We introduce a new model of one-dimensional （1D） photonic crystal composed of alternately arranged RHM and LHM layers with positive and negative refractive indices respectively, for which the transmission spectra of...We introduce a new model of one-dimensional （1D） photonic crystal composed of alternately arranged RHM and LHM layers with positive and negative refractive indices respectively, for which the transmission spectra of the model are calculated numerically with the transfer matrix method, and the bandgap structure and the polarization properties are analyzed. We found that the introduction of negative refractive index layers （i.e. LHM medium layers） gives rise to some peculiar band-gap structure and polarization properties as follows. Firstly, the forbidden bands are extremely wide and the transmission bands are very sharp without oscillation;and secondly, the change of incident angle has different influences on the forbidden bands of TE and TM modes. For the TM mode, the forbidden band width decreases substantially and finally vanishes, and for the TE mode with central wavelength, the total reflection happens at anv incident anale.展开更多
A new type of highly nonlinear photonic bandgap fiber with modified honeycomb lattice is brought forward. Based on full-vector plane-wave method, the structure of bandgaps and the distributions of fundamental mode fie...A new type of highly nonlinear photonic bandgap fiber with modified honeycomb lattice is brought forward. Based on full-vector plane-wave method, the structure of bandgaps and the distributions of fundamental mode field are analyzed. Then its nonlinear coefficient is calculated, and the effect of each structural pa- rameter on the nonlinear coefficient is discussed. At last, considering many factors synthetically, we make some optimization design of the structural parameters. It can be concluded that this new type of photonic bandgap fiber can gain the nonlinear coefficient of 30 W^-1 km^-1.展开更多
A new method based on UV photosensitivity is proposed to fabricate big scale two dimensional photonic crystal.The optical transmission properties of designed periodic structure are investigated by numerical analysis.T...A new method based on UV photosensitivity is proposed to fabricate big scale two dimensional photonic crystal.The optical transmission properties of designed periodic structure are investigated by numerical analysis.The results show that the 2D photonic crystal fabricated by the new method has a desirable photonic bandgap of TE mode.展开更多
Based on the density functional theory （DFT）, the electronic structures and optical properties of Mg2Pb are calculated by using the local density approximation （LDA） and plane wave pseudo-potential method. The cal...Based on the density functional theory （DFT）, the electronic structures and optical properties of Mg2Pb are calculated by using the local density approximation （LDA） and plane wave pseudo-potential method. The calculation results show that the indirect band gap width of Mg2Pb is 0.02796 eV. The optical properties of MgzPb have isotropic characteristics, the static dielectric function of Mg2Pb is ε1（0） = 10.33 and the refractive index is n0 = 3.5075. The maximum absorption coefficient is 4.8060×10^5 cm-1. The absorption in the photon energy range of 25-40 eV approaches to zero, shows the optical colorless and transparent behaviors.展开更多
Two new conjugated copolymers, PBDT-T6-TTF and PBDT-T12-TTF, were derived from a novel 4-fluorobenzoyl thienothi- ophene （TTF）. In addition, two types of benzodithiophene （BDT） units with 2,3-dihexylthienyl （T6）...Two new conjugated copolymers, PBDT-T6-TTF and PBDT-T12-TTF, were derived from a novel 4-fluorobenzoyl thienothi- ophene （TTF）. In addition, two types of benzodithiophene （BDT） units with 2,3-dihexylthienyl （T6） and 2,3-didodecylthienyl （T12） substituents, respectively, were successfully synthesized. The effect of the dual two-dimensional （2D） substitutions of the building blocks upon the optoelectronic properties of the polymers was investigated. Generally, the two polymers exhibited good solubility and broad absorption, showing similar optical band gaps of ~1.53 eV. However, PBDT-T6-TTF with its shorter alkyl chain length possessed a larger extinction coefficient in thin solid film. The highest occupied molecular orbital （HOMO） level of PBDT-T6-TTF was located at -5.38 eV while that of PBDT-T12-TTF was at -5.51 eV. In space charge-limited- current （SCLC） measurement, PBDT-T6-TTF and PBDT-T12-TTF displayed respective hole mobilities of 3.0~10-~ and 1.6x10 5 cm2 V-1 s-l. In polymer solar cells, PBDT-T6-TTF and PBDT-T12-TTF showed respective power conversion efficiencies （PCEs） of 2.86% and 1.67%. When 1,8-diiodooctane （DIO） was used as the solvent additive, the PCE of PBDT-T6-TTF was remarkably elevated to 4.85%, but the use of DIO for the PBDT-T12-TTF-blend film resulted in a lower PCE of 0.91%. Atomic force microscopy （AFM） indicated that the superior efficiency of PBDT-T6-TTF with 3% DIO （v/v） should be related to the better continuous phase separation of the blend film. Nevertheless, the morphology of the PBDT-T12-TTF deteriorated when the 3% DIO （v/v） was added. Our results suggest that the alkyl-chain length on the 2D BDT units play an important role in determining the optoelectronic properties of dual 2D BDT-TT-based polymers.展开更多
文摘We introduce a new model of one-dimensional （1D） photonic crystal composed of alternately arranged RHM and LHM layers with positive and negative refractive indices respectively, for which the transmission spectra of the model are calculated numerically with the transfer matrix method, and the bandgap structure and the polarization properties are analyzed. We found that the introduction of negative refractive index layers （i.e. LHM medium layers） gives rise to some peculiar band-gap structure and polarization properties as follows. Firstly, the forbidden bands are extremely wide and the transmission bands are very sharp without oscillation;and secondly, the change of incident angle has different influences on the forbidden bands of TE and TM modes. For the TM mode, the forbidden band width decreases substantially and finally vanishes, and for the TE mode with central wavelength, the total reflection happens at anv incident anale.
基金Supported by the National 863 Project of China (2004AA31G200) .
文摘A new type of highly nonlinear photonic bandgap fiber with modified honeycomb lattice is brought forward. Based on full-vector plane-wave method, the structure of bandgaps and the distributions of fundamental mode field are analyzed. Then its nonlinear coefficient is calculated, and the effect of each structural pa- rameter on the nonlinear coefficient is discussed. At last, considering many factors synthetically, we make some optimization design of the structural parameters. It can be concluded that this new type of photonic bandgap fiber can gain the nonlinear coefficient of 30 W^-1 km^-1.
文摘A new method based on UV photosensitivity is proposed to fabricate big scale two dimensional photonic crystal.The optical transmission properties of designed periodic structure are investigated by numerical analysis.The results show that the 2D photonic crystal fabricated by the new method has a desirable photonic bandgap of TE mode.
基金supported by the National Natural Science Foundation of China(Grant No.51201079)the Scientific Research Foundation for Introduced Talents of KMUST(Grant No.KKSY201251033)the Scientific Research Fund of Department of Education of Yunnan Province(Grant No.2012Z099)
文摘Based on the density functional theory （DFT）, the electronic structures and optical properties of Mg2Pb are calculated by using the local density approximation （LDA） and plane wave pseudo-potential method. The calculation results show that the indirect band gap width of Mg2Pb is 0.02796 eV. The optical properties of MgzPb have isotropic characteristics, the static dielectric function of Mg2Pb is ε1（0） = 10.33 and the refractive index is n0 = 3.5075. The maximum absorption coefficient is 4.8060×10^5 cm-1. The absorption in the photon energy range of 25-40 eV approaches to zero, shows the optical colorless and transparent behaviors.
基金financially supported by the National Natural Science Foundation of China(21225418 and 51173048)the National Basic Research Program of China(2013CB834705 and 2014CB643505)GDUPS(2013)
文摘Two new conjugated copolymers, PBDT-T6-TTF and PBDT-T12-TTF, were derived from a novel 4-fluorobenzoyl thienothi- ophene （TTF）. In addition, two types of benzodithiophene （BDT） units with 2,3-dihexylthienyl （T6） and 2,3-didodecylthienyl （T12） substituents, respectively, were successfully synthesized. The effect of the dual two-dimensional （2D） substitutions of the building blocks upon the optoelectronic properties of the polymers was investigated. Generally, the two polymers exhibited good solubility and broad absorption, showing similar optical band gaps of ~1.53 eV. However, PBDT-T6-TTF with its shorter alkyl chain length possessed a larger extinction coefficient in thin solid film. The highest occupied molecular orbital （HOMO） level of PBDT-T6-TTF was located at -5.38 eV while that of PBDT-T12-TTF was at -5.51 eV. In space charge-limited- current （SCLC） measurement, PBDT-T6-TTF and PBDT-T12-TTF displayed respective hole mobilities of 3.0~10-~ and 1.6x10 5 cm2 V-1 s-l. In polymer solar cells, PBDT-T6-TTF and PBDT-T12-TTF showed respective power conversion efficiencies （PCEs） of 2.86% and 1.67%. When 1,8-diiodooctane （DIO） was used as the solvent additive, the PCE of PBDT-T6-TTF was remarkably elevated to 4.85%, but the use of DIO for the PBDT-T12-TTF-blend film resulted in a lower PCE of 0.91%. Atomic force microscopy （AFM） indicated that the superior efficiency of PBDT-T6-TTF with 3% DIO （v/v） should be related to the better continuous phase separation of the blend film. Nevertheless, the morphology of the PBDT-T12-TTF deteriorated when the 3% DIO （v/v） was added. Our results suggest that the alkyl-chain length on the 2D BDT units play an important role in determining the optoelectronic properties of dual 2D BDT-TT-based polymers.
