Based on the commercially available avalanche photodiodes, the basic needs of gated-mode operation for single photon are discussed. Gated-mode technique based on the experimental data for detection of single photon is...Based on the commercially available avalanche photodiodes, the basic needs of gated-mode operation for single photon are discussed. Gated-mode technique based on the experimental data for detection of single photon is analyzed at communication wavelengths so that the basic operation parameters can decide properly for efficient detection of single photon. The bias voltage has related to the punch-through voltage in combining the cooling technique with synchronization to decrease the dark counts.展开更多
With the rapid development of the machining and manufacturing industry,welding has been widely used in forming connections of structural parts.At present,manual methods are often used for welding and quality inspectio...With the rapid development of the machining and manufacturing industry,welding has been widely used in forming connections of structural parts.At present,manual methods are often used for welding and quality inspection,with low efficiency and unstable product quality.Due to the requirements of visual inspection of weld feature size,a visual inspection system for weld feature size based on line structured light(LSL)is designed and built in this paper.An adaptive light stripe sub-pixel center extraction algorithm and a feature point extraction algorithm for welding light stripe are proposed.The experiment results show that the detection error of the weld width is 0.216 mm,the detection error of the remaining height is 0.035 mm,the single measurement costs 109 ms,and the inspection stability and repeatability of the system is 1%.Our approach can meet the online detection requirements of practical applications.展开更多
The optical noninvasive diagnostic of characteristic of silicon semiconductor devices by using a InGaAsP/InP semiconductor laser as an optical probe is reported. The principle of experimental method is based on the de...The optical noninvasive diagnostic of characteristic of silicon semiconductor devices by using a InGaAsP/InP semiconductor laser as an optical probe is reported. The principle of experimental method is based on the dependence of the optical refractive index on the carrier charge density in the active region of devices and detection of variation of refractive index by two laser beam interferometric techniques.展开更多
Objective: This study aimed to establish chemiluminescent immunoassay (CLIA) for quantitative determination of theophylline levels in human serum. Methods: To measure the concentration of theophylline (n=122) and eval...Objective: This study aimed to establish chemiluminescent immunoassay (CLIA) for quantitative determination of theophylline levels in human serum. Methods: To measure the concentration of theophylline (n=122) and evaluate the assay.Results: The linear range of the CLIA method was 0.51~40 mg/L (Y=1.02X+0.44, r=0.995). The intra and inter CV (coefficient variance) of CLIA were 3.20% and 3.57%, respectively. The average recovery rate was 102.3%. This method was free from interference by brilirubin (<200 μmol/L), hemoglobin (<10 g/L), and triglycerides (<15 mmol/L). Conclusion: This method is simple, convenient and precise for clinical pharmacokinetics study oftheophylline.展开更多
The ratio measurement by means of the sensing optical fiber and the reference fiber with different beginning positions, and the technique to improve the stability of the sensor are first described. Then the ability to...The ratio measurement by means of the sensing optical fiber and the reference fiber with different beginning positions, and the technique to improve the stability of the sensor are first described. Then the ability to restrain and compensate the interference of the same nature through the double channel ratio measurement is illustrated. Finally, the performance of sensor and its engineering design are discussed.展开更多
A method to determine Fe(Ⅲ) by thin layer resin phase spectrophotometry has been developed in this paper. The colored complex formed by Fe(Ⅲ) and 1,2-benzendiol is concentrated on the 717^# resin, then Fe(Ⅲ) ...A method to determine Fe(Ⅲ) by thin layer resin phase spectrophotometry has been developed in this paper. The colored complex formed by Fe(Ⅲ) and 1,2-benzendiol is concentrated on the 717^# resin, then Fe(Ⅲ) can be determined directly by making thin layer. The method is sensitive with a apparent molar absorption of 4.8×10^4L/mol.cm, which is 16 times higher than that of liquid phase spectrophotornetry, most coexisting ions do not influence the determination. The detection limit for Fe(Ⅲ) is 1.47μg/L with the precision of 3.3% [n=6, 7μg/50mL Fe(Ⅲ)]. The calibration curve is linear in the range of 0-25μg/50mL. The preposed method was applied to the determination of Fe(Ⅲ) in water sample with satisfactory results.展开更多
According to Maxwell’s theory, the optical transmission characteristics in GeSi/Si superlattice nanocrystalline layer have been analyzed and calculated. The calculated result shows that when the total thickness L is ...According to Maxwell’s theory, the optical transmission characteristics in GeSi/Si superlattice nanocrystalline layer have been analyzed and calculated. The calculated result shows that when the total thickness L is 340nm, the single mode lightwave can be transmitted only at periodic number M≥15.5. In addition, at the direction of transmission, when the transmission distance is larger than 500μm, the lightwave intensity is decreased greatly. Based on the above parameters, the design and manufacture of GeSi/Si superlattice nanocrystalline photodetector are carried out.展开更多
We propose two schemes for preparing four-photon cluster state through cross-Kerr nonlinearity. Two coherent fields interact when they enter a nonlinear Kerr medium. If the interaction time is chosen appropriately in ...We propose two schemes for preparing four-photon cluster state through cross-Kerr nonlinearity. Two coherent fields interact when they enter a nonlinear Kerr medium. If the interaction time is chosen appropriately in each Kerr medium, four-photon cluster state can be generated based on the results of two homodyne detectors in the first scheme. These schemes only use Kerr medium and homodyne measurements on coherent light fields, which can be effciently made in quantum optical laboratories. In addition, weak cross-Kerr nonlinearity is sufficient. All of the properties make these schemes feasible in experiments.展开更多
A design for a fisheye optical system is modified in order to enable IR vision in addition to the visible and UV lighting. The proposed modification goes to replace the optical material of the movable lens by another ...A design for a fisheye optical system is modified in order to enable IR vision in addition to the visible and UV lighting. The proposed modification goes to replace the optical material of the movable lens by another with less thermal dispersion. The choice of appropriate materials lead to a good focus appeared on the retina for a wide spectral range includes UV, visible, and near IR lighting. Then, the performance of the modified design is verified through some optical measures for imaging quality determinations. These optical measures are determined with the aid of Zemax software, which also used for testing performance of the modified fisheye optical system. The analysis mainly focuses on the energy distribution in the light spot on the focal surface. The results show that the modified design of the fisheye is acceptable.展开更多
It has been more than half a century since the release of the first Shimadzu UV-VIS (UV-visible) spectrophotometer QB-50 in 1952, and during this time more than 160,000 UV-VIS spectrometers have been produced and in...It has been more than half a century since the release of the first Shimadzu UV-VIS (UV-visible) spectrophotometer QB-50 in 1952, and during this time more than 160,000 UV-VIS spectrometers have been produced and installed in a wide variety of different applications. A lot of technical innovations have been implemented to improve the performance and significantly reduce the stray light levels. The latest innovation during development of sophisticated spectrophotometers is based on a new holographic exposure method and optimized etching process which has made it possible to produce both high-efficient and exceptionally low stray light gratings. These LO-RAY-LIGH~ gratings have guaranteed values of stray light at the intermediate position between zero-order and first-order lights. The values are measured by Shimadzu's laser stray-light-measuring system. The latest development in the series of UV-VIS spectrophotometers is the UV-2700 which is a true double beam double monochromator system in a compact design for high-precision spectral analysis of a wide range of samples including organic and inorganic compounds, biological samples, optical materials and photovoltaics. The high performance optical system is designed with "LO-RAY-LIGH" diffraction gratings, featuring highest efficiency and exceptionally low stray light. The spectrophotometer operates in the wavelength range from 185 nm to 900 nm and allows highly sophisticated applications such as direct measurement of high density samples up to 8 absorbance units without dilution.展开更多
In this letter, we propose a scheme of a special quantum optical Fredkin gate assisted by optical manip- ulations and postselection from the coincidence measurements, and then modify it with cross-Kerr nonlinearities ...In this letter, we propose a scheme of a special quantum optical Fredkin gate assisted by optical manip- ulations and postselection from the coincidence measurements, and then modify it with cross-Kerr nonlinearities to be suitable for the realization of all possible positive operator-valued measurements of bipartite polarization states. This scheme is feasible in the lab with the current experimental technology.展开更多
In the strapdown inertial navigation system, the Fiber Optical Gyro(FOG) must have high precision to give accurate navigation information. In this paper, a digital closed loop detection method based on the ramp wave m...In the strapdown inertial navigation system, the Fiber Optical Gyro(FOG) must have high precision to give accurate navigation information. In this paper, a digital closed loop detection method based on the ramp wave modulating technigue is introduced. DSP and FPGA have many advantages in digital signal proeessing. In the design, by using DSP, a complex arithmetic operation is completed to meet the needs of closed loop control of FOG within a short time. All kinds of control signals are produced easily by FPGA, under which DSP could work properly. Combining the DSP and FPGA,the detecting method is implemented successfully. In the end, the result of test and performance is given. From the result we can conclude that the precision of FOG is improved and the noises are limited to a low level.展开更多
Two methods for particulate pigments(i.e.,quantitative filter technique,QFT,and in vivo measurement,InVivo,respectively)and two methods for dissolved pigments(i.e.,Acetone Extracts,AceEx,and high-performance liquid ch...Two methods for particulate pigments(i.e.,quantitative filter technique,QFT,and in vivo measurement,InVivo,respectively)and two methods for dissolved pigments(i.e.,Acetone Extracts,AceEx,and high-performance liquid chromatography,HPLC,respectively) were used to obtain the optical absorption coefficient spectra for cultures of four typical algal species.Through normalization and analysis of the spectra,it is shown that(1) the four methods are able to measure optical absorption spectra of particulate and/or dissolved pigments;(2)that the optical absorption spectra of particulate and dissolved pigments were consistent in terms of the peak position in the blue wavelength,and the difference of the peak position in the near infrared wavelength was ~10nm between each other;and(3)that the leveling effect of the absorption spectra of particulate pigments was significant.These four methods can all effectively measure the absorption coefficients of phytoplankton pigments,while each one has its unique advantages in different applications.Therefore,appropriate method should be carefully selected for various application due to their intrinsic difference.展开更多
A novel thermal-assisted ultra-violet(UV) photocatalysis digestion method for the determination of total phosphorus(TP) in water samples was introduced in this work. The photocatalytic experiments for TP digestion wer...A novel thermal-assisted ultra-violet(UV) photocatalysis digestion method for the determination of total phosphorus(TP) in water samples was introduced in this work. The photocatalytic experiments for TP digestion were conducted using a 365 nm wavelength UV light and Ti O2 particles as the photocatalyst. Sodium tripolyphosphate and sodium glycerophosphate were used as the typical components of TP and the digested samples were then determined by spectrophotometry after phosphomolybdenum blue reaction. The effects of operational parameters such as reaction time and temperature were studied for the digestion of TP and the kinetic analysis of two typical components was performed in this paper. The pseudo-first-order rate constants k of two phosphorus compounds at different temperatures were obtained and the Arrhenius equation was employed to explain the effect of temperature on rate constant k. Compared with the conventional thermal digestion method for TP detection, it was found that the temperature was decreased from 120 °C to 60 °C with same conversion rate and time in this thermal-assisted UV digestion method, which enabled the digestion process work at normal pressure. Compared with the individual ultra-violet(UV) photocatalysis process, the digestion time was also decreased from several hours to half an hour using the thermal-assisted UV digestion method. This method will not lead to secondary pollution since no oxidant was needed in the thermal-assisted UV photocatalysis digestion process, which made it more compatible with electrochemical detection of TP.展开更多
The modulation phase shift method was used to measure chromatic dispersion in a standard single mode fiber for telecommunication. The modulation phase difference of the transmitted light at the wavelength of 1532.16 n...The modulation phase shift method was used to measure chromatic dispersion in a standard single mode fiber for telecommunication. The modulation phase difference of the transmitted light at the wavelength of 1532.16 nm modulated by a radio frequency signal was measured, relative to the transmitted light at the wavelength of 1549.33 nm modulated by the same signal. By introducing a reference light at the wavelength of 1310 nm, a 1310/1550 nm wavelength division multiplexing was used instead of the high cost dense wavelength division multiplexing. In the experiment, two testing lights were coupled with the reference light to the fiber spools of different lengths, respectively. By finite difference method, the chromatic dispersion between the two testing lights was measured, and the fixed errors generated during transmission were less than 0.5 ps/(nm·km).展开更多
In recent years, tighter regulation has been already enforced on harmful substances such as NOx, CO, and particles. Considering the above situation, it is important to monitor controlling factors of engine systems in ...In recent years, tighter regulation has been already enforced on harmful substances such as NOx, CO, and particles. Considering the above situation, it is important to monitor controlling factors of engine systems in order to improve efficiencies of their operations. As to car engines, an increasing concern in environmental issues such as air pollution, global warming and petroleum depletion has helped drive researches into various ways. Laser diagnostics has been applied to measure species concentration in the actual industrial fields. However there are several challenges to proceed in applying laser diagnostics to practical application. Especially stability of the measurement system is one of the most difficult issues. The purpose of this research is the development of a prompt measurement technique which can be applicable to various engine conditions. The Tunable Diode Laser Absorption Spectroscopy (TDLAS) using the hollow fiber has been developed to satisfy above requirements. By using a hollow fiber, misalignment of an optical axis and vulnerability of measurement environment such as vibration can be greatly reduced with sensitive and fast response features. It was demonstrated that this method can be applicable to measure gas compositions in engine exhaust with a range of millisecond response time. A sensitive method using tunable UV diode laser absorption spectroscopy was also discussed to detect NOx in exhausts.展开更多
Modern opticai theory has shown that the far field or Fraunbofer diffraction equipment is identical to the Fourier spectral analyzer. In the Fourier speetral analyzer the Fourier spectra or the Fraunhofer diffaction p...Modern opticai theory has shown that the far field or Fraunbofer diffraction equipment is identical to the Fourier spectral analyzer. In the Fourier speetral analyzer the Fourier spectra or the Fraunhofer diffaction pattern of a graph is formed on the back focal plane when a laser beam is directed on the graph lying on the front foeal plane ; the Fourier spectra of the graph is also subjected to change during the deformation of the graph. Through analyzing the change of Fourier spectra the deformation of the graph can be obtained. A few years ago,based on the above principles the authors proposed a new technique of strain measurement by laser spectral analysis. Demonstration and discussion will be made in detail in this paper.展开更多
An optical chemical sensor has been developed for the determination of iodine based on the reversible fluorescence quenching of 2, 2, 7, 7, 12, 12, 17, 17-octamethyl-21, 22, 23, 24-tetraoxaquaterene-Li (LiTOE) imm...An optical chemical sensor has been developed for the determination of iodine based on the reversible fluorescence quenching of 2, 2, 7, 7, 12, 12, 17, 17-octamethyl-21, 22, 23, 24-tetraoxaquaterene-Li (LiTOE) immobilized in a plasticized poly(vinyl chloride) (PVC) membrane. The optimum membrane of the sensor consists of 100 mg of PVC, 200 mg of bis (2-ethytbexyl) sebacate (BOS) and 3.0 mg of LiTOE. The maximum response of the optode membrane for iodine is obtained in Tris-HCl buffer solutlon (pH 8.0). With the optimum conditions described, the proposed sensor responds linearly in the measuring range of 3.90×10^-2 to 3.90×10^-4 mol/L, and has a detection limit of 6.0×10^-8 mol/L. The response time of the sensor is less than I rain. In addition to high reproducibility and reversibility of the fluorescence signal, the sensor also exhibits good selectivity. It is not interfered by some common anions and cations. It is applied for the determination of iodine in table salt samples. The results agree with those obtained by another method.展开更多
We present an optical scheme to almost completely teleport a bipartite entangled coherent state using afour-partite cluster-type entangled coherent state as quantum channel.The scheme is based on optical elements such...We present an optical scheme to almost completely teleport a bipartite entangled coherent state using afour-partite cluster-type entangled coherent state as quantum channel.The scheme is based on optical elements suchas beam splitters,phase shifters,and photon detectors.We also obtain the average fidelity of the teleportation process.It is shown that the average fidelity is quite close to unity if the mean photon number of the coherent state is not toosmall.展开更多
基金National"973"Project(G2001039302) Key S & T Project of Guangdong Province(2003A103405) Key S&T Project of Guangzhou City(1992-2-035-01)
文摘Based on the commercially available avalanche photodiodes, the basic needs of gated-mode operation for single photon are discussed. Gated-mode technique based on the experimental data for detection of single photon is analyzed at communication wavelengths so that the basic operation parameters can decide properly for efficient detection of single photon. The bias voltage has related to the punch-through voltage in combining the cooling technique with synchronization to decrease the dark counts.
基金supported by the National Natural Science Foundation of China(No. 51975293)the Aeronautical Science Foundation of China(No. 2019ZD052010)
文摘With the rapid development of the machining and manufacturing industry,welding has been widely used in forming connections of structural parts.At present,manual methods are often used for welding and quality inspection,with low efficiency and unstable product quality.Due to the requirements of visual inspection of weld feature size,a visual inspection system for weld feature size based on line structured light(LSL)is designed and built in this paper.An adaptive light stripe sub-pixel center extraction algorithm and a feature point extraction algorithm for welding light stripe are proposed.The experiment results show that the detection error of the weld width is 0.216 mm,the detection error of the remaining height is 0.035 mm,the single measurement costs 109 ms,and the inspection stability and repeatability of the system is 1%.Our approach can meet the online detection requirements of practical applications.
文摘The optical noninvasive diagnostic of characteristic of silicon semiconductor devices by using a InGaAsP/InP semiconductor laser as an optical probe is reported. The principle of experimental method is based on the dependence of the optical refractive index on the carrier charge density in the active region of devices and detection of variation of refractive index by two laser beam interferometric techniques.
文摘Objective: This study aimed to establish chemiluminescent immunoassay (CLIA) for quantitative determination of theophylline levels in human serum. Methods: To measure the concentration of theophylline (n=122) and evaluate the assay.Results: The linear range of the CLIA method was 0.51~40 mg/L (Y=1.02X+0.44, r=0.995). The intra and inter CV (coefficient variance) of CLIA were 3.20% and 3.57%, respectively. The average recovery rate was 102.3%. This method was free from interference by brilirubin (<200 μmol/L), hemoglobin (<10 g/L), and triglycerides (<15 mmol/L). Conclusion: This method is simple, convenient and precise for clinical pharmacokinetics study oftheophylline.
文摘The ratio measurement by means of the sensing optical fiber and the reference fiber with different beginning positions, and the technique to improve the stability of the sensor are first described. Then the ability to restrain and compensate the interference of the same nature through the double channel ratio measurement is illustrated. Finally, the performance of sensor and its engineering design are discussed.
基金Advanced Fund Item of Jiangsu University (07KJB610021)
文摘A method to determine Fe(Ⅲ) by thin layer resin phase spectrophotometry has been developed in this paper. The colored complex formed by Fe(Ⅲ) and 1,2-benzendiol is concentrated on the 717^# resin, then Fe(Ⅲ) can be determined directly by making thin layer. The method is sensitive with a apparent molar absorption of 4.8×10^4L/mol.cm, which is 16 times higher than that of liquid phase spectrophotornetry, most coexisting ions do not influence the determination. The detection limit for Fe(Ⅲ) is 1.47μg/L with the precision of 3.3% [n=6, 7μg/50mL Fe(Ⅲ)]. The calibration curve is linear in the range of 0-25μg/50mL. The preposed method was applied to the determination of Fe(Ⅲ) in water sample with satisfactory results.
文摘According to Maxwell’s theory, the optical transmission characteristics in GeSi/Si superlattice nanocrystalline layer have been analyzed and calculated. The calculated result shows that when the total thickness L is 340nm, the single mode lightwave can be transmitted only at periodic number M≥15.5. In addition, at the direction of transmission, when the transmission distance is larger than 500μm, the lightwave intensity is decreased greatly. Based on the above parameters, the design and manufacture of GeSi/Si superlattice nanocrystalline photodetector are carried out.
基金National Natural Science Foundation of China under Grant No.10574022the Natural Science Foundation of Fujian Province of China under Grant Nos.2007J0002 and 2007J0197the Foundation for Universities in Fujian Province under Grant No.2007F5041
文摘We propose two schemes for preparing four-photon cluster state through cross-Kerr nonlinearity. Two coherent fields interact when they enter a nonlinear Kerr medium. If the interaction time is chosen appropriately in each Kerr medium, four-photon cluster state can be generated based on the results of two homodyne detectors in the first scheme. These schemes only use Kerr medium and homodyne measurements on coherent light fields, which can be effciently made in quantum optical laboratories. In addition, weak cross-Kerr nonlinearity is sufficient. All of the properties make these schemes feasible in experiments.
文摘A design for a fisheye optical system is modified in order to enable IR vision in addition to the visible and UV lighting. The proposed modification goes to replace the optical material of the movable lens by another with less thermal dispersion. The choice of appropriate materials lead to a good focus appeared on the retina for a wide spectral range includes UV, visible, and near IR lighting. Then, the performance of the modified design is verified through some optical measures for imaging quality determinations. These optical measures are determined with the aid of Zemax software, which also used for testing performance of the modified fisheye optical system. The analysis mainly focuses on the energy distribution in the light spot on the focal surface. The results show that the modified design of the fisheye is acceptable.
文摘It has been more than half a century since the release of the first Shimadzu UV-VIS (UV-visible) spectrophotometer QB-50 in 1952, and during this time more than 160,000 UV-VIS spectrometers have been produced and installed in a wide variety of different applications. A lot of technical innovations have been implemented to improve the performance and significantly reduce the stray light levels. The latest innovation during development of sophisticated spectrophotometers is based on a new holographic exposure method and optimized etching process which has made it possible to produce both high-efficient and exceptionally low stray light gratings. These LO-RAY-LIGH~ gratings have guaranteed values of stray light at the intermediate position between zero-order and first-order lights. The values are measured by Shimadzu's laser stray-light-measuring system. The latest development in the series of UV-VIS spectrophotometers is the UV-2700 which is a true double beam double monochromator system in a compact design for high-precision spectral analysis of a wide range of samples including organic and inorganic compounds, biological samples, optical materials and photovoltaics. The high performance optical system is designed with "LO-RAY-LIGH" diffraction gratings, featuring highest efficiency and exceptionally low stray light. The spectrophotometer operates in the wavelength range from 185 nm to 900 nm and allows highly sophisticated applications such as direct measurement of high density samples up to 8 absorbance units without dilution.
基金supported by the Research Projects of Huaqiao University under Grant No.07BS406
文摘In this letter, we propose a scheme of a special quantum optical Fredkin gate assisted by optical manip- ulations and postselection from the coincidence measurements, and then modify it with cross-Kerr nonlinearities to be suitable for the realization of all possible positive operator-valued measurements of bipartite polarization states. This scheme is feasible in the lab with the current experimental technology.
文摘In the strapdown inertial navigation system, the Fiber Optical Gyro(FOG) must have high precision to give accurate navigation information. In this paper, a digital closed loop detection method based on the ramp wave modulating technigue is introduced. DSP and FPGA have many advantages in digital signal proeessing. In the design, by using DSP, a complex arithmetic operation is completed to meet the needs of closed loop control of FOG within a short time. All kinds of control signals are produced easily by FPGA, under which DSP could work properly. Combining the DSP and FPGA,the detecting method is implemented successfully. In the end, the result of test and performance is given. From the result we can conclude that the precision of FOG is improved and the noises are limited to a low level.
基金Supported by the National Natural Science Foundation of China(No.41276184)the Key Laboratory of Marine Remote Sensing and Acoustics(Nanjing University of Information Science and Technology),Jiangsu Province,China(No.KHYS1404)
文摘Two methods for particulate pigments(i.e.,quantitative filter technique,QFT,and in vivo measurement,InVivo,respectively)and two methods for dissolved pigments(i.e.,Acetone Extracts,AceEx,and high-performance liquid chromatography,HPLC,respectively) were used to obtain the optical absorption coefficient spectra for cultures of four typical algal species.Through normalization and analysis of the spectra,it is shown that(1) the four methods are able to measure optical absorption spectra of particulate and/or dissolved pigments;(2)that the optical absorption spectra of particulate and dissolved pigments were consistent in terms of the peak position in the blue wavelength,and the difference of the peak position in the near infrared wavelength was ~10nm between each other;and(3)that the leveling effect of the absorption spectra of particulate pigments was significant.These four methods can all effectively measure the absorption coefficients of phytoplankton pigments,while each one has its unique advantages in different applications.Therefore,appropriate method should be carefully selected for various application due to their intrinsic difference.
基金Supported by the National Natural Science Foundation(61372053)the National High Technology Research and Development Program(2012AA040506)
文摘A novel thermal-assisted ultra-violet(UV) photocatalysis digestion method for the determination of total phosphorus(TP) in water samples was introduced in this work. The photocatalytic experiments for TP digestion were conducted using a 365 nm wavelength UV light and Ti O2 particles as the photocatalyst. Sodium tripolyphosphate and sodium glycerophosphate were used as the typical components of TP and the digested samples were then determined by spectrophotometry after phosphomolybdenum blue reaction. The effects of operational parameters such as reaction time and temperature were studied for the digestion of TP and the kinetic analysis of two typical components was performed in this paper. The pseudo-first-order rate constants k of two phosphorus compounds at different temperatures were obtained and the Arrhenius equation was employed to explain the effect of temperature on rate constant k. Compared with the conventional thermal digestion method for TP detection, it was found that the temperature was decreased from 120 °C to 60 °C with same conversion rate and time in this thermal-assisted UV digestion method, which enabled the digestion process work at normal pressure. Compared with the individual ultra-violet(UV) photocatalysis process, the digestion time was also decreased from several hours to half an hour using the thermal-assisted UV digestion method. This method will not lead to secondary pollution since no oxidant was needed in the thermal-assisted UV photocatalysis digestion process, which made it more compatible with electrochemical detection of TP.
基金Doctoral Foundation of Education Ministry of China(No 20040056008) National Natural Science Foundation ofChina (No 50539060)
文摘The modulation phase shift method was used to measure chromatic dispersion in a standard single mode fiber for telecommunication. The modulation phase difference of the transmitted light at the wavelength of 1532.16 nm modulated by a radio frequency signal was measured, relative to the transmitted light at the wavelength of 1549.33 nm modulated by the same signal. By introducing a reference light at the wavelength of 1310 nm, a 1310/1550 nm wavelength division multiplexing was used instead of the high cost dense wavelength division multiplexing. In the experiment, two testing lights were coupled with the reference light to the fiber spools of different lengths, respectively. By finite difference method, the chromatic dispersion between the two testing lights was measured, and the fixed errors generated during transmission were less than 0.5 ps/(nm·km).
文摘In recent years, tighter regulation has been already enforced on harmful substances such as NOx, CO, and particles. Considering the above situation, it is important to monitor controlling factors of engine systems in order to improve efficiencies of their operations. As to car engines, an increasing concern in environmental issues such as air pollution, global warming and petroleum depletion has helped drive researches into various ways. Laser diagnostics has been applied to measure species concentration in the actual industrial fields. However there are several challenges to proceed in applying laser diagnostics to practical application. Especially stability of the measurement system is one of the most difficult issues. The purpose of this research is the development of a prompt measurement technique which can be applicable to various engine conditions. The Tunable Diode Laser Absorption Spectroscopy (TDLAS) using the hollow fiber has been developed to satisfy above requirements. By using a hollow fiber, misalignment of an optical axis and vulnerability of measurement environment such as vibration can be greatly reduced with sensitive and fast response features. It was demonstrated that this method can be applicable to measure gas compositions in engine exhaust with a range of millisecond response time. A sensitive method using tunable UV diode laser absorption spectroscopy was also discussed to detect NOx in exhausts.
文摘Modern opticai theory has shown that the far field or Fraunbofer diffraction equipment is identical to the Fourier spectral analyzer. In the Fourier speetral analyzer the Fourier spectra or the Fraunhofer diffaction pattern of a graph is formed on the back focal plane when a laser beam is directed on the graph lying on the front foeal plane ; the Fourier spectra of the graph is also subjected to change during the deformation of the graph. Through analyzing the change of Fourier spectra the deformation of the graph can be obtained. A few years ago,based on the above principles the authors proposed a new technique of strain measurement by laser spectral analysis. Demonstration and discussion will be made in detail in this paper.
文摘An optical chemical sensor has been developed for the determination of iodine based on the reversible fluorescence quenching of 2, 2, 7, 7, 12, 12, 17, 17-octamethyl-21, 22, 23, 24-tetraoxaquaterene-Li (LiTOE) immobilized in a plasticized poly(vinyl chloride) (PVC) membrane. The optimum membrane of the sensor consists of 100 mg of PVC, 200 mg of bis (2-ethytbexyl) sebacate (BOS) and 3.0 mg of LiTOE. The maximum response of the optode membrane for iodine is obtained in Tris-HCl buffer solutlon (pH 8.0). With the optimum conditions described, the proposed sensor responds linearly in the measuring range of 3.90×10^-2 to 3.90×10^-4 mol/L, and has a detection limit of 6.0×10^-8 mol/L. The response time of the sensor is less than I rain. In addition to high reproducibility and reversibility of the fluorescence signal, the sensor also exhibits good selectivity. It is not interfered by some common anions and cations. It is applied for the determination of iodine in table salt samples. The results agree with those obtained by another method.
基金Supported by the National Natural Science Foundation of China under Grant No.60708003the National Key Basic Research Program of China under Grant No.2006CB921604the Basic Key Program of Shanghai Municipality under Grant No.07JC14017
文摘We present an optical scheme to almost completely teleport a bipartite entangled coherent state using afour-partite cluster-type entangled coherent state as quantum channel.The scheme is based on optical elements suchas beam splitters,phase shifters,and photon detectors.We also obtain the average fidelity of the teleportation process.It is shown that the average fidelity is quite close to unity if the mean photon number of the coherent state is not toosmall.