光分解塑料垃圾袋

日本尤尼卡公司研制成功一种光分解塑料垃圾袋。在自然条件下，从常态变成粉末分解仅需3个月时间即可。

Fabrication of a monoclinic/hexagonal junction in WO_3 and its enhanced photocatalytic degradation of rhodamine B

A series of WO3 samples with different crystalline phases were prepared by the thermal decomposition method from ammonium tungstate hydrate.X-ray diffraction（XRD）,scanning electron microscopy（SEM）,high-resolution transmission electron microscopy（HRTEM）,X-ray photoelectron spectroscopy,and N2 adsorption-desorption were used to characterize the crystalline phase,morphology,particle size,chemical composition,and surface area of the WO3 samples.The formation of hexagonal（h-WO3） and monoclinic（m-WO3） crystal structures of WO3 at different temperatures or different times was confirmed by XRD.m-WO3 is formed at 600 ℃,while m-WO3 starts to transform into h-WO3 at 800℃.However,h-WO3,which forms at 800℃,may transform into m-WO3 by increasing the calcination temperature to 1000℃.SEM results indicate that m-WO3 particles exhibit a bulky shape with heavy aggregates,while h-WO3 particles exhibit a rod-like shape.Moreover,m-WO3 crystals are sporadically patched on the surface of the h-WO3 rod-like particles,resulting in the exposure of both m-WO3 and h-WO3 on the surface.It is observed that the monoclinic phase（m-WO3）/hexagonal phase（h-WO3） junction was fabricated by tuning the calcination temperature and calcination time.The relative ratios between m-WO3 and h-WO3 in the phase junction can readily be tailored by control of the calcination time.The photocatalytic activities of WO3 with different crystalline phases were evaluated by the photocatalytic degradation of rhodamine B as a model pollutant.A higher photocatalytic activity was observed in the WO3 sample with the m-WO3/h-WO3junction as compared with the sample with only m-WO3.The improvement of photocatalytic activity can be attributed to the reduction of the electron-hole recombination rate owing to the formation of the phase junction,whose presence has been confirmed by HRTEM and photoluminescence spectra.

工业有机废气污染治理技术及其进展探讨

阐述了近年来国内外在工业有机废气治理中常用技术和正在发展的新技术和最新研究,指出了当前有机废气治理技术存在的问题和发展方向。

Finding a Smooth Frame Decomposition of a Graph

Let G be a graph and A be a subset of the edges of G. A frame decomposition of G is a pair (G-A,A) such t ha t G-A is connected. A smooth frame decomposition of G is a frame decompo sition satisfying the two conditions: (1) Every leaf of G-A has a connected cotree and (2) The set of bridges of G-B(G-A) is A, where B(G-A) is the set of bridges of G-A. An efficient algorithm on finding a smooth frame decompositi on of a graph is provided.

2,3-二氨基萘的合成与应用

叙述了 2 ,3 -二氨基萘的合成方法和性质 ,介绍了其在分析硒和光变色化合物。

MoS_2-石墨烯的制备及其电催化析氢性能的研究

本文利用改进的Hummers方法合成层状的石墨烯,并用原位合成法在石墨烯上负载了颗粒状二硫化钼。通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X-射线光电子能谱分析仪(XPS)、粉末X-射线衍射仪(XRD)、比表面及孔隙度分析仪对所合成物质的形貌、结构、比表面积及孔径进行分析;使用电化学工作站测试催化剂的线性循环伏安和Tafel曲线来分析所合成催化剂的电化学析氢性能。结果表明在所有样品中石墨烯/二硫化钼-21.7复合物的电催化性能最好,其在电流密度为-10 mA·cm^(-2)时过电位为-193 mV。

Pharmacokinetics and Biodegradation of Chitosan in Rats

Chitosan, an excellent biomedical material, has received a widespread in vivo application. In contrast, its metabolism and distribution once being implanted were less documented. In this study, the pharmacokinetics and biodegradation of fluorescein isothiocyanate(FITC) labeled and muscle implantation administrated chitosan in rats were investigated with fluorescence spectrophotometry, histological assay and gel chromatography. After implantation, chitosan was degraded gradually during its distribution to diverse organs. Among the tested organs, liver and kidney were found to be the first two highest in chitosan content, which was followed by heart, brain and spleen. Urinary excretion was believed to be the major pathway of chitosan elimination, yet 80% of chitosan administered to rats was not trackable in their urine. This indicated that the majority of chitosan was degraded in tissues. In average, the molecular weight of the degradation products of chitosan in diverse organs and urine was found to be <65 k Da. This further confirmed the in vivo degradation of chitosan. Our findings provided new evidences for the intensive and safe application of chitosan as a biomedical material.

Linearity optimization of edge filter demodulators in FBG_s

A kind of electric circuit is improved to optimize the linearity of edge filter demodulators in FBG .By using a logarithm amplifier and an extraction operation, the linear range of optimized edge filter demodulators has been broadened effectively, and the requirement of optical filter＇s linear range has been reduced. Theoretical analyses and the simulation results indi-cated that the linear range of optimized edge fdter demodulator＇s covers the whole transition region of the edge filter, while a strict linearity of the optical filter is not necessary.

Pseudo-spectral Approximations for a Class of the Kdv-Burgers Type Equation

In this paper, the pseudo-spectral approximations for a class of the Kdv-Burgers type equation is presented. Convergence and stability of the approximation have been proved by Sobolev's inequalities and the bounded extensive method of the nonlinear function. Finally, the numerical examples are proposed.

Analysis of Infrared Divergence in OZI-Forbidden Decays of Orthoquarkonia

It is interesting to investigate the OZI-forbidden decays of orthoquarkoknium, J/ψ→γπ^0（γη,γη′）, J/ψ→π^＋π^-（π^0π^0）. At first glance, there is infrared divergence in the above processes. In this work, to clear the mist we use the factorization method with the light cone wavefunction of the final state light meson. We prove straightforwardly that the infrared divergence can be eliminated completely.

An Approach to Underwater Image Enhancement Based on Image Structural Decomposition

Underwater imaging posts a challenge due to the degradation by the absorption and scattering occurred during light propagation as well as poor lighting conditions in water medium Although image filtering techniques are utilized to improve image quality effectively, problems of the distortion of image details and the bias of color correction still exist in output images due to the complexity of image texture distribution. This paper proposes a new underwater image enhancement method based on image struc- tural decomposition. By introducing a curvature factor into the Mumford_Shah_G decomposition algorithm, image details and struc- ture components are better preserved without the gradient effect. Thus, histogram equalization and Retinex algorithms are applied in the decomposed structure component for global image enhancement and non-uniform brightness correction for gray level and the color images, then the optical absorption spectrum in water medium is incorporate to improve the color correction. Finally, the en- hauced structure and preserved detail component are re.composed to generate the output. Experiments with real underwater images verify the image improvement by the proposed method in image contrast, brightness and color fidelity.

Decomposition Method for Complex 3D Problems in Electron Optics

The decomposition method was successfully used in solving of 3D problems with complex geometry shape in electron optics for the FDM （Finite Difference Method） and FEM （Finite Element Method） mostly to implement fast and robust parallel algorithms and computer codes. We suggest a new version of similar approach for the BEM （Boundary Element Method） based on the alternating method by Schwartz. This approach substantially reduce the dimension of dense global matrix of algebraic system produced by BEM algorithm to solve a complex problem on as single CPU （Central Processor Unit） desktop computer. New algorithm is iterative one, but exponential convergence for the Schwatlz＇s algorithm creates the fast numerical procedures. We describe the results of numerical simulation for a multi electrode ion transport system. The algorithms were implemented in the computer code ＂POISSON-3＂.

A second order finite difference-spectral method for space fractional diffusion equations

A high order finite difference-spectral method is derived for solving space fractional diffusion equations,by combining the second order finite difference method in time and the spectral Galerkin method in space.The stability and error estimates of the temporal semidiscrete scheme are rigorously discussed,and the convergence order of the proposed method is proved to be O(τ2+Nα-m)in L2-norm,whereτ,N,αand m are the time step size,polynomial degree,fractional derivative index and regularity of the exact solution,respectively.Numerical experiments are carried out to demonstrate the theoretical analysis.

Improved water-splitting performances of CuW_(1-x)Mo_xO_4 photoanodes synthesized by spray pyrolysis

CuW（1-x）MoxO4 solid solution of CuWO4 and CuMoO4, which is a copper-based multi-component oxide semiconductor, possesses much narrower band gap than CuWO4. In theory, it can absorb a larger part of the visible spectrum, widening the use of solar spectroscopy and obtaining a higher photo-to-chemical conversion efficiency. In this study, CuW（1-x）MoxO4 thin-film photoanodes on conducting glass were prepared using a simple and low-cost spray pyrolysis method. The resulting CuW（1-x）MoxO4 photoanodes perform higher photocurrent than CuWO4 photoanodes under AM 1.5 G simulated sunlight illumination（100 m W cm^（-2））in 0.1 mol L^（-1） phosphate buffer at pH 7. Combined with IPCE and Mott-Schottky analysis, the enhancement of the photocurrent is due to the improvement of photon utilization and the increase of carrier concentration with the incorporation of Mo atoms. Moreover, with the optimal Mo/W atomic ratio,the photocurrent density increases obviously from 0.07 to 0.46 m A cm^（-2） at 1.23 V（RHE） bias. In addition, compared with particle-assembled thin-film photoanodes prepared by solidphase reaction and drop-necking treatment, the photoanodes prepared by spray pyrolysis have obvious advantages in terms of reducing resistance and facilitating charge transport.

Performance of CO-OFDM system with RS-Turbo concatenated code

In this paper,the RS-Turbo concatenated code is applied to coherent optical orthogonal frequency division multiplexing(CO-OFDM) system.RS(186,166,8) and Turbo code with code rate of 1/2 are employed for RS-Turbo concatenated code.Two decoding algorithms,which are Max-Log-MAP algorithm and Log-MAP algorithm,are adopted for Turbo decoding,and the iteration Berlekamp-Massey(BM) algorithm is adopted for RS decoding.The simulation results show that the bit error rate(BER) performance of CO-OFDM system with RS-Turbo concatenated code is significantly improved at high optical signal to noise ratio(OSNR),and the iteration number is reduced compared with that of the Turbo coded system.Furthermore,when the Max-Log-MAP algorithm is adopted for Turbo decoding,the transmission distance of CO-OFDM system with RS-Turbo concatenated code can reach about 400 km without error,while that of the Turbo coded system can only reach about 240 km when BER is lower than 10^(-4) order of magnitude.

Quantum dot-sensitized solar cells employing Pt/C_(60) counter electrode provide an efficiency exceeding 2%

A microporous platinum/fullerenes (Pt/C 60) counter electrode was prepared by using a facile rapid thermal decomposition method,and the quantum-dot sensitized solar cell (QDSSC) of Pt/C 60-TiO 2-CdS-ZnS and Pt/C 60-TiO 2-CdTe-ZnS was fabrication.The technique forms a good contact between QDs and TiO 2 films.The photovoltaic performances of the as-prepared cells were investigated.The QDSSCs with Pt/C 60 counter electrode show high power conversion efficiency of 1.90% and 2.06%,respectively (under irradiation of a simulated solar light with an intensity of 100 mW cm 2),which is comparable to the one fabricated using conventional Pt electrode.

Direct visualization of the charge transfer in conjugated polymers

Ion-induced charge-transfer states in conjugated polyelectrolytes were experimentally investigated by Justin M.Hodgkiss and his co-workers [J Am Chem Soc,2009,131(25):8913].In this work,charged and neutral conjugated polyelectrolytes were further studied with quantum chemistry methods.The calculation result shows that the absorption spectra are roughly in visible and ultraviolet light regions,and the two absorption peaks are located in the wavelength span 300-400 nm for charged polyelectrolytes.However,in neutral conjugated polyelectrolytes,the peaks of the absorption spectra showed a blue shift compared with those of the charged polyelectrolytes.Charge transfer (CT) properties of the studied compounds were also investigated with both the three-dimensional real-space analysis method of transition and charge difference densities,and the two-dimensional real-space analysis method of transition density matrices based on the simulated absorption spectra.The calculation results revealed the charge transfer in conjugated polyelectrolytes on the excitation states.