近日,我校化学化工学院青年教师李盼博士在环境/化工领域国际权威期刊Applied Catalysis B:Environmental(SCI一区,影响因子14.23)上发表题为"Unraveling the selectivity puzzle of H2 evolution over CO2 photoreduction using Z...近日,我校化学化工学院青年教师李盼博士在环境/化工领域国际权威期刊Applied Catalysis B:Environmental(SCI一区,影响因子14.23)上发表题为"Unraveling the selectivity puzzle of H2 evolution over CO2 photoreduction using ZnS nanocatalysts with phase junction"(DOI:10.1016/j.apcatb.2020.119115)的研究论文,原文链接为:https://www.sciencedirect.com/science/article/abs/pii/S0926337320305300.展开更多
In this paper,we report the synthesis and characterization of a wheel-shaped icosanuclear Cu-containing polyoxometalate(POM),K_(12)Li_(13)[Cu_(2)0Cl(OH)_(24)(H_(2)O)_(12)(P_(8)W_(48)O_(184))]·22H_(2)O(K_(12)Li_(1...In this paper,we report the synthesis and characterization of a wheel-shaped icosanuclear Cu-containing polyoxometalate(POM),K_(12)Li_(13)[Cu_(2)0Cl(OH)_(24)(H_(2)O)_(12)(P_(8)W_(48)O_(184))]·22H_(2)O(K_(12)Li_(13)-Cu_(2)0P_(8)W_(48)).The resulting cation-exchanged tetrabutylammonium salt of the polyoxoanion Cu_(2)0P_(8)W_(48)(TBA-Cu_(2)0P_(8)W_(48))exhibits high efficiency for visible-light-driven H_(2) production in the presence of an[Ir(ppy)2(dtbbpy)][PF_(6)]photosensitizer and a triethanolamine electron donor.Under optimal conditions,the turnover number for H_(2) production reaches~2892 after 5 h of photocatalysis and thereafter continuously increases to~13400 in a long-term 120 h reaction,representing the best performance among all reported transition-metal-substituted POM catalysts.Mechanistic studies confirm the existence of reductive and oxidative quenching processes,of which the reductive quenching pathway is dominant.Various stability tests demonstrate that the TBA-Cu_(2)0P_(8)W_(48) catalyst slowly dissociates Cu ions under turnover conditions;however,both the starting TBA-Cu_(2)0P_(8)W_(48) and its molecular decomposition products are dominant active species for efficient and long-term H_(2) production.展开更多
Benzofuran is an essential structural component found in a wide range of natural products,agrochemicals and drugs,possessing a range of biological activities.In recent years,there have been numerous reports of success...Benzofuran is an essential structural component found in a wide range of natural products,agrochemicals and drugs,possessing a range of biological activities.In recent years,there have been numerous reports of successful syntheses of benzofuran derivatives via intra-and inter-molecular cyclizations using diverse catalysts.This review gives an exhaustive and methodical survey of the procedures for making benzofurans.展开更多
文摘近日,我校化学化工学院青年教师李盼博士在环境/化工领域国际权威期刊Applied Catalysis B:Environmental(SCI一区,影响因子14.23)上发表题为"Unraveling the selectivity puzzle of H2 evolution over CO2 photoreduction using ZnS nanocatalysts with phase junction"(DOI:10.1016/j.apcatb.2020.119115)的研究论文,原文链接为:https://www.sciencedirect.com/science/article/abs/pii/S0926337320305300.
文摘In this paper,we report the synthesis and characterization of a wheel-shaped icosanuclear Cu-containing polyoxometalate(POM),K_(12)Li_(13)[Cu_(2)0Cl(OH)_(24)(H_(2)O)_(12)(P_(8)W_(48)O_(184))]·22H_(2)O(K_(12)Li_(13)-Cu_(2)0P_(8)W_(48)).The resulting cation-exchanged tetrabutylammonium salt of the polyoxoanion Cu_(2)0P_(8)W_(48)(TBA-Cu_(2)0P_(8)W_(48))exhibits high efficiency for visible-light-driven H_(2) production in the presence of an[Ir(ppy)2(dtbbpy)][PF_(6)]photosensitizer and a triethanolamine electron donor.Under optimal conditions,the turnover number for H_(2) production reaches~2892 after 5 h of photocatalysis and thereafter continuously increases to~13400 in a long-term 120 h reaction,representing the best performance among all reported transition-metal-substituted POM catalysts.Mechanistic studies confirm the existence of reductive and oxidative quenching processes,of which the reductive quenching pathway is dominant.Various stability tests demonstrate that the TBA-Cu_(2)0P_(8)W_(48) catalyst slowly dissociates Cu ions under turnover conditions;however,both the starting TBA-Cu_(2)0P_(8)W_(48) and its molecular decomposition products are dominant active species for efficient and long-term H_(2) production.
文摘Benzofuran is an essential structural component found in a wide range of natural products,agrochemicals and drugs,possessing a range of biological activities.In recent years,there have been numerous reports of successful syntheses of benzofuran derivatives via intra-and inter-molecular cyclizations using diverse catalysts.This review gives an exhaustive and methodical survey of the procedures for making benzofurans.
