In this paper, an identification method to estimate the unbalances is introduced, which is based on the boundary element method (BEM). By using the vibration response measured at some points on the flexible rotor the ...In this paper, an identification method to estimate the unbalances is introduced, which is based on the boundary element method (BEM). By using the vibration response measured at some points on the flexible rotor the unbalances can be identified conveniently. Therefore, the rotor can be balanced without test runs.展开更多
The phase equilibria and compositions in Mg-rich side at 300 ℃ were investigated in Mg-Zn-Ca ternary system through the equilibrated alloy method by using scanning electron microscopy,electron probe microanalysis,X-r...The phase equilibria and compositions in Mg-rich side at 300 ℃ were investigated in Mg-Zn-Ca ternary system through the equilibrated alloy method by using scanning electron microscopy,electron probe microanalysis,X-ray diffraction and transmission electron microscopy.The results show that two ternary compounds T1 and T2 can be in equilibrium with the Mg-based solid solution in Mg-Zn-Ca system.T1 phase is a linear compound with the composition region(molar fraction) of 15% Ca,20.5%-48.9% Zn and balanced Mg at 300 ℃.Its hexagonal structure parameters decrease with increasing Zn content,i.e.a=0.992-0.945 nm,c=1.034-1.003 nm.T2 phase has hexagonal structure with the composition region of 26.4%-28.4% Mg,63.2%-65.5% Zn and 7.1%-8.4% Ca.At 300 ℃,the solubility of Zn in the Mg-based solid solution increases for the addition of Ca,the maximum solubility of Zn is 3.7%.Three-phase fields consisting of--Mg+Mg2Ca+T1,--Mg+T1+T2,--Mg+T2+MgZn and MgZn+T2+Mg2Zn3 exist in the Mg-Zn-Ca system at 300 ℃.展开更多
Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis (EPMA). Experimental results sho...Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis (EPMA). Experimental results show that there is a solid solutionβ(Ti,Zr) which dissolves Al up to 16.3% (mole fraction). Ti and Zr can substitute each other in most Ti-Al and Al-Zr binaryintermediate phases to a certain degree while the maximum solubility of Zr in Ti3Al and TiAl reaches up to 17.9% and 4.0% (molefraction), respectively. The isothermal section consists of 16 single-phased regions, 27 two-phased regions and 14 three-phasedregions. No ternary phase was detected.展开更多
A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square ...A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square well potential for intermolecular interaction is used. With pairwise combination rules for these potentials three adjustable parameters are needed. The experimental critical point and phase equilibrium data are compared with the values predicted using the equation of state. Good agreement is obtained for the analysis of the critical pressure composition data and molar volumes.展开更多
Adsorption equilibrium isotherms of benzene in the concentrationrange of 500-4000 mg·m^-3 on two commercial activated carbons wereobtained using long-column method under 30 deg. C and differenthumidity condi- tio...Adsorption equilibrium isotherms of benzene in the concentrationrange of 500-4000 mg·m^-3 on two commercial activated carbons wereobtained using long-column method under 30 deg. C and differenthumidity condi- tions. Results show that the benzene and water vaporshave depression effects upon the adsorption of each other and thatthe unfavorable effect of water vapor resembles its single-componentisotherm on activated carbon. A com- petitive adsorption model wasproposed to explore the depression mechanisms of the non-ideal,non-similar binary adsorption systems.展开更多
The discrete element method (DEM) was used to simulate the flow characteristic and strength characteristic of the conditioned sands in the earth pressure balance (EPB) tunneling. In the laboratory the conditioned sand...The discrete element method (DEM) was used to simulate the flow characteristic and strength characteristic of the conditioned sands in the earth pressure balance (EPB) tunneling. In the laboratory the conditioned sands were reproduced and the slump test and the direct shear test of the conditioned sands were implemented. A DEM equivalent model that can simulate the macro mechanical characteristic of the conditioned sands was proposed,and the corresponding numerical models of the slump test and the shear test were established. By selecting proper DEM model parameters,the errors of the slump values between the simulation results and the test results are in the range of 10.3%-14.3%,and the error of the curves between the shear displacement and the shear stress calculated with the DEM simulation is 4.68%-16.5% compared with that of the laboratory direct shear test. This illustrates that the proposed DEM equivalent model can approximately simulate the mechanical characteristics of the conditioned sands,which provides the basis for further simulation of the interaction between the conditioned soil and the chamber pressure system of the EPB machine.展开更多
The pseudo-ternary system(Na Cl + Na_2SO_4+ H_2O) of coal gasification wastewater was studied at T =(268.15 to 373.15) K. The solubility and density of the equilibrium liquid phase were determined by the isothermal so...The pseudo-ternary system(Na Cl + Na_2SO_4+ H_2O) of coal gasification wastewater was studied at T =(268.15 to 373.15) K. The solubility and density of the equilibrium liquid phase were determined by the isothermal solution saturation method. The equilibrium solids were also investigated by the Schreinemaker's method of wet residues and X-ray powder diffraction(XRD). According to the experimental data, the phase diagrams were determined. It was found that there was no significant solubility difference on the Na Cl-rich side between the ternary system(Na Cl + Na_2SO_4+ H_2O) in coal gasification wastewater and in pure water. However, the solubility on the Na_2SO_4-rich side of coal gasification wastewater was apparently higher than that of pure water. The increase in the solubility of Na_2SO_4 was most likely caused by the effects of other impurities apart from Na Cl and Na_2SO_4 in coal gasification wastewater. The measured data and phase equilibrium diagrams can provide fundamental basis for salt recovery in coal gasification wastewater.展开更多
Based on the principle of energy conservation,the applicable technique for drained cell retrofitted from conventional one was analyzed with 2D finite element model. The model employed a 1D heat transfer scheme to comp...Based on the principle of energy conservation,the applicable technique for drained cell retrofitted from conventional one was analyzed with 2D finite element model. The model employed a 1D heat transfer scheme to compute iteratively the freeze profile until the thickness variable reached the terminating requirement. The calculated 2D heat dissipation from the cell surfaces was converted into the overall 3D heat loss. The potential drop of the system, freeze profile and heat balance were analyzed to evaluate their variation with technical parameters when designing the 150 kA conventional cell based drained cell. The simulation results show that the retrofitted drained cell is able to keep thermal balance under the conditions that the current is 190 kA, the anodic current density is 0.96 A/cm2, the anode-cathode distance is 2.5 cm, the alumina cover is 16 cm thick with a thermal conductivity of 0.20 W/(m·℃ ) and the electrolysis temperature is 946 ℃ .展开更多
The rotor with bending faults that occurrs on the rotating machinery usually vibrates seriously. This paper investigates to apply the active balancing device on a flexible rotor with bending faults to solve the vibrat...The rotor with bending faults that occurrs on the rotating machinery usually vibrates seriously. This paper investigates to apply the active balancing device on a flexible rotor with bending faults to solve the vibration problem. Two problems are studied by finite element method firstly: Where the balance actuator is fixed on the shaft and how much the balancing capacity of the active balancing device is needed. The experiment is then carried out on the test rig, which consists of a flexible rotor with bending faults. The test results indicate that the bending rotor peak vibration response can be decreased from 550~m to 40~tm below by using the active balancing device. The peak vibration response decreases approximately by 93 %. The synchronous vibration due to the rotor bending faults can be controlled effectively by using ac- tive balancing device. The active balancing device is especially adapted to solve the problem caused by thermal distortion with time-variation and randomness, which is varied with working conditions, thus it has good practical value in practice.展开更多
Traditional rigid body limit equilibrium method (RBLEM) was adopted for the stability evaluation and analysis of rock slope under earthquake scenario. It is not able to provide the real stress distribution of the st...Traditional rigid body limit equilibrium method (RBLEM) was adopted for the stability evaluation and analysis of rock slope under earthquake scenario. It is not able to provide the real stress distribution of the structure, while the strength reduction method relies on the arbitrary decision on the failure criteria. The dynamic limit equilibrium solution was proposed for the stability analysis of sliding block based on 3-D multi-grid method, by incorporating implicit stepping integration FEM. There are two independent meshes created in the analysis: One original 3-D FEM mesh is for the simulation of target structure and provides the stress time-history, while the other surface grid is for the simulation of sliding surface and could be selected and designed freely. As long as the stress time-history of the geotechnical structure under earthquake scenario is obtained based on 3-D nonlinear dynamic FEM analysis, the time-history of the force on sliding surface could be derived by projecting the stress time-history from 3-D FEM mesh to surface grid. After that, the safety factor time-history of the sliding block will be determined through applying limit equilibrium method. With those information in place, the structure's aseismatic stability ean be further studied. The above theory and method were also applied to the aseismatic stability analysis of Dagangshan arch dam's right bank high slope and compared with the the result generated by Quasi-static method. The comparative analysis reveals that the method not only raises the FEM's capability in accurate simulation of complicated geologic structure, but also increases the flexibility and comprehensiveness of limit equilibrium method. This method is reliable and recommended for further application in other real geotechnical engineering.展开更多
The element partitioning in a Pb-Bi concentrate oxygen-rich bath smelting process was studied using thermodynamic equilibrium simulation method. Effects of oxygen to feed ratio(OFR) and sulfur dioxide partial pressure...The element partitioning in a Pb-Bi concentrate oxygen-rich bath smelting process was studied using thermodynamic equilibrium simulation method. Effects of oxygen to feed ratio(OFR) and sulfur dioxide partial pressure(pSO2) on the partitionings of Bi, Pb, As, Sb, Cu and Ag were analyzed and compared with industrial data. The results suggested that the optimal OFR was between 6.3 and 6.8 kmol/t to maximize Bi, Pb, Cu and Ag partitioning in the metal phase. Further increase of OFR led to the drop of metal partitioning and increase of slag liquidus temperature. High pSO2 led to high deportment of Bi and Pb in the gas phase mainly in the form of sulfides, suggesting that a low pSO2 was conducive for reducing the dust ratio.展开更多
In this paper, a back propagation artificial neural network (BP-ANN) model is presented for the simultaneous estimation of vapour liquid equilibria (VLE) of four binary systems viz chlorodifluoromethan-carbondioxi...In this paper, a back propagation artificial neural network (BP-ANN) model is presented for the simultaneous estimation of vapour liquid equilibria (VLE) of four binary systems viz chlorodifluoromethan-carbondioxide, trifluoromethan-carbondioxide, carbondisulfied-trifluoromethan and carbondisulfied-chlorodifluoromethan. VLE data of the systems were taken from the literature for wide ranges of temperature (222.04-343.23K) and pressure (0.105 to 7.46MPa). BP-ANN trained by the Levenberg-Marquardt algorithm in the MATLAB neural network toolbox was used for building and optimizing the model. It is shown that the established model could estimate the VLE with satisfactory precision and accuracy for the four systems with the root mean square error in the range of 0.054-0.119. Predictions using BP-ANN were compared with the conventional Redlich-Kwang-Soave (RKS) equation of state, suggesting that BP-ANN has better ability in estimation as compared with the RKS equation (the root mean square error in the range of 0.115-0.1546).展开更多
Vapor-liquid equilibrium(VLE) data were measured for ternary system water + ethanol + 1-butyl-3methylimidazolium acetate([bmim][OAc]),in a relatively wide range of ionic liquid(IL) mass fractions up to 0.8.Six sets of...Vapor-liquid equilibrium(VLE) data were measured for ternary system water + ethanol + 1-butyl-3methylimidazolium acetate([bmim][OAc]),in a relatively wide range of ionic liquid(IL) mass fractions up to 0.8.Six sets of complete T-x-y data were obtained,in which the mole fraction of ethanol on IL-free basis was fixed separately at 0.1,0.2,0.4,0.6,0.8,and approximate 0.98.The non-random-two-liquid(NRTL) and electrolyte non-random-two-liquid(eNRTL) equations were used for correlation,showing similar deviations.The ternary VLE was also modeled with the correlation from two data sets,with the mole fractions of ethanol on IL-free basis being 0.1 and approximate 0.98.The VLE data were also reproduced satisfactorily.With the eNRTL model,the root-mean-square deviation for temperature is 0.79 K and that for vapor-phase mole fraction is 0.0094.The calculations are in good agreement with experimental data.The effect of the IL on the VLE behavior of the volatile components is also illustrated.展开更多
Using a laser observation technique,the solubilities of trans-1,2-cyclohexanediol in butyl acetate+wa- ter were measured at the temperature range from 298.15K to 323.15K by a synthetic method at atmospheric pres- sure...Using a laser observation technique,the solubilities of trans-1,2-cyclohexanediol in butyl acetate+wa- ter were measured at the temperature range from 298.15K to 323.15K by a synthetic method at atmospheric pres- sure.It is shown that the solubilities of trans-1,2-cyclohexanediol in butyl acetate+water were affected greatly by the proportion of butyl acetate and water,and presented maximum value at given temperature.The UNIFAC model was used to correlate the experimental data.The average relative deviation(ARD)between experimental and calculated values is 3.03%.展开更多
Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffrac...Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffraction(XRD)techniques,isothermal sections at 1073 and 1173 K of this system were constructed and existence of ternary phase Ti2(Ni,Pt)3 was confirmed.In addition,binary compounds Ti3Pt5 and TiPt3-were found to be stable at 1073 and 1173 K,and remarkable ternary solubility in some binary compounds was detected,e.g.,solubility of Pt in TiNi can be up to about 36%(molar fraction)at 1073 K and 40%(molar fraction)at 1173 K.Furthermore,a ternary invariant transition reaction TiNi3+Ti3Pt5→Ti2(Ni,Pt)3+TiPt3+at a temperature between 1073 and 1173 K was deduced.展开更多
In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery (ECBM) with CO2 injection into coal, we inve...In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery (ECBM) with CO2 injection into coal, we investigated the preferential adsorption of CH4 and CO2 on coals. Adsorption of pure CO2, CH4 and their binary mixtures on high-rank coals from Qinshui Basin in China were employed to study the preferential adsorption behaviour. Multiple regression equations were presented to predict CH4 equi- librium concentration from equilibrium pressure and its initial-composition in feed gas. The results show that preferential adsorption of CO2 on coals over the entire pressure range under competitive sorption conditions was observed, however, preferential adsorption of CH4 over CO2 on low-volatile bituminous coal from higher CH4-compostion in source gas was found at up to 1O MPa pressure. Preferential adsorp- tion of CO2 increases with increase of CH4 concentration in source gas, and decreases with increasing pressure. Although there was no systematic investigation of the effect of coal rank on preferential adsorp- tion, there are obvious differences in preferential adsorption of gas between low-volatile bituminous coal and anthracite. The obtained preferential adsorption gives rise to the assumption that CO2 sequestration in coal beds with subsequent CO2-ECBM might be an ootion in Qinshui Basins, China.展开更多
Liquid-liquid equilibrium (LLE) data for the ternary systemwater-ethanol-dimethyl succinate have been determined experimentallyat temperatures ranging from 298.15 to 318.15 K at 5 K intervals.Complete phase diagrams w...Liquid-liquid equilibrium (LLE) data for the ternary systemwater-ethanol-dimethyl succinate have been determined experimentallyat temperatures ranging from 298.15 to 318.15 K at 5 K intervals.Complete phase diagrams were obtained by determining solubility andthe tie-line data. Tie-line compositions were correlated byOthmer-Tobias method. The universal quasichemical functional groupactivity coefficient (UNIFAC) and modified UNIFAC methods were usedto predict the phase equilibrium in the system using the interactionparameters deter- Mined from experimental data between groups CH_3,CH_2, OH, CH_3 COO and H_2O.展开更多
Rotating machines are very sensitive to mass unbalance which has a harmful effect on its running accuracy and service life. Therefore,a variety of dynamic balancing methods and devices are studied to reduce the vibrat...Rotating machines are very sensitive to mass unbalance which has a harmful effect on its running accuracy and service life. Therefore,a variety of dynamic balancing methods and devices are studied to reduce the vibration caused by mass unbalance. On-line active balancing is a new balancing procedure which is more convenient and precise than the previous methods. In this paper,an electromagnetic balancer based on ring coils and permanent magnets is presented. The balancer has a simple structure and the self-locking function without clutch,and transfers power by the non-contact electromagnetic field. In order to justify the rationality of its design,a two-dimension(2D) electromagnetic finite element model is conducted to verify that this magnetic circuit has no flux leakage and saturation. A three-dimension (3D) 1/10 model of the balancer is built to obtain the self-locking torque and driving torque. Based on the research work above,an electromagnetic balancer is developed. By testing the balancer using COCO80,it is verified effective to reduce the rotor unbalance at the speed of 1300 r/min.展开更多
文摘In this paper, an identification method to estimate the unbalances is introduced, which is based on the boundary element method (BEM). By using the vibration response measured at some points on the flexible rotor the unbalances can be identified conveniently. Therefore, the rotor can be balanced without test runs.
基金Project(50731002) supported by the National Natural Science Foundation of ChinaProject(20082030) supported by the Natural Science Foundation of Liaoning Province,China
文摘The phase equilibria and compositions in Mg-rich side at 300 ℃ were investigated in Mg-Zn-Ca ternary system through the equilibrated alloy method by using scanning electron microscopy,electron probe microanalysis,X-ray diffraction and transmission electron microscopy.The results show that two ternary compounds T1 and T2 can be in equilibrium with the Mg-based solid solution in Mg-Zn-Ca system.T1 phase is a linear compound with the composition region(molar fraction) of 15% Ca,20.5%-48.9% Zn and balanced Mg at 300 ℃.Its hexagonal structure parameters decrease with increasing Zn content,i.e.a=0.992-0.945 nm,c=1.034-1.003 nm.T2 phase has hexagonal structure with the composition region of 26.4%-28.4% Mg,63.2%-65.5% Zn and 7.1%-8.4% Ca.At 300 ℃,the solubility of Zn in the Mg-based solid solution increases for the addition of Ca,the maximum solubility of Zn is 3.7%.Three-phase fields consisting of--Mg+Mg2Ca+T1,--Mg+T1+T2,--Mg+T2+MgZn and MgZn+T2+Mg2Zn3 exist in the Mg-Zn-Ca system at 300 ℃.
基金Project(51171210)supported by the National Natural Science Foundation of ChinaProject(2014CB6644002)supported by the Major State Basic Research Development Program of China
文摘Through alloy sampling combined with diffusion triple technique, phase equilibria in Al-Ti-Zr ternary system at 1073 Kwere experimentally determined with electron probe microanalysis (EPMA). Experimental results show that there is a solid solutionβ(Ti,Zr) which dissolves Al up to 16.3% (mole fraction). Ti and Zr can substitute each other in most Ti-Al and Al-Zr binaryintermediate phases to a certain degree while the maximum solubility of Zr in Ti3Al and TiAl reaches up to 17.9% and 4.0% (molefraction), respectively. The isothermal section consists of 16 single-phased regions, 27 two-phased regions and 14 three-phasedregions. No ternary phase was detected.
文摘A rational equation of state of the perturbation type with a repulsion and attraction term has been applied to reproduce critical curves of six different binary systems up to high temperatures and pressures. A square well potential for intermolecular interaction is used. With pairwise combination rules for these potentials three adjustable parameters are needed. The experimental critical point and phase equilibrium data are compared with the values predicted using the equation of state. Good agreement is obtained for the analysis of the critical pressure composition data and molar volumes.
文摘Adsorption equilibrium isotherms of benzene in the concentrationrange of 500-4000 mg·m^-3 on two commercial activated carbons wereobtained using long-column method under 30 deg. C and differenthumidity condi- tions. Results show that the benzene and water vaporshave depression effects upon the adsorption of each other and thatthe unfavorable effect of water vapor resembles its single-componentisotherm on activated carbon. A com- petitive adsorption model wasproposed to explore the depression mechanisms of the non-ideal,non-similar binary adsorption systems.
基金Project (2007CB714006) supported by the National Basic Research Program of China
文摘The discrete element method (DEM) was used to simulate the flow characteristic and strength characteristic of the conditioned sands in the earth pressure balance (EPB) tunneling. In the laboratory the conditioned sands were reproduced and the slump test and the direct shear test of the conditioned sands were implemented. A DEM equivalent model that can simulate the macro mechanical characteristic of the conditioned sands was proposed,and the corresponding numerical models of the slump test and the shear test were established. By selecting proper DEM model parameters,the errors of the slump values between the simulation results and the test results are in the range of 10.3%-14.3%,and the error of the curves between the shear displacement and the shear stress calculated with the DEM simulation is 4.68%-16.5% compared with that of the laboratory direct shear test. This illustrates that the proposed DEM equivalent model can approximately simulate the mechanical characteristics of the conditioned sands,which provides the basis for further simulation of the interaction between the conditioned soil and the chamber pressure system of the EPB machine.
基金Supported by the National Key Research and Development Program of China(2016YFB0600504)
文摘The pseudo-ternary system(Na Cl + Na_2SO_4+ H_2O) of coal gasification wastewater was studied at T =(268.15 to 373.15) K. The solubility and density of the equilibrium liquid phase were determined by the isothermal solution saturation method. The equilibrium solids were also investigated by the Schreinemaker's method of wet residues and X-ray powder diffraction(XRD). According to the experimental data, the phase diagrams were determined. It was found that there was no significant solubility difference on the Na Cl-rich side between the ternary system(Na Cl + Na_2SO_4+ H_2O) in coal gasification wastewater and in pure water. However, the solubility on the Na_2SO_4-rich side of coal gasification wastewater was apparently higher than that of pure water. The increase in the solubility of Na_2SO_4 was most likely caused by the effects of other impurities apart from Na Cl and Na_2SO_4 in coal gasification wastewater. The measured data and phase equilibrium diagrams can provide fundamental basis for salt recovery in coal gasification wastewater.
基金Projects(50374081 60634020) supported by the National Natural Science Foundation of China
文摘Based on the principle of energy conservation,the applicable technique for drained cell retrofitted from conventional one was analyzed with 2D finite element model. The model employed a 1D heat transfer scheme to compute iteratively the freeze profile until the thickness variable reached the terminating requirement. The calculated 2D heat dissipation from the cell surfaces was converted into the overall 3D heat loss. The potential drop of the system, freeze profile and heat balance were analyzed to evaluate their variation with technical parameters when designing the 150 kA conventional cell based drained cell. The simulation results show that the retrofitted drained cell is able to keep thermal balance under the conditions that the current is 190 kA, the anodic current density is 0.96 A/cm2, the anode-cathode distance is 2.5 cm, the alumina cover is 16 cm thick with a thermal conductivity of 0.20 W/(m·℃ ) and the electrolysis temperature is 946 ℃ .
基金Supported by the National Natural Science Foundation of China under Plaffoma ( No. 50375013 and 50375014) and Key Research Item of Ministry of Education of China under Plafform ( No. 03024).
文摘The rotor with bending faults that occurrs on the rotating machinery usually vibrates seriously. This paper investigates to apply the active balancing device on a flexible rotor with bending faults to solve the vibration problem. Two problems are studied by finite element method firstly: Where the balance actuator is fixed on the shaft and how much the balancing capacity of the active balancing device is needed. The experiment is then carried out on the test rig, which consists of a flexible rotor with bending faults. The test results indicate that the bending rotor peak vibration response can be decreased from 550~m to 40~tm below by using the active balancing device. The peak vibration response decreases approximately by 93 %. The synchronous vibration due to the rotor bending faults can be controlled effectively by using ac- tive balancing device. The active balancing device is especially adapted to solve the problem caused by thermal distortion with time-variation and randomness, which is varied with working conditions, thus it has good practical value in practice.
基金Project(2013-KY-2) supported by the State Key Laboratory of Hydroscience and Engineering of Hydroscience, ChinaProject(50925931)supported by the National Funds for Distinguished Young Scientists, China
文摘Traditional rigid body limit equilibrium method (RBLEM) was adopted for the stability evaluation and analysis of rock slope under earthquake scenario. It is not able to provide the real stress distribution of the structure, while the strength reduction method relies on the arbitrary decision on the failure criteria. The dynamic limit equilibrium solution was proposed for the stability analysis of sliding block based on 3-D multi-grid method, by incorporating implicit stepping integration FEM. There are two independent meshes created in the analysis: One original 3-D FEM mesh is for the simulation of target structure and provides the stress time-history, while the other surface grid is for the simulation of sliding surface and could be selected and designed freely. As long as the stress time-history of the geotechnical structure under earthquake scenario is obtained based on 3-D nonlinear dynamic FEM analysis, the time-history of the force on sliding surface could be derived by projecting the stress time-history from 3-D FEM mesh to surface grid. After that, the safety factor time-history of the sliding block will be determined through applying limit equilibrium method. With those information in place, the structure's aseismatic stability ean be further studied. The above theory and method were also applied to the aseismatic stability analysis of Dagangshan arch dam's right bank high slope and compared with the the result generated by Quasi-static method. The comparative analysis reveals that the method not only raises the FEM's capability in accurate simulation of complicated geologic structure, but also increases the flexibility and comprehensiveness of limit equilibrium method. This method is reliable and recommended for further application in other real geotechnical engineering.
基金financial supports from the National Key R&D Program of China (2018YFC1901604)the Natural Science Foundation of Hunan Province,China (2018JJ3662)+1 种基金the China Scholarship Council (201706375005)the China Postdoctoral Science Foundation (2018M632988)。
文摘The element partitioning in a Pb-Bi concentrate oxygen-rich bath smelting process was studied using thermodynamic equilibrium simulation method. Effects of oxygen to feed ratio(OFR) and sulfur dioxide partial pressure(pSO2) on the partitionings of Bi, Pb, As, Sb, Cu and Ag were analyzed and compared with industrial data. The results suggested that the optimal OFR was between 6.3 and 6.8 kmol/t to maximize Bi, Pb, Cu and Ag partitioning in the metal phase. Further increase of OFR led to the drop of metal partitioning and increase of slag liquidus temperature. High pSO2 led to high deportment of Bi and Pb in the gas phase mainly in the form of sulfides, suggesting that a low pSO2 was conducive for reducing the dust ratio.
文摘In this paper, a back propagation artificial neural network (BP-ANN) model is presented for the simultaneous estimation of vapour liquid equilibria (VLE) of four binary systems viz chlorodifluoromethan-carbondioxide, trifluoromethan-carbondioxide, carbondisulfied-trifluoromethan and carbondisulfied-chlorodifluoromethan. VLE data of the systems were taken from the literature for wide ranges of temperature (222.04-343.23K) and pressure (0.105 to 7.46MPa). BP-ANN trained by the Levenberg-Marquardt algorithm in the MATLAB neural network toolbox was used for building and optimizing the model. It is shown that the established model could estimate the VLE with satisfactory precision and accuracy for the four systems with the root mean square error in the range of 0.054-0.119. Predictions using BP-ANN were compared with the conventional Redlich-Kwang-Soave (RKS) equation of state, suggesting that BP-ANN has better ability in estimation as compared with the RKS equation (the root mean square error in the range of 0.115-0.1546).
基金Supported by the National Natural Science Foundation of China (20776132)
文摘Vapor-liquid equilibrium(VLE) data were measured for ternary system water + ethanol + 1-butyl-3methylimidazolium acetate([bmim][OAc]),in a relatively wide range of ionic liquid(IL) mass fractions up to 0.8.Six sets of complete T-x-y data were obtained,in which the mole fraction of ethanol on IL-free basis was fixed separately at 0.1,0.2,0.4,0.6,0.8,and approximate 0.98.The non-random-two-liquid(NRTL) and electrolyte non-random-two-liquid(eNRTL) equations were used for correlation,showing similar deviations.The ternary VLE was also modeled with the correlation from two data sets,with the mole fractions of ethanol on IL-free basis being 0.1 and approximate 0.98.The VLE data were also reproduced satisfactorily.With the eNRTL model,the root-mean-square deviation for temperature is 0.79 K and that for vapor-phase mole fraction is 0.0094.The calculations are in good agreement with experimental data.The effect of the IL on the VLE behavior of the volatile components is also illustrated.
基金Supported by the Natural Science Foundation of Henan Province (No.0211020800).
文摘Using a laser observation technique,the solubilities of trans-1,2-cyclohexanediol in butyl acetate+wa- ter were measured at the temperature range from 298.15K to 323.15K by a synthetic method at atmospheric pres- sure.It is shown that the solubilities of trans-1,2-cyclohexanediol in butyl acetate+water were affected greatly by the proportion of butyl acetate and water,and presented maximum value at given temperature.The UNIFAC model was used to correlate the experimental data.The average relative deviation(ARD)between experimental and calculated values is 3.03%.
基金Project(2016YFB0701404)supported by the National Key Research and Development Program of ChinaProject(51171210)supported by the National Natural Science Foundation of China
文摘Phase equilibria in Ti?Ni?Pt ternary system have been experimentally determined through diffusion triple technique combined with alloy samples approach.Assisted with electron probe microanalysis(EPMA)and X-ray diffraction(XRD)techniques,isothermal sections at 1073 and 1173 K of this system were constructed and existence of ternary phase Ti2(Ni,Pt)3 was confirmed.In addition,binary compounds Ti3Pt5 and TiPt3-were found to be stable at 1073 and 1173 K,and remarkable ternary solubility in some binary compounds was detected,e.g.,solubility of Pt in TiNi can be up to about 36%(molar fraction)at 1073 K and 40%(molar fraction)at 1173 K.Furthermore,a ternary invariant transition reaction TiNi3+Ti3Pt5→Ti2(Ni,Pt)3+TiPt3+at a temperature between 1073 and 1173 K was deduced.
基金supported by the National Natural Science Foundation of China(Nos.51174127 and 21176145)the Natural Science Foundation of Shandong Province(No.ZR2011DM005)the Open Research Fund Program of Key Laboratory of Mine Disaster Prevention and Control(Shandong University of Science and Technology)(No.MDPC0806)
文摘In order to better understand the prevailing mechanism of CO2 storage in coal and estimate CO2 sequestration capacity of a coal seam and enhanced coalbed methane recovery (ECBM) with CO2 injection into coal, we investigated the preferential adsorption of CH4 and CO2 on coals. Adsorption of pure CO2, CH4 and their binary mixtures on high-rank coals from Qinshui Basin in China were employed to study the preferential adsorption behaviour. Multiple regression equations were presented to predict CH4 equi- librium concentration from equilibrium pressure and its initial-composition in feed gas. The results show that preferential adsorption of CO2 on coals over the entire pressure range under competitive sorption conditions was observed, however, preferential adsorption of CH4 over CO2 on low-volatile bituminous coal from higher CH4-compostion in source gas was found at up to 1O MPa pressure. Preferential adsorp- tion of CO2 increases with increase of CH4 concentration in source gas, and decreases with increasing pressure. Although there was no systematic investigation of the effect of coal rank on preferential adsorp- tion, there are obvious differences in preferential adsorption of gas between low-volatile bituminous coal and anthracite. The obtained preferential adsorption gives rise to the assumption that CO2 sequestration in coal beds with subsequent CO2-ECBM might be an ootion in Qinshui Basins, China.
文摘Liquid-liquid equilibrium (LLE) data for the ternary systemwater-ethanol-dimethyl succinate have been determined experimentallyat temperatures ranging from 298.15 to 318.15 K at 5 K intervals.Complete phase diagrams were obtained by determining solubility andthe tie-line data. Tie-line compositions were correlated byOthmer-Tobias method. The universal quasichemical functional groupactivity coefficient (UNIFAC) and modified UNIFAC methods were usedto predict the phase equilibrium in the system using the interactionparameters deter- Mined from experimental data between groups CH_3,CH_2, OH, CH_3 COO and H_2O.
基金The National Science and Technology Major Project of China(No.2010ZX04012-014)
文摘Rotating machines are very sensitive to mass unbalance which has a harmful effect on its running accuracy and service life. Therefore,a variety of dynamic balancing methods and devices are studied to reduce the vibration caused by mass unbalance. On-line active balancing is a new balancing procedure which is more convenient and precise than the previous methods. In this paper,an electromagnetic balancer based on ring coils and permanent magnets is presented. The balancer has a simple structure and the self-locking function without clutch,and transfers power by the non-contact electromagnetic field. In order to justify the rationality of its design,a two-dimension(2D) electromagnetic finite element model is conducted to verify that this magnetic circuit has no flux leakage and saturation. A three-dimension (3D) 1/10 model of the balancer is built to obtain the self-locking torque and driving torque. Based on the research work above,an electromagnetic balancer is developed. By testing the balancer using COCO80,it is verified effective to reduce the rotor unbalance at the speed of 1300 r/min.