliometer. The equilibrium compositions of the vapor phase of binary systems were calculated indirectly from the total pressure-temperature-liquid composition (pTx). The experimental data were correlated with the Wilson and NRTL(non-random two liquid) equations. The parameters of the Wilson model were employed to predict the ternary VLE data. The calculated boiling points were in good agreement with the experimental ones.展开更多
Based on a special catalyst and fiber Bragg gratings (FBGs), an optical sensing system is proposed to measure the concen- tration of methane. The temperature of the catalyst rises rapidly as the concentration of metha...Based on a special catalyst and fiber Bragg gratings (FBGs), an optical sensing system is proposed to measure the concen- tration of methane. The temperature of the catalyst rises rapidly as the concentration of methane increases, and hence it can be detected by an FBG-type sensor through monitoring the wavelength shift of the reflection spectrum. The experimental results show the good performances of our system, such as the high resolution and temperature stability.展开更多
Liquid-liquid equilibrium (LLE) data for the ternary systemwater-ethanol-dimethyl succinate have been determined experimentallyat temperatures ranging from 298.15 to 318.15 K at 5 K intervals.Complete phase diagrams w...Liquid-liquid equilibrium (LLE) data for the ternary systemwater-ethanol-dimethyl succinate have been determined experimentallyat temperatures ranging from 298.15 to 318.15 K at 5 K intervals.Complete phase diagrams were obtained by determining solubility andthe tie-line data. Tie-line compositions were correlated byOthmer-Tobias method. The universal quasichemical functional groupactivity coefficient (UNIFAC) and modified UNIFAC methods were usedto predict the phase equilibrium in the system using the interactionparameters deter- Mined from experimental data between groups CH_3,CH_2, OH, CH_3 COO and H_2O.展开更多
The vapor-liquid equilibrium data of four binary systems (acetic acid +p-xylene, methyl acetate +n-propyl acetate, n-propyl acetate +p-xylene and methyl acetate +p-xylene) are measured at 101.33 kPa with Ellis equilib...The vapor-liquid equilibrium data of four binary systems (acetic acid +p-xylene, methyl acetate +n-propyl acetate, n-propyl acetate +p-xylene and methyl acetate +p-xylene) are measured at 101.33 kPa with Ellis equilibrium still, and then both the NRTL and UNIQUAC models are used in combination with the HOC model for correlating and estimating the vapor-liquid equilibrium of these four binary systems. The estimated binary VLE results using correlated parameters agree well with the measured data except the methyl acetate +p-xylene system which easily causes bumping and liquid rushing out of the sampling tap due to their dramatically different boiling points. The correlation results by NRTL and UNIQUAC models have little difference on the average absolute deviations of temperature and composition of vapor phase, and the results by NRTL model are slightly better than those by UNIQUAC model except for the methyl acetate +n-propyl acetate system, for which the latter gives more accurate correlations.展开更多
Conventional Pd/γ-A12O3 methane sensors are easily poisoned in a sulfur-containing atmosphere, with a subsequent decrease in sensitivity and the working life of methane sensors. We mainly investigated the effect of n...Conventional Pd/γ-A12O3 methane sensors are easily poisoned in a sulfur-containing atmosphere, with a subsequent decrease in sensitivity and the working life of methane sensors. We mainly investigated the effect of nanotechnology and a cerium co-catalyst on the stability and anti-sulfur performance of methane sensors. In our experiment, an anti-sulfur methane sensor was prepared by immersing cerium-containing γ-alumina nanometer elements into a Pt-Pd bimetallic nanometer catalyst. The experi- ment about the sensitivity and stability performance of different catalytic methane sensors indicate that sensitivity, decreased by catalyst sulfur poisoning, is improved significantly by adding cerium to the vector. As well, the long-term operational stability of methane sensors increased significantly.展开更多
文摘The coordination reactions of Cu(Ⅱ) and Ni(Ⅱ) with acid alizarine blue B (AABB) in the presence of cetyltrimethylammonium bromide (CTAB) micelle were investigated using the microsurface adsorptionspectral correction technique (MSASC). The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu(Ⅱ) or Ni(Ⅱ)and AABB. The binding ratio of AABB to CTAB was 1:2.5, and monomeric aggregate, AABB2CTAB5, was formed with an adsorption constant of 5.95×10^5 at 20 ℃ or 2.48×10^5 at 40 ℃. In the ternary complexation, the ratio of AABB:Cu and AABB:Ni were 1:1 and 1:2.5, respectively. Two types of aggregates, Cu2.AABB2·CTAB80 and Ni5.AABB2.CTAB80, were formed.
基金Project (No. PSF/Res/P-AU/Bio (246)) supported by Pakistan Sci-ence Foundation (PSF)
文摘Infectious bursal disease virus (IBDV) was inactivated by two different chemicals—formaldehyde and binary ethylenimine (BEI). Formaldehyde was used at 0.1% and 0.2%, while BEI was used at concentrations of 0.001 and 0.002 mol/L. These four vaccines were tested for their efficiency in generating humoral immune response in different groups of broiler chicks. Both BEI-inactivated vaccines gave relatively higher antibody titers and were almost twice as efficient as formaldehyde-inactivated ones.
基金Supported by the China Petrochemical Corporation.
文摘The vapor-liquid equilibrium (VLE) data for the dimethyl carbonate-n-butyl acetate binary system were measured by an Ellis equilibrated distillator. The experimental data were checked for their thermodynamic consistency through statistical methods. The VLE data was correlated with Wilson and NRTL activity coefficient models and also with the calculation of the vapor phase fugacity coefficient by the modified Peng-Robinson equation of state.
基金Supported by the National Natural Science Foundation of China (20476025, 20776040), Shanghai Municipal Science and Technology Commission of China (05DJ14002) and Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology of China (XLHX2007002).
文摘Viscosities and densities for 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) and N, N-dimethylformamide (DMF) binary mixtures have been measured at the temperature range from 293.15 K to 318.15 K. It is shown that the viscosities and densities decrease monotonously with temperature and the content of DMF. Various correlation methods including Arrhenius-like equation, Sedclon et al.'s equation, Redlich-Kister equation with four parameters, and other empirical equations were applied to evaluate these experimental data. A model based on an equation of state Ior estimating the viscosity of mixtures containing ionic liquids were proposed by coupling with the excess Gibbs free energy model of viscosity, which can synchronously calculate the viscosity and the molar volume. The results show that the model gives a deviation of 8.29% for the viscosity, and a deviation of 1.05% for the molar volume when only one temperature-independent adjustable parameter is adopted. The correlation accuracy is further improved when two parameters or one temperature-dependent parameter is used.
基金supported by the National Key R&D Program of China (No.2018YFB1501404)
文摘This work proved that biomass-based polyols (sorbitol, xylitol, erythritol, glycerol and ethanediol) were able to be converted into high-value chemical (p-xylene) by catalytic cracking of polyols, alkylation of aromatics, and the isomerization of xylenes over the SiO2-modified zeolites. Compared to the conventional HZSM-5 zeolite, the SiO2-containing zeolites considerably increased the selectivity and yield of p-xylene due to the reduction of external surface acidity and the narrowing of pore entrance. The influences of the methanol additive, reaction temperature, and types of polyols on the selectivity and yield of p-xylene were investigated in detail. Catalytic cracking of polyols with methanol significantly enhanced the production of p-xylene by the alkylation of toluene with methanol. The highest p-xylene yield of 10.9 C-mol% with a p-xylene/xylenes ratio of 91.1% was obtained over the 15wt%SiO2/HZSM-5 catalyst. The reaction pathway for the formation of p-xylene was addressed according to the study of the key reactions and the characterization of catalysts.
基金Supported by the Project of the Science&Technology New Star of Pearl River in Guangzhou(2011J2200056)the Fundamental Research Funds for the Central Universities,SCUT(2014ZZ0057,2015ZM046)the National Natural Science Foundation of China(20906028,21506066)
文摘Liquid-liquid equilibrium (LLE) data for the ternary system 2-methoxy-2-methylpropane (methyl tert-butyl ether) + p-cresol + water was measured at atmospheric pressure and temperatures of 298.15 K and 313.15 K. From the distribution coefficients and selectivity, it was found that 2-methoxy-2-methylpropane is an efficient solvent to extract p-cresol from wastewater. The consistency of the experimental tie-line data was verified with the Hand and Bachman equations. These data were also correlated with the non-random two liquid (NRTL) and universal quasi-chemical correlation activity coefficient (UN1QUAC) models to yield binary interac- tion parameters for p-cresol extraction process evaluation. Both models agreed with experiments very well, yet the NRTL model showed even smaller average deviation than the UNIQUAC model.
基金Supported by the Natural Science Foundation of Jiangxi Province(No.0020019).
文摘Vapor-liquid equilibrium (VLE) for a ternary system of methyldichlorosilane + methylvinyldichlorosi-lane + toluene and constituent binary systems were measured at 101.3kPa using a new type of magnetical pump-ebulliometer. The equilibrium compositions of the vapor phase of binary systems were calculated indirectly from the total pressure-temperature-liquid composition (pTx). The experimental data were correlated with the Wilson and NRTL(non-random two liquid) equations. The parameters of the Wilson model were employed to predict the ternary VLE data. The calculated boiling points were in good agreement with the experimental ones.
基金partially supported by Zhejiang provincial government(under grant No. 2004C31G2010019)Hangzhou municipalgovernment (under grant No. 20051321B14)
文摘Based on a special catalyst and fiber Bragg gratings (FBGs), an optical sensing system is proposed to measure the concen- tration of methane. The temperature of the catalyst rises rapidly as the concentration of methane increases, and hence it can be detected by an FBG-type sensor through monitoring the wavelength shift of the reflection spectrum. The experimental results show the good performances of our system, such as the high resolution and temperature stability.
文摘Liquid-liquid equilibrium (LLE) data for the ternary systemwater-ethanol-dimethyl succinate have been determined experimentallyat temperatures ranging from 298.15 to 318.15 K at 5 K intervals.Complete phase diagrams were obtained by determining solubility andthe tie-line data. Tie-line compositions were correlated byOthmer-Tobias method. The universal quasichemical functional groupactivity coefficient (UNIFAC) and modified UNIFAC methods were usedto predict the phase equilibrium in the system using the interactionparameters deter- Mined from experimental data between groups CH_3,CH_2, OH, CH_3 COO and H_2O.
基金Supported by the Major State Basic Research Development Program of China (2012CB720500), the National Natural Science Foundation of China (U1162202, 61174118) and the Shanghai Leading Academic Discipline Project (B504).
文摘The vapor-liquid equilibrium data of four binary systems (acetic acid +p-xylene, methyl acetate +n-propyl acetate, n-propyl acetate +p-xylene and methyl acetate +p-xylene) are measured at 101.33 kPa with Ellis equilibrium still, and then both the NRTL and UNIQUAC models are used in combination with the HOC model for correlating and estimating the vapor-liquid equilibrium of these four binary systems. The estimated binary VLE results using correlated parameters agree well with the measured data except the methyl acetate +p-xylene system which easily causes bumping and liquid rushing out of the sampling tap due to their dramatically different boiling points. The correlation results by NRTL and UNIQUAC models have little difference on the average absolute deviations of temperature and composition of vapor phase, and the results by NRTL model are slightly better than those by UNIQUAC model except for the methyl acetate +n-propyl acetate system, for which the latter gives more accurate correlations.
基金support for this work, provided by the National Natural Science Foundation of China (No60910005)
文摘Conventional Pd/γ-A12O3 methane sensors are easily poisoned in a sulfur-containing atmosphere, with a subsequent decrease in sensitivity and the working life of methane sensors. We mainly investigated the effect of nanotechnology and a cerium co-catalyst on the stability and anti-sulfur performance of methane sensors. In our experiment, an anti-sulfur methane sensor was prepared by immersing cerium-containing γ-alumina nanometer elements into a Pt-Pd bimetallic nanometer catalyst. The experi- ment about the sensitivity and stability performance of different catalytic methane sensors indicate that sensitivity, decreased by catalyst sulfur poisoning, is improved significantly by adding cerium to the vector. As well, the long-term operational stability of methane sensors increased significantly.