Mixed Ga–Zn oxynitrides were synthesized using coprecipitation, wet-precipitation, and sol-id-solution methods. The oxynitrides were used as supports for Rh nanoparticle catalysts in photo-catalytic water splitting, ...Mixed Ga–Zn oxynitrides were synthesized using coprecipitation, wet-precipitation, and sol-id-solution methods. The oxynitrides were used as supports for Rh nanoparticle catalysts in photo-catalytic water splitting, CO oxidation, and H2 oxidation. Mixed Ga–Zn oxynitrides produced by wet precipitation and nitridation had good visible-light-absorption properties and high surface areas, so they were used to support uniformly sized poly(vinylpyrrolidone)-stabilized Rh nanoparticles. The nanoparticle size range was 2–9 nm. These catalysts had negligible activity in photocatalytic H2 production by water splitting with methanol as a sacrificial agent. Other mixed Ga–Zn oxynitrides were also inactive. A reference sample provided by Domen also showed very low activity. The in-fluence of particle size on Rh-catalyzed oxidation of CO and H2 was investigated. For CO oxidation, the activities of small particles were higher for particles with higher Rh oxidation degrees. The op-posite holds for H2 oxidation.展开更多
A photocatalyst Cu-BiVO4 was synthesized by the hydrothermal method and was characterized by XRD, UV-vis DRS, and N2 adsorption-desorption measurement. The catalytic activity of the Cu-BiVO4 samples was studied on des...A photocatalyst Cu-BiVO4 was synthesized by the hydrothermal method and was characterized by XRD, UV-vis DRS, and N2 adsorption-desorption measurement. The catalytic activity of the Cu-BiVO4 samples was studied on desulfurization of thiophene dissolved in n-octane, which was used as a model light oil, via photocatalytic oxidation reaction under illumination by visible light. The catalyst characterization results indicated that the loading of Cu on the catalyst did not change the crystal phase of BiVO4, and the crystallinity of the Cu-BiVO4 sample was found to be better at pH=7. The Cu-BiVO4 samples presented a significant bathochromic shift of the absorption band in the visible region, and the absorption intensity increased for the composite catalyst. The desulfurization experiments showed that the Cu-BiVO4 sample prepared at a pH value of 7 had a better catalytic activity. Under proper operating conditions, the desulfurization rate of the model compound achieved by Cu-BiVO4 sample prepared at pH=7 could reach as high as 90%.展开更多
O644.1 97053496吩噻嗪在苯和环己烷中的光化学研究=Photochemicalreaction of dibenzothiazine in benzene andcyclohexane[刊,中]/王素华,陈德文,郭建新,王皓(中科院化学所分子动态与稳态结构国家重点实验室.北京(100080))//科学通报....O644.1 97053496吩噻嗪在苯和环己烷中的光化学研究=Photochemicalreaction of dibenzothiazine in benzene andcyclohexane[刊,中]/王素华,陈德文,郭建新,王皓(中科院化学所分子动态与稳态结构国家重点实验室.北京(100080))//科学通报.—1996,41(23).—2159—2161 用ESR方法研究了吩噻嗪在氧化饱和的非极性溶剂苯、环己烷中的光化学行为,并从理论上作了相关计算,这对于探索氧在吩噻嗪的光物理化学过程中的作用有重要意义。图1表1参7(方舟)O644.1展开更多
基金the financial support by the Royal Netherlands Academy of Sciences and Arts and the Chinese Ministry of Science and Technology as part of the Program Strategic Scientific Alliances (PSA)supported by ESRF
文摘Mixed Ga–Zn oxynitrides were synthesized using coprecipitation, wet-precipitation, and sol-id-solution methods. The oxynitrides were used as supports for Rh nanoparticle catalysts in photo-catalytic water splitting, CO oxidation, and H2 oxidation. Mixed Ga–Zn oxynitrides produced by wet precipitation and nitridation had good visible-light-absorption properties and high surface areas, so they were used to support uniformly sized poly(vinylpyrrolidone)-stabilized Rh nanoparticles. The nanoparticle size range was 2–9 nm. These catalysts had negligible activity in photocatalytic H2 production by water splitting with methanol as a sacrificial agent. Other mixed Ga–Zn oxynitrides were also inactive. A reference sample provided by Domen also showed very low activity. The in-fluence of particle size on Rh-catalyzed oxidation of CO and H2 was investigated. For CO oxidation, the activities of small particles were higher for particles with higher Rh oxidation degrees. The op-posite holds for H2 oxidation.
基金supported by the National Natural Science Foundation of China (No. 21003103)the Nature Scientific Research Foundation of Shaanxi Provincial Education Office of China (No. 2010JS061)Natural Science Foundation Program of Yan’an University (YD2011-19)
文摘A photocatalyst Cu-BiVO4 was synthesized by the hydrothermal method and was characterized by XRD, UV-vis DRS, and N2 adsorption-desorption measurement. The catalytic activity of the Cu-BiVO4 samples was studied on desulfurization of thiophene dissolved in n-octane, which was used as a model light oil, via photocatalytic oxidation reaction under illumination by visible light. The catalyst characterization results indicated that the loading of Cu on the catalyst did not change the crystal phase of BiVO4, and the crystallinity of the Cu-BiVO4 sample was found to be better at pH=7. The Cu-BiVO4 samples presented a significant bathochromic shift of the absorption band in the visible region, and the absorption intensity increased for the composite catalyst. The desulfurization experiments showed that the Cu-BiVO4 sample prepared at a pH value of 7 had a better catalytic activity. Under proper operating conditions, the desulfurization rate of the model compound achieved by Cu-BiVO4 sample prepared at pH=7 could reach as high as 90%.
文摘O644.1 97053496吩噻嗪在苯和环己烷中的光化学研究=Photochemicalreaction of dibenzothiazine in benzene andcyclohexane[刊,中]/王素华,陈德文,郭建新,王皓(中科院化学所分子动态与稳态结构国家重点实验室.北京(100080))//科学通报.—1996,41(23).—2159—2161 用ESR方法研究了吩噻嗪在氧化饱和的非极性溶剂苯、环己烷中的光化学行为,并从理论上作了相关计算,这对于探索氧在吩噻嗪的光物理化学过程中的作用有重要意义。图1表1参7(方舟)O644.1
