叶绿素的检测和监测在植物生理、水质状况、农业管理和生态系统健康等方面具有重要意义。笔者设计了一种基于微波光子滤波器(MPF)射频强度的叶绿素检测系统,该系统利用叶绿素质量浓度变化导致光纤端面反射率发生变化的原理,根据射频强...叶绿素的检测和监测在植物生理、水质状况、农业管理和生态系统健康等方面具有重要意义。笔者设计了一种基于微波光子滤波器(MPF)射频强度的叶绿素检测系统,该系统利用叶绿素质量浓度变化导致光纤端面反射率发生变化的原理,根据射频强度与叶绿素质量浓度之间的关系,实现对叶绿素的检测。该系统具有体积小、抗干扰能力强的特点,而且可以实现长距离检测。在该系统中,宽谱光源、微波信号源、掺铒光纤放大器、电光调制器、隔离器、光耦合器、光电探测器、频谱仪、光纤等构成了迈克耳孙干涉仪结构的微波光子滤波器。提取不同蔬菜的叶绿素溶液,采用该系统对叶绿素溶液进行检测,验证了其在植物叶绿素检测方面的可行性。采用该系统检测了叶绿素实验原液以及由叶绿素标准溶液配制的不同质量浓度梯度的叶绿素溶液,验证了射频强度与叶绿素质量浓度之间存在较好的线性关系,其中最大射频强度与叶绿素质量浓度的线性拟合度(R2)达到了0.9741,灵敏度为0.007881 d B/(μg·L^(-1)),最小射频强度与叶绿素质量浓度的线性拟合度达到了0.9841,灵敏度为0.02258 d B/(μg·L^(-1))。上述实验结果表明该系统在高质量浓度叶绿素和低质量浓度叶绿素情况下均具有较好的传感性能。展开更多
The plasma resonance fiber optic sensor has a research values in theory and is widely used in engineering because of its simple structure and high sensitivity. It is a simple and sensitive method to measure the refrac...The plasma resonance fiber optic sensor has a research values in theory and is widely used in engineering because of its simple structure and high sensitivity. It is a simple and sensitive method to measure the refractive index with optical fiber plasma wave. We make use of this characteristic to manufacture the plasma resonance fiber optic sensor which can detect the cure of epoxy compo site. We study the method of testing the solutions which have different refractive index with plasma resonance fiber optic sensor. A fiber optic sensing probe which has reliable performance and convenient operation for detecting the refractive index has been designed. The system for detecting the solution refractive index is developed and used to measure the refractive index of epoxy during the different phases in the cure process. Result shows that this system is credible and stable, the parameters tested are in accord with the facts.展开更多
The solvents and substituents of two similar fluorescent sensors for cyanide, 7-diethylamino- 3-formylcoumarin （sensor a） and 7-diethylamino-3-（2-nitrovinyl）coumarin （sensor b）, are proposed to account for their...The solvents and substituents of two similar fluorescent sensors for cyanide, 7-diethylamino- 3-formylcoumarin （sensor a） and 7-diethylamino-3-（2-nitrovinyl）coumarin （sensor b）, are proposed to account for their distinct sensing mechanisms and experimental phenomena. The time-dependent density functional theory has been applied to investigate the ground states and the first singlet excited electronic states of the sensor as well as their possible Michael reaction products with cyanide, with a view to monitoring their geometries and photophysieal properties. The theoretical study indicates that the protic water solvent could lead to final Michael addition product of sensor a in the ground state, while the aprotic acetonitrile solvent could lead to carbanion as the final product of sensor b. Furthermore, the Michael reaction product of sensor a has been proved to have a torsion structure in its first singlet excited state. Correspondingly, sensor b also has a torsion structure around the nitrovinyl moiety in its first singlet excited state, while not in its carbanion structure. This could explain the observed strong fluorescence for sensor a and the quenching fluorescence for the sensor b upon the addition of the cyanide anions in the relevant sensing mechanisms.展开更多
One-dimensional alumina photonic crystals with defect modes were successfully fabricated through inserting a constant voltage waveform into the periodic voltage signals. The trans-mission spectra show that the thickne...One-dimensional alumina photonic crystals with defect modes were successfully fabricated through inserting a constant voltage waveform into the periodic voltage signals. The trans-mission spectra show that the thickness of defects plays a key role in determining the trans-mittance of defect modes. When the thickness was ？180 nm, an obvious defect mode with the high transmittance of 55% and a narrow full width at half maximum of 18 nm was observed in the original photonic band gaps. The defect mode shifted linearly with the increasing of refractive index of the analytes infiltrated into pores, indicating its potential application in chemical sensing or bio-sensing.展开更多
The special character of a PCF which is used as a gas or liquid sensor is discussed. The field distribution is analyzed when the solid core PCF is injected with different medium that has different relative dielectric ...The special character of a PCF which is used as a gas or liquid sensor is discussed. The field distribution is analyzed when the solid core PCF is injected with different medium that has different relative dielectric constant （or refractive index）. And the experiential formulas of the relation between refractive index of some kinds of liquid and their concentration are given, in order to measure the concentration of the relative liquid. At the same time, the effect of propagation constant on PCF sensor character is also discussed. Furthermore, the photonic medium relative dielectric constant, when it is injected with . band-gap （PBG） of PCF （PBG-PCF） is calculated at different different medium. That is the principle basis for this kind of PCF sensors.展开更多
Two novel rhodamine-based fluorescence enhanced molecular probes （RA1 and RA2） were synthesized, which were both designed as comparative fiuoroionophore and chromophore for the optical detection of Hg^2＋. The recog...Two novel rhodamine-based fluorescence enhanced molecular probes （RA1 and RA2） were synthesized, which were both designed as comparative fiuoroionophore and chromophore for the optical detection of Hg^2＋. The recognizing behaviors were investigated both experimentally and computationally. They exhibited high selectivity and sensitivity for Hg^2＋ over other commonly coexistent metal ions in CH3CN/H2O （1：1, V/V） solution. Test shows that hydroxy benzene of rich electron was beneficial to the chelate of Hg^2＋ with sensors. The detection limit was measured to be at least 0.14 p.mol/L. After addition of Hg^2＋, the color changed from colourless to pink, which was easily and hydrogel sensor. detected by the naked eye in both solution展开更多
By accurately measuring the displacement between the roller surface and the optical fiber probe relative to a null position, we can test the roller wear. The whole testing method and system were introduced. Each part ...By accurately measuring the displacement between the roller surface and the optical fiber probe relative to a null position, we can test the roller wear. The whole testing method and system were introduced. Each part of the testing system was illustrated. And also a novel fiber-optic sensor with three probes in equal transverse space is adopted. Using this sensor, the effects of fluctuations in the light source, reflectivity changing of target surface and the intensity losses in the fiber lines are automatically compensated. This method offers such advantages as non-contact, no electromagnetic interference, simplicity, low cost, high sensitivity, good accuracy and stability.展开更多
A novel technique of immobilizing indicator dyes by electrostatic adsorption and covalent bonding to fabricate optical sensors was developed.3-Amino-9-ethylcarbazole(AEC)was attached to the outmost surface of quartz g...A novel technique of immobilizing indicator dyes by electrostatic adsorption and covalent bonding to fabricate optical sensors was developed.3-Amino-9-ethylcarbazole(AEC)was attached to the outmost surface of quartz glass slide via aminosilanizing the slide,crosslinking chitosan,adsorbing Au nanoparticle,self-assembling HS(CH2)11OH,and coupling AEC.Thus, an AEC-immobilized optical sensor was obtained.The sensor exhibits a wide linear response range from 7.0×10- 7to 1.0×10 -4 mol/L and a correlation coefficient of 0.995 9 for the detection of 2-nitrophenol.The detection limit and response time of the sensor are 1.0×10- 7mol/L and less than 10 s,respectively.The fluorescence intensity of the used sensor can be restored to the blank value by simply rinsing with blank buffer.A very effective matrix for immobilizing indicator dye is provided by the proposed technique, which is adaptable to other indicator dyes with amino groups besides AEC.展开更多
The paper systematically describes the theoretical research on Cerenkov effect of REB in optical fibres. The analytical expressions for light generation ,collection efficiency ,electron incident angle .the Cerenkov ra...The paper systematically describes the theoretical research on Cerenkov effect of REB in optical fibres. The analytical expressions for light generation ,collection efficiency ,electron incident angle .the Cerenkov radiation sensitivity of the optical fibre to the current density of the REB stream.and the response of the sensitivity to both electron energy and electron incident angles are given. The typical sensor system for REB measurement is presented. The dynamic range and bandwidth are quantitatively analyzed. The calculation results are illustrated,展开更多
To obtain the influence rules of the coating parameters of a long-period fiber grating(LPFG)with respect to temperature,strain and refractive index sensing properties,based on the mode coupling theory,a strict four-la...To obtain the influence rules of the coating parameters of a long-period fiber grating(LPFG)with respect to temperature,strain and refractive index sensing properties,based on the mode coupling theory,a strict four-layer theorietical model of a metal film coated LPFG is established,and these parameters that affect the spectral characteristics of the metal film coated LPFG are studied.The simulation results show that there is an optimal metal film thickness on the surface of the LPFG that will induce the surface-plasmon resonance(SP R)effect,which results in higher sensitivity to the environmental temperature and refractive index but has little influence on the strain There is theoretical evidence that when the silver thickness is between0.8and1.2nm,the refractive index sensitivity will reach the peak point of42.4026,at which the refractive index sensor sensitivity is increased by4.S%.The theoretical results of coating a long-period fiber grating provide a good theoretical basis and guidance for LPFG design and parameters optimization展开更多
A laser-scanning calibre measuring and digital indicating grating photosensor gauging systems are introduced,which are used to measure the dimensions of bullet.In the paper,we expound the operation principle and desig...A laser-scanning calibre measuring and digital indicating grating photosensor gauging systems are introduced,which are used to measure the dimensions of bullet.In the paper,we expound the operation principle and design idea of the principal parts and units.展开更多
The main goal of this work is to explore the possibility of using Au-modified hydroxyapatite(HA) as a potential sensor material. Tube-like HA structure was fabricated with the aid of a Nafion N-117 cation exchange mem...The main goal of this work is to explore the possibility of using Au-modified hydroxyapatite(HA) as a potential sensor material. Tube-like HA structure was fabricated with the aid of a Nafion N-117 cation exchange membrane and gold(Au) nanoparticles were added by a hydrothermal method. The morphology, structure and composition were characterized by scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), and X-ray photoelectron spectroscopy(XPS). The gas sensing properties were also investigated. Results show that Au nanoparticles are dispersed into the HA powder, which is tube-like, with rough inner and outer surfaces. Compared with pure HA, Au-modified HA exhibits improved sensing properties for NH_3. 5%(mass fraction) Au-modified HA shows the highest response with relatively short response/recovery time. The response is up to 79.2% when the corresponding sensor is exposed to 200×10^(-6) NH_3 at room temperature, and the response time and recovery time are 20 s and 25 s, respectively. For lower concentration, like 50×10^(-6), the response is still up to 70.8%. Good selectivity and repeatability are also observed. The sensing mechanism of high response and selectivity for NH_3 gas was also discussed. These results suggest that Au-HA composite is a promising material for NH_3 sensors operating at room temperature.展开更多
文摘叶绿素的检测和监测在植物生理、水质状况、农业管理和生态系统健康等方面具有重要意义。笔者设计了一种基于微波光子滤波器(MPF)射频强度的叶绿素检测系统,该系统利用叶绿素质量浓度变化导致光纤端面反射率发生变化的原理,根据射频强度与叶绿素质量浓度之间的关系,实现对叶绿素的检测。该系统具有体积小、抗干扰能力强的特点,而且可以实现长距离检测。在该系统中,宽谱光源、微波信号源、掺铒光纤放大器、电光调制器、隔离器、光耦合器、光电探测器、频谱仪、光纤等构成了迈克耳孙干涉仪结构的微波光子滤波器。提取不同蔬菜的叶绿素溶液,采用该系统对叶绿素溶液进行检测,验证了其在植物叶绿素检测方面的可行性。采用该系统检测了叶绿素实验原液以及由叶绿素标准溶液配制的不同质量浓度梯度的叶绿素溶液,验证了射频强度与叶绿素质量浓度之间存在较好的线性关系,其中最大射频强度与叶绿素质量浓度的线性拟合度(R2)达到了0.9741,灵敏度为0.007881 d B/(μg·L^(-1)),最小射频强度与叶绿素质量浓度的线性拟合度达到了0.9841,灵敏度为0.02258 d B/(μg·L^(-1))。上述实验结果表明该系统在高质量浓度叶绿素和低质量浓度叶绿素情况下均具有较好的传感性能。
文摘The plasma resonance fiber optic sensor has a research values in theory and is widely used in engineering because of its simple structure and high sensitivity. It is a simple and sensitive method to measure the refractive index with optical fiber plasma wave. We make use of this characteristic to manufacture the plasma resonance fiber optic sensor which can detect the cure of epoxy compo site. We study the method of testing the solutions which have different refractive index with plasma resonance fiber optic sensor. A fiber optic sensing probe which has reliable performance and convenient operation for detecting the refractive index has been designed. The system for detecting the solution refractive index is developed and used to measure the refractive index of epoxy during the different phases in the cure process. Result shows that this system is credible and stable, the parameters tested are in accord with the facts.
基金This work was supported by the National Key Basic Research Special Foundation （No.2007CB815202 and No.2009CB220010） and the National Natural Science Foundation of China （No.20833008）.
文摘The solvents and substituents of two similar fluorescent sensors for cyanide, 7-diethylamino- 3-formylcoumarin （sensor a） and 7-diethylamino-3-（2-nitrovinyl）coumarin （sensor b）, are proposed to account for their distinct sensing mechanisms and experimental phenomena. The time-dependent density functional theory has been applied to investigate the ground states and the first singlet excited electronic states of the sensor as well as their possible Michael reaction products with cyanide, with a view to monitoring their geometries and photophysieal properties. The theoretical study indicates that the protic water solvent could lead to final Michael addition product of sensor a in the ground state, while the aprotic acetonitrile solvent could lead to carbanion as the final product of sensor b. Furthermore, the Michael reaction product of sensor a has been proved to have a torsion structure in its first singlet excited state. Correspondingly, sensor b also has a torsion structure around the nitrovinyl moiety in its first singlet excited state, while not in its carbanion structure. This could explain the observed strong fluorescence for sensor a and the quenching fluorescence for the sensor b upon the addition of the cyanide anions in the relevant sensing mechanisms.
基金ACKNOWLEDGMENTS This work was supported by the National Basic Research Program of China （No.2012CB932303）,the National Natural Science Foundation of China （No.11074254 and No.51171176）, Hundred Talent Program of Chinese Academy of Sciences, and the President Foundation of Hefei Institute of Physical Sciences.
文摘One-dimensional alumina photonic crystals with defect modes were successfully fabricated through inserting a constant voltage waveform into the periodic voltage signals. The trans-mission spectra show that the thickness of defects plays a key role in determining the trans-mittance of defect modes. When the thickness was ？180 nm, an obvious defect mode with the high transmittance of 55% and a narrow full width at half maximum of 18 nm was observed in the original photonic band gaps. The defect mode shifted linearly with the increasing of refractive index of the analytes infiltrated into pores, indicating its potential application in chemical sensing or bio-sensing.
文摘The special character of a PCF which is used as a gas or liquid sensor is discussed. The field distribution is analyzed when the solid core PCF is injected with different medium that has different relative dielectric constant （or refractive index）. And the experiential formulas of the relation between refractive index of some kinds of liquid and their concentration are given, in order to measure the concentration of the relative liquid. At the same time, the effect of propagation constant on PCF sensor character is also discussed. Furthermore, the photonic medium relative dielectric constant, when it is injected with . band-gap （PBG） of PCF （PBG-PCF） is calculated at different different medium. That is the principle basis for this kind of PCF sensors.
文摘Two novel rhodamine-based fluorescence enhanced molecular probes （RA1 and RA2） were synthesized, which were both designed as comparative fiuoroionophore and chromophore for the optical detection of Hg^2＋. The recognizing behaviors were investigated both experimentally and computationally. They exhibited high selectivity and sensitivity for Hg^2＋ over other commonly coexistent metal ions in CH3CN/H2O （1：1, V/V） solution. Test shows that hydroxy benzene of rich electron was beneficial to the chelate of Hg^2＋ with sensors. The detection limit was measured to be at least 0.14 p.mol/L. After addition of Hg^2＋, the color changed from colourless to pink, which was easily and hydrogel sensor. detected by the naked eye in both solution
文摘By accurately measuring the displacement between the roller surface and the optical fiber probe relative to a null position, we can test the roller wear. The whole testing method and system were introduced. Each part of the testing system was illustrated. And also a novel fiber-optic sensor with three probes in equal transverse space is adopted. Using this sensor, the effects of fluctuations in the light source, reflectivity changing of target surface and the intensity losses in the fiber lines are automatically compensated. This method offers such advantages as non-contact, no electromagnetic interference, simplicity, low cost, high sensitivity, good accuracy and stability.
基金Project(20775010)supported by the National Natural Science Foundation of ChinaProject(208095)supported by the Key Project ofMinistry of Education,China+1 种基金Project(07A006)supported by the Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(07JJ3020)supported by Hunan Provincial Natural Science Foundation of China
文摘A novel technique of immobilizing indicator dyes by electrostatic adsorption and covalent bonding to fabricate optical sensors was developed.3-Amino-9-ethylcarbazole(AEC)was attached to the outmost surface of quartz glass slide via aminosilanizing the slide,crosslinking chitosan,adsorbing Au nanoparticle,self-assembling HS(CH2)11OH,and coupling AEC.Thus, an AEC-immobilized optical sensor was obtained.The sensor exhibits a wide linear response range from 7.0×10- 7to 1.0×10 -4 mol/L and a correlation coefficient of 0.995 9 for the detection of 2-nitrophenol.The detection limit and response time of the sensor are 1.0×10- 7mol/L and less than 10 s,respectively.The fluorescence intensity of the used sensor can be restored to the blank value by simply rinsing with blank buffer.A very effective matrix for immobilizing indicator dye is provided by the proposed technique, which is adaptable to other indicator dyes with amino groups besides AEC.
文摘The paper systematically describes the theoretical research on Cerenkov effect of REB in optical fibres. The analytical expressions for light generation ,collection efficiency ,electron incident angle .the Cerenkov radiation sensitivity of the optical fibre to the current density of the REB stream.and the response of the sensitivity to both electron energy and electron incident angles are given. The typical sensor system for REB measurement is presented. The dynamic range and bandwidth are quantitatively analyzed. The calculation results are illustrated,
基金National Natural Science Foundation of China(No.51309001)Scientific Research Key Project of Anhui Province(No.KJ2017A041)
文摘To obtain the influence rules of the coating parameters of a long-period fiber grating(LPFG)with respect to temperature,strain and refractive index sensing properties,based on the mode coupling theory,a strict four-layer theorietical model of a metal film coated LPFG is established,and these parameters that affect the spectral characteristics of the metal film coated LPFG are studied.The simulation results show that there is an optimal metal film thickness on the surface of the LPFG that will induce the surface-plasmon resonance(SP R)effect,which results in higher sensitivity to the environmental temperature and refractive index but has little influence on the strain There is theoretical evidence that when the silver thickness is between0.8and1.2nm,the refractive index sensitivity will reach the peak point of42.4026,at which the refractive index sensor sensitivity is increased by4.S%.The theoretical results of coating a long-period fiber grating provide a good theoretical basis and guidance for LPFG design and parameters optimization
文摘A laser-scanning calibre measuring and digital indicating grating photosensor gauging systems are introduced,which are used to measure the dimensions of bullet.In the paper,we expound the operation principle and design idea of the principal parts and units.
基金Project(51272289) supported by the National Natural Science Foundation of China
文摘The main goal of this work is to explore the possibility of using Au-modified hydroxyapatite(HA) as a potential sensor material. Tube-like HA structure was fabricated with the aid of a Nafion N-117 cation exchange membrane and gold(Au) nanoparticles were added by a hydrothermal method. The morphology, structure and composition were characterized by scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), and X-ray photoelectron spectroscopy(XPS). The gas sensing properties were also investigated. Results show that Au nanoparticles are dispersed into the HA powder, which is tube-like, with rough inner and outer surfaces. Compared with pure HA, Au-modified HA exhibits improved sensing properties for NH_3. 5%(mass fraction) Au-modified HA shows the highest response with relatively short response/recovery time. The response is up to 79.2% when the corresponding sensor is exposed to 200×10^(-6) NH_3 at room temperature, and the response time and recovery time are 20 s and 25 s, respectively. For lower concentration, like 50×10^(-6), the response is still up to 70.8%. Good selectivity and repeatability are also observed. The sensing mechanism of high response and selectivity for NH_3 gas was also discussed. These results suggest that Au-HA composite is a promising material for NH_3 sensors operating at room temperature.
