A new rare earth complex Tb（p-CIBA）3phen was synthesized and introduced into organic tight emitting devices （OLEDs） as emitting material. The Tb（p-CIBA）3phen was doped into PVK to improve the filmforming and hol...A new rare earth complex Tb（p-CIBA）3phen was synthesized and introduced into organic tight emitting devices （OLEDs） as emitting material. The Tb（p-CIBA）3phen was doped into PVK to improve the filmforming and hole-transporting property. Two kinds of devices were fabricated. The device structure is as the following. Single-layer device： ITO/PVK： Tb （p-CIBA） 3 phen /LiF/Al; double-layer device： ITO/PVK： Tb（p-CIBA）3phen/AIQ/LiF/AI. The performances of both devices were investigated carefully. We found that the emission of PVK was completely restrained,and only the green emission was observed from the electroluminescence. The full width at half maximum （FWHM） was less than 10 nm. The highest EL brighthess of the single-layer device is 25.4 cd/cm^2 at a fixed bias of 18 V,and the highest EL brightness of the double-layer device reaches 234.8 cd/cm^2 at a voltage of 20 V.展开更多
Multifunctional devices integrated with electrochromism and energy storage or energy production functions are attractive because these devices can be used as an effective approach to address the energy crisis and envi...Multifunctional devices integrated with electrochromism and energy storage or energy production functions are attractive because these devices can be used as an effective approach to address the energy crisis and environmental pollution in society today. In this review, we explain the operation principles of electrochromic energy storage devices including electrochromic supercapacitors,electrochromic batteries, and the photoelectrochromic devices. Furthermore, the material candidates and structure types of these multifunctional devices are discussed in detail. The major challenges of these devices along with a further outlook are highlighted at the end.展开更多
It is necessary to evaluate the interactions between the different functional layers in optoelectronic devices to optimize device performance.Recently,the I-rich allinorganic perovskite CsPbI2 Br has attracted tremend...It is necessary to evaluate the interactions between the different functional layers in optoelectronic devices to optimize device performance.Recently,the I-rich allinorganic perovskite CsPbI2 Br has attracted tremendous attention for use in solar cell applications because of its suitable band gap and favorable photo and thermal stabilities.It has been reported that the undesirable phase degradation of the photoactiveαphase CsPbI2 Br to the non-perovskiteδphase could be triggered by high humidity.To obtain stable devices,it is thus important to protect CsPbI2 Br from moisture.In this paper,CuI,a non-hygroscopic p-type hole-transporting material,is found to induce the phase degradation ofα-CsPbI2 Br to theδ-CsPbI2 Br.The rate and extent of phase degradation of CsPbI2 Br are closely associated with the heating temperature and coverage of a Cu I granular capping layer.This discovery is different from the widely reported water-induced phase degradation of CsPbI2 Br.Our work highlights the importance of careful selection of hole-transporting materials during the processing of I-rich all-inorganic CsPbX3(X=Br,I)perovskites to realize high-performance optoelectronic devices.展开更多
The polystyrene-based polymer blends, partially miscible poly(bisphenol A carbonate)/polystyrene (PC/PS) and completely miscible poly(2,6-dimethylphenylene oxide)/polystyrene (PPO/PS), in nanorods with gradient compos...The polystyrene-based polymer blends, partially miscible poly(bisphenol A carbonate)/polystyrene (PC/PS) and completely miscible poly(2,6-dimethylphenylene oxide)/polystyrene (PPO/PS), in nanorods with gradient composition distribution were discussed. The polymer blend nanorods were prepared by infiltrating the polymer blends into nanopores of anodic aluminum oxide (AAO) templates via capillary action. Their morphology was investigated by micro-Fourier transform infrared spectroscopy (micro-FTIR) and nano-thermal analysis (nano-TA) with spatial resolution. The composition gradient of polymer blends in the nanopores is governed by the difference of viscosity and miscibility between the two polymers in the blends and the pore diameter. The capillary wetting of porous AAO templates by polymer blends offers a unique method to fabricate functional nanostructured materials with gradient composition distribution for the potential application to nanodevices.展开更多
基金Supported by National Natural Science Foundation of China (90201004) Beijing Science and Technology Foundation ( H030430020410)Hebei provice Natural Science Foundation (203148) .
文摘A new rare earth complex Tb（p-CIBA）3phen was synthesized and introduced into organic tight emitting devices （OLEDs） as emitting material. The Tb（p-CIBA）3phen was doped into PVK to improve the filmforming and hole-transporting property. Two kinds of devices were fabricated. The device structure is as the following. Single-layer device： ITO/PVK： Tb （p-CIBA） 3 phen /LiF/Al; double-layer device： ITO/PVK： Tb（p-CIBA）3phen/AIQ/LiF/AI. The performances of both devices were investigated carefully. We found that the emission of PVK was completely restrained,and only the green emission was observed from the electroluminescence. The full width at half maximum （FWHM） was less than 10 nm. The highest EL brighthess of the single-layer device is 25.4 cd/cm^2 at a fixed bias of 18 V,and the highest EL brightness of the double-layer device reaches 234.8 cd/cm^2 at a voltage of 20 V.
基金the National Natural Science Foundation of China (51572058, 91216123, 51174063, 51502057)the Natural Science Foundation of Heilongjiang Province (E201436)+1 种基金the International Science & Technology Cooperation Program of China(2013DFR10630, 2015DFE52770)the Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP 20132302110031)
文摘Multifunctional devices integrated with electrochromism and energy storage or energy production functions are attractive because these devices can be used as an effective approach to address the energy crisis and environmental pollution in society today. In this review, we explain the operation principles of electrochromic energy storage devices including electrochromic supercapacitors,electrochromic batteries, and the photoelectrochromic devices. Furthermore, the material candidates and structure types of these multifunctional devices are discussed in detail. The major challenges of these devices along with a further outlook are highlighted at the end.
基金supported primarily by the National Key Research and Development Program of China(2018YFA0209303)the National Natural Science Foundation of China(U1663228,51902153,51972165 and 61377051)the Fundamental Research Funds for the Central Universities of China。
文摘It is necessary to evaluate the interactions between the different functional layers in optoelectronic devices to optimize device performance.Recently,the I-rich allinorganic perovskite CsPbI2 Br has attracted tremendous attention for use in solar cell applications because of its suitable band gap and favorable photo and thermal stabilities.It has been reported that the undesirable phase degradation of the photoactiveαphase CsPbI2 Br to the non-perovskiteδphase could be triggered by high humidity.To obtain stable devices,it is thus important to protect CsPbI2 Br from moisture.In this paper,CuI,a non-hygroscopic p-type hole-transporting material,is found to induce the phase degradation ofα-CsPbI2 Br to theδ-CsPbI2 Br.The rate and extent of phase degradation of CsPbI2 Br are closely associated with the heating temperature and coverage of a Cu I granular capping layer.This discovery is different from the widely reported water-induced phase degradation of CsPbI2 Br.Our work highlights the importance of careful selection of hole-transporting materials during the processing of I-rich all-inorganic CsPbX3(X=Br,I)perovskites to realize high-performance optoelectronic devices.
基金supported by a Grant-in-Aid for the Global COE Program "Science for Future Molecular Systems" from the Ministry of Education, Culture, Science, Sports and Technology of JapanZ.S. thanks the National Natural Science Foundation of China (50921062) for support
文摘The polystyrene-based polymer blends, partially miscible poly(bisphenol A carbonate)/polystyrene (PC/PS) and completely miscible poly(2,6-dimethylphenylene oxide)/polystyrene (PPO/PS), in nanorods with gradient composition distribution were discussed. The polymer blend nanorods were prepared by infiltrating the polymer blends into nanopores of anodic aluminum oxide (AAO) templates via capillary action. Their morphology was investigated by micro-Fourier transform infrared spectroscopy (micro-FTIR) and nano-thermal analysis (nano-TA) with spatial resolution. The composition gradient of polymer blends in the nanopores is governed by the difference of viscosity and miscibility between the two polymers in the blends and the pore diameter. The capillary wetting of porous AAO templates by polymer blends offers a unique method to fabricate functional nanostructured materials with gradient composition distribution for the potential application to nanodevices.
