The PD（X^3∑^-） interaction potential is constructed using the CCSD（T） theory and the basis set, augcc-pV5Z. Using this potential, the spectroscopic parameters are accurately determined. The present Do, De, Re, ω...The PD（X^3∑^-） interaction potential is constructed using the CCSD（T） theory and the basis set, augcc-pV5Z. Using this potential, the spectroscopic parameters are accurately determined. The present Do, De, Re, ωe, ωeχe, αe, and Be are of 3.056 99 eV, 3.161 75 eV, 0.142 39 nm, 1701.558 cm^-1, 23.6583 cm^-1, 0.085 99 cm^-1, and 4.3963 cm^-1, respectively, which almost perfectly conform with the measurements. A total of 26 vibrational states is predicted when J = 0 by solving the radial Sehrodinger equation of nuclear motion. The complete vibrational levels, classical turning points, initial rotation and centrifugal distortion constants when J = 0 are reported for the first time, which favorably agree with the experiments. The total and various partial-wave cross sections are calculated for the elastic impact between two ground-state P and D atoms at 1.0 × 10^-12 - 1.0 × 10^-4 a.u. when they approach each other along the PD（X^3∑^-） potential. No shape resonances exist in the total elastic cross sections, though the peaks can be found for each partial wave until l=6. The shape of the total elastic cross sections is dominated by the s partial wave at very low temperatures. Due to the weakness of the shape resonances of each partial wave, they are all passed into oblivion by the strong total elastic cross sections.展开更多
A new polymer composite thin film DMACB/PEK-c is reported. After poling of the film, the refractive indices n t and n n, that is the in-film-plane and the normal-to-film-plane refractive indices at 633 nm and the thic...A new polymer composite thin film DMACB/PEK-c is reported. After poling of the film, the refractive indices n t and n n, that is the in-film-plane and the normal-to-film-plane refractive indices at 633 nm and the thickness d were determined using the quasi-waveguide m -line method. The results of measurement and calculation are: n t=1.657 3±0.001 7, n n=1.627 8±0.001 9, and d =1.427 8±0.003 1 μm.展开更多
A coherent mid-infrared laser source,which can be tuned from 7.2 μm to 12.2 μm based on the type-Ⅰ phase-matched difference frequency generation(DFG) in an uncoated ZnGeP2(ZGP) crystal,is reported.The two pump wave...A coherent mid-infrared laser source,which can be tuned from 7.2 μm to 12.2 μm based on the type-Ⅰ phase-matched difference frequency generation(DFG) in an uncoated ZnGeP2(ZGP) crystal,is reported.The two pump waves are from a type-Ⅱ phase-matched dual-wavelength KTP optical parametric oscillator(OPO) of which the signal and idler waves are tuned during 1.85-1.96 μm(extraordinary wave) and 2.5-2.33 μm(ordinary wave),respectively.The maximum energy of the generated mid-infrared laser is 10 μJ at 9.22 μm,corresponding to the peak power of 2.2 kW.展开更多
基金Supported by the Program for Science & Technology Innovation Talents in Universities of Henan Province in China under GrantNo. 2008HASTIT008the National Natural Science Foundation of China under Grant Nos. 60777012 and 10874064
文摘The PD（X^3∑^-） interaction potential is constructed using the CCSD（T） theory and the basis set, augcc-pV5Z. Using this potential, the spectroscopic parameters are accurately determined. The present Do, De, Re, ωe, ωeχe, αe, and Be are of 3.056 99 eV, 3.161 75 eV, 0.142 39 nm, 1701.558 cm^-1, 23.6583 cm^-1, 0.085 99 cm^-1, and 4.3963 cm^-1, respectively, which almost perfectly conform with the measurements. A total of 26 vibrational states is predicted when J = 0 by solving the radial Sehrodinger equation of nuclear motion. The complete vibrational levels, classical turning points, initial rotation and centrifugal distortion constants when J = 0 are reported for the first time, which favorably agree with the experiments. The total and various partial-wave cross sections are calculated for the elastic impact between two ground-state P and D atoms at 1.0 × 10^-12 - 1.0 × 10^-4 a.u. when they approach each other along the PD（X^3∑^-） potential. No shape resonances exist in the total elastic cross sections, though the peaks can be found for each partial wave until l=6. The shape of the total elastic cross sections is dominated by the s partial wave at very low temperatures. Due to the weakness of the shape resonances of each partial wave, they are all passed into oblivion by the strong total elastic cross sections.
文摘A new polymer composite thin film DMACB/PEK-c is reported. After poling of the film, the refractive indices n t and n n, that is the in-film-plane and the normal-to-film-plane refractive indices at 633 nm and the thickness d were determined using the quasi-waveguide m -line method. The results of measurement and calculation are: n t=1.657 3±0.001 7, n n=1.627 8±0.001 9, and d =1.427 8±0.003 1 μm.
基金supported by the Major State Basic Research Development Program of China (No. 2007CB310403)the National Natural Science Foundation of China (No. 60801017)Research Fund for the Doctoral Program of Higher Education (No. 20070420118)
文摘A coherent mid-infrared laser source,which can be tuned from 7.2 μm to 12.2 μm based on the type-Ⅰ phase-matched difference frequency generation(DFG) in an uncoated ZnGeP2(ZGP) crystal,is reported.The two pump waves are from a type-Ⅱ phase-matched dual-wavelength KTP optical parametric oscillator(OPO) of which the signal and idler waves are tuned during 1.85-1.96 μm(extraordinary wave) and 2.5-2.33 μm(ordinary wave),respectively.The maximum energy of the generated mid-infrared laser is 10 μJ at 9.22 μm,corresponding to the peak power of 2.2 kW.
